CN109116461A - A kind of DUV wide spectrum is without the glue polarizer - Google Patents

A kind of DUV wide spectrum is without the glue polarizer Download PDF

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Publication number
CN109116461A
CN109116461A CN201811103430.0A CN201811103430A CN109116461A CN 109116461 A CN109116461 A CN 109116461A CN 201811103430 A CN201811103430 A CN 201811103430A CN 109116461 A CN109116461 A CN 109116461A
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CN
China
Prior art keywords
glue
bbo
polarizer
duv
bbo crystal
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201811103430.0A
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Chinese (zh)
Inventor
张妹玉
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Minjiang University
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Minjiang University
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Publication date
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Priority to CN201811103430.0A priority Critical patent/CN109116461A/en
Publication of CN109116461A publication Critical patent/CN109116461A/en
Pending legal-status Critical Current

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    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00Optical elements other than lenses
    • G02B5/30Polarising elements
    • G02B5/3025Polarisers, i.e. arrangements capable of producing a definite output polarisation state from an unpolarised input state
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00Optical elements other than lenses
    • G02B5/30Polarising elements
    • G02B5/3083Birefringent or phase retarding elements

Abstract

The present invention relates to a kind of DUV wide spectrums without the glue polarizer, including the first bbo crystal, the second bbo crystal and the intermediate-index layer that two bbo crystal joint places are arranged in;The bbo crystal is cut by certain angle, and the optical axis of bbo crystal is parallel to incident light surface, and the optical axis of two panels BBO is parallel to each other;The intermediate-index layer respectively with two bbo crystal optical contants.The present invention is operable between wavelength 220nm-1000nm, and polarised light extinction ratio is greater than 30dB.

Description

A kind of DUV wide spectrum is without the glue polarizer
Technical field
The present invention relates to polarizer design field, especially a kind of DUV wide spectrum is without the glue polarizer.
Background technique
With the development of Modern Optics Technology, various polarizing devices apply more and more, common polarizing devices There is Glan-Thomson, Glan-Taylor, Glan-laser, the polarizing device of glass mould and plastics base, glass mould and plastic device disappear Light ratio difference, it is poor to the resistivity of high power laser light and ultraviolet light, and the crystalline material that Glan prism generallys use has YVO4Or Natural Iceland spar composition, although can work in very wide wave-length coverage as between 400nm-2000nm, due to material spy Property, it is poor less than 350nm or less light transmission in ultraviolet band, restricted from ultraviolet band is applied to, although also having based on BBO The Glan prism of material, but be typically only capable to reach in one section of wave-length coverage of ultraviolet very little, having no can be used in 220nm- The Glan prism of 1000nm range.
Summary of the invention
In view of this, the purpose of the present invention is to propose to a kind of DUV wide spectrums without the glue polarizer, it is operable with wavelength 220nm- Between 1000nm, polarised light extinction ratio is greater than 30dB.
The present invention is realized using following scheme: a kind of DUV wide spectrum is without the glue polarizer, including the first bbo crystal, second Bbo crystal and the intermediate-index layer that two bbo crystal joint places are set;The bbo crystal is cut by certain angle, And the optical axis of bbo crystal is parallel to incident light surface, and the optical axis of two panels BBO is parallel to each other;The intermediate-index layer difference With two bbo crystal optical contants.
Preferably, guaranteeing that deep ultraviolet has good light transmission without organic matter glue between two bbo crystals of the invention.
Further, the intermediate-index layer uses SiO2Material, Mgf2Material or fused quartz glass material, light transmission Wave band is 215nm-2000nm.
Further, the intermediate-index layer is SiO2Film layer or Mgf2Film layer.
Further, the intermediate-index layer fused quartz glass layer good using deep ultraviolet through performance, transmission region From 215nm-2000nm;The fused quartz glass layer with a thickness of 1-10000um.
Further, incident interface o light total reflection of the DUV wide spectrum without the glue polarizer, e light transmission, light are incident Angle is 62.48 degree of -64.37 degree, i.e., prism cutting angle is 27.52 degree of -25.63 degree, and wherein transmission region is 220nm- 1000nm, transmitance are greater than 50%, and extinction ratio is 1000:1 between wavelength 220nm-970nm.
Further, the bbo crystal uses α-BBO material or β-BBO material, transmission region 215nm- 2000nm。
Further, uv-curable glue or heat cure are used after the intermediate-index layer and two bbo crystal optical contants Glue sealing, so that optical cement interface and air insulated, while the bond strength between this auxiliary glue enhancing two panels.
Further, the face that first bbo crystal is contacted with the second bbo crystal with air, is coated with the SiO of single layer2Film, Mgf2The composite multilayer membrane of film or both composition, realizes the broadband anti-reflection film from 215nm-1000nm.
Particularly, the present invention is narrow-minded in vacuum condition or air conditions decentralization, does not pollute to optical surface.
Preferably, the present invention uses BBO, ultraviolet fused quartz glass or Mgf2Crystal makes 220nm-970nm optical polarization The polarizer.Polarizer type is Glan-Thomson, and BBO is optical birefringence crystal, with traditional CaCO3,YVO4Compared at DUV sections With translucency, while having biggish o light e optical index poor.BBO is designed as triangular prism, cutting angle is taken to make just BBO and fused quartz or other optical materials interface o light total reflection, e light transmission, while with second piece of same BBO Prism compensation The e light deflection of light due to caused by refraction by prism.Binderless binding technology is used between two pieces of prisms, a piece of UV grade of optical cement melts Quartz glass, full optical path use spectral transmission in the full spectrum of 220nm-970nm without organic composition glue.
Compared with prior art, the invention has the following beneficial effects: the operation wavelength of the polarizer of the present invention is in 220nm- Between 970nm, polarised light extinction ratio is greater than 30dB.
Detailed description of the invention
Fig. 1 is structural representation Fig. 1 of the embodiment of the present invention.
Fig. 2 is structural representation Fig. 2 of the embodiment of the present invention.
Fig. 3 is BBO of the embodiment of the present invention and fused quartz glass refractive index schematic diagram.
Fig. 4 is o light and e light total reflection angle schematic diagram of BBO of the embodiment of the present invention material relative to melting quartz glass.
Fig. 5 is the surface BBO of embodiment of the present invention Mgf2 single layer anti reflective coating reflectivity schematic diagram.
Fig. 6 is DUV of embodiment of the present invention wide spectrum without glue polarizer o light transmission rate schematic diagram.
Fig. 7 is DUV of embodiment of the present invention wide spectrum without glue polarizer e light transmission rate schematic diagram.
Fig. 8 is DUV of embodiment of the present invention wide spectrum without glue polarizer extinction ratio schematic diagram.
Specific embodiment
The present invention will be further described with reference to the accompanying drawings and embodiments.
It is noted that described further below be all exemplary, it is intended to provide further instruction to the application.Unless another It indicates, all technical and scientific terms used herein has usual with the application person of an ordinary skill in the technical field The identical meanings of understanding.
It should be noted that term used herein above is merely to describe specific embodiment, and be not intended to restricted root According to the illustrative embodiments of the application.As used herein, unless the context clearly indicates otherwise, otherwise singular Also it is intended to include plural form, additionally, it should be understood that, when in the present specification using term "comprising" and/or " packet Include " when, indicate existing characteristics, step, operation, device, component and/or their combination.
A kind of DUV wide spectrum is present embodiments provided without the glue polarizer, including the first bbo crystal, the second bbo crystal, with And the intermediate-index layer of two bbo crystal joint places is set;The bbo crystal is cut by certain angle, and bbo crystal Optical axis be parallel to incident light surface, the optical axis of two panels BBO is parallel to each other;The intermediate-index layer respectively with two BBO crystalline substances Body optical contant.
Preferably, guaranteeing that deep ultraviolet has good light transmission without organic matter glue between two bbo crystals of the invention.
In the present embodiment, the intermediate-index layer uses SiO2Material, Mgf2Material or fused quartz glass material, Transmission region is 215nm-2000nm.
In the present embodiment, the intermediate-index layer is SiO2Film layer or Mgf2Film layer.
In the present embodiment, the intermediate-index layer fused quartz glass layer good using deep ultraviolet through performance, light transmission Wave band is from 215nm-2000nm;The fused quartz glass layer with a thickness of 1-10000um.
In the present embodiment, incident interface o light total reflection of the DUV wide spectrum without the glue polarizer, e light transmission, light Incident angle is 62.48 degree of -64.37 degree, i.e. prism cutting angle is 27.52 degree of -25.63 degree, and wherein transmission region is 220nm-1000nm, transmitance is greater than 50%, extinction ratio > 1000:1, operation wavelength 220nm-970nm.
In the present embodiment, the bbo crystal uses α-BBO material or β-BBO material, transmission region 215nm- 2000nm。
In the present embodiment, uv-curable glue or heat are used after the intermediate-index layer and two bbo crystal optical contants Solidification glue sealing, so that optical cement interface and air insulated, while the bond strength between this auxiliary glue enhancing two panels.
In the present embodiment, the face that first bbo crystal is contacted with the second bbo crystal with air, is coated with single layer SiO2Film, Mgf2The composite multilayer membrane of film or both composition, realizes the broadband anti-reflection film from 215nm-1000nm.
Particularly, the present embodiment is narrow-minded in vacuum condition or air conditions decentralization, does not pollute to optical surface.
Preferably, the present invention uses BBO, ultraviolet fused quartz glass or Mgf2Crystal makes 220nm-970nm optical polarization The polarizer.Polarizer type is Glan-Thomson, and BBO is optical birefringence crystal, with traditional CaCO3,YVO4Compared at DUV sections With translucency, while having biggish o light e optical index poor.BBO is designed as triangular prism, cutting angle is taken to make just BBO and fused quartz or other optical materials interface o light total reflection, e light transmission, while with second piece of same BBO Prism compensation The e light deflection of light due to caused by refraction by prism.Binderless binding technology is used between two pieces of prisms, a piece of UV grade of optical cement melts Quartz glass, full optical path use spectral transmission in the full spectrum of 220nm-970nm without organic composition glue.
Particularly, in the present embodiment, optical axis is parallel to each other between first bbo crystal optical axis and second bbo crystal As shown in Figure 1, the optical axis between two panels BBO is parallel to each other, it is parallel with the plane of incidence to can be used optical axis, the normal direction side on incident inclined-plane Into the plane formed with light transmission direction, as shown in Figure 1;Or using on optical axis and incident inclined-plane with normal orientation and light Transmission direction forms unilateral vertical, as shown in Figure 2.It therebetween is the good fused quartz glass of UV transmission;BBO and molten stone It is combined between English glass using optical cement.
In framework shown in Fig. 1, non-polarized light enters crystal, and (polarization state is perpendicular to incident light and light for o light on interface The plane of axis composition) it is reflected, go out to project crystal from side;E light penetrates interface, and into other one piece of crystal, radiation direction is mended It repays to original parallel direction, polarization state is parallel with optical axis direction.
Similarly shown in 2 in framework, polarization state and optical axis direction exiting parallel, perpendicular to plane of incidence.
In the present embodiment, BBO has excellent UV transmission range, still has excellent light transmission at 200nm; And UV grade fused quartz has excellent light transmission using synthesis fused quartz, can achieve 150nm or so still with excellent Light transmission.α-BBO is used as birefringece crystal simultaneously, and o light, e light and fused quartz glass refractive index are as shown in Figure 3.The e light of BBO Refractive index with wavelength from the increase of 200-2000nm its value between 1.7-1.54, o optical index changes between 1.9-1.64, Fused quartz glass is between 1.49-1.46.In each wave band, there are nFused quartz<ne<no
In the present embodiment, as shown in figure 4, for bbo crystal o light and e the light angle of total reflection at different wavelengths it Between there are a fixed difference, when the angle of reflection of o light changes from 200nm-2000nm, increase to 63.5 ° from 52 °;E light it is complete When angle of reflection increases from 200nm-2000nm, increase to 74.1 ° from 61 °.It is appropriate to choose cutting angle and wave-length coverage, o light can be made Under the premise of total reflection, e light is not totally reflected, while incident angle is close to Brewster's angle, can keep one it is higher Transmitance;To which realization is polarized function and obtains high polarisation extinction coefficient.Wave band is chosen between 220nm-970nm, is cut Chamfer degree is between 27.52-25.63 ° shown in θ as shown in figure 1, thus realize 220nm-970nm it is good be polarized effect.
In the present embodiment, as shown in figure 5, since the e optical index of BBO is between 1.46-1.5, o light 1.9-1.64 table Face reflection will cause biggish smooth reflection loss.It is coated with single layer anti reflective coating in the crystal plane of incidence and light emission face, central wavelength is excellent Change and go out in the light transmittance lower 230nm that compares, reduces loss, for incident wavelength in 230nm, surface reflectivity reaches < 1.5% Level.
In the present embodiment, as shown in fig. 6, under the premise of having outgoing and plane of incidence anti-reflection film, since cutting angle exists Under the premise of being totally reflected o light entrance crystal and air inclined-plane, e light makes e light keep higher light transmission close to Brewster's angle Rate, as shown in the figure from 240nm-980nm, e light transmittance can be close to e light transmittance between 90%, 230nm-240nm and be greater than E light transmission rate is greater than 50% between 80%, 220nm-230nm.
In the present embodiment, as shown in fig. 7, the o light transmission simulated, transmissivity is small between 220nm-980nm Transmissivity is less than 1% between 0.04%, 970nm-1000nm.In the device of actual fabrication, between 220nm-970nm, o Light transmittance < 0.1%.
In the present embodiment, as shown in figure 8, between 220nm-970nm, extinction ratio > 1000:1 has excellent be polarized Performance.Between 220nm-940nm, extinction ratio theoretical value is on 50dB, actually can reach > 40dB.
Particularly, α-bbo crystal is cut into prism first by the present embodiment, as shown in Figures 1 and 2;It is fixed that crystal is carried out again To the C axis direction of crystal being strictly parallel to the plane of incidence, both perpendicular to upper cutting surface as shown in Figure 1, or cutting perpendicular to lateral incision Face is as shown in Figure 2.It is trimmed to using fine grinding direction close at brilliant size, then carries out S1, S2, S3, the optics in the face S4 respectively again Frosted, polishing, make surface reach < λ/10, and the surface accuracy of λ=633nm reaches the surface finish level of American army mark 10-5. Single layer MgF is carried out to the face of S1 and S2 again2Or SiO2Anti-reflection film, central wavelength optimize at 230nm.
Thereafter the fused quartz glass of instrument bevel size dimension carries out frosted, polishing, and surface face shape reaches < λ/10, and λ= The surface accuracy of 633nm, reaches the surface finish level of American army mark 10-5, and thickness can be between 1-10000 μm, in this implementation 1mm thickness is taken in mode.
BBO prism hypotenuse/facet surfaces are contacted in fused quartz glass two sides, two prisms optical axis phase by difference optical cement using optical contant technique Mutually parallel, alignment assembling can deepen ultraviolet adhesive curing to increase air-tightness and being firmly combined property at contact surface;Or it is adopted in side Using plate to be glued at prism side can be to improve firmness as reinforcement.
The foregoing is merely presently preferred embodiments of the present invention, all equivalent changes done according to scope of the present invention patent with Modification, is all covered by the present invention.

Claims (8)

1. a kind of DUV wide spectrum is without the glue polarizer, it is characterised in that: including the first bbo crystal, the second bbo crystal and setting Intermediate-index layer two bbo crystal joint places;The bbo crystal is cut by certain angle, and the optical axis of bbo crystal It is parallel to incident light surface, the optical axis of two panels BBO is parallel to each other;The intermediate-index layer respectively with two bbo crystal optical cements It closes.
2. a kind of DUV wide spectrum according to claim 1 is without the glue polarizer, it is characterised in that: the intermediate-index layer Using SiO2Material, Mgf2Material or fused quartz glass material, transmission region 215nm-2000nm.
3. a kind of DUV wide spectrum according to claim 2 is without the glue polarizer, it is characterised in that: the intermediate-index layer For SiO2Film layer or Mgf2Film layer.
4. a kind of DUV wide spectrum according to claim 2 is without the glue polarizer, it is characterised in that: the intermediate-index layer Using the good fused quartz glass layer of deep ultraviolet through performance, transmission region is from 215nm-2000nm;The fused quartz glass layer With a thickness of 1-10000um.
5. a kind of DUV wide spectrum according to claim 1 is without the glue polarizer, it is characterised in that: the DUV wide spectrum is without glue The incident interface o light total reflection of the polarizer, e light transmission, angle of incidence of light are 62.48 degree of -64.37 degree, i.e. prism cutting angle Degree is 27.52 degree of -25.63 degree, and wherein transmission region is 220nm-1000nm, and transmitance is greater than 50%, in wavelength 220nm- Extinction ratio is 1000:1 between 970nm.
6. a kind of DUV wide spectrum according to claim 1 is without the glue polarizer, it is characterised in that: the bbo crystal uses α- BBO material or-BBO material, transmission region 215nm-2000nm.
7. a kind of DUV wide spectrum according to claim 1 is without the glue polarizer, it is characterised in that: the intermediate-index layer It is sealed with uv-curable glue or heat-curable glue is used after two bbo crystal optical contants, so that optical cement interface and air insulated.
8. a kind of DUV wide spectrum according to claim 1 is without the glue polarizer, it is characterised in that: first bbo crystal with The face that second bbo crystal is contacted with air is coated with the SiO of single layer2Film, Mgf2Film or both composition composite multilayer membrane, realize from The broadband anti-reflection film of 215nm-1000nm.
CN201811103430.0A 2018-09-20 2018-09-20 A kind of DUV wide spectrum is without the glue polarizer Pending CN109116461A (en)

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Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101551484A (en) * 2009-05-08 2009-10-07 福州福特科光电有限公司 Deep ultraviolet ultra-wideband polarizer
CN102096141A (en) * 2010-12-23 2011-06-15 福建福晶科技股份有限公司 Alpha-BBO polarizing prism

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101551484A (en) * 2009-05-08 2009-10-07 福州福特科光电有限公司 Deep ultraviolet ultra-wideband polarizer
CN102096141A (en) * 2010-12-23 2011-06-15 福建福晶科技股份有限公司 Alpha-BBO polarizing prism

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
上海交通大学出版社: "《抗蚀剂及其微细加工技术》", 31 March 1989 *

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Application publication date: 20190101