CN109118245A - A kind of method and its application recognizing feature using Chu Cheng note as commodity - Google Patents
A kind of method and its application recognizing feature using Chu Cheng note as commodity Download PDFInfo
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- CN109118245A CN109118245A CN201810763402.5A CN201810763402A CN109118245A CN 109118245 A CN109118245 A CN 109118245A CN 201810763402 A CN201810763402 A CN 201810763402A CN 109118245 A CN109118245 A CN 109118245A
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- G—PHYSICS
- G06—COMPUTING; CALCULATING OR COUNTING
- G06Q—INFORMATION AND COMMUNICATION TECHNOLOGY [ICT] SPECIALLY ADAPTED FOR ADMINISTRATIVE, COMMERCIAL, FINANCIAL, MANAGERIAL OR SUPERVISORY PURPOSES; SYSTEMS OR METHODS SPECIALLY ADAPTED FOR ADMINISTRATIVE, COMMERCIAL, FINANCIAL, MANAGERIAL OR SUPERVISORY PURPOSES, NOT OTHERWISE PROVIDED FOR
- G06Q30/00—Commerce
- G06Q30/018—Certifying business or products
- G06Q30/0185—Product, service or business identity fraud
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Abstract
The invention discloses a kind of using Chu Cheng note as commodity recognizes the method and its application of feature.Chu Cheng essential oil is added in ink with special ratios, then ink is sprayed into commodity packaging surface impressing pattern or text, later again to printing area overlay film to save fragrance.Product is marked using Chu Cheng note, authenticity of products is determined using smell combination chemical feature constituent analysis.For consumer, it can directly open overlay film and smell to debate by fragrance and carry out the true and false discrimination of product, in addition can carry out qualitative and quantitative analysis to fragrance component and accurately to determine the true and false.A kind of new approach is provided for package anti-counterfeiting, increases the fraud difficulty of personator.Whether the application of this method can also identify the storage environments of commodity, time qualified.Operation of the present invention is easy, low in cost, has application prospect well.
Description
Technical field
The invention belongs to anti-counterfeiting technology fields, are specifically related to a kind of by assigning perfume to commodity outer packing and with Chu
Method of the orange perfume rhythm as commodity identification feature.Meanwhile what the invention further relates to this method in commodity counterfeit prevention, discrimination specifically answering
With.
Background technique
Fraud fake traffic and AIDS, drugs, environmental pollution become the big public hazards of Century Square side by side.Currently, world community man
Commodity personation activity is very rampant, and by taking particularly for tobacco items commodity as an example, the degree for being imitated or palming off is very serious.According to statistics, 2015
False smoke quantity is increased sharply after year, China's cigarette proposed tax favorable price, and 2016 up to 45.68%, false smoke not only led the majority of consumers into a trap, damage
Evil consumer legitimate right, also seriously endangers the normal development of cigarette industry, causes huge tax to be lost, national interests are suffered huge
Big loss.
Existing commodity counterfeit prevention means except by trade mark, production technology etc. as judge commercial articles true and false according in addition to, for
Commodity outer packing can also using antiforge laser holographic, colored fiber is anti-fake, miniature printing is anti-fake, photochromatic printing ink is anti-fake, superfine wire
The technologies such as anti-fake, two-dimension code anti-counterfeit, but these anti-counterfeiting technologies are also gradually grasped by fake producer, and the anti-fake effect of discrimination is more and more not
It is fully up to expectations.With the development of science and technology, the research of anti-counterfeiting technology has been directed to contemporary optics, analytical chemistry, computer and more matchmakers
Body technique, computer image recognition technology, electromagnetic induction technology, biotechnology, genetic engineering, Modern administrology etc. are multiple
Important subject gradually develops into a new frontier science.But in the prior art there is not yet being recognized using note as commodity
The method of feature, and the relevant report of commodity counterfeit prevention discrimination is carried out accordingly.
Summary of the invention
In view of the above-mentioned deficiencies in the prior art, it is an object of the present invention to provide it is a kind of using Chu Cheng note to commodity outer packing assign
Perfume (or spice), and using the detected by scent of the note as commodity recognize feature method.
The object of the invention is also to provide concrete application of the method in commodity counterfeit prevention, discrimination.
The purpose of the present invention is achieved by the following technical programs.
Unless otherwise indicated, percentage of the present invention is mass percent.
A method of recognizing feature using Chu Cheng note as commodity, it is characterised in that: by Chu Cheng essential oil according to off-set oil
The 1%~10% of black quality mixes, then with gained mixture in commodity packaging surface impressing pattern or text, later again to print
Region overlay film processed is to save fragrance.
The Chu Cheng essential oil is the essential oil being prepared by squeezing and molecular distillation from Chu Chengzhong, has sweetness
Orange fragrance and soft fragrant note, no bitter taste.
The Chu Cheng is one kind of rock sugar navel orange, is the peculiar orange class of Yunnan Province.
The squeezing and molecularly distilled specifically: using Chu Cheng fresh fruit as raw material, using squeezing method to orange peel and orange
Meat is squeezed, and is settled after being filtered after water-oil separating, and lyophilization obtains Chu Cheng first oil, is carried out using ultrafiltration membrane to first oil
Secondary filter cutting, removes depigmentation and impurity, then with multiple-grade molecular distillation cutting technique removal part small molecule and macromolecular at
Divide and obtains required Chu Cheng essential oil.
The printing area is the complete outer surface of commodity packaging or any position of commodity packaging outer surface.
It is described to printing area overlay film, specifically: printing area is coated using transparent membrane, makes printing area and outer
Portion's air exclusion, but transparent membrane is not adhered with printing area.
The transparent membrane is polypropylene (PP), polyvinyl chloride (PVC) or Biaxially oriented polypropylene (BOPP) film.
It is above-mentioned that application of the method for feature in commodity counterfeit prevention, discrimination is recognized using Chu Cheng note as commodity.
The application specifically: after consumer buys commodity, the overlay film that need to only open printing area carries out smelling, has bright
Aobvious characteristic perfume is regular and in the shelf-life conforming articls；Without obvious characteristic fragrance or fragrance it is abnormal can principium identification
For counterfeit goods or non-conformity article.
The application specifically: in order to more accurately identify commodity true and false, commodity production enterprise is to used in it
Chu Cheng essential oil carries out chromatogram image analysis according to iso standard, specifies the type and accounting numberical range of its main chemical compositions, makees
For quality judging quota；When discerning the false from the genuine, the overpack of commodity to be identified is taken, random cropping printing area is as analysis sample
Product, carry out chromatogram image analysis, when the type of main chemical compositions be not inconsistent or the accounting numerical value of main chemical compositions in it is any
One exceeds judging quota range, then determines the commodity for counterfeit goods or non-conformity article.
The foundation iso standard carries out chromatogram image analysis, specifically: according to ISO 11024-1 (essential oil-chromatogram
As General Requirement-part 1: the foundation of chromatogram image in standard) and ISO11024-2 (essential oil-chromatogram image is general to be wanted
Seek-part 2: essential oil chromatogram image using) carry out chromatogram image analysis.
Compared with the existing technology, the invention has the following advantages that
1, the present invention is pioneering using Chu Cheng note as the identification feature of commodity, different from the past to need to rely on vision or touching
The discrimination method of feel, the present invention recognize commercial articles true and false by the quantitative combined method of smell and fragrance component, for packaging
It is anti-fake that a kind of new approach is provided, increase the fraud difficulty of personator.
2, this method is applied to commodity counterfeit prevention, and two methods can be quantified by smell and fragrance component and are carried out to commercial articles true and false
Identification.Consumer's purchase or when commodity in use, by smelling, whether there is or not obvious characteristic fragrance to distinguish commodity.Manufacturing enterprise is special
Appraisal organization, commercial quality can be distinguished by the qualitative, quantitative that chromatography component is analyzed, to effectively realize commodity true and false
Differentiation, improve the accuracy of identification.
3, the application of this method can not only effectively judge commodity true and false, can also identify storage environment, the time of commodity
It is whether qualified.
4, operation of the present invention is easy, low in cost, and identification is convenient, accurate.
Detailed description of the invention
Fig. 1 is the flow diagram that commodity discrimination is carried out using the method for the present invention；
Fig. 2 is the total ion chromatogram of Chu Cheng essential oil described in embodiment 5.
Specific embodiment
The present invention is described in further detail with reference to the accompanying drawings and examples, but drawings and examples are not pair
The restriction of technical solution of the present invention.It is all based on present invention teach that made variation or equivalent replacement, should belong to the present invention
Protection scope.
Embodiment 1
Identification feature using Chu Cheng note as cigarette packaging strip box.
1, using Chu Cheng fresh fruit as raw material, pericarp and pulp are separated after it is sorted and is cleaned, pericarp is squeezed to obtain
Chu Cheng essential oil 1# squeezes to obtain Chu Cheng essential oil 2# to pulp, merges 1#, 2# Chu Cheng essential oil, is put into freezer freezing, through filter cloth suction filtering,
Obtain the first oil product of Chu Cheng essential oil.First oil product is put into freezer and freezes 24 hours through molecular film filtering and removing pigment and wax, warp
600 mesh filter cloth suction filterings remove wax, are then distilled three times using molecular distillation technique, and specifically level-one heavy constituent carries out two
Grade distillation, second level light component carry out three-stage distillation and retain light component, i.e., removal part small molecule and macromolecular components obtain Chu Cheng
Essential oil purified product.Detailed step and parameter are as follows after assay optimization, remove small molecular weight impurity, device parameter for the first time are as follows:
80 pa of vacuum degree, main distiller temperature 45 C, 25 DEG C of preheating temperature, 35 DEG C of condensate temperature；Second of removal big molecular impurity,
Device parameter are as follows: 40 pa of vacuum degree, 65 DEG C of main distiller temperature, 25 DEG C of preheating temperature, 30 DEG C of condensate temperature；Third time is distilled
Required product, device parameter can be obtained are as follows: 20 pa of vacuum degree, main distiller temperature 60 C, 25 DEG C of preheating temperature, condensate temperature
33℃.Essential oil is smelt by professional debates, and determines that its note is characterized by fresh and sweet orange fragrance and soft fragrant note,
Without bitter taste.
2, the chromatogram image of Chu Cheng essential oil is analyzed according to ISO 11024-1 and ISO 11024-2 standard, chemistry at
Divide testing result such as table 1.
1 Chu Cheng Essential Oil result (unit: %) of table
3, Chu Cheng essential oil is added in ink with 1% additive amount, then ink is sprayed to the two dimension of cigarette packaging strip box
The specific regions such as code or cigarette trade mark text, then carry out coating processing with polypropylene (PP) film to spraying area.
4, cigarette package: product is obtained according to normal production of cigarettes flow package.
5, cigarette barrel is stored 90 days under 30 DEG C of temperature, 60% environment of relative humidity, is randomly selected 10 products, is torn
The overlay film on barrel surface, smelling discovery have the orange fragrance and soft fragrant note of apparent sweetness.
Embodiment 2
Embodiment 1 is repeated, has following difference: Chu Cheng essential oil is added in ink with 10% additive amount；In cigarette packet
The outer surface of dress barrel all uses the fragrance oil ink print picture and text, then uses Biaxially oriented polypropylene (BOPP) film overlay film；
Cigarette barrel is stored 1 year under 25 DEG C of temperature, 40% environment of relative humidity, is randomly selected 10 products, is torn barrel surface
Overlay film, smelling discovery still have the orange fragrance and soft fragrant note of apparent sweetness.
Embodiment 3
Embodiment 1 is repeated, has following difference: Chu Cheng essential oil is added in ink with 10% additive amount；In cigarette packet
The outer surface of dress barrel all uses the fragrance oil ink print picture and text, then uses polyvinyl chloride (PVC) film overlay film；Cigarette barrel
It is stored 1 year under 40 DEG C of temperature, 80% environment of relative humidity, randomly selects 10 products, tear the overlay film on barrel surface, smell
Hear orange fragrance and soft fragrant note that discovery still has apparent sweetness.
Embodiment 4
1 products obtained therefrom of embodiment is launched, and opens overlay film after consumer's purchase, can be with smelling to apparent fresh and sweet orange
Sub- fragrance and soft fragrant note, if without overlay film, or tear and do not have fresh and sweet orange fragrance and soft after overlay film
Fragrant note, or have other miscellaneous gas, then can determine that purchased product is false.
Embodiment 5
The like products for randomly choosing different channel sales from the market takes packaging material to carry out true and false discrimination: tearing first
It opens overlay film and debates whether the product has fresh and sweet orange fragrance and soft fragrant note by smelling.For with approximation characteristic perfume
The product of gas further cuts flavoring overlay film region as analysis sample, using Agilent7890A/5975C gas-chromatography-matter
Spectrum combined instrument+autosampler analyzes sample.
Chromatographic condition are as follows: RXi-5sil MS quartz capillary column (60m × 0.25mm × 0.25 μm), carrier gas are that helium is (pure
Degree is 99.999%) flow velocity: 1.0mL/min.Temperature program: 60 DEG C of initial temperature, 6min is kept；With the rate liter of 3 DEG C/min
Temperature is to 180 DEG C；230 DEG C are warming up to the rate of 10 DEG C/min again, keeps 10min.Injector temperature: 250 DEG C, sample volume: 1.0
μ L, split ratio: 10:1, solvent delay 6min.
Mass Spectrometry Conditions are as follows: ion source: electricity bombardment ionization source (EI)；Ion source temperature: 230 DEG C；Quadrupole rod temperature: 150 DEG C；
Ionizing energy: 70eV；Transmission line temperature: 280 DEG C；Scanning range (m/z): 40~450, mass spectrum retrieves picture library: Nist11 composes library.
Total ion chromatogram obtained by test sample, which is shown in after Fig. 2, result are retrieved using Nist11, combines ESO fragrant
Smart retention index compares qualitative, and the percentage contents of chemical component in Chu Cheng essential oil are calculated in area normalization, altogether
58 compounds have been determined, have accounted for chemical component 97.344% in Chu Cheng essential oil.Wherein australene, β-in orange oil in Chu Cheng essential oil
14 main feature compounds contents such as firpene, sabinene, limonene such as table 2, by compared with 1 data of table, 14 main compounds
It detects, and its content can determine that the product is true within the scope of standard requirements.
Main feature compounds content in 2 Chu Cheng essential oil of table
Embodiment 6
Embodiment 5 is repeated, there is following difference:
The main features compounds content such as australene, nopinene, sabinene, limonene such as table 3 in sample, by comparing, the sweet tea
Orange oil n-octaldehyde and geranial are not detected, and detect 12 main compounds, wherein australene, laurene, limonene and neral four
A compounds content is not within the scope of standard requirements.Comprehensive scent, which is smelt, debates result, main chemical compositions and content (table 3) analysis knot
Fruit can determine that the product is false.
Main feature compounds content in 3 Chu Cheng essential oil of table
* it note: is not detected.
Claims (10)
1. a kind of method for recognizing feature using Chu Cheng note as commodity, it is characterised in that: by Chu Cheng essential oil according to printing ink
The 1%~10% of quality mixes, then with gained mixture in commodity packaging surface impressing pattern or text, later again to printing
Region overlay film is to save fragrance.
2. the method according to claim 1 for recognizing feature using Chu Cheng note as commodity, it is characterised in that: Chu
Orange essential oil is that have fresh and sweet orange fragrance and soft by squeezing and the essential oil that is prepared from Chu Chengzhong of molecular distillation
Fragrant note, no bitter taste.
3. the method according to claim 2 for recognizing feature using Chu Cheng note as commodity, which is characterized in that the pressure
Squeezing and molecular distillation specifically: using Chu Cheng fresh fruit as raw material, orange peel and orange meat are squeezed using squeezing method, water-oil separating
After be filtered sedimentation, lyophilization obtains Chu Cheng first oil, using ultrafiltration membrane to first oil carry out secondary filter cutting, remove depigmentation
And impurity, then required Chu Chengjing is obtained with multiple-grade molecular distillation cutting technique removal part small molecule and macromolecular components
Oil.
4. the method according to claim 1 for recognizing feature using Chu Cheng note as commodity, it is characterised in that: the print
Region processed is the complete outer surface of commodity packaging or any position of commodity packaging outer surface.
5. the method according to claim 1 for recognizing feature using Chu Cheng note as commodity, it is characterised in that: pair
Printing area overlay film specifically: printing area is coated using transparent membrane, completely cuts off printing area and outside air, but transparent
Film is not adhered with printing area.
6. the method according to claim 5 for recognizing feature using Chu Cheng note as commodity, it is characterised in that: described is saturating
Bright film is polypropylene, polyvinyl chloride or bidirectional stretching polypropylene film.
7. described in claim 1 recognize application of the method for feature in commodity counterfeit prevention, discrimination using Chu Cheng note as commodity.
8. application according to claim 7, it is characterised in that: after consumer buys commodity, open the overlay film of printing area
Smelling is carried out, have obvious characteristic fragrance is regular and in the shelf-life conforming articls；It is different without obvious characteristic fragrance or fragrance
It is normal can principium identification be counterfeit goods or non-conformity article.
9. application according to claim 7, it is characterised in that: as commodity production enterprise to Chu Cheng essential oil used in it according to
Chromatogram image analysis is carried out according to iso standard, specifies the type and accounting numberical range of its main chemical compositions, is judged as quality
Index；When discerning the false from the genuine, the overpack of commodity to be identified is taken, random cropping printing area carries out chromatography as analysis sample
Image analysis, when the type of main chemical compositions be not inconsistent or the accounting numerical value of main chemical compositions in any one beyond commenting
Sentence indication range, then determines the commodity for counterfeit goods or non-conformity article.
10. application according to claim 9, it is characterised in that: the foundation iso standard carries out chromatogram image analysis,
Specifically: according to ISO 11024-1 essential oil-chromatogram image General Requirement-part 1: the foundation of chromatogram image in standard；And
ISO11024-2 essential oil-chromatogram image General Requirement-part 2: essential oil chromatogram image utilizes progress chromatogram image analysis.
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| CN201810763402.5A CN109118245A (en) | 2018-07-12 | 2018-07-12 | A kind of method and its application recognizing feature using Chu Cheng note as commodity |
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| CN201810763402.5A CN109118245A (en) | 2018-07-12 | 2018-07-12 | A kind of method and its application recognizing feature using Chu Cheng note as commodity |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110481567A (en) * | 2019-08-09 | 2019-11-22 | 苏州凯云迪电子科技有限公司 | Vehicle safety warning system, method and security warning vehicle based on smell |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1244275A (en) * | 1996-12-20 | 2000-02-09 | 联邦印刷有限公司 | Value and security product with at least one security characteristic, method for its production and method for detection of security characteristics |
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2018
- 2018-07-12 CN CN201810763402.5A patent/CN109118245A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1244275A (en) * | 1996-12-20 | 2000-02-09 | 联邦印刷有限公司 | Value and security product with at least one security characteristic, method for its production and method for detection of security characteristics |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110481567A (en) * | 2019-08-09 | 2019-11-22 | 苏州凯云迪电子科技有限公司 | Vehicle safety warning system, method and security warning vehicle based on smell |
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