CN109123900A - A kind of ventilation waterproof sole combined material - Google Patents
A kind of ventilation waterproof sole combined material Download PDFInfo
- Publication number
- CN109123900A CN109123900A CN201710509071.8A CN201710509071A CN109123900A CN 109123900 A CN109123900 A CN 109123900A CN 201710509071 A CN201710509071 A CN 201710509071A CN 109123900 A CN109123900 A CN 109123900A
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- CN
- China
- Prior art keywords
- parts
- combined material
- ventilation waterproof
- waterproof sole
- coupling agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B13/00—Soles; Sole-and-heel integral units
- A43B13/02—Soles; Sole-and-heel integral units characterised by the material
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B13/00—Soles; Sole-and-heel integral units
- A43B13/02—Soles; Sole-and-heel integral units characterised by the material
- A43B13/04—Plastics, rubber or vulcanised fibre
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)
Abstract
The invention discloses a kind of ventilation waterproof sole combined materials, are formulated as follows: 11-17 parts of glass fibre, 18-25 parts of polypropylene amine, 7-9 parts of melamine, 2-8 parts of vinylacetate, 7-11 parts of hydrophobic resin, 2-4 parts of coupling agent, 1-2 parts of dispersing agent, 0.3-1.2 parts of thickener, 0.3-0.9 parts of defoaming agent.There is the features such as present invention has good permeability, and waterproofness is good good elasticity and damping effect, simultaneous processing to facilitate environmental protection.
Description
Technical field
The invention belongs to technical field of shoe making, and in particular to a kind of ventilation waterproof sole combined material.
Background technique
Chinese shoemaking is a dark horse, and in short more than ten years, becomes the maximum footwear producing country in the whole world and exported country, special
It is not after China's entry into the WTO, powerful developing state, the nearly 40- of the world shoes industry yield Yi Zhan total amount is more presented in Chinese shoemaking
50%, in global footwear trade, China's footwear export amount has also accounted for 25%, both ranks first in the world.Currently, China
Footwear consumption figure accounts for the 22% of world's aggregate consumption, is one of most important leather shoes country of consumption in the whole world.New century, with high-new skill
The continuous development of art, the demand to material for shoes wearability are also constantly increasing.Currently, being badly in need of that a kind of comfort level is high, gas permeability
Good sport shoe sole material, to meet the needs in market.
Summary of the invention
The object of the present invention is to provide a kind of ventilation waterproof sole combined material, the present invention has good permeability, waterproofness
The features such as good, there is good elasticity and damping effect, simultaneous processing to facilitate environmental protection.
A kind of ventilation waterproof sole combined material, be formulated it is as follows: 11-17 parts of glass fibre, 18-25 parts of polypropylene amine,
7-9 parts of melamine, 2-8 parts of vinylacetate, 7-11 parts of hydrophobic resin, 2-4 parts of coupling agent, 1-2 parts of dispersing agent, thickener
0.3-1.2 parts, 0.3-0.9 parts of defoaming agent.
The hydrophobic resin uses polyamide (PA), polylactic resin (PLA), polyethylene terephthalate
(PET), one of polymethyl methacrylate (PMMA).
The coupling agent uses silane coupling agent or titanate coupling agent.
The silane coupling agent uses vinyl silanes, amino silane, phenyl tributanoximo silane, methacryloxypropyl
One of base silane.
The titanate coupling agent uses monoalkoxytitanates.
The dispersing agent uses glyceryl tristearate or barium stearate.
The thickener uses one of methylcellulose, hydroxyethyl cellulose, hydroxypropyl cellulose.
The defoaming agent uses polyoxyethylene polyoxypropylene pentaerythrite ether, polyoxyethylene polyoxy propyl alcohol amidogen ether, polyoxy third
One of alkene glycerin ether.
The preparation method of the ventilation waterproof sole combined material, its step are as follows:
Step 1, polypropylene amine, vinylacetate and coupling agent are added in autoclave, sealing pressing coupling reaction,
The pressure is 1-1.4MPa, and the reaction time is 10-40min；
Step 2, melamine and hydrophobic resin are added in autoclave, carry out heating reaction, is mixed
Rubber, the heating temperature are 70-90 DEG C, reaction time 10-15min；
Step 3, dispersing agent, thickener and defoaming agent are put into reaction kettle and are stirred, obtain forerunner after mixing
Liquid；
Step 4, precursor liquid is poured slowly into film forming device at room temperature, is paved；
Step 5, film forming device is put into vacuum oven, it is ensured that be horizontally arranged, at a certain temperature freeze-day with constant temperature
Obtain combined material.
Drying temperature in the step 5 is 50-70 DEG C.
Compared with prior art, the invention has the following advantages:
1, the features such as present invention has good permeability, and waterproofness is good has good elasticity and damping effect, simultaneous processing
Facilitate environmental protection.
2, the present invention solves defect easy to aging and short service life, non-aging and with long service life excellent to realize
Point.
3, the composite material that uses of the present invention not only has the advantages that small density, wear-resistant, impact resistance, elasticity are excellent etc., but also
Easily fabricated various shape, convenient for integrally formed.
Specific embodiment
The present invention is described further below with reference to embodiment:
Embodiment 1
A kind of ventilation waterproof sole combined material is formulated as follows: 11 parts of glass fibre, 18 parts of polypropylene amine, melamine
7 parts of amine, 2 parts of vinylacetate, 7 parts of hydrophobic resin, 2 parts of coupling agent, 1 part of dispersing agent, 0.3 part of thickener, defoaming agent 0.3
Part.
The hydrophobic resin uses polyamide (PA).
The coupling agent uses silane coupling agent.
The silane coupling agent uses vinyl silanes.
The dispersing agent uses glyceryl tristearate.
The thickener uses methylcellulose.
The defoaming agent uses polyoxyethylene polyoxypropylene pentaerythrite ether.
The preparation method of the ventilation waterproof sole combined material, its step are as follows:
Step 1, polypropylene amine, vinylacetate and coupling agent are added in autoclave, sealing pressing coupling reaction,
The pressure is 1MPa, and the reaction time is 10min；
Step 2, melamine and hydrophobic resin are added in autoclave, carry out heating reaction, is mixed
Rubber, the heating temperature are 70 DEG C, reaction time 10min；
Step 3, dispersing agent, thickener and defoaming agent are put into reaction kettle and are stirred, obtain forerunner after mixing
Liquid；
Step 4, precursor liquid is poured slowly into film forming device at room temperature, is paved；
Step 5, film forming device is put into vacuum oven, it is ensured that be horizontally arranged, at a certain temperature freeze-day with constant temperature
Obtain combined material.
Drying temperature in the step 5 is 50 DEG C.
Embodiment 2
A kind of ventilation waterproof sole combined material is formulated as follows: 17 parts of glass fibre, 25 parts of polypropylene amine, melamine
9 parts of amine, 8 parts of vinylacetate, 11 parts of hydrophobic resin, 4 parts of coupling agent, 2 parts of dispersing agent, 1.2 parts of thickener, defoaming agent 0.9
Part.
The hydrophobic resin uses polylactic resin (PLA).
The coupling agent uses titanate coupling agent.
The titanate coupling agent uses monoalkoxytitanates.
The dispersing agent uses barium stearate.
The thickener uses hydroxyethyl cellulose.
The defoaming agent uses polyoxyethylene polyoxy propyl alcohol amidogen ether.
The preparation method of the ventilation waterproof sole combined material, its step are as follows:
Step 1, polypropylene amine, vinylacetate and coupling agent are added in autoclave, sealing pressing coupling reaction,
The pressure is 1.4MPa, and the reaction time is 40min；
Step 2, melamine and hydrophobic resin are added in autoclave, carry out heating reaction, is mixed
Rubber, the heating temperature are 90 DEG C, reaction time 15min；
Step 3, dispersing agent, thickener and defoaming agent are put into reaction kettle and are stirred, obtain forerunner after mixing
Liquid；
Step 4, precursor liquid is poured slowly into film forming device at room temperature, is paved；
Step 5, film forming device is put into vacuum oven, it is ensured that be horizontally arranged, at a certain temperature freeze-day with constant temperature
Obtain combined material.
Drying temperature in the step 5 is 70 DEG C.
Embodiment 3
A kind of ventilation waterproof sole combined material is formulated as follows: 14 parts of glass fibre, 22 parts of polypropylene amine, melamine
8 parts of amine, 6 parts of vinylacetate, 9 parts of hydrophobic resin, 3 parts of coupling agent, 2 parts of dispersing agent, 0.7 part of thickener, defoaming agent 0.6
Part.
The hydrophobic resin uses polymethyl methacrylate (PMMA).
The coupling agent uses silane coupling agent.
The silane coupling agent uses amino silane.
The dispersing agent uses glyceryl tristearate.
The thickener uses hydroxypropyl cellulose.
The defoaming agent uses polypropylene glycerol aether.
The preparation method of the ventilation waterproof sole combined material, its step are as follows:
Step 1, polypropylene amine, vinylacetate and coupling agent are added in autoclave, sealing pressing coupling reaction,
The pressure is 1.3MPa, and the reaction time is 30min；
Step 2, melamine and hydrophobic resin are added in autoclave, carry out heating reaction, is mixed
Rubber, the heating temperature are 80 DEG C, reaction time 12min；
Step 3, dispersing agent, thickener and defoaming agent are put into reaction kettle and are stirred, obtain forerunner after mixing
Liquid；
Step 4, precursor liquid is poured slowly into film forming device at room temperature, is paved；
Step 5, film forming device is put into vacuum oven, it is ensured that be horizontally arranged, at a certain temperature freeze-day with constant temperature
Obtain combined material.
Drying temperature in the step 5 is 60 DEG C.
The foregoing is merely one embodiment of the invention, are not intended to limit the present invention, all to use equivalent substitution or equivalent transformation
Mode technical solution obtained, fall within the scope of protection of the present invention.
Claims (10)
1. a kind of ventilation waterproof sole combined material, which is characterized in that its formula is as follows: 11-17 parts of glass fibre, polypropylene amine
18-25 parts, 7-9 parts of melamine, 2-8 parts of vinylacetate, 7-11 parts of hydrophobic resin, 2-4 parts of coupling agent, dispersing agent 1-2
Part, 0.3-1.2 parts of thickener, 0.3-0.9 parts of defoaming agent.
2. a kind of ventilation waterproof sole combined material according to claim 1, which is characterized in that the hydrophobic resin
Using polyamide (PA), polylactic resin (PLA), polyethylene terephthalate (PET), polymethyl methacrylate
One of (PMMA).
3. a kind of ventilation waterproof sole combined material according to claim 1, which is characterized in that the coupling agent uses
Silane coupling agent or titanate coupling agent.
4. a kind of ventilation waterproof sole combined material according to claim 3, which is characterized in that the silane coupling agent
Using one of vinyl silanes, amino silane, phenyl tributanoximo silane, methacryloxypropyl silane.
5. a kind of ventilation waterproof sole combined material according to claim 3, which is characterized in that the titanate esters coupling
Agent uses monoalkoxytitanates.
6. a kind of ventilation waterproof sole combined material according to claim 1, which is characterized in that the dispersing agent uses
Glyceryl tristearate or barium stearate.
7. a kind of ventilation waterproof sole combined material according to claim 1, which is characterized in that the thickener uses
One of methylcellulose, hydroxyethyl cellulose, hydroxypropyl cellulose.
8. a kind of ventilation waterproof sole combined material according to claim 1, which is characterized in that the defoaming agent uses
One of polyoxyethylene polyoxypropylene pentaerythrite ether, polyoxyethylene polyoxy propyl alcohol amidogen ether, polypropylene glycerol aether.
9. a kind of ventilation waterproof sole combined material according to claim 1, which is characterized in that the ventilation waterproof footwear
The preparation method of bottom combined material, its step are as follows:
Step 1, polypropylene amine, vinylacetate and coupling agent are added in autoclave, sealing pressing coupling reaction is described
Pressure is 1-1.4MPa, and the reaction time is 10-40min；
Step 2, melamine and hydrophobic resin are added in autoclave, carry out heating reaction, obtains mixed rubber,
The heating temperature is 70-90 DEG C, reaction time 10-15min；
Step 3, dispersing agent, thickener and defoaming agent are put into reaction kettle and are stirred, obtain precursor liquid after mixing；
Step 4, precursor liquid is poured slowly into film forming device at room temperature, is paved；
Step 5, film forming device is put into vacuum oven, it is ensured that horizontal positioned, freeze-day with constant temperature can be obtained at a certain temperature
Combined material.
10. a kind of ventilation waterproof sole combined material according to claim 9, which is characterized in that in the step 5
Drying temperature is 50-70 DEG C.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710509071.8A CN109123900A (en) | 2017-06-28 | 2017-06-28 | A kind of ventilation waterproof sole combined material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710509071.8A CN109123900A (en) | 2017-06-28 | 2017-06-28 | A kind of ventilation waterproof sole combined material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109123900A true CN109123900A (en) | 2019-01-04 |
Family
ID=64803135
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710509071.8A Pending CN109123900A (en) | 2017-06-28 | 2017-06-28 | A kind of ventilation waterproof sole combined material |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109123900A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109836630A (en) * | 2019-01-21 | 2019-06-04 | 茂泰(福建)鞋材有限公司 | A kind of high-weatherability white rubber sole and preparation method thereof |
-
2017
- 2017-06-28 CN CN201710509071.8A patent/CN109123900A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109836630A (en) * | 2019-01-21 | 2019-06-04 | 茂泰(福建)鞋材有限公司 | A kind of high-weatherability white rubber sole and preparation method thereof |
| CN109836630B (en) * | 2019-01-21 | 2021-02-26 | 茂泰(福建)鞋材有限公司 | High-weather-resistance white rubber sole and preparation method thereof |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20190104 |
|
| WD01 | Invention patent application deemed withdrawn after publication |