CN109112859A - A kind of color fixing agent and preparation method thereof for reactive dyeing - Google Patents
A kind of color fixing agent and preparation method thereof for reactive dyeing Download PDFInfo
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- CN109112859A CN109112859A CN201810854128.2A CN201810854128A CN109112859A CN 109112859 A CN109112859 A CN 109112859A CN 201810854128 A CN201810854128 A CN 201810854128A CN 109112859 A CN109112859 A CN 109112859A
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/02—After-treatment
- D06P5/04—After-treatment with organic compounds
- D06P5/08—After-treatment with organic compounds macromolecular
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/38—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using reactive dyes
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/02—After-treatment
- D06P5/04—After-treatment with organic compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/02—After-treatment
- D06P5/04—After-treatment with organic compounds
- D06P5/06—After-treatment with organic compounds containing nitrogen
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/02—After-treatment
- D06P5/10—After-treatment with compounds containing metal
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Abstract
The invention discloses a kind of color fixing agent for reactive dyeing, are made of following parts by weight raw material: high-efficient penetrant, polydimethyl diallyl ammonium chloride, triethylene tetramine, hydroxypropyltrimethylammonium chloride chitosan, Dodecyl Polyoxyethylene Ether, vinylacetate, boric acid, epoxychloropropane, ethyl alcohol, Sodium Polyacrylate, hydroquinone, deionized water, emulsifier, soda ash.The invention also discloses a kind of preparation methods of color fixing agent for reactive dyeing.Colour fixation of the present invention is good, environmentally friendly, pollution-free, and production technology is easy, and production cost is low, and performance is stablized, and is suitable for industrialized production, has a vast market foreground.
Description
Technical field
The invention belongs to field of fine chemical, specifically a kind of color fixing agent and its preparation side for reactive dyeing
Method.
Background technique
Reactive dye are cheap, chromatography is complete, bright in colour, are widely used in cotton fabric dyeing process.Although reactive dye
Reactive group in molecule is easily and fiber is with Covalent bonding together, but color fastness is unsatisfactory.It is in dyeing course, especially
When dye is dark, often occur to make the presence of a large amount of not fixed reactive dye on dyed fabric because dye strength is excessively high, these
Fixed dyestuff is not difficult to remove from dyed fabric, this some dyes will fade in washing process；Meanwhile some activity
It is formed by chemical bond facile hydrolysis between base and fiber, causes wet colour fastness lower.And the color fixing agent of early stage such as color fixing agent Y is first
The product of the reactions such as aldehyde, dicyandiamide and ammonium chloride, although every fastness of product dyed thereby can be improved, there are content of formaldehyde compared with
Height the problems such as being detrimental to health, has not met International Textile requirement.With the continuous expansion of World Textile trade and people
The continuous improvement of people's living standard, environmental consciousness puts forward higher requirements the indexs such as the comfortable of textile, cleaning, safety.
Since the 21th century, to product dyed thereby items fastness, more stringent requirements are proposed for World Textile Market, through fixation
Agent treated product dyed thereby will not only have the jails such as the soaping, wash of certain grade, rub resistance, perspiration resistance, sun-resistant, chlorine-resistant drift
Degree, but also require without formaldehyde, it is nontoxic, do not influence fabric feeling and discoloration etc..Therefore, research meets ecological, environmental protective, Wu Jia
The new reactive dyes of aldehyde are a significant job with color fixing agent.
Summary of the invention
The color fixing agent and preparation method thereof that the purpose of the present invention is to provide a kind of for reactive dyeing, on solving
State the problem of proposing in background technique.
To achieve the above object, the invention provides the following technical scheme:
A kind of color fixing agent for reactive dyeing is made of: high-efficient penetrant 10~20 following parts by weight raw material
Part, 16~20 parts of polydimethyl diallyl ammonium chloride, 15~25 parts of triethylene tetramine, hydroxypropyltrimethylammonium chloride chitosan
11~15 parts, 2~6 parts of Dodecyl Polyoxyethylene Ether, 0.6~2 part of vinylacetate, 3~9 parts of boric acid, epoxychloropropane 10~
14 parts, 16~20 parts of ethyl alcohol, 6~9 parts of Sodium Polyacrylate, 20~24 parts of hydroquinone, 35~45 parts of deionized water, emulsifier 10
~30 parts, 50~100 parts of soda ash.
As a further solution of the present invention: the color fixing agent for reactive dyeing, it is former by following parts by weight
Material composition: 14~18 parts of high-efficient penetrant, 17~19 parts of polydimethyl diallyl ammonium chloride, 18~22 parts of triethylene tetramine,
12~14 parts of hydroxypropyltrimethylammonium chloride chitosan, 3~5 parts of Dodecyl Polyoxyethylene Ether, 1~1.5 part of vinylacetate, boron
5~7 parts of acid, 17~19 parts of ethyl alcohol, 7~8 parts of Sodium Polyacrylate, 21~23 parts of hydroquinone, is gone 11~13 parts of epoxychloropropane
38~42 parts of ionized water, 15~25 parts of emulsifier, 65~85 parts of soda ash.
As a further solution of the present invention: the color fixing agent for reactive dyeing, it is former by following parts by weight
Material composition: 15 parts of high-efficient penetrant, 18 parts of polydimethyl diallyl ammonium chloride, 20 parts of triethylene tetramine, Hydroxyproyl Trimethyl
13 parts of ammonium chloride chitosan, 4 parts of Dodecyl Polyoxyethylene Ether, 1.2 parts of vinylacetate, 6 parts of boric acid, 12 parts of epoxychloropropane,
18 parts of ethyl alcohol, 7.5 parts of Sodium Polyacrylate, 22 parts of hydroquinone, 40 parts of deionized water, 20 parts of emulsifier, 75 parts of soda ash.
A kind of preparation method of the color fixing agent for reactive dyeing, comprising the following steps:
(1) polydimethyl diallyl ammonium chloride is mixed with deionized water, polydimethyl diallyl ammonium chloride is made
Solution；Boric acid is mixed with deionized water, boric acid solution is made；Vinylacetate is mixed with deionized water, acetic acid second is made
Enester solution；
(2) by above-mentioned high-efficient penetrant, triethylene tetramine, hydroxypropyltrimethylammonium chloride chitosan, lauryl alcohol polyoxy
Vinethene, epoxychloropropane, Sodium Polyacrylate, hydroquinone, deionized water and soda ash mixing, are warming up to 76 degrees Celsius, and
Stir process 20min is stirred at this temperature, vinyl acetate solution is then added dropwise while stirring, drips latter near 60 DEG C and is added
Enter boric acid solution, then 50 DEG C at a temperature of stir 30min, mixed liquor A；
(3) polydimethyl diallyl ammonium chloride solution is added in the mixed liquor A in step (2), is heated to 95~99
DEG C, and 55~60min is kept at this temperature, it is then ultrasonically treated, the time of ultrasonic treatment is 18~30min, is obtained
Mixed liquid B；
(4) ethyl alcohol and emulsifier are added in the mixed liquid B in step (3), after vacuum distillation, obtains viscous liquid C；
(5) vacuumize process is carried out to the viscous liquid C, then is obtained after being dried described for reactive dyeing
Color fixing agent.
As a further solution of the present invention: in step (1), polydimethyl diallyl ammonium chloride and deionized water are prepared
At the polydimethyl diallyl ammonium chloride solution of mass content 28%.
As a further solution of the present invention: in step (1), boric acid is configured to the boron of mass content 40% with deionized water
Acid solution.
As a further solution of the present invention: in step (1), vinylacetate and deionized water are configured to mass content
32% vinyl acetate solution.
As a further solution of the present invention: in step (3), ultrasonic power 1000W, ultrasonic temperature is 74~82 DEG C.
A kind of application for the color fixing agent of reactive dyeing in printing and dyeing.
Compared with prior art, the beneficial effects of the present invention are:
The present invention is applied for fabric surface, can improve the surface nature of fabric, is improved printing quality, is especially substantially mentioned
The water-resistance of high fabric solves the problems, such as that color fixing agent hydrophobicity is poor.Color fixing agent of the invention can significantly improve the superficiality of fabric
Matter especially greatly improves fabric and meets color density value after water.Colour fixation of the present invention is good, environmentally friendly, pollution-free, production technology letter
Just, production cost is low, and performance is stablized, and is suitable for industrialized production, has a vast market foreground.
Specific embodiment
Technical solution of the present invention will be clearly and completely described below, it is clear that described embodiment is this hair
Bright a part of the embodiment, instead of all the embodiments.Based on the embodiments of the present invention, those of ordinary skill in the art are not having
Every other embodiment obtained under the premise of creative work is made, shall fall within the protection scope of the present invention.
Embodiment 1
A kind of color fixing agent for reactive dyeing is made of following parts by weight raw material: 10 parts of high-efficient penetrant gathers
16 parts of dimethyl diallyl ammonium chloride, 15 parts of triethylene tetramine, 11 parts of hydroxypropyltrimethylammonium chloride chitosan, lauryl alcohol are poly-
It is 2 parts of ethylene oxide ether, 0.6 part of vinylacetate, 3 parts of boric acid, 10 parts of epoxychloropropane, 16 parts of ethyl alcohol, 6 parts of Sodium Polyacrylate, right
Benzenediol 20,35 parts of deionized water, 10 parts of emulsifier, 50 parts of soda ash.
A kind of preparation method of the color fixing agent for reactive dyeing, comprising the following steps:
(1) polydimethyl diallyl ammonium chloride is mixed with deionized water, polydimethyl diallyl ammonium chloride is made
Solution；Boric acid is mixed with deionized water, boric acid solution is made；Vinylacetate is mixed with deionized water, acetic acid second is made
Enester solution；
(2) by above-mentioned high-efficient penetrant, triethylene tetramine, hydroxypropyltrimethylammonium chloride chitosan, lauryl alcohol polyoxy
Vinethene, epoxychloropropane, Sodium Polyacrylate, hydroquinone, deionized water and soda ash mixing, are warming up to 76 degrees Celsius, and
Stir process 20min is stirred at this temperature, vinyl acetate solution is then added dropwise while stirring, drips latter near 60 DEG C and is added
Enter boric acid solution, then 50 DEG C at a temperature of stir 30min, mixed liquor A；
(3) polydimethyl diallyl ammonium chloride solution is added in the mixed liquor A in step (2), is heated to 95 DEG C, and
55min is kept at this temperature, is then ultrasonically treated, and the time of ultrasonic treatment is 18min, obtains mixed liquid B；
(4) ethyl alcohol and emulsifier are added in the mixed liquid B in step (3), after vacuum distillation, obtains viscous liquid C；
(5) vacuumize process is carried out to the viscous liquid C, then is obtained after being dried described for reactive dyeing
Color fixing agent.
In step (1), polydimethyl diallyl ammonium chloride is configured to the poly- diformazan of mass content 28% with deionized water
Base diallyl ammonium chloride solution.
In step (1), boric acid is configured to the boric acid solution of mass content 40% with deionized water.
In step (1), vinylacetate is configured to the vinyl acetate solution of mass content 32% with deionized water.
In step (3), ultrasonic power 1000W, ultrasonic temperature is 74 DEG C.
A kind of application for the color fixing agent of reactive dyeing in printing and dyeing.
Embodiment 2
A kind of color fixing agent for reactive dyeing is made of following parts by weight raw material: 14 parts of high-efficient penetrant gathers
17 parts of dimethyl diallyl ammonium chloride, 18 parts of triethylene tetramine, 12 parts of hydroxypropyltrimethylammonium chloride chitosan, lauryl alcohol are poly-
3 parts of ethylene oxide ether, 1 part of vinylacetate, 5 parts of boric acid, 11 parts of epoxychloropropane, 17 parts of ethyl alcohol, 7 parts of Sodium Polyacrylate, to benzene
21 parts of diphenol, 38 parts of deionized water, 15 parts of emulsifier, 65 parts of soda ash.
A kind of preparation method of the color fixing agent for reactive dyeing, comprising the following steps:
(1) polydimethyl diallyl ammonium chloride is mixed with deionized water, polydimethyl diallyl ammonium chloride is made
Solution；Boric acid is mixed with deionized water, boric acid solution is made；Vinylacetate is mixed with deionized water, acetic acid second is made
Enester solution；
(2) by above-mentioned high-efficient penetrant, triethylene tetramine, hydroxypropyltrimethylammonium chloride chitosan, lauryl alcohol polyoxy
Vinethene, epoxychloropropane, Sodium Polyacrylate, hydroquinone, deionized water and soda ash mixing, are warming up to 76 degrees Celsius, and
Stir process 20min is stirred at this temperature, vinyl acetate solution is then added dropwise while stirring, drips latter near 60 DEG C and is added
Enter boric acid solution, then 50 DEG C at a temperature of stir 30min, mixed liquor A；
(3) polydimethyl diallyl ammonium chloride solution is added in the mixed liquor A in step (2), is heated to 96 DEG C, and
56min is kept at this temperature, is then ultrasonically treated, and the time of ultrasonic treatment is 20min, obtains mixed liquid B；
(4) ethyl alcohol and emulsifier are added in the mixed liquid B in step (3), after vacuum distillation, obtains viscous liquid C；
(5) vacuumize process is carried out to the viscous liquid C, then is obtained after being dried described for reactive dyeing
Color fixing agent.
In step (1), polydimethyl diallyl ammonium chloride is configured to the poly- diformazan of mass content 28% with deionized water
Base diallyl ammonium chloride solution.
In step (1), boric acid is configured to the boric acid solution of mass content 40% with deionized water.
In step (1), vinylacetate is configured to the vinyl acetate solution of mass content 32% with deionized water.
In step (3), ultrasonic power 1000W, ultrasonic temperature is 76 DEG C.
A kind of application for the color fixing agent of reactive dyeing in printing and dyeing.
Embodiment 3
A kind of color fixing agent for reactive dyeing is made of following parts by weight raw material: 15 parts of high-efficient penetrant gathers
18 parts of dimethyl diallyl ammonium chloride, 20 parts of triethylene tetramine, 13 parts of hydroxypropyltrimethylammonium chloride chitosan, lauryl alcohol are poly-
4 parts of ethylene oxide ether, 1.2 parts of vinylacetate, 6 parts of boric acid, 12 parts of epoxychloropropane, 18 parts of ethyl alcohol, 7.5 parts of Sodium Polyacrylate,
22 parts of hydroquinone, 40 parts of deionized water, 20 parts of emulsifier, 75 parts of soda ash.
A kind of preparation method of the color fixing agent for reactive dyeing, comprising the following steps:
(1) polydimethyl diallyl ammonium chloride is mixed with deionized water, polydimethyl diallyl ammonium chloride is made
Solution；Boric acid is mixed with deionized water, boric acid solution is made；Vinylacetate is mixed with deionized water, acetic acid second is made
Enester solution；
(2) by above-mentioned high-efficient penetrant, triethylene tetramine, hydroxypropyltrimethylammonium chloride chitosan, lauryl alcohol polyoxy
Vinethene, epoxychloropropane, Sodium Polyacrylate, hydroquinone, deionized water and soda ash mixing, are warming up to 76 degrees Celsius, and
Stir process 20min is stirred at this temperature, vinyl acetate solution is then added dropwise while stirring, drips latter near 60 DEG C and is added
Enter boric acid solution, then 50 DEG C at a temperature of stir 30min, mixed liquor A；
(3) polydimethyl diallyl ammonium chloride solution is added in the mixed liquor A in step (2), is heated to 97 DEG C, and
57min is kept at this temperature, is then ultrasonically treated, and the time of ultrasonic treatment is 22min, obtains mixed liquid B；
(4) ethyl alcohol and emulsifier are added in the mixed liquid B in step (3), after vacuum distillation, obtains viscous liquid C；
(5) vacuumize process is carried out to the viscous liquid C, then is obtained after being dried described for reactive dyeing
Color fixing agent.
In step (1), polydimethyl diallyl ammonium chloride is configured to the poly- diformazan of mass content 28% with deionized water
Base diallyl ammonium chloride solution.
In step (1), boric acid is configured to the boric acid solution of mass content 40% with deionized water.
In step (1), vinylacetate is configured to the vinyl acetate solution of mass content 32% with deionized water.
In step (3), ultrasonic power 1000W, ultrasonic temperature is 78 DEG C.
A kind of application for the color fixing agent of reactive dyeing in printing and dyeing.
Embodiment 4
A kind of color fixing agent for reactive dyeing is made of following parts by weight raw material: 18 parts of high-efficient penetrant gathers
19 parts of dimethyl diallyl ammonium chloride, 22 parts of triethylene tetramine, 14 parts of hydroxypropyltrimethylammonium chloride chitosan, lauryl alcohol are poly-
It is 5 parts of ethylene oxide ether, 1.5 parts of vinylacetate, 7 parts of boric acid, 13 parts of epoxychloropropane, 19 parts of ethyl alcohol, 8 parts of Sodium Polyacrylate, right
23 parts of benzenediol, 42 parts of deionized water, 25 parts of emulsifier, 85 parts of soda ash.
A kind of preparation method of the color fixing agent for reactive dyeing, comprising the following steps:
(1) polydimethyl diallyl ammonium chloride is mixed with deionized water, polydimethyl diallyl ammonium chloride is made
Solution；Boric acid is mixed with deionized water, boric acid solution is made；Vinylacetate is mixed with deionized water, acetic acid second is made
Enester solution；
(2) by above-mentioned high-efficient penetrant, triethylene tetramine, hydroxypropyltrimethylammonium chloride chitosan, lauryl alcohol polyoxy
Vinethene, epoxychloropropane, Sodium Polyacrylate, hydroquinone, deionized water and soda ash mixing, are warming up to 76 degrees Celsius, and
Stir process 20min is stirred at this temperature, vinyl acetate solution is then added dropwise while stirring, drips latter near 60 DEG C and is added
Enter boric acid solution, then 50 DEG C at a temperature of stir 30min, mixed liquor A；
(3) polydimethyl diallyl ammonium chloride solution is added in the mixed liquor A in step (2), is heated to 98 DEG C, and
58min is kept at this temperature, is then ultrasonically treated, and the time of ultrasonic treatment is 26min, obtains mixed liquid B；
(4) ethyl alcohol and emulsifier are added in the mixed liquid B in step (3), after vacuum distillation, obtains viscous liquid C；
(5) vacuumize process is carried out to the viscous liquid C, then is obtained after being dried described for reactive dyeing
Color fixing agent.
In step (1), polydimethyl diallyl ammonium chloride is configured to the poly- diformazan of mass content 28% with deionized water
Base diallyl ammonium chloride solution.
In step (1), boric acid is configured to the boric acid solution of mass content 40% with deionized water.
In step (1), vinylacetate is configured to the vinyl acetate solution of mass content 32% with deionized water.
In step (3), ultrasonic power 1000W, ultrasonic temperature is 80 DEG C.
A kind of application for the color fixing agent of reactive dyeing in printing and dyeing.
Embodiment 5
A kind of color fixing agent for reactive dyeing is made of following parts by weight raw material: 20 parts of high-efficient penetrant gathers
20 parts of dimethyl diallyl ammonium chloride, 25 parts of triethylene tetramine, 15 parts of hydroxypropyltrimethylammonium chloride chitosan, lauryl alcohol are poly-
6 parts of ethylene oxide ether, 2 parts of vinylacetate, 9 parts of boric acid, 14 parts of epoxychloropropane, 20 parts of ethyl alcohol, 9 parts of Sodium Polyacrylate, to benzene
24 parts of diphenol, 45 parts of deionized water, 30 parts of emulsifier, 100 parts of soda ash.
A kind of preparation method of the color fixing agent for reactive dyeing, comprising the following steps:
(1) polydimethyl diallyl ammonium chloride is mixed with deionized water, polydimethyl diallyl ammonium chloride is made
Solution；Boric acid is mixed with deionized water, boric acid solution is made；Vinylacetate is mixed with deionized water, acetic acid second is made
Enester solution；
(2) by above-mentioned high-efficient penetrant, triethylene tetramine, hydroxypropyltrimethylammonium chloride chitosan, lauryl alcohol polyoxy
Vinethene, epoxychloropropane, Sodium Polyacrylate, hydroquinone, deionized water and soda ash mixing, are warming up to 76 degrees Celsius, and
Stir process 20min is stirred at this temperature, vinyl acetate solution is then added dropwise while stirring, drips latter near 60 DEG C and is added
Enter boric acid solution, then 50 DEG C at a temperature of stir 30min, mixed liquor A；
(3) polydimethyl diallyl ammonium chloride solution is added in the mixed liquor A in step (2), is heated to 99 DEG C, and
60min is kept at this temperature, is then ultrasonically treated, and the time of ultrasonic treatment is 30min, obtains mixed liquid B；
(4) ethyl alcohol and emulsifier are added in the mixed liquid B in step (3), after vacuum distillation, obtains viscous liquid C；
(5) vacuumize process is carried out to the viscous liquid C, then is obtained after being dried described for reactive dyeing
Color fixing agent.
In step (1), polydimethyl diallyl ammonium chloride is configured to the poly- diformazan of mass content 28% with deionized water
Base diallyl ammonium chloride solution.
In step (1), boric acid is configured to the boric acid solution of mass content 40% with deionized water.
In step (1), vinylacetate is configured to the vinyl acetate solution of mass content 32% with deionized water.
In step (3), ultrasonic power 1000W, ultrasonic temperature is 82 DEG C.
A kind of application for the color fixing agent of reactive dyeing in printing and dyeing.
Comparative example 1
In addition to no vinylacetate, preparation process and embodiment 5 are consistent.
Comparative example 2
In addition to no boric acid, preparation process and embodiment 5 are consistent.
Comparative example 3
In addition to no vinylacetate, boric acid, preparation process and embodiment 5 are consistent.
Color fixing agent obtained by above-described embodiment 1~5 and comparative example 1~3 is printed and dyed respectively in fabric surface, to fabric color
Block wash by water 1 minute after measure four color densities, four color density height illustrate that water-resistance is good after bath, four color densities be C (indigo plant), M (red),
Y (Huang), K (ink).It measures color density value and is shown in Table 1.
Table 1
As can be seen from Table 1, after lacking vinylacetate or boric acid, after fabric color lump bath 1min, the color of four colors
Density value has very big decline, and it is poor to illustrate to lack color fixing agent water-resistance obtained when vinylacetate or boric acid；In comparison,
The color fixing agent of Examples 1 to 5 preparation, after fabric color lump bath 1min, color density value detected is high, illustrates water repelling property
It is greatly improved.
The foregoing descriptions are merely the embodiment using this origination techniques content, any those skilled in the art use this wound
Make done modifications and changes, all belong to the scope of the patents of this creation opinion, and is not limited to those disclosed embodiments.
If not specified, technological means employed in embodiment is conventional means known to those skilled in the art, institute
The reagent and product of use are also available commercial.The source of agents useful for same, trade name and its composition is listed when necessary
Ingredient person, is indicated on the first occurrence.
Claims (9)
1. a kind of color fixing agent for reactive dyeing, characterized in that be made of following parts by weight raw material: high-efficient penetrant
10~20 parts, 16~20 parts of polydimethyl diallyl ammonium chloride, 15~25 parts of triethylene tetramine, hydroxypropyl-trimethyl ammonium chloride
11~15 parts of chitosan, 2~6 parts of Dodecyl Polyoxyethylene Ether, 0.6~2 part of vinylacetate, 3~9 parts of boric acid, epoxy chloropropionate
10~14 parts of alkane, 16~20 parts of ethyl alcohol, 6~9 parts of Sodium Polyacrylate, 20~24 parts of hydroquinone, 35~45 parts of deionized water, cream
10~30 parts of agent, 50~100 parts of soda ash.
2. the color fixing agent according to claim 1 for reactive dyeing, characterized in that by following parts by weight raw material
Composition: 14~18 parts of high-efficient penetrant, 17~19 parts of polydimethyl diallyl ammonium chloride, 18~22 parts of triethylene tetramine, hydroxyl
12~14 parts of hydroxypropyltrimonium chloride chitosan, 3~5 parts of Dodecyl Polyoxyethylene Ether, 1~1.5 part of vinylacetate, boric acid
5~7 parts, 11~13 parts of epoxychloropropane, 17~19 parts of ethyl alcohol, 7~8 parts of Sodium Polyacrylate, 21~23 parts of hydroquinone, go from
38~42 parts of sub- water, 15~25 parts of emulsifier, 65~85 parts of soda ash.
3. the color fixing agent according to claim 1 for reactive dyeing, characterized in that by following parts by weight raw material
Composition: 15 parts of high-efficient penetrant, 18 parts of polydimethyl diallyl ammonium chloride, 20 parts of triethylene tetramine, Hydroxyproyl Trimethyl chlorine
Change 13 parts of ammonium chitosan, 4 parts of Dodecyl Polyoxyethylene Ether, 1.2 parts of vinylacetate, 6 parts of boric acid, 12 parts of epoxychloropropane, second
18 parts of alcohol, 7.5 parts of Sodium Polyacrylate, 22 parts of hydroquinone, 40 parts of deionized water, 20 parts of emulsifier, 75 parts of soda ash.
4. a kind of preparation method of the color fixing agent for reactive dyeing as described in claims 1 to 3 is any, feature
It is, comprising the following steps:
(1) polydimethyl diallyl ammonium chloride is mixed with deionized water, polydimethyl diallyl ammonium chloride solution is made；
Boric acid is mixed with deionized water, boric acid solution is made；Vinylacetate is mixed with deionized water, it is molten that vinylacetate is made
Liquid；
(2) by above-mentioned high-efficient penetrant, triethylene tetramine, hydroxypropyltrimethylammonium chloride chitosan, lauryl alcohol polyoxyethylene
Ether, epoxychloropropane, Sodium Polyacrylate, hydroquinone, deionized water and soda ash mixing, are warming up to 76 degrees Celsius, and in the temperature
Degree is lower to stir stir process 20min, and vinyl acetate solution is then added dropwise while stirring, drips latter near 60 DEG C and boron is added
Acid solution, then 50 DEG C at a temperature of stir 30min, mixed liquor A；
(3) polydimethyl diallyl ammonium chloride solution is added in the mixed liquor A in step (2), is heated to 95~99 DEG C, and
55~60min is kept at this temperature, is then ultrasonically treated, and the time of ultrasonic treatment is 18~30min, obtains mixed liquor
B；
(4) ethyl alcohol and emulsifier are added in the mixed liquid B in step (3), after vacuum distillation, obtains viscous liquid C；
(5) vacuumize process is carried out to the viscous liquid C, then obtains the consolidating for reactive dyeing after being dried
Toner.
5. the preparation method of the color fixing agent according to claim 4 for reactive dyeing, characterized in that step (1)
In, polydimethyl diallyl ammonium chloride is configured to the polydimethyl diallyl ammonium chloride of mass content 28% with deionized water
Solution.
6. the preparation method of the color fixing agent according to claim 4 for reactive dyeing, characterized in that step (1)
In, boric acid is configured to the boric acid solution of mass content 40% with deionized water.
7. the preparation method of the color fixing agent according to claim 4 for reactive dyeing, characterized in that step (1)
In, vinylacetate is configured to the vinyl acetate solution of mass content 32% with deionized water.
8. the preparation method of the color fixing agent according to claim 4 for reactive dyeing, characterized in that step (3)
In, ultrasonic power 1000W, ultrasonic temperature is 74~82 DEG C.
9. a kind of application for the color fixing agent of reactive dyeing in printing and dyeing as described in claims 1 to 3 is any.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810854128.2A CN109112859A (en) | 2018-07-30 | 2018-07-30 | A kind of color fixing agent and preparation method thereof for reactive dyeing |
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| CN106541724A (en) * | 2016-12-12 | 2017-03-29 | 郑州艾莫弗信息技术有限公司 | A kind of ink-jet paper color fixing agent and preparation method thereof |
| CN106758516A (en) * | 2016-12-12 | 2017-05-31 | 刘海平 | The preparation method and obtained color fixing agent of a kind of paper color fixing agent |
| CN107938399A (en) * | 2017-11-30 | 2018-04-20 | 安徽宏远无纺布业有限公司 | A kind of color fixing agent for cloth and preparation method thereof |
| CN108149495A (en) * | 2016-12-05 | 2018-06-12 | 福泉曼易思纺织有限公司 | A kind of color fixing agent and preparation method thereof |
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| CN108149495A (en) * | 2016-12-05 | 2018-06-12 | 福泉曼易思纺织有限公司 | A kind of color fixing agent and preparation method thereof |
| CN106541724A (en) * | 2016-12-12 | 2017-03-29 | 郑州艾莫弗信息技术有限公司 | A kind of ink-jet paper color fixing agent and preparation method thereof |
| CN106758516A (en) * | 2016-12-12 | 2017-05-31 | 刘海平 | The preparation method and obtained color fixing agent of a kind of paper color fixing agent |
| CN107938399A (en) * | 2017-11-30 | 2018-04-20 | 安徽宏远无纺布业有限公司 | A kind of color fixing agent for cloth and preparation method thereof |
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Application publication date: 20190101 |