CN109098302B - Expansion type metal fireproof plugging plate - Google Patents

Expansion type metal fireproof plugging plate Download PDF

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Publication number
CN109098302B
CN109098302B CN201811003260.9A CN201811003260A CN109098302B CN 109098302 B CN109098302 B CN 109098302B CN 201811003260 A CN201811003260 A CN 201811003260A CN 109098302 B CN109098302 B CN 109098302B
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expansion
fireproof
fireproof coating
base material
plugging plate
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CN109098302A (en
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胡涛
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Guangdong Heiwei Fireproof Technology Co ltd
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Guangdong Heiwei Fireproof Technology Co ltd
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    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04BGENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
    • E04B1/00Constructions in general; Structures which are not restricted either to walls, e.g. partitions, or floors or ceilings or roofs
    • E04B1/62Insulation or other protection; Elements or use of specified material therefor
    • E04B1/92Protection against other undesired influences or dangers
    • E04B1/94Protection against other undesired influences or dangers against fire
    • E04B1/941Building elements specially adapted therefor
    • E04B1/942Building elements specially adapted therefor slab-shaped
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04Homopolymers or copolymers of esters
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18Fireproof paints including high temperature resistant paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/70Additives characterised by shape, e.g. fibres, flakes or microspheres
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2217Oxides; Hydroxides of metals of magnesium
    • C08K2003/2224Magnesium hydroxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2227Oxides; Hydroxides of metals of aluminium
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/32Phosphorus-containing compounds
    • C08K2003/321Phosphates
    • C08K2003/322Ammonium phosphate
    • C08K2003/323Ammonium polyphosphate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/38Boron-containing compounds
    • C08K2003/387Borates

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Architecture (AREA)
  • Physics & Mathematics (AREA)
  • Electromagnetism (AREA)
  • Civil Engineering (AREA)
  • Structural Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Building Environments (AREA)

Abstract

The invention discloses an expansion type metal fireproof plugging plate which comprises a base material, a high-expansion fireproof coating and a fireproof coating layer which are sequentially stacked, wherein the base material is a galvanized steel plate; the high-expansion fireproof coating is coated on the base material and consists of colloidal resin, a flame retardant and a diluent; the fireproof coating layer is coated on the high-expansion fireproof coating. According to the intumescent metal fireproof plugging plate, the galvanized steel sheet is used as the base material, so that the strength of the fireproof plugging plate is ensured, the bearing capacity is improved, and secondary damage caused by collapse of a building is avoided; no flying floc is generated in the production process, so that the environmental pollution and the damage to the health of workers are reduced; the plugging plate takes the galvanized steel sheet as a base material to be coated with the fireproof layer, so that the damage is less, the defective rate is low, and the production cost is reduced; the plate is very thin, so that the installation space is saved, and the transportation cost is reduced.

Description

Expansion type metal fireproof plugging plate
Technical Field
The invention relates to the technical field of fireproof plugging, in particular to an expansion type metal fireproof plugging plate.
Background
At the moment that the land demand is increasingly severe, the modern building industry separates from traditional brick and wood structure, the mode of adopting concrete whole building to pour increases the height of building, the "air pavilion" becomes the normality of most people's house life, however under such residential environment, in case the conflagration takes place in the building, the condition of a fire can pass through curtain seam, cable run-through and various pipeline transfer, further enlarge the intensity of a fire, poisonous flue gas also can upwards spread through building and equipment seam mouth rapidly simultaneously, increase stranded personnel's the degree of difficulty of fleing, constitute very big threat to resident's life safety. Therefore, the fire-proof blocking technology is developed for effectively limiting the spread of fire and toxic smoke generated in the fire, thereby protecting the safety of personnel and equipment in areas except the ignition source. The fireproof plugging plates adopted in the current market mainly comprise mineral wool plates and rock wool plates, and the fireproof plugging plates are limited by materials in the using process, have insufficient strength and limited bearing capacity, and are easy to collapse when being squeezed by a heavy object to cause secondary damage; the flying cotton wool generated in the production process of the mineral wool board and the rock wool board is easy to migrate in the environment to cause air pollution, and meanwhile, the life health of operation workers is threatened; the mineral wool board and the rock wool board are both formed by bonding granular substances through viscose, and the pores among the granules are large, so that the mineral wool board and the rock wool board are easy to damage in the production process, high in defective rate and high in production cost; the mineral wool board is great in thickness when being used as the fire prevention shutoff with the rock wool board, and installation space is great and the cost of transportation is high.
Disclosure of Invention
Aiming at the problems that the strength is not enough, the collapse is easy, flying floc is generated to pollute the environment, the life health of workers is threatened, the breakage is easy, the production cost is high, the thickness and the installation space are large, the transportation cost is high and the like in the prior art, the invention discloses an expansion type metal fire-proof plugging plate, which comprises a base material, a high expansion fire-proof coating and a fire-proof coating which are sequentially stacked, wherein the base material is a galvanized steel plate; the high-expansion fireproof coating is coated on the base material and consists of colloidal resin, a flame retardant and a diluent; the fireproof coating layer is coated on the high-expansion fireproof coating.
Furthermore, the thickness of the expansion type metal fireproof plugging plate is between 1.7 and 2.3 millimeters.
Further, the high-expansion fireproof coating is composed of 40 mass percent of colloidal resin, 53.5 mass percent of flame retardant and 6.5 mass percent of diluent.
Further, the colloidal resin is acrylate copolymerization resin.
Further, the flame retardant consists of low-temperature expandable graphite, magnesium hydroxide, aluminum hydroxide, zinc borate, ammonium polyphosphate and monopentaerythritol.
Further, the diluent is ethyl acetate.
Furthermore, the expansion type metal fireproof plugging plate is connected with a building through an anchor bolt.
Furthermore, the fireproof coating layer is aluminum foil glass fiber cloth.
Compared with the prior art, the invention can obtain the following technical effects:
according to the intumescent metal fireproof plugging plate, the galvanized steel sheet is used as the base material, so that the strength of the fireproof plugging plate is ensured, the bearing capacity is improved, and secondary damage caused by collapse of a building is avoided; no flying floc is generated in the production process, so that the environmental pollution and the damage to the health of workers are reduced; the plugging plate takes the galvanized steel sheet as a base material to be coated with the fireproof layer, so that the damage is less, the defective rate is low, and the production cost is reduced; the plate is very thin, so that the installation space is saved, and the transportation cost is reduced.
Drawings
The accompanying drawings, which are included to provide a further understanding of the application and are incorporated in and constitute a part of this application, illustrate embodiment(s) of the application and together with the description serve to explain the application and not to limit the application. In the drawings:
fig. 1 is a schematic structural view of an expanded metal fire-proof plugging plate of the present invention.
Detailed Description
Embodiments of the invention are illustrated in the drawings and, for purposes of clarity, numerous implementation details are set forth in the following description. It should be understood, however, that these implementation details are not to be interpreted as limiting the invention. That is, in some embodiments of the invention, such implementation details are not necessary. In addition, some conventional structures and components are shown in simplified schematic form in the drawings.
It should be noted that all the directional indications such as up, down, left, right, front and rear … … in the embodiment of the present invention are only used to explain the relative positional relationship, movement, etc. between the components in a specific posture as shown in the drawings, and if the specific posture is changed, the directional indication is changed accordingly.
In addition, the descriptions related to the first, the second, etc. in the present invention are only used for description purposes, do not particularly refer to an order or sequence, and do not limit the present invention, but only distinguish components or operations described in the same technical terms, and are not understood to indicate or imply relative importance or implicitly indicate the number of indicated technical features. Thus, a feature defined as "first" or "second" may explicitly or implicitly include at least one such feature. In addition, technical solutions between the various embodiments can be combined with each other, but must be realized by a person skilled in the art, and when the technical solutions are contradictory or cannot be realized, the combination of the technical solutions should be considered to be absent and not be within the protection scope of the present invention.
The invention provides an expansion type metal fireproof plugging plate which is applied to the technical field of fireproof plugging and is used for separating an ignition source from the outside when a building catches fire so as to prevent the fire from expanding and threatening the life health of personnel. Referring to fig. 1, fig. 1 is a schematic structural view of an intumescent metal fire-proof plugging plate of the present invention. As shown in the figure, the intumescent metal fire-proof plugging plate of the invention comprises a substrate 1, a high-expansion fire-proof coating 2 and a fire-proof coating layer 3 which are stacked in sequence. The base material 1 is a galvanized steel sheet, the high-expansion fireproof coating 2 is coated on the base material 1, and the high-expansion fireproof coating 2 is composed of colloidal resin, a flame retardant and a diluent. The fireproof coating layer 3 is coated on the high-expansion fireproof coating layer 2, so that the high-expansion fireproof coating layer 2 is prevented from directly contacting with the environment, the high-expansion fireproof coating layer 2 is prevented from being damaged, and the fireproof performance is further influenced.
According to the invention, the galvanized steel sheet is used as the base material 1, so that the strength of the expansion type metal fireproof plugging plate is ensured, the bearing capacity is improved, and secondary damage to the environment and personnel due to the fact that the plate is not strong enough to be heavily collapsed is avoided; when the surface of the steel is galvanized, a compact protective layer can be formed on the surface of the steel, and when the zinc coating is damaged, the zinc coating can prevent the base material 1 from being corroded through the cathodic protection effect and protect the base material 1; the galvanized steel sheet has compact internal structure, the processing process can not cause the disintegration of the galvanized steel sheet, the damage is less, the defective rate is low, the unformed base material can be re-manufactured in a furnace, the recycling is convenient, the waste is reduced, and the production cost is reduced.
The thickness of the expansion type metal fireproof plugging plate is between 1.7 and 2.3 millimeters, compared with the existing plugging plate made of the mineral wool plate and the rock wool plate, the expansion type metal fireproof plugging plate is very thin, on the premise of ensuring the fireproof performance and the strength of the plugging plate, the installation space is saved, the amount of the plugging plate which can be transported at one time in the transportation process is greatly increased, and the transportation cost is reduced.
The high-expansion fireproof coating 2 consists of 40 mass percent of colloidal resin, 53.5 mass percent of flame retardant and 6.5 mass percent of diluent, the viscosity of the colloidal resin is very high, the diluent is added in the preparation process of the fireproof layer to dilute the colloidal resin, and the colloidal resin and the flame retardant are stirred and uniformly mixed. The fire retardant is adhered to the colloidal resin to form a fire-retardant micelle, the fire-retardant micelle is firmly connected through the strong adhesive force of the colloidal resin, the amount of the fire-retardant micelle is continuously increased, and the fire-retardant coating is formed.
The colloidal resin of the high-expansion fireproof coating 2 is acrylate copolymerized resin which has strong adhesive force, excellent heat resistance, chemical resistance and water resistance and can well meet the production requirements of the fireproof layer.
The flame retardant of the high-expansion fireproof coating 2 consists of low-temperature expandable graphite, magnesium hydroxide, aluminum hydroxide, zinc borate, ammonium polyphosphate and monopentaerythritol, and a plurality of layers of expansion materials are used for protecting a plugging opening to improve the fireproof coefficient. The low-temperature expandable graphite has the characteristics of low initial expansion temperature, large expansion volume and small mass loss after being heated, is heated to expand at a low temperature, is changed into a worm shape from the original scaly shape, forms a low-density heat insulation layer, effectively insulates heat and reduces heat conduction. The magnesium hydroxide and the aluminum hydroxide generate combined water when being heated and decomposed at high temperature, so that the environment is not polluted, the generated combined water absorbs environment heat, the surface temperature of the base material is reduced, the heat conducted into an adjacent space through the base material is reduced, and the possibility of spontaneous combustion of the adjacent space due to the temperature rise is reduced; meanwhile, the generated combustible gas is cooled in combination with a water heat absorption process, so that the generated combustible gas is prevented from being combusted at high temperature to further cause explosion, and the dangerous case is enlarged; the magnesium hydroxide and the aluminum hydroxide are decomposed to generate aluminum oxide or magnesium oxide, a stable covering layer is formed on the surface of the base material, and heat conduction is further blocked. The zinc borate is heated and decomposed to generate combined water, the combined water absorbs heat to reduce the ambient temperature and simultaneously dilutes oxygen in the air, the fire behavior in a fire zone is inhibited, the zinc borate is decomposed to generate boron oxide, and a covering layer is formed on the surface of the base material and can effectively inhibit the generation of combustible gas and prevent oxidation reaction and thermal decomposition reaction. The ammonium polyphosphate and the monopentaerythritol are matched to obtain the intumescent flame retardant, and the ammonium polyphosphate and the monopentaerythritol expand in heated volume to form a heat insulating layer and block heat transmission. The flame retardant used in the high-expansion fireproof coating 2 is a halogen-free flame retardant, no toxic and harmful gas is generated in the decomposition process, and no secondary damage is caused to trapped people.
The diluent adopted by the high-expansion fireproof coating 2 is ethyl acetate, the ethyl acetate has excellent solubility and can be used as the diluent, and carbon dioxide is generated when the ethyl acetate is heated and decomposed, so that the fire condition in a fire area is effectively inhibited.
The expansion type metal fireproof plugging plate is connected with a building through the anchor bolt, is convenient to assemble and disassemble, and cannot damage the building. Compared with the traditional installation mode, the installation effect is not influenced by temperature without gluing.
The fireproof coating layer 3 is made of aluminum foil glass fiber cloth which has the performances of water resistance, oil resistance and acid and alkali resistance, and protects the high-expansion fireproof coating layer 2, so that the high-expansion fireproof coating layer 2 is prevented from losing efficacy, and the service life of the high-expansion fireproof coating layer 2 is prolonged.
In summary, in one or more embodiments of the present invention, the expanded metal fireproof plugging plate uses the galvanized steel sheet as the base material, so as to ensure the strength of the fireproof plugging plate, improve the bearing capacity, and avoid secondary damage caused by collapse of the building; no flying floc is generated in the production process, so that the environmental pollution and the damage to the health of workers are reduced; the plugging plate takes the galvanized steel sheet as a base material to be coated with the fireproof layer, so that the damage is less, the defective rate is low, and the production cost is reduced; the plate is very thin, so that the installation space is saved, and the transportation cost is reduced.
The above description is only an embodiment of the present invention, and is not intended to limit the present invention. Various modifications and alterations to this invention will become apparent to those skilled in the art. Any modification, equivalent replacement, improvement, etc. made within the spirit and principle of the present invention should be included in the scope of the claims of the present invention.

Claims (1)

1. An expansion type metal fireproof plugging plate is characterized by comprising a base material (1), a high-expansion fireproof coating (2) and a fireproof coating layer (3) which are sequentially stacked, wherein the base material (1) is a galvanized steel plate; the high-expansion fireproof coating (2) is coated on the base material (1), and the high-expansion fireproof coating (2) consists of colloidal resin, 53.5% of flame retardant and 6.5% of diluent in percentage by mass; the flame retardant consists of low-temperature expandable graphite, magnesium hydroxide, aluminum hydroxide, zinc borate, ammonium polyphosphate and monopentaerythritol, and the diluent is ethyl acetate; the fireproof coating layer (3) is coated on the high-expansion fireproof coating layer (2);
wherein, the thickness of the expansion type metal fireproof plugging plate is between 1.7 and 2.3 millimeters; the colloidal resin is acrylate copolymerized resin; the expansion type metal fireproof plugging plate is connected with a building through an anchor bolt; the fireproof coating layer (3) is aluminum foil glass fiber cloth;
the flame retardant is adhered to the colloidal resin to form a flame-retardant micelle, the flame-retardant micelle is firmly connected through the strong adhesive force of the colloidal resin, the amount of the flame-retardant micelle is continuously increased, and a fireproof coating is formed; the low-temperature expandable graphite has low initial expansion temperature, large expansion volume after being heated, and is expanded by heating at low temperature, and the original scaly shape is changed into a worm shape to form a low-density heat insulation layer; carbon dioxide is generated when the ethyl acetate is heated and decomposed.
CN201811003260.9A 2018-08-30 2018-08-30 Expansion type metal fireproof plugging plate Active CN109098302B (en)

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CN109098302B true CN109098302B (en) 2020-09-04

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CN111019673B (en) * 2019-11-07 2022-03-01 浙江华消科技有限公司 Article comprising a surface coating
CN112500783A (en) * 2020-10-20 2021-03-16 北京卓越电力建设有限公司 Composite silicon rubber fireproof coating layer and fireproof plugging plate comprising same
WO2023000250A1 (en) * 2021-07-22 2023-01-26 3M创新有限公司 Fireproof composite board and fireproof structure

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CN101747693B (en) * 2008-12-12 2012-07-04 张静 Environment-friendly nano fire-retardant coating
CN202644899U (en) * 2012-06-20 2013-01-02 潘建英 Six-face wrapped aluminium foil glass fabric phenolic resin heat preservation plate
CN104893435A (en) * 2015-05-21 2015-09-09 芜湖蒲草电子商务有限公司 Wear-resistant fireproof paint for corrugated cartons and preparation method thereof
KR20180108593A (en) * 2016-01-21 2018-10-04 세키스이가가쿠 고교가부시키가이샤 Refractory multilayer sheet
CN107141939A (en) * 2017-06-16 2017-09-08 安徽康瑞高科新材料技术工程有限公司 A kind of fireproof coating

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