CN109146509A - A kind of method and its application recognizing feature using lilac note as commodity - Google Patents
A kind of method and its application recognizing feature using lilac note as commodity Download PDFInfo
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- CN109146509A CN109146509A CN201810763381.7A CN201810763381A CN109146509A CN 109146509 A CN109146509 A CN 109146509A CN 201810763381 A CN201810763381 A CN 201810763381A CN 109146509 A CN109146509 A CN 109146509A
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- G06Q—INFORMATION AND COMMUNICATION TECHNOLOGY [ICT] SPECIALLY ADAPTED FOR ADMINISTRATIVE, COMMERCIAL, FINANCIAL, MANAGERIAL OR SUPERVISORY PURPOSES; SYSTEMS OR METHODS SPECIALLY ADAPTED FOR ADMINISTRATIVE, COMMERCIAL, FINANCIAL, MANAGERIAL OR SUPERVISORY PURPOSES, NOT OTHERWISE PROVIDED FOR
- G06Q30/00—Commerce
- G06Q30/018—Certifying business or products
- G06Q30/0185—Product, service or business identity fraud
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Abstract
The invention discloses a kind of using lilac note as commodity recognizes the method and its application of feature.Cloves flower essential oil is added in ink with special ratios, then ink is sprayed into commodity packaging surface impressing pattern or text, later again to printing area overlay film to save fragrance.Product is marked using lilac note, authenticity of products is determined using smell combination chemical feature constituent analysis.For consumer, it can directly open overlay film and smell to debate by fragrance and carry out the true and false discrimination of product, in addition can carry out qualitative and quantitative analysis to fragrance component and accurately to determine the true and false.A kind of new approach is provided for package anti-counterfeiting, increases the fraud difficulty of personator.Whether the application of this method can also identify the storage environments of commodity, time qualified.Operation of the present invention is easy, low in cost, has application prospect well.
Description
Technical field
The invention belongs to anti-counterfeiting technology fields, are specifically related to a kind of by assigning perfume to commodity outer packing and with fourth
Method of the fragrant flower note as commodity identification feature.Meanwhile that the invention further relates to this method is specific in commodity counterfeit prevention, discrimination
Using.
Background technique
Fraud fake traffic and AIDS, drugs, environmental pollution become the big public hazards of Century Square side by side.Currently, world community man
Commodity personation activity is very rampant, and by taking particularly for tobacco items commodity as an example, the degree for being imitated or palming off is very serious.According to statistics, 2015
False smoke quantity is increased sharply after year, China's cigarette proposed tax favorable price, and 2016 up to 45.68%, false smoke not only led the majority of consumers into a trap, damage
Evil consumer legitimate right, also seriously endangers the normal development of cigarette industry, causes huge tax to be lost, national interests are suffered huge
Big loss.
Existing commodity counterfeit prevention means except by trade mark, production technology etc. as judge commercial articles true and false according in addition to, for
Commodity outer packing can also using antiforge laser holographic, colored fiber is anti-fake, miniature printing is anti-fake, photochromatic printing ink is anti-fake, superfine wire
The technologies such as anti-fake, two-dimension code anti-counterfeit, but these anti-counterfeiting technologies are also gradually grasped by fake producer, and the anti-fake effect of discrimination is more and more not
It is fully up to expectations.With the development of science and technology, the research of anti-counterfeiting technology has been directed to contemporary optics, analytical chemistry, computer and more matchmakers
Body technique, computer image recognition technology, electromagnetic induction technology, biotechnology, genetic engineering, Modern administrology etc. are multiple
Important subject gradually develops into a new frontier science.But in the prior art there is not yet being recognized using note as commodity
The method of feature, and the relevant report of commodity counterfeit prevention discrimination is carried out accordingly.
Summary of the invention
In view of the above-mentioned deficiencies in the prior art, it is an object of the present invention to provide it is a kind of using lilac note to commodity outer packing
Perfume is assigned, and recognizes the method for feature using the detected by scent of the note as commodity.
The object of the invention is also to provide concrete application of the method in commodity counterfeit prevention, discrimination.
The purpose of the present invention is achieved by the following technical programs.
Unless otherwise indicated, percentage of the present invention is mass percent.
A method of recognizing feature using lilac note as commodity, it is characterised in that: by cloves flower essential oil according to print
The 1%~10% of brush ink quality mixes, then with gained mixture in commodity packaging surface impressing pattern or text, Zhi Houzai
To printing area overlay film to save fragrance.
The cloves flower essential oil, be by steam distillation from the dry flower of Myrtaceae family cloves
The essential oil of acquisition has pungent fragrant and eugenol characteristic perfume.
The Myrtaceae family cloves be myrtle, main product in Indonesia, India, Madagascar and
The ground such as Vietnam and the Hainan in China, Guangdong, Guangxi, Yunnan.
The steam distillation specifically: the cloves bud for weighing crushing is fitted into flask, is filled in steam distillation
It is distilled in setting, until stopping heating when no grease and solution clear, collecting distillate addition sodium chloride makes solution
Saturation is added after appropriate ether mixes well and adds appropriate anhydrous sodium sulfate then in ether layer with separatory funnel removing water layer
Sufficiently water suction, and it is filtered with filter paper into round-bottomed flask, round-bottomed flask is set into water-bath recycling ether, obtains essential oil.
The printing area is the complete outer surface of commodity packaging or any position of commodity packaging outer surface.
It is described to printing area overlay film, specifically: printing area is coated using transparent membrane, makes printing area and outer
Portion's air exclusion, but transparent membrane is not adhered with printing area.
The transparent membrane is polypropylene (PP), polyvinyl chloride (PVC) or Biaxially oriented polypropylene (BOPP) film.
It is above-mentioned that application of the method for feature in commodity counterfeit prevention, discrimination is recognized using lilac note as commodity.
The application specifically: after consumer buys commodity, the overlay film that need to only open printing area carries out smelling, has bright
Aobvious characteristic perfume is regular and in the shelf-life conforming articls；Without obvious characteristic fragrance or fragrance it is abnormal can principium identification
For counterfeit goods or non-conformity article.
The application specifically: in order to more accurately identify commodity true and false, commodity production enterprise is to used in it
Cloves flower essential oil carries out chromatogram image analysis according to iso standard, specifies the type and accounting numberical range of its main chemical compositions,
As quality judging quota；When discerning the false from the genuine, the overpack of commodity to be identified is taken, random cropping printing area is as analysis sample
Product, carry out chromatogram image analysis, when the type of main chemical compositions be not inconsistent or the accounting numerical value of main chemical compositions in it is any
One exceeds judging quota range, then determines the commodity for counterfeit goods or non-conformity article.
The foundation iso standard carries out chromatogram image analysis, specifically: according to ISO 11024-1 (essential oil-chromatogram
As General Requirement-part 1: the foundation of chromatogram image in standard) and ISO11024-2 (essential oil-chromatogram image is general to be wanted
Seek-part 2: essential oil chromatogram image using) carry out chromatogram image analysis.
Compared with the existing technology, the invention has the following advantages that
1, the present invention is pioneering using lilac note as the identification feature of commodity, it is different from the past need to rely on vision or
The discrimination method of tactile, the present invention recognize commercial articles true and false by the quantitative combined method of smell and fragrance component, for packet
Fill it is anti-fake a kind of new approach is provided, increase the fraud difficulty of personator.
2, this method is applied to commodity counterfeit prevention, and two methods can be quantified by smell and fragrance component and are carried out to commercial articles true and false
Identification.Consumer's purchase or when commodity in use, by smelling, whether there is or not obvious characteristic fragrance to distinguish commodity.Manufacturing enterprise is special
Appraisal organization, commercial quality can be distinguished by the qualitative, quantitative that chromatography component is analyzed, to effectively realize commodity true and false
Differentiation, improve the accuracy of identification.
3, the application of this method can not only effectively judge commodity true and false, can also identify storage environment, the time of commodity
It is whether qualified.
4, operation of the present invention is easy, low in cost, and identification is convenient, accurate.
Detailed description of the invention
Fig. 1 is the flow diagram that commodity discrimination is carried out using the method for the present invention；
Fig. 2 is the total ion chromatogram of cloves bud essential oil described in embodiment 5.
Specific embodiment
The present invention is described in further detail with reference to the accompanying drawings and examples, but drawings and examples are not pair
The restriction of technical solution of the present invention.It is all based on present invention teach that made variation or equivalent replacement, should belong to the present invention
Protection scope.
Embodiment 1
Identification feature using lilac note as cigarette packaging strip box.
1, the essential oil obtained from the dried flower flower bud of Myrtaceae family cloves with steam distillation, weighs 50g powder
Broken drying cloves bud particle is fitted into 250mL flask, distillation 9-10h is carried out in steam distillation device, until no oil
Stop heating when shape object and solution clear.Sodium chloride, which is added, in the distillate of collection is saturated solution, and appropriate ether is added and fills
Remove water layer with separatory funnel after point mixing adds appropriate anhydrous sodium sulfate sufficiently to absorb water then in ether layer, and with filter paper mistake
Round-bottomed flask is filtered, round-bottomed flask is set into 50 DEG C of recycling ether of water-bath, obtains essential oil.Essential oil is smelt by professional debates, really
Its fixed note is characterized by pungent fragrant and eugenol characteristic perfume.
2, the chromatogram image of clove bud oil is analyzed according to ISO 11024-1 and ISO 11024-2 standard, chemistry
Composition detection result such as table 1.
1 clove bud oil chemical composition analysis result (unit: %) of table
3, clove bud oil is added in ink with 1% additive amount, then ink is sprayed to the two of cigarette packaging strip box
The specific regions such as code or cigarette trade mark text are tieed up, coating processing then is carried out with polypropylene (PP) film to spraying area.
4, cigarette package: product is obtained according to normal production of cigarettes flow package.
5, cigarette barrel is stored 90 days under 30 DEG C of temperature, 60% environment of relative humidity, is randomly selected 10 products, is torn
The overlay film on barrel surface, smelling discovery have apparent pungent fragrant and eugenol characteristic perfume.
Embodiment 2
Embodiment 1 is repeated, has following difference: clove bud oil is added in ink with 10% additive amount；In cigarette
The outer surface of package barrel box all uses the fragrance oil ink print picture and text, is then covered with Biaxially oriented polypropylene (BOPP) film
Film；Cigarette barrel is stored 1 year under 25 DEG C of temperature, 40% environment of relative humidity, is randomly selected 10 products, is torn barrel table
The overlay film in face, smelling discovery still have apparent pungent fragrant and eugenol characteristic perfume.
Embodiment 3
Embodiment 1 is repeated, has following difference: clove bud oil is added in ink with 10% additive amount；In cigarette
The outer surface of package barrel box all uses the fragrance oil ink print picture and text, then uses polyvinyl chloride (PVC) film overlay film；Tobacco shred
Box is stored 1 year under 40 DEG C of temperature, 80% environment of relative humidity, is randomly selected 10 products, is torn the overlay film on barrel surface,
Smelling discovery still has apparent pungent fragrant and eugenol characteristic perfume.
Embodiment 4
1 products obtained therefrom of embodiment is launched, and opens overlay film after consumer's purchase, can be with smelling to apparent pungent fragrant and fourth
The characteristic perfume of fragrant phenol, if not having pungent fragrant and eugenol feature note, Huo Zheyou without overlay film, or after tearing overlay film
Other miscellaneous gas then can determine that purchased product is false.
Embodiment 5
The like products for randomly choosing different channel sales from the market takes packaging material to carry out true and false discrimination: tearing first
It opens overlay film and debates the characteristic perfume whether product has eugenol by smelling.For the product with approximation characteristic fragrance, into one
Step cuts flavoring overlay film region as analysis sample, using Agilent7890A/5975C gas chromatograph-mass spectrometer (GC-MS)+automatic
Sample injector analyzes sample.
Chromatographic condition are as follows: RXi-5sil MS quartz capillary column (60m × 0.25mm × 0.25 μm), carrier gas are that helium is (pure
Degree is 99.999%) flow velocity: 1.0mL/min.Temperature program: 60 DEG C of initial temperature, 6min is kept；With the rate liter of 3 DEG C/min
Temperature is to 180 DEG C；230 DEG C are warming up to the rate of 10 DEG C/min again, keeps 10min.Injector temperature: 250 DEG C, sample volume: 1.0
μ L, split ratio: 10:1, solvent delay 6min.
Mass Spectrometry Conditions are as follows: ion source: electricity bombardment ionization source (EI)；Ion source temperature: 230 DEG C；Quadrupole rod temperature: 150 DEG C；
Ionizing energy: 70eV；Transmission line temperature: 280 DEG C；Scanning range (m/z): 40~450, mass spectrum retrieves picture library: Nist11 composes library.
Total ion chromatogram obtained by test sample, which is shown in after Fig. 2, result are retrieved using Nist11, combines ESO fragrant
Smart retention index compares qualitative, and the percentage contents of chemical component in clove bud oil are calculated in area normalization,
27 compounds have been determined altogether, have accounted for chemical component 96.913% in clove bud oil.Wherein eugenol, β-stone in clove bud oil
Bamboo alkene, 3 main feature compounds contents of acetic acid cloves ester such as table 2, by the way that compared with 1 data of table, 3 main compounds are examined
Out, and its content is within the scope of standard requirements, can determine that the product is true.
3 main feature compounds contents in 2 clove bud oil of table
Embodiment 6
Embodiment 5 is repeated, there is following difference:
Eugenol, β-carypohyllene, 3 main feature compounds contents of acetic acid cloves ester such as table 3 in sample, by comparing,
3 main feature compounds of the clove bud oil detect, but β-carypohyllene and acetic acid cloves ester content be not in standard requirements model
In enclosing.Comprehensive scent, which is smelt, debates result, main chemical compositions and content (table 3) analysis as a result, can determine that the product is false.
3 main feature compounds contents in 3 clove bud oil of table
Claims (10)
1. a kind of method for recognizing feature using lilac note as commodity, it is characterised in that: by cloves flower essential oil according to printing
The 1%~10% of ink quality mixes, right again later then with gained mixture in commodity packaging surface impressing pattern or text
Printing area overlay film is to save fragrance.
2. the method according to claim 1 for recognizing feature using lilac note as commodity, it is characterised in that: described
Cloves flower essential oil is the essential oil obtained from the dry flower of Myrtaceae family cloves by steam distillation, tool
There is pungent fragrant and eugenol characteristic perfume.
3. the method according to claim 2 for recognizing feature using lilac note as commodity, which is characterized in that described
Steam distillation specifically: the cloves bud for weighing crushing is fitted into flask, is distilled in steam distillation device, until
Do not have to stop heating when grease and solution clear, collecting distillate addition sodium chloride is saturated solution, and appropriate second is added
Ether mix well after with separatory funnel remove water layer add appropriate anhydrous sodium sulfate sufficiently to absorb water then in ether layer, and with filter
Paper is filled into round-bottomed flask, and round-bottomed flask is set water-bath recycling ether, obtains essential oil.
4. the method according to claim 1 for recognizing feature using lilac note as commodity, it is characterised in that: described
Printing area is the complete outer surface of commodity packaging or any position of commodity packaging outer surface.
5. the method according to claim 1 for recognizing feature using lilac note as commodity, it is characterised in that: described
To printing area overlay film specifically: coated to printing area using transparent membrane, completely cut off printing area and outside air, but thoroughly
Bright film is not adhered with printing area.
6. the method according to claim 5 for recognizing feature using lilac note as commodity, it is characterised in that: described
Transparent membrane is polypropylene, polyvinyl chloride or bidirectional stretching polypropylene film.
7. method the answering in commodity counterfeit prevention, discrimination described in claim 1 for recognizing feature using lilac note as commodity
With.
8. application according to claim 7, it is characterised in that: after consumer buys commodity, open the overlay film of printing area
Smelling is carried out, have obvious characteristic fragrance is regular and in the shelf-life conforming articls；It is different without obvious characteristic fragrance or fragrance
It is normal can principium identification be counterfeit goods or non-conformity article.
9. application according to claim 7, it is characterised in that: as commodity production enterprise to cloves flower essential oil used in it
Chromatogram image analysis is carried out according to iso standard, the type and accounting numberical range of its main chemical compositions is specified, is commented as quality
Sentence index；When discerning the false from the genuine, the overpack of commodity to be identified is taken, random cropping printing area carries out color as analysis sample
Compose image analysis, when the type of main chemical compositions be not inconsistent or the accounting numerical value of main chemical compositions in any one exceed
Judging quota range then determines the commodity for counterfeit goods or non-conformity article.
10. application according to claim 9, it is characterised in that: the foundation iso standard carries out chromatogram image analysis,
Specifically: according to ISO 11024-1 essential oil-chromatogram image General Requirement-part 1: the foundation of chromatogram image in standard；And
ISO11024-2 essential oil-chromatogram image General Requirement-part 2: essential oil chromatogram image utilizes progress chromatogram image analysis.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201810763381.7A CN109146509A (en) | 2018-07-12 | 2018-07-12 | A kind of method and its application recognizing feature using lilac note as commodity |
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| CN201810763381.7A CN109146509A (en) | 2018-07-12 | 2018-07-12 | A kind of method and its application recognizing feature using lilac note as commodity |
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| CN109146509A true CN109146509A (en) | 2019-01-04 |
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Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1244275A (en) * | 1996-12-20 | 2000-02-09 | 联邦印刷有限公司 | Value and security product with at least one security characteristic, method for its production and method for detection of security characteristics |
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- 2018-07-12 CN CN201810763381.7A patent/CN109146509A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1244275A (en) * | 1996-12-20 | 2000-02-09 | 联邦印刷有限公司 | Value and security product with at least one security characteristic, method for its production and method for detection of security characteristics |
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Application publication date: 20190104 |