CN109111990A - Utilize the method and its application of wax in impulse electric field efficient removal olive oil - Google Patents

Utilize the method and its application of wax in impulse electric field efficient removal olive oil Download PDF

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Publication number
CN109111990A
CN109111990A CN201811172101.1A CN201811172101A CN109111990A CN 109111990 A CN109111990 A CN 109111990A CN 201811172101 A CN201811172101 A CN 201811172101A CN 109111990 A CN109111990 A CN 109111990A
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China
Prior art keywords
olive oil
electric field
wax
quick
oil
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CN201811172101.1A
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Chinese (zh)
Inventor
孙炜炜
梅芷莹
陈�胜
蔡超
陈建
苗丽坤
蹇顺华
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China Tobacco Hunan Industrial Co Ltd
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China Tobacco Hunan Industrial Co Ltd
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Priority to CN201811172101.1A priority Critical patent/CN109111990A/en
Publication of CN109111990A publication Critical patent/CN109111990A/en
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    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11BPRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
    • C11B3/00Refining fats or fatty oils
    • C11B3/16Refining fats or fatty oils by mechanical means
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11BPRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
    • C11B3/00Refining fats or fatty oils
    • C11B3/008Refining fats or fatty oils by filtration, e.g. including ultra filtration, dialysis

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  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Microbiology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Fats And Perfumes (AREA)
  • Edible Oils And Fats (AREA)

Abstract

The present invention provides a kind of method and application using wax in impulse electric field efficient removal olive oil.The method is that for 24 hours, the surfactant that its weight 0.01-0.05% is then added is stirred to surfactant sufficiently to be dissolved balanced stock under the conditions of 20-25 DEG C by olive oil;Impulse electric field operating room is subsequently poured into treatment conditions are as follows: electric field strength 15-30kV/cm, treatment temperature are 20-25 DEG C, and pulse width is 10-20 μ s, and pulse frequency is 300-600Hz circular treatment 1-2 times, the olive oil product after dewaxing after filtering.This method is with easy to operate, the used time is short, high-efficient, and the characteristics of not introducing poisonous and harmful substance, its dewaxing effect is obvious, quick-fried pearl essential oil is modulated using oil based on the olive oil after dewaxing, do not have to find the phenomenon of oil body muddiness during storage, its stable molding in the quick-fried pearl molding link of cigarette, quick-fried pearl ratio of briquetting is high, and the quality of quick-fried pearl product can be effectively ensured.

Description

Utilize the method and its application of wax in impulse electric field efficient removal olive oil
Technical field
It is specifically a kind of using in impulse electric field efficient removal olive oil the present invention relates to cigarette flavors field The method and its application of wax.
Background technique
Olive oil is the grease extracted from olive fresh fruit with mechanical means appropriate, and general cold press takes oil, with Extra Virgin is most well-known, best in quality, is not required to refine, and price is also most expensive.Virgin oil has unique fragrance taste, Still it is liquid at 0 DEG C, cool tone oil can be made and cooking oil uses.Virgin oil is consumed deeply with the characteristics of its " green, health " Person likes that human body is up to 93.4% to the absorptivity of olive oil, has and reduces cardiovascular disease, promotes child's bone and nerveous system The multiple efficacies such as system development, enjoy the good reputation of " vegetable oil queen ", are widely used to the fields such as food, medicine, daily use chemicals.First squeezing Olive oil belongs to a kind of substance in pure natural source, rich in macromolecular substances such as protein, waxes, during production and storage Phenomena such as being also easy to produce precipitating, floccule, impurity destroys the stable homogeneous of oil liquid system.
Wax in grease is the ester that advanced monocarboxylic acid and high alcohol are formed.Wax can be dissolved in oil at 40 DEG C or more Rouge, therefore in the crude oil that either squeezing method or lixiviation process are produced, generally all contain a certain amount of wax.The various crude oil content of wax Amount has very big difference, and the paraffin content of most of crude oils is atomic, but the paraffin content of some crude oils is then higher.As maize germ oil contains Wax amount 0.01%~0.04%, sunflower oil paraffin content 0.06%~0.2%%.Room temperature (30 DEG C) hereinafter, wax in grease Solubility reduce, be precipitated the crystal grain of wax and become oleosol, with the extension of period of storage, the crystal grain of wax is gradually increased and becomes At suspended substance, system becomes " thick disperse system "-suspension at this time, embodies the unstability of sol system, the transparency of oil product Decline, and gas flavour and palatability is made to be deteriorated, to reduce the edible quality of grease, nutritive value and industrial application value.
Impulse electric field (Pulsed Electric Fields, PEF) processing technique is a kind of Food Green emerging in recent years Color processing technology is mainly used for the non-thermal sterilization processing to liquid, soft solid materials.Its sterilization mechanism is worn using cell membrane electricity Hole principle causes cell membrane potential chaotic, causes bacterium by the cell membrane of high intensity pulses electric field flash disruption microorganism Extremely, cryogenic conditions largely avoid negative effect of the thermal sterilization to food sense organ and physical characteristic.The technology is being located Temperature is lower during reason, processing the time it is shorter, be extremely suitable for the working process of heat sensitive material, natural products effectively at The extensive concern of insider is attracted in terms of the extraction divided.Chinese patent 201710854380.9 discloses a kind of soilless cultivation The high-pressure pulse electric sterilization system and method for nutrient solution, is added in by the high-pressure pulse electric for generating high-voltage pulse power source and is killed The two poles of the earth of bacterium process chamber, so that the microorganisms such as bacterium, fungi for containing in nutrient solution in sterilization processing room are due to electroporation Reason and crack death, germicidal efficiency is improved under the premise of not generating by-product.Chinese patent 201810138599.3 is public A kind of preserving fruit and vegetable utilizing device based on nanosecond pulse low voltage electric field of cloth, operation of the present invention method is convenient, pollution-free, is suitable for each The perishable rotten preserving fruit and vegetable utilizing of kind, has very high application value.Chinese patent 201310118625.3 discloses a kind of arteries and veins Rush electric field processing chamber, solve that the directly cooling water-cooling method modularity of existing pulse electric field process chamber is poor, cooling efficiency is low and The problems such as real-time is poor has many advantages, such as that impulse electric field processing is integrated with temperature control, easy to use and heating effect control is significant. But above-mentioned patented technology is not directed to the method using wax in impulse electric field fast eliminating olive oil.
During the production of the quick-fried pearl of Dendranthema indicum molding, base oil of the virgin oil as quick-fried pearl essential oil, due to olive Olive oil contains the reason of a small amount of wax (about 280mg/kg), seriously affects the interior quality and quality stable type of quick-fried pearl essential oil, It is easy to appear phenomena such as ratio of briquetting is low, solid pearl is more, notch is big, core shift when quick-fried pearl online production, quick-fried pearl cannot be effectively ensured The quality of product.Existing technology is to be filtered processing to olive oil using 200 mesh filter clothes, and the processing time is longer, and effect Unobvious, the wax content in olive oil is reduced to 220mg/kg by 280mg/kg.It can be fast therefore, it is necessary to seek one kind The method of wax in speed, efficient removal olive oil carries out pre-treatment to olive oil, to stablize the quality of quick-fried pearl essential oil.
Summary of the invention
It is a kind of using in impulse electric field efficient removal olive oil the purpose of the present invention is in view of the deficiencies of the prior art, providing The method and its application of wax, this method make wax molecule pole using additional uneven electric field by impulse electric field processing technique Change, negatively charged wax crystal grain is enriched with and settles under electric field action, in anode, makes oil-wax separation, reaches the mesh of electric field dewaxing , dewaxing effect is good, and oil modulates quick-fried pearl essential oil based on the olive oil after dewaxing, without discovery oil body during storage Muddy phenomenon, and stable molding during preparing quick-fried pearl, and ratio of briquetting is high.
To achieve the above object, a kind of side using wax in impulse electric field efficient removal olive oil provided by the invention Method, it is characterised in that specific step is as follows:
(1) by olive oil under the conditions of 20-25 DEG C balanced stock for 24 hours, for use;
(2) surfactant of its weight 0.01-0.05% is added into olive oil, and in 300-500 revs/min of condition Lower stirring 0.5-1h, to guarantee that surfactant sufficiently dissolves;
(3) material in step (2) is poured into impulse electric field operating room circular treatment 1-2 times, dewax after filtering to obtain the final product after Olive oil product, impulse electric field treatment conditions are as follows: electric field strength 15-30kV/cm, treatment temperature be 20-25 DEG C, pulse Width is 10-20 μ s, pulse frequency 300-600Hz.
The present invention preferably technical solution: the operating environment temperature in the step (2) is 20-25 DEG C.
The present invention preferably technical solution: the surfactant in the step (2) is polyacrylamide, aliphatic alkyl Sulfate, sugar ester, any one in sapn.
The present invention provide it is a kind of using in impulse electric field efficient removal olive oil wax method removal wax after olive The application of oil, it is characterised in that: will be oily based on olive oil after removing wax in the above method, according to the mass ratio of 2-5% Example adds quick-fried pearl essence, obtains quick-fried pearl essential oil after mixing, then after Fruit storage 10-20min, drips with being placed in It dripping pill lapping in ball machine rubber cement tank and is placed in and contains the curing agent in ball device according to the conventional production process of the quick-fried pearl of cigarette Cigarette is made with quick-fried pearl.
Olive oil in the present invention is commercially available olive oil.
The present invention has the advantages that
(1) of the invention to make wax molecular polarization using additional uneven electric field by impulse electric field processing technique, band is negative The wax crystal grain of charge is enriched with and settles under electric field action, in anode, makes oil-wax separation, achievees the purpose that electric field dewaxes, place After reason, 50mg/kg or less is greatly reduced in wax content;
(2) surfactant is added in the method for the invention, facilitates the crystallization of wax;It is non-in surfactant molecule Polar group has stronger affinity with the alkyl of wax and forms copolymer, greatly increases oil-wax interface surface tension, Wax is also easy to separate with grease;
(3) present invention has many advantages, such as that easy to operate, the used time is short, high-efficient, and does not introduce poisonous and harmful substance;
(4) dewaxing effect of the present invention is obvious, and 50mg/kg is greatly reduced in the wax content in olive oil, uses dewaxing Oil modulates quick-fried pearl essential oil based on olive oil afterwards, does not have to find the phenomenon of oil body muddiness during storage, specifically in cigarette The application effect of quick-fried pearl molding link are as follows: online stable molding, quick-fried pearl ratio of briquetting is high, does not find that solid pearl, notch be big, core shift Phenomena such as, the quality of quick-fried pearl product can be effectively ensured.
Specific embodiment
Below in conjunction with specific embodiment, the present invention is described in further detail.
A kind of method using wax in impulse electric field efficient removal olive oil provided in embodiment one, specific steps It is as follows:
(1) by olive oil at 20 °C balanced stock for 24 hours, for use;
(2) 0.05% polyacrylamide is added into olive oil, 1h is stirred under the conditions of 300 revs/min, to guarantee table Face activating agent sufficiently dissolves, and operating environment temperature is 25 DEG C;
(3) material in step (2) is poured into impulse electric field operating room circular treatment 1 time, impulse electric field treatment conditions: Electric field strength is 15kV/cm, and treatment temperature is 22 DEG C, and pulse width is 10 μ s, pulse frequency 360Hz;Up to de- after filtering Olive oil product A after wax.
A kind of method using wax in impulse electric field efficient removal olive oil provided in embodiment two, specific steps It is as follows:
(1) by olive oil under the conditions of 25 DEG C balanced stock for 24 hours, for use;
(2) 0.01% sapn is added into olive oil, stirs 0.5h under the conditions of 500 revs/min, to guarantee that surface is living Property agent sufficiently dissolve, operating environment temperature be 23 DEG C;
(3) material in step (2) is poured into impulse electric field operating room circular treatment 2 times, process conditions: electric field strength is 30kV/cm, treatment temperature are 22 DEG C, and pulse width is 20 μ s, pulse frequency 300Hz;Up to the olive after dewaxing after filtering Oil product B;
A kind of method using wax in impulse electric field efficient removal olive oil provided in embodiment three, specific steps It is as follows:
(1) by olive oil under the conditions of 24 DEG C balanced stock for 24 hours, for use;
(2) 0.03% aliphatic alkyl sulfate is added into olive oil, stirs 0.5h under the conditions of 400 revs/min, To guarantee that surfactant sufficiently dissolves, operating environment temperature is 23 DEG C;
(3) material in step (2) is poured into impulse electric field operating room circular treatment 1 time, process conditions: electric field strength is 18kV/cm, treatment temperature are 25 DEG C, and pulse width is 16 μ s, pulse frequency 400Hz;Up to the olive after dewaxing after filtering Oil product C.
A kind of method using wax in impulse electric field efficient removal olive oil provided in example IV, specific steps It is as follows:
(1) by olive oil under the conditions of 21 DEG C balanced stock for 24 hours, for use.
(2) 0.04% chaff ester is added into olive oil, stirs 0.5h under the conditions of 450 revs/min, to guarantee that surface is living Property agent sufficiently dissolve, operating environment temperature be 22 DEG C.
(3) material in step (2) is poured into impulse electric field operating room circular treatment 2 times, process conditions: electric field strength is 17kV/cm, treatment temperature are 23 DEG C, and pulse width is 15 μ s, pulse frequency 500Hz;Up to the olive after dewaxing after filtering Oil product D.
Application examples: application of the olive oil in quick-fried pearl essential oil after impulse electric field dewaxing.
By oil based on treated in aforementioned four embodiment olive oil product A, B, C, D, respectively according to 2% matter Amount ratio adds Dendranthema indicum essence, after mixing up to quick-fried pearl essential oil A, B, C, D, and respectively passes through four kinds of quick-fried pearl essential oils After Fruit storage 10-20min, referring to the conventional production process of the quick-fried pearl of enterprises cigarette, and it is placed in pill dripping machine rubber cement tank In dripping pill lapping and be placed in contain ball device in curing agent according to the preparation process of dripping pill be made cigarette with quick-fried pearl A, B, C, D。
The Indexs measures such as pressure, moisture, rubber specific gravity, testing result such as table are carried out first against the quality of four kinds of quick-fried pearls Shown in 1:
The quality measurements of the quick-fried pearl sample of table 1
Blank is using the quick-fried pearl essential oil of oil allotment based on the olive oil not dewaxed, as core liquid system in table 1 Standby quick-fried pearl sample.
Testing result shows: it is oily based on the olive oil after dewaxing treatment of the present invention, have with quick-fried pearl wall material, molding equipment There is good adaptability, online stable molding, quick-fried pearl ratio of briquetting is high, phenomena such as not finding big solid pearl, notch, core shift, quick-fried The various indexs of pearl finished product are good, and in the ideal range, the ratio of briquetting of quick-fried pearl is 96% or more.
In order to further look at the stability of the olive oil after dewaxing treatment, at 20 °C by the sample in embodiment Storage 90 days, the state of oil liquid during observation storage, and the wax content in measurement system, specific testing result are as shown in table 2:
Wax content (mg/kg) variation of the olive oil during storage after the dewaxing of table 2
Sample 0 month 3 months
Blank 280.42 280.27
Embodiment 1 45.09 45.11
Embodiment 2 43.87 43.72
Embodiment 3 44.28 44.52
Embodiment 4 42.09 42.18
Note: blank is using the olive oil not dewaxed.
It is in table 2 the result shows that: system is more stable after 90 days for the olive oil after dewaxing, floccule does not occur;Relatively Before non-dewaxing treatment, it is obvious that wax content reduces amplitude.

Claims (4)

1. a kind of method using wax in impulse electric field efficient removal olive oil, it is characterised in that specific step is as follows:
(1) by olive oil under the conditions of 20-25 DEG C balanced stock for 24 hours, for use;
(2) surfactant of its weight 0.01-0.05% is added into olive oil, and is stirred under the conditions of 300-500 revs/min 0.5-1h is mixed, to guarantee that surfactant sufficiently dissolves;
(3) material in step (2) is poured into impulse electric field operating room circular treatment 1-2 times, the olive after dewaxing after filtering Olive oil product, impulse electric field treatment conditions are as follows: electric field strength 15-30kV/cm, treatment temperature are 20-25 DEG C, pulse width For 10-20 μ s, pulse frequency 300-600Hz.
2. a kind of method using wax in impulse electric field efficient removal olive oil according to claim 1, feature exist In: the operating environment temperature in the step (2) is 20-25 DEG C.
3. a kind of method using wax in impulse electric field efficient removal olive oil according to claim 1, feature exist In: surfactant in the step (2) be polyacrylamide, it is aliphatic alkyl sulfate, sugar ester, any one in sapn Kind.
4. a kind of application for removing the olive oil after wax using method described in any one of claims 1 to 33, special Sign is: will be in the above method using oil based on olive oil after impulse electric field efficient removal wax, according to the quality of 2-5% Ratio adds quick-fried pearl essence, obtains quick-fried pearl essential oil after mixing, then after Fruit storage 10-20min, and is placed in Dripping pill lapping in pill dripping machine rubber cement tank and it is placed in the conventional production work for containing the curing agent in ball device according to the quick-fried pearl of cigarette Cigarette is made with quick-fried pearl in skill.
CN201811172101.1A 2018-10-09 2018-10-09 Utilize the method and its application of wax in impulse electric field efficient removal olive oil Pending CN109111990A (en)

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Cited By (4)

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Publication number Priority date Publication date Assignee Title
CN111642586A (en) * 2020-06-29 2020-09-11 崇左市青林金花茶开发有限公司 Processing method for efficiently removing wax on surface of golden camellia
CN111642587A (en) * 2020-06-29 2020-09-11 崇左市青林金花茶开发有限公司 Cold-drying processing method of high-quality golden camellia
CN111713566A (en) * 2020-06-29 2020-09-29 崇左市青林金花茶开发有限公司 Processing method for improving dissolving-out speed of nutrient substances in golden camellia
CN112980586A (en) * 2021-04-08 2021-06-18 武汉黄鹤楼香精香料有限公司 Purification method of pearl blasting essential oil

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CN108004024A (en) * 2018-01-16 2018-05-08 武汉黄鹤楼香精香料有限公司 A kind of ginkgo leaf cigarette is applied with quick-fried pearl essential oil and preparation method thereof and in cigarette

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111642586A (en) * 2020-06-29 2020-09-11 崇左市青林金花茶开发有限公司 Processing method for efficiently removing wax on surface of golden camellia
CN111642587A (en) * 2020-06-29 2020-09-11 崇左市青林金花茶开发有限公司 Cold-drying processing method of high-quality golden camellia
CN111713566A (en) * 2020-06-29 2020-09-29 崇左市青林金花茶开发有限公司 Processing method for improving dissolving-out speed of nutrient substances in golden camellia
CN111642586B (en) * 2020-06-29 2023-07-25 崇左市青林金花茶开发有限公司 Treatment method for efficiently removing wax on surface of golden camellia
CN112980586A (en) * 2021-04-08 2021-06-18 武汉黄鹤楼香精香料有限公司 Purification method of pearl blasting essential oil

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Application publication date: 20190101