CN109126443A - A kind of preparation method of automobile-used formaldehyde quick removal agent - Google Patents
A kind of preparation method of automobile-used formaldehyde quick removal agent Download PDFInfo
- Publication number
- CN109126443A CN109126443A CN201810902908.XA CN201810902908A CN109126443A CN 109126443 A CN109126443 A CN 109126443A CN 201810902908 A CN201810902908 A CN 201810902908A CN 109126443 A CN109126443 A CN 109126443A
- Authority
- CN
- China
- Prior art keywords
- automobile
- removal agent
- preparation
- quick removal
- molybdenum
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 title claims abstract description 127
- 239000003795 chemical substances by application Substances 0.000 title claims abstract description 26
- 238000002360 preparation method Methods 0.000 title claims abstract description 21
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims abstract description 21
- 229910052750 molybdenum Inorganic materials 0.000 claims abstract description 21
- 239000011733 molybdenum Substances 0.000 claims abstract description 21
- 229910052792 caesium Inorganic materials 0.000 claims abstract description 20
- TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 claims abstract description 20
- HORQAOAYAYGIBM-UHFFFAOYSA-N 2,4-dinitrophenylhydrazine Chemical compound NNC1=CC=C([N+]([O-])=O)C=C1[N+]([O-])=O HORQAOAYAYGIBM-UHFFFAOYSA-N 0.000 claims abstract description 14
- 230000000694 effects Effects 0.000 claims abstract description 12
- 239000000341 volatile oil Substances 0.000 claims description 33
- 241000196324 Embryophyta Species 0.000 claims description 25
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 21
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 15
- 239000002904 solvent Substances 0.000 claims description 15
- -1 polyoxyethylene Polymers 0.000 claims description 12
- 239000008367 deionised water Substances 0.000 claims description 10
- 229910021641 deionized water Inorganic materials 0.000 claims description 10
- QXYJCZRRLLQGCR-UHFFFAOYSA-N dioxomolybdenum Chemical compound O=[Mo]=O QXYJCZRRLLQGCR-UHFFFAOYSA-N 0.000 claims description 10
- 239000011812 mixed powder Substances 0.000 claims description 10
- 238000002156 mixing Methods 0.000 claims description 10
- 210000002966 serum Anatomy 0.000 claims description 10
- 238000003756 stirring Methods 0.000 claims description 10
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 6
- SLAMLWHELXOEJZ-UHFFFAOYSA-N 2-nitrobenzoic acid Chemical compound OC(=O)C1=CC=CC=C1[N+]([O-])=O SLAMLWHELXOEJZ-UHFFFAOYSA-N 0.000 claims description 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 5
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 5
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 5
- 229920001213 Polysorbate 20 Polymers 0.000 claims description 5
- 230000032683 aging Effects 0.000 claims description 5
- 238000000498 ball milling Methods 0.000 claims description 5
- AIYUHDOJVYHVIT-UHFFFAOYSA-M caesium chloride Chemical compound [Cl-].[Cs+] AIYUHDOJVYHVIT-UHFFFAOYSA-M 0.000 claims description 5
- 229960000935 dehydrated alcohol Drugs 0.000 claims description 5
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 5
- 238000004090 dissolution Methods 0.000 claims description 5
- 239000000194 fatty acid Substances 0.000 claims description 5
- 229930195729 fatty acid Natural products 0.000 claims description 5
- 239000012065 filter cake Substances 0.000 claims description 5
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 5
- 239000000256 polyoxyethylene sorbitan monolaurate Substances 0.000 claims description 5
- 235000010486 polyoxyethylene sorbitan monolaurate Nutrition 0.000 claims description 5
- 229940068977 polysorbate 20 Drugs 0.000 claims description 5
- 239000002002 slurry Substances 0.000 claims description 5
- 229910052708 sodium Inorganic materials 0.000 claims description 5
- 239000011734 sodium Substances 0.000 claims description 5
- 244000178870 Lavandula angustifolia Species 0.000 claims description 4
- 235000010663 Lavandula angustifolia Nutrition 0.000 claims description 4
- 235000011449 Rosa Nutrition 0.000 claims description 4
- 239000001102 lavandula vera Substances 0.000 claims description 4
- 235000018219 lavender Nutrition 0.000 claims description 4
- 235000009024 Ceanothus sanguineus Nutrition 0.000 claims description 3
- 235000005979 Citrus limon Nutrition 0.000 claims description 3
- 244000131522 Citrus pyriformis Species 0.000 claims description 3
- 235000005976 Citrus sinensis Nutrition 0.000 claims description 3
- 240000002319 Citrus sinensis Species 0.000 claims description 3
- 240000003553 Leptospermum scoparium Species 0.000 claims description 3
- 235000015459 Lycium barbarum Nutrition 0.000 claims description 3
- 240000000513 Santalum album Species 0.000 claims description 3
- 235000008632 Santalum album Nutrition 0.000 claims description 3
- 239000010656 jasmine oil Substances 0.000 claims description 3
- 239000003921 oil Substances 0.000 claims description 3
- 235000019198 oils Nutrition 0.000 claims description 3
- 239000010502 orange oil Substances 0.000 claims description 3
- 235000004347 Perilla Nutrition 0.000 claims 1
- 244000124853 Perilla frutescens Species 0.000 claims 1
- 238000000034 method Methods 0.000 abstract description 10
- 239000003054 catalyst Substances 0.000 abstract description 6
- 239000002516 radical scavenger Substances 0.000 abstract description 3
- 239000002386 air freshener Substances 0.000 abstract description 2
- 239000000376 reactant Substances 0.000 abstract description 2
- 239000007921 spray Substances 0.000 abstract description 2
- 238000005507 spraying Methods 0.000 abstract description 2
- 239000012855 volatile organic compound Substances 0.000 description 12
- 238000006555 catalytic reaction Methods 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 230000003647 oxidation Effects 0.000 description 4
- 238000007254 oxidation reaction Methods 0.000 description 4
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 4
- 229930195733 hydrocarbon Natural products 0.000 description 3
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 3
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 241000207840 Jasminum Species 0.000 description 2
- 235000010254 Jasminum officinale Nutrition 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 150000001299 aldehydes Chemical class 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000006731 degradation reaction Methods 0.000 description 2
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 2
- 229910052737 gold Inorganic materials 0.000 description 2
- 239000010931 gold Substances 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 description 2
- 239000002808 molecular sieve Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 239000005011 phenolic resin Substances 0.000 description 2
- 229920001568 phenolic resin Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 229910052697 platinum Inorganic materials 0.000 description 2
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- HIXDQWDOVZUNNA-UHFFFAOYSA-N 2-(3,4-dimethoxyphenyl)-5-hydroxy-7-methoxychromen-4-one Chemical compound C=1C(OC)=CC(O)=C(C(C=2)=O)C=1OC=2C1=CC=C(OC)C(OC)=C1 HIXDQWDOVZUNNA-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- 229930040373 Paraformaldehyde Natural products 0.000 description 1
- 208000027418 Wounds and injury Diseases 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000003463 adsorbent Substances 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 150000001555 benzenes Chemical class 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 150000008282 halocarbons Chemical class 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- 239000012774 insulation material Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- VUZPPFZMUPKLLV-UHFFFAOYSA-N methane;hydrate Chemical compound C.O VUZPPFZMUPKLLV-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 1
- 229910000510 noble metal Inorganic materials 0.000 description 1
- 239000006259 organic additive Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 229920002866 paraformaldehyde Polymers 0.000 description 1
- 239000003209 petroleum derivative Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 229910052761 rare earth metal Inorganic materials 0.000 description 1
- 229910001404 rare earth metal oxide Inorganic materials 0.000 description 1
- 150000002910 rare earth metals Chemical class 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 1
- 229910001887 tin oxide Inorganic materials 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
- B01D53/8668—Removing organic compounds not provided for in B01D53/8603 - B01D53/8665
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/20—Metals or compounds thereof
- B01D2255/202—Alkali metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/20—Metals or compounds thereof
- B01D2255/207—Transition metals
- B01D2255/20769—Molybdenum
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Lubricants (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Abstract
The invention discloses a kind of preparation methods of automobile-used formaldehyde quick removal agent, for the small feature in family car space, a kind of automobile-used formaldehyde quick removal agent of preparation, the quick removal agent is with 2,4- dinitrophenylhydrazine is reactant, and caesium, molybdenum houghite are efficient rapid catalyst；In use, spraying just as using air freshener in the car, the effect for removing formaldehyde can be basically reached in 1 minute, efficiently quickly.Its formaldehyde removing rate is tested, after 1 minute, formaldehyde removing rate is up to 95%, and formaldehyde removing rate is up to 99.8% after ten minutes.The formaldehyde scavenger of this method preparation, not only preparation method is simple, and can directly be made as spray, easy to use.
Description
Technical field
The present invention relates to formaldehyde scavenger technical field more particularly to a kind of preparation sides of automobile-used formaldehyde quick removal agent
Method.
Background technique
VOC is the english abbreviation of volatile organic compounds (volatile organic compounds), world health
Organize (WTO) to total volatile organic compounds (TVOC) is defined as: fusing point lower than room temperature and boiling point between 50 ~ 260 DEG C
Volatile organic compounds general name.The main component of VOC has: hydro carbons, halogenated hydrocarbons, oxygen hydrocarbon and nitrogen hydrocarbon, it includes: benzene series
Object, organic chloride, freon series, organic ketone, amine, alcohol, ether, ester, acid and petroleum hydrocarbon compound etc..Interior VOC mainly comes
Derived from carpet in car, roof felt, instrument board plastic plate, seat and other decoration glue, wherein the interior carpet used, interior
The VOC volatile quantity of crest blanket and top felt is higher, this is directly related with binding material phenolic resin used in its manufacturing process,
The synthesis material that phenolic resin adhesive uses is formaldehyde, if reaction is not exclusively, free formaldehyde, the portion can be contained in adhesive
Divide formaldehyde to will increase the VOC of automotive interior, and contains in the materials such as plastics, fabric, material of paint, thermal insulation material that automobile uses
Organic solvent, additive and auxiliary agent etc. are discharged into car, also will increase the VOC value of automotive interior.Due to vapour interior space compared with
Small, good airproof performance, thus in automobile influence of the exceeded VOC to human body than VOC exceeded in room to the extent of injury of human body more
Greatly.
A kind of method of catalysis oxidation removal formaldehyde of United States Patent (USP) US 5,585,083 invention, inventor will
The platinum of 12wt% is supported on tin oxide as catalyst, and using the oxygen in air as oxidant, the catalysis oxidation of PARA FORMALDEHYDE PRILLS(91,95) is removed
There is good effect.The advantages of this method is that do not have the consumption of additional energy source that can reach low-temperature catalyzed degradation first in reaction
The effect of aldehyde.The rare earth oxide or complex rare-earth oxidate containing valuable metal of Chinese patent CN 1698932A gold-supported are catalyst, gold
Content when being 3wt.%, the effect of preferable catalytic degradation formaldehyde can be also obtained at a temperature of 100 DEG C or so.But two special
Benefit all employs the expensive noble metal such as platinum and gold, and the price is very expensive for catalyst.102198404 B of Chinese patent CN
The silver-carrying nano manganese dioxide-catalyst of offer, using the manganese dioxide molecular sieve of silver-colored carried with doped as activating component, the catalyst
It catalysis oxidation formaldehyde can react at low temperature, by formaldehyde, complete oxidation is carbon dioxide and water under cryogenic, to go
Except formaldehyde.The patented method technique is more complex, and industrialization difficulty is larger.104984757 A of Chinese patent CN discloses one kind
The preparation method of formaldehyde quick removal agent, the formaldehyde quick removal agent equally use the higher metallic silver of price, and in order to
Reinforce removal effect, uses molecular sieve as strong adsorbent, therefore the product can not be made as liquid, removal effect still needs to be mentioned
It is high.
Summary of the invention
Technical problems based on background technology, the invention proposes a kind of preparation sides of automobile-used formaldehyde quick removal agent
Method.
Technical scheme is as follows:
A kind of preparation method of automobile-used formaldehyde quick removal agent, comprising the following steps:
(1) two kinds or more of plants essential oils are uniformly mixed, obtain mixed plant essential oil；
(2) sodium metaaluminate and sodium hydroxide are dissolved in deionized water and are configured to solution A；Cesium chloride is dissolved in deionized water to be configured to
Solution B；Solution C is configured in B by pouring into after molybdenum dioxide diluted hydrochloric acid dissolution；O-nitrobenzoic acid is dissolved in odium stearate
It is configured to mixed serum D；Then under strong stirring or ultrasonic wave effect, while mixing slurry is added dropwise in solution A and solution C
Mixed serum E is configured in liquid D；Ageing filters, and filter cake dries to obtain caesium, molybdenum houghite；
(3) caesium, molybdenum houghite and 2,4-dinitrophenylhydrazine are subjected to dry ball milling, cross 800 meshes, obtains mixed powder；
(4) polysorbate 20, polyoxyethylene fatty acid ester and dehydrated alcohol are uniformly mixed, obtain solubilizer；
(5) solubilizer is added in mixed plant essential oil, is stirred evenly under room temperature, mixed powder is then added, continue to stir
It mixes uniformly, is eventually adding water mixing.
Preferably, in the step (1), the two kinds or more of plants essential oils can be Rosa Damascana, Rome
Camomile essential oil, Lavender, fragrant Fructus Perillae quintessence oil, sweet orange oil, tea tree ethereal oil, lemon, refined jasmine oil and sandalwood essential oil
In any two kinds or more of combination.
Preferably, in the step (3), the mass ratio of caesium, molybdenum houghite and 2,4-dinitrophenylhydrazine is (8-15):
1。
Preferably, the automobile-used formaldehyde quick removal agent, by following weight percent at being grouped as: mixed plant essence
Oily 10-13%, solubilizer 10-15%, caesium, molybdenum houghite 0.1-0.4%, 2,4 dinitrophenyl hydrazine 0.01-0.05% and water
Surplus.
The invention has the beneficial effects that: the present invention feature small for family car space, a kind of automobile-used first of preparation
Aldehyde quick removal agent, for the quick removal agent using 2,4-dinitrophenylhydrazine as reactant, caesium, molybdenum houghite are efficient quick catalysis
Agent；In use, spraying just as using air freshener in the car, the effect for removing formaldehyde can be basically reached in 1 minute,
Efficiently quickly.Its formaldehyde removing rate is tested, after 1 minute, formaldehyde removing rate is up to 95%, and formaldehyde removing rate is reachable after ten minutes
99.5% or more.The formaldehyde scavenger of this method preparation, not only preparation method is simple, and can directly be made as spray, makes
With conveniently.
Specific embodiment
Embodiment 1:
A kind of preparation method of automobile-used formaldehyde quick removal agent, comprising the following steps:
(1) two kinds or more of plants essential oils are uniformly mixed, obtain mixed plant essential oil；
(2) sodium metaaluminate and sodium hydroxide are dissolved in deionized water and are configured to solution A；Cesium chloride is dissolved in deionized water to be configured to
Solution B；Solution C is configured in B by pouring into after molybdenum dioxide diluted hydrochloric acid dissolution；O-nitrobenzoic acid is dissolved in odium stearate
It is configured to mixed serum D；Then under strong stirring or ultrasonic wave effect, while mixing slurry is added dropwise in solution A and solution C
Mixed serum E is configured in liquid D；Ageing filters, and filter cake dries to obtain caesium, molybdenum houghite；
(3) caesium, molybdenum houghite and 2,4-dinitrophenylhydrazine are subjected to dry ball milling, cross 800 meshes, obtains mixed powder；
(4) polysorbate 20, polyoxyethylene fatty acid ester and dehydrated alcohol are uniformly mixed, obtain solubilizer；
(5) solubilizer is added in mixed plant essential oil, is stirred evenly under room temperature, mixed powder is then added, continue to stir
It mixes uniformly, is eventually adding water mixing.
In the step (1), the two kinds or more of plants essential oils can be Rosa Damascana, flores anthemidis essence
Combination in oil, Lavender and sandalwood essential oil.
The automobile-used formaldehyde quick removal agent, by following weight percent at being grouped as: mixed plant essential oil
12.5%, solubilizer 15%, caesium, molybdenum houghite 0.3%, 2,4 dinitrophenyl hydrazine 0.02% and water surplus.
Embodiment 2:
A kind of preparation method of automobile-used formaldehyde quick removal agent, comprising the following steps:
(1) two kinds or more of plants essential oils are uniformly mixed, obtain mixed plant essential oil；
(2) sodium metaaluminate and sodium hydroxide are dissolved in deionized water and are configured to solution A；Cesium chloride is dissolved in deionized water to be configured to
Solution B；Solution C is configured in B by pouring into after molybdenum dioxide diluted hydrochloric acid dissolution；O-nitrobenzoic acid is dissolved in odium stearate
It is configured to mixed serum D；Then under strong stirring or ultrasonic wave effect, while mixing slurry is added dropwise in solution A and solution C
Mixed serum E is configured in liquid D；Ageing filters, and filter cake dries to obtain caesium, molybdenum houghite；
(3) caesium, molybdenum houghite and 2,4-dinitrophenylhydrazine are subjected to dry ball milling, cross 800 meshes, obtains mixed powder；
(4) polysorbate 20, polyoxyethylene fatty acid ester and dehydrated alcohol are uniformly mixed, obtain solubilizer；
(5) solubilizer is added in mixed plant essential oil, is stirred evenly under room temperature, mixed powder is then added, continue to stir
It mixes uniformly, is eventually adding water mixing.
In the step (1), the two kinds or more of plants essential oils can be tea tree ethereal oil, lemon and jasmine
The combination of jasmine essential oil.
The automobile-used formaldehyde quick removal agent, by following weight percent at being grouped as: mixed plant essential oil 10%,
Solubilizer 15%, caesium, molybdenum houghite 0.4%, 2,4 dinitrophenyl hydrazine 0.05% and water surplus.
Embodiment 3:
A kind of preparation method of automobile-used formaldehyde quick removal agent, comprising the following steps:
(1) two kinds or more of plants essential oils are uniformly mixed, obtain mixed plant essential oil；
(2) sodium metaaluminate and sodium hydroxide are dissolved in deionized water and are configured to solution A；Cesium chloride is dissolved in deionized water to be configured to
Solution B；Solution C is configured in B by pouring into after molybdenum dioxide diluted hydrochloric acid dissolution；O-nitrobenzoic acid is dissolved in odium stearate
It is configured to mixed serum D；Then under strong stirring or ultrasonic wave effect, while mixing slurry is added dropwise in solution A and solution C
Mixed serum E is configured in liquid D；Ageing filters, and filter cake dries to obtain caesium, molybdenum houghite；
(3) caesium, molybdenum houghite and 2,4-dinitrophenylhydrazine are subjected to dry ball milling, cross 800 meshes, obtains mixed powder；
(4) polysorbate 20, polyoxyethylene fatty acid ester and dehydrated alcohol are uniformly mixed, obtain solubilizer；
(5) solubilizer is added in mixed plant essential oil, is stirred evenly under room temperature, mixed powder is then added, continue to stir
It mixes uniformly, is eventually adding water mixing.
In the step (1), the two kinds or more of plants essential oils can be Rosa Damascana, Lavender,
The combination of sweet orange oil and refined jasmine oil.
The automobile-used formaldehyde quick removal agent, by following weight percent at being grouped as: mixed plant essential oil 13%,
Solubilizer 10%, caesium, molybdenum houghite 0.1%, 2,4 dinitrophenyl hydrazine 0.01% and water surplus.
Comparative example 1
Caesium, molybdenum houghite in embodiment 1 is replaced with into iron, molybdenum houghite, remaining proportion and preparation method are constant.
Reference examples
The solid formaldehyde remover prepared using 104984757 A embodiment 1 of Chinese patent CN.
Embodiment 1-3 and the sample of comparative example 1 are uniformly sprayed at length, width and height in the confined space of 5m*2m*2m, sprayed
Amount is 5ml, while the solid formaldehyde remover for placing the reference examples of a box 50g is used as and compares test, test 1min, 5min,
(initial concentration is set as 0.2mg/m to the removal rate of 10min and 30min indoor formaldehyde3).
By the above test data it is recognised that the formaldehyde removal speed of automobile-used formaldehyde quick removal agent of the invention is fast, imitates
Fruit is very good.
The foregoing is only a preferred embodiment of the present invention, but scope of protection of the present invention is not limited thereto,
Anyone skilled in the art in the technical scope disclosed by the present invention, according to the technique and scheme of the present invention and its
Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.
Claims (4)
1. a kind of preparation method of automobile-used formaldehyde quick removal agent, which comprises the following steps:
(1) two kinds or more of plants essential oils are uniformly mixed, obtain mixed plant essential oil；
(2) sodium metaaluminate and sodium hydroxide are dissolved in deionized water and are configured to solution A；Cesium chloride is dissolved in deionized water to be configured to
Solution B；Solution C is configured in B by pouring into after molybdenum dioxide diluted hydrochloric acid dissolution；O-nitrobenzoic acid is dissolved in odium stearate
It is configured to mixed serum D；Then under strong stirring or ultrasonic wave effect, while mixing slurry is added dropwise in solution A and solution C
Mixed serum E is configured in liquid D；Ageing filters, and filter cake dries to obtain caesium, molybdenum houghite；
(3) caesium, molybdenum houghite and 2,4-dinitrophenylhydrazine are subjected to dry ball milling, cross 800 meshes, obtains mixed powder；
(4) polysorbate 20, polyoxyethylene fatty acid ester and dehydrated alcohol are uniformly mixed, obtain solubilizer；
(5) solubilizer is added in mixed plant essential oil, is stirred evenly under room temperature, mixed powder is then added, continue to stir
It mixes uniformly, is eventually adding water mixing.
2. the preparation method of automobile-used formaldehyde quick removal agent as described in claim 1, which is characterized in that the step (1)
In, the two kinds or more of plants essential oils can be Rosa Damascana, flores anthemidis essential oil, Lavender, fragrant purple perilla essence
Any two kinds or more of combination in oil, sweet orange oil, tea tree ethereal oil, lemon, refined jasmine oil and sandalwood essential oil.
3. the preparation method of automobile-used formaldehyde quick removal agent as described in claim 1, which is characterized in that the step (3)
In, the mass ratio of caesium, molybdenum houghite and 2,4-dinitrophenylhydrazine is (8-15): 1.
4. the preparation method of automobile-used formaldehyde quick removal agent as described in claim 1, which is characterized in that the automobile-used formaldehyde
Quick removal agent, by following weight percent at being grouped as: mixed plant essential oil 10-13%, solubilizer 10-15%, caesium, molybdenum
Houghite 0.1-0.4%, 2,4 dinitrophenyl hydrazine 0.01-0.05% and water surplus.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810902908.XA CN109126443B (en) | 2018-08-09 | 2018-08-09 | Preparation method of formaldehyde rapid scavenging agent for vehicle |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810902908.XA CN109126443B (en) | 2018-08-09 | 2018-08-09 | Preparation method of formaldehyde rapid scavenging agent for vehicle |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN109126443A true CN109126443A (en) | 2019-01-04 |
| CN109126443B CN109126443B (en) | 2020-05-05 |
Family
ID=64792270
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810902908.XA Active CN109126443B (en) | 2018-08-09 | 2018-08-09 | Preparation method of formaldehyde rapid scavenging agent for vehicle |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109126443B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110075688A (en) * | 2019-05-21 | 2019-08-02 | 陕西鸿鹰实业有限公司 | The composition and preparation method thereof of potent decomposing formaldehyde and harmful substance of persistently degrading |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2189217A1 (en) * | 2008-11-17 | 2010-05-26 | Technical University of Denmark | Nanoparticular metal oxide/anatase catalysts. |
| CN102796216A (en) * | 2012-08-09 | 2012-11-28 | 福建师范大学 | Preparation method of rare earth hydrotalcite-like compound/polymer nanocomposite |
| CN102941111A (en) * | 2012-11-20 | 2013-02-27 | 中国科学院生态环境研究中心 | Metal carrier loaded catalyst for purifying formaldehyde at room temperature |
| CN104226306A (en) * | 2014-10-14 | 2014-12-24 | 北京恒泰实达科技股份有限公司 | Catalyst for oxidizing and eliminating formaldehyde at room temperature and preparation method thereof |
| CN104436999A (en) * | 2013-09-24 | 2015-03-25 | 宁波市雨辰环保科技有限公司 | Formaldehyde absorbent and using method thereof |
| CN106477977A (en) * | 2016-10-10 | 2017-03-08 | 杭州金庭悦环保科技有限公司 | A kind of radiation shielding coating with formaldehyde reduced for a long time effect and preparation method thereof |
| CN107801738A (en) * | 2017-11-28 | 2018-03-16 | 云南百叶集生物科技有限公司 | A kind of plant composition and preparation method thereof, application |
| CN108261916A (en) * | 2016-12-30 | 2018-07-10 | 康宁股份有限公司 | Segmented air filtration system and its preparation and application |
-
2018
- 2018-08-09 CN CN201810902908.XA patent/CN109126443B/en active Active
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2189217A1 (en) * | 2008-11-17 | 2010-05-26 | Technical University of Denmark | Nanoparticular metal oxide/anatase catalysts. |
| CN102796216A (en) * | 2012-08-09 | 2012-11-28 | 福建师范大学 | Preparation method of rare earth hydrotalcite-like compound/polymer nanocomposite |
| CN102941111A (en) * | 2012-11-20 | 2013-02-27 | 中国科学院生态环境研究中心 | Metal carrier loaded catalyst for purifying formaldehyde at room temperature |
| CN104436999A (en) * | 2013-09-24 | 2015-03-25 | 宁波市雨辰环保科技有限公司 | Formaldehyde absorbent and using method thereof |
| CN104226306A (en) * | 2014-10-14 | 2014-12-24 | 北京恒泰实达科技股份有限公司 | Catalyst for oxidizing and eliminating formaldehyde at room temperature and preparation method thereof |
| CN106477977A (en) * | 2016-10-10 | 2017-03-08 | 杭州金庭悦环保科技有限公司 | A kind of radiation shielding coating with formaldehyde reduced for a long time effect and preparation method thereof |
| CN108261916A (en) * | 2016-12-30 | 2018-07-10 | 康宁股份有限公司 | Segmented air filtration system and its preparation and application |
| CN107801738A (en) * | 2017-11-28 | 2018-03-16 | 云南百叶集生物科技有限公司 | A kind of plant composition and preparation method thereof, application |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110075688A (en) * | 2019-05-21 | 2019-08-02 | 陕西鸿鹰实业有限公司 | The composition and preparation method thereof of potent decomposing formaldehyde and harmful substance of persistently degrading |
Also Published As
| Publication number | Publication date |
|---|---|
| CN109126443B (en) | 2020-05-05 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Kusuma et al. | The extraction of essential oils from patchouli leaves (Pogostemon cablin Benth) using a microwave air-hydrodistillation method as a new green technique | |
| Wan et al. | Encapsulation of heteropolyanion‐based ionic liquid within the metal–organic framework MIL‐100 (Fe) for biodiesel production | |
| Tan et al. | Removal of lead from aqueous solution with native and chemically modified corncobs | |
| CN100431952C (en) | Preparation method of high specific surface area active charcoal based on formaldehyde-phenol resin | |
| Félix et al. | Characterization of wood plastic composites made from landfill-derived plastic and sawdust: Volatile compounds and olfactometric analysis | |
| CN109749466A (en) | A kind of suppression cigarette taste removal additive and preparation method thereof and modified pitch | |
| CN109107380A (en) | A kind of preparation method of the long-acting VOC scavenger applied to carpet for automobile | |
| CN104945227A (en) | Ethylene glycol hydrofining method | |
| Borah et al. | A green synthesis of palladium nanoparticles by Sapindus mukorossi seed extract and use in efficient room temperature Suzuki–Miyaura cross‐coupling reaction | |
| CN109126443A (en) | A kind of preparation method of automobile-used formaldehyde quick removal agent | |
| CN103421173A (en) | Formaldehyde-purifying alkyd resin and preparation method thereof | |
| Tan et al. | Selective Oxidation of Glycerol to Glyceric Acid in Base‐Free Aqueous Solution at Room Temperature Catalyzed by Platinum Supported on Carbon Activated with Potassium Hydroxide | |
| CN105195099A (en) | Preparation method of beta-cyclodextrin modified macroporous amino glucan adsorbent | |
| DE2900384A1 (en) | PROCEDURE FOR ACTIVATING A CATALYST | |
| Wang et al. | Controllable click synthesis of poly (ionic liquid) s by surfactant-free ionic liquid microemulsions for selective dyes reduction | |
| Isinkaralar et al. | Equilibrium study of benzene, toluene, ethylbenzene, and xylene (BTEX) from gas streams by black pine cones-derived activated carbon | |
| CN105132175A (en) | Strawberry essence for oil-based ink and preparation method of strawberry essence | |
| Bhusari et al. | Kinetics of catalyzed esterification of acetic acid with n‐butanol using carbonized agro‐waste | |
| Chen et al. | Demethylation of lignin with mild conditions and preparation of green adhesives to reduce formaldehyde emissions and health risks | |
| Phetrungnapha et al. | Removal of free fatty acid from waste cooking oil using an adsorbent derived from cassava peels | |
| Sumathirathne et al. | Synthesis of novel porous tannin-phenol-formaldehyde cation exchange resin from Terminalia arjuna (Kumbuk) | |
| CN101934238B (en) | Preparation method of ethylene epoxidized silver catalyst | |
| CN108499534B (en) | Compact gas separation hybrid material containing graphene metal organic framework and preparation method thereof | |
| CN114539550B (en) | Third type porous ionic liquid based on UiO-66 and preparation method and application thereof | |
| CN107652252B (en) | A method of preparing gamma-valerolactone |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20201106 Address after: 16-1-7, 2 / F, No. 16, anningzhuang East Road, Haidian District, Beijing Patentee after: Beijing xinjuweishi Environmental Protection Technology Co.,Ltd. Address before: 230000 room 1414, building D, Yinhe Xingfu Plaza, intersection of Luzhou Avenue and Fuzhou Road, Baohe District, Hefei City, Anhui Province Patentee before: Anhui keyiguo Network Technology Co.,Ltd. Effective date of registration: 20201106 Address after: 230000 room 1414, building D, Yinhe Xingfu Plaza, intersection of Luzhou Avenue and Fuzhou Road, Baohe District, Hefei City, Anhui Province Patentee after: Anhui keyiguo Network Technology Co.,Ltd. Address before: 451191, Xianghe Road 1, Longhu Town, Zhengzhou, Henan, Xinzheng Patentee before: HENAN INSTITUTE OF ENGINEERING |
|
| TR01 | Transfer of patent right | ||
| CP03 | Change of name, title or address |
Address after: No. 1-6, Floor, Building 2, Beichenggen Community, Changping Town, Changping District, Beijing, 100000 Patentee after: Beijing xinjuweishi Environmental Protection Technology Co.,Ltd. Country or region after: China Address before: 16-1-7, floor 2, No. 16, anningzhuang East Road, Haidian District, Beijing Patentee before: Beijing xinjuweishi Environmental Protection Technology Co.,Ltd. Country or region before: China |
|
| CP03 | Change of name, title or address |