CN109097993A - A kind of fibre framework materials dipping solution - Google Patents
A kind of fibre framework materials dipping solution Download PDFInfo
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- CN109097993A CN109097993A CN201811051109.2A CN201811051109A CN109097993A CN 109097993 A CN109097993 A CN 109097993A CN 201811051109 A CN201811051109 A CN 201811051109A CN 109097993 A CN109097993 A CN 109097993A
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/395—Isocyanates
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/693—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural or synthetic rubber, or derivatives thereof
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/32—Polyesters
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/34—Polyamides
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/34—Polyamides
- D06M2101/36—Aromatic polyamides
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The present invention relates to a kind of fibre framework materials dipping solutions, belong to impregnation preparation technical field.Dipping solution of the invention is by blocked isocyanate, rubber latex, self-cross linking type acrylic resin and water composition.Dipping solution of the invention is without harmful substances such as resorcinol, formaldehyde and epoxy resin, it is environmentally protective, utilize self-cross linking type acrylic resin, interaction between blocked isocyanate and rubber latex three forms cross-linked network structure, both it ensure that adhesive strength, it is provided with certain flexible group again, it is easier to which rear road processing uses.Recipe ingredient is simple, and glue formula system is more stable, and the presence of acrylic resin improves the rigidity after solidifying, and realizes the excellent bonds of rubber fabric and rubber, meets the bonding of fibre framework materials and rubber, reaches or the dipping effect better than traditional RFL.
Description
Technical field
The invention belongs to impregnation preparation technical fields, and in particular to a kind of fibre framework materials dipping solution.
Background technique
Fibre framework materials dipping solution can trace back to 1938, and DuPont patent US2128635 discloses RFL
(Resorcin-Formaldehyde-Latex) formula, the adhesion process for the fabrics such as artificial silk, nylon and rubber.Along with new fiber
The appearance of framework material, in 1967, DuPont patent US3307966 was disclosed again using sealing end diisocyanate and ring
For the mixed liquor (everybody is commonly called as D417 formula at present) of oxygen resin as a bath, RFL is two baths, is handled polyester fiber, is come
Promote the bond properties between polyester fiber framework material and rubber.
All the time, people have carried out continuous research to fibre framework materials dipping solution, answer in theoretic knowledge and practice
With aspect, very big development is all achieved.The main body of dipping solution constitutes main or resorcinol-formaldehyde resin and various novel
Rubber latex.With material science in recent years advance by leaps and bounds and highest attention of the people to environmental protection and occupational health, soaking
Glue technical field, people start the attention of research is gone to the side for how reducing and using or avoid using poisonous and harmful substance
To, carried out it is a series of research and applied for related patents.
Patent US5565507, Milliken company discloses for polyester fiber and nylon fiber skeleton, and one kind is by three
Epoxy resin compound more than degree of functionality, Carboxy, the dipping solution of butadiene-vinylpyridine copylymer latex composition.
Patent EP20040002126, Diolen company disclose it is a kind of can be used for polyester industrial fiber by rubber latex, ring
Oxygen resin compound, the dipping solution of polyamines composition.
Patent EP2955268A1, Kordsa company, which discloses, can be used for nylon, polyester, artificial silk, aramid fiber, by third
Olefin(e) acid resin, epoxy resin compound block diisocyanate or base polyurethane prepolymer for use as, the dipping solution of latex composition.
Patent CN102414362A, bridgestone company, which discloses, can be used for polyester fiber and nylon fiber, by epoxidation
Close object, blocked polyisocyanates and/or amine, rubber latex, the dipping solution of composition.
JP2013 064037A is disclosed a kind of by the polyurethane resin containing blocked isocyanate end group, epoxy compound
The dipping solution that object, the functional polymer of the group containing oxazoline, polyethyleneimine, latex form.
The research direction and patent application of these companies at present is all RFL to be replaced (Resorcin-Formaldehyde-Latex body
System) in resorcinol-formaldehyde resin, avoid using resorcinol, formaldehyde this kind poisonous and harmful substance.In order to realize this
Purpose, while it being able to satisfy dipping solution bond properties again, these patents, which are substantially all, has selected epoxy resin compound as formula
Component, in addition rubber latex etc. realizes the bond properties of system.It is well known that in dipping solution rubber latex need steady in a long-term
Alkaline condition is wanted, and the stabilization and activity of epoxy resin compound can be deteriorated under alkaline condition, ultimately cause dipping solution skinning
And bond properties is deteriorated, and is unfavorable for scale and uses and industrialize tissue production.Meanwhile epoxy-resin systems are sticky, water dissolution
Rate is low, and material weighing and charging basket flushing are not easy, and influences to weigh accuracy.There is unreacted residual epoxy chlorine third in epoxy resin
The harmful substances such as alkane, thick epoxy resin easily adhere on worker's body, protective gloves and clothing, it is more difficult to clean.HSE
Also growing interest, the use of epoxy resin may cause a hidden trouble and endanger to occupational health for use of the rule to epoxy resin.
Summary of the invention
Technical problem to be solved by the present invention lies in view of the above shortcomings of the prior art, provide a kind of fiber skeleton
Material dipping solution.Dipping solution of the invention introduces self-crosslinking acrylic resin flexible group in formula system, improves
Formula system rigidity is easy to rear road processing and uses, environmentally protective without using harmful substances such as resorcinol and formaldehyde, uses effect
Fruit is good.
In order to solve the above technical problems, the technical solution adopted by the present invention is that: a kind of fibre framework materials dipping solution,
It is characterized in that, which has the feature that
A kind of fibre framework materials dipping solution, including blocked isocyanate, rubber latex, self-cross linking type acrylic acid tree
Rouge and water.
Each component is calculated by weight as in the dipping solution: 5-75 parts of blocked isocyanate dry weight, self-cross linking type propylene
5-75 parts of acid resin dry weight, 20-90 parts of rubber latex dry weight, remaining is water, impregnation fluid solid content 5-30%.
The blocked isocyanate is aliphatic or aromatic series containing two or two or more terminal isocyanate groups groups
Compound, and the terminal isocyanate groups group is blocked agent sealing end, end-capping reagent is caprolactam, diacetylmonoxime, phenol or dimethyl
Pyrazoles.
The rubber latex is butadiene-vinylpyridine copylymer latex, butadiene latex, styrene-butadiene latex, Heveatex, EPDM latex, binary
One or more of ethylene propylene rubber latex, NBR latex, carboxylated butadiene-vinylpyridine copylymer latex, carboxylated styrene-butadiene latex or carboxylic acrylonitrile butadiene rubber latex.
The self-cross linking type acrylic resin is one or more of water-soluble or dispersed acrylic resin.
There are two types of containing in the self-cross linking type acrylic resin and the two or more functional groups for having respond, functional group are
Hydroxyl, carboxyl, amide groups, methylol, ketone carbonyl, hydrazide group or amido.
Contain acrylic acid and its derivative in the polymer segment of the self-cross linking type acrylic resin, derivative is propylene
One or more of acid, methacrylic acid, itaconic acid, crotonic acid, cinnamic acid, maleic acid.
A kind of application of fibre framework materials dipping solution, with or without the processed fiber skeleton material of pre-activate
Material, is impregnated with the dipping solution, is then dried and is heat-treated, 0.1-10min, 180- are dried under the conditions of 120-200 DEG C
250 DEG C of heat treatment 0.1-10min.
The fibre framework materials are polyester PET fiber, polyester PEN fiber, nylon 66 fiber, nylon 6 fiber, artificial silk
One or more of fiber, aramid fiber.
Compared with the prior art, the present invention has the following advantages:
1. the present invention is using having self-cross linking type acrylic resin, the compound and rubber latex of blocked isocyanate are carried out
Mixing, forms cross-linked network structure using the interaction between three, both ensure that adhesive strength, compared with RF resin, again
It is provided with certain flexible group, it is easier to which rear road processing uses.
2. the present invention does not contain epoxy resin, group without using harmful substances such as resorcinol, formaldehyde and epoxy resin
Divide simply, glue formula system is more stable, and the presence of acrylic resin in formula improves the rigidity after solidifying, realizes leaching
The excellent bonds of glue fabric and rubber, dipping solution meet the bonding of fibre framework materials and rubber, reach or better than traditional RFL's
Dipping effect.
Specific embodiment
Below in conjunction with specific embodiment, the present invention is further illustrated.
Embodiment 1-12
By the dipping solution for preparing embodiment 1-12 and comparative example 1 according to the formula in table 1, each component, which is uniformly mixed, be can be used.
In embodiment 1-12, fibre framework materials using polyester tire cord fabric thread (polyester PET-HMLS industrial filament, 1670dtex/2,
370 twists/m), double bath impregnations are carried out, (raw material is purchased from EMS-Griltech company of Switzerland using widely known D417 for a bath
Blocked isocyanate IL-6 (solid content 60%) and epoxy resin G1701, formula solid content are the 3.5%) impregnation that two baths use
Formula of liquid is specifically shown in table 1.
Gum dipping process, 150 DEG C of drying temperature of a bath, 1min；230 DEG C of heat treatment temperature, 1min.Two bath drying temperatures 150
DEG C, 1min；230 DEG C of heat treatment temperature, 1min.
Comparative example 1
In comparative example 1, the fibre framework materials of use and a bath dipping solution are identical with embodiment 1-6；Using biography
RFL (Resorcin-Formaldehyde-Latex) is united as two-bath gum dipping liquid, gum dipping process is identical as embodiment 1-6.
Test the cord after 1 dipping process of embodiment 1-12 and comparative example, test method: H bonding force presses GB/T
2942-2009 method, power required for measurement single cord is extracted out from vulcanized rubber block, this bonding force is to act on cord-
Shear force value in rubber interface, the cord structure that both ends rubber block is connect with centre, which is constituted, is similar to alphabetical " H " type；Remove surface
Bonding force presses GB/T 32109-2015 method, by the way that " sandwich " form is made in two layers of sample cord and three layers of rubber, through altogether
After vulcanization, coverage condition of the rubber on cord after Tear strength and the tearing between cord and rubber is investigated.Embodiment 1-
12 and comparative example 1 dipping solution with when see Table 1 for details for test result.
1 embodiment 1-12 of table and the dipping solution of comparative example 1 are with when test result
Blocked isocyanate a is caprolactam blocking isocyanate, the IL-6 (solid content of EMS-Griltech company of Switzerland
60%)
Self-crosslinking acrylic resin b is ACRYGEN 61192 (solid content 44%), Shanghai Ou Nuo forensic chemistry Co., Ltd
(OMNOVA)
Rubber latex c is butadiene-vinylpyridine copylymer latex Pliocord VP106S (solid content 40%), Shanghai Ou Nuo forensic chemistry Co., Ltd
(OMNOVA)。
1 embodiment 1-12 of continued and the dipping solution of comparative example 1 are with when test result
Blocked isocyanate d is that diacetylmonoxime blocks blocked isocyanate 6366 (solid content 45%), and Cohan wound polymer has
Limit company.
Self-crosslinking acrylic resin e is RS-9699 (solid content 50%), Ahmedabad richness company.
Rubber latex f is butadiene-vinylpyridine copylymer latex Pliocord VP106S (solid content 40%, Shanghai Ou Nuo forensic chemistry Co., Ltd)
With styrene-butadiene latex (40%, Jiangsu Ya Tai Chemical Co., Ltd.): wherein dry weight ratio, butadiene-vinylpyridine copylymer latex/styrene-butadiene latex=7:3.
The result from table 1, it can be seen that two baths are matched using too low solid content (5%), the PET and rubber adhesion after impregnation
Effect is bad, and this point is consistent with theory, i.e., bonding force increases with the increase of rubber absorption capacity, when rubber absorption capacity reaches a certain level
Afterwards, bonding force can just be stablized constant.Too low blocked isocyanate (5%) and self-crosslinking acrylic resin content in embodiment 1
(5%) and in embodiment 2-4, too low butadiene-vinylpyridine copylymer latex content (20%) does not all obtain good bonding effect, and in reality
It applies in a 5-6, it can be seen that proportion appropriate realizes the excellent bonds of PET fiber and rubber.Envelope can be speculated from experimental result
Isocyanates and self-crosslinking acrylic resin are closed in addition to the cross-linking reaction inside dipping solution to be participated in, it is also necessary to have a certain number of
Group is reacted with PET fiber.It when dosage is very few, reacts, and is cross-linked with each other inside glue with PET fiber, two aspects all cannot
Form the chemical bonding of sufficient intensity.Equally, the co-vulcanization effect when rubber latex dosage is too low, between dipping solution and rubber
It can reduce, affect the sulfurating strength with rubber.
Result illustrates dipping solution of the invention without resorcinol in table 1, and formaldehyde in the case where epoxy resin, is realized
Polyester and the good bonding effect of rubber, have reached the identical bonding with traditional RFL (Resorcin-Formaldehyde-Latex system)
It is horizontal.
Embodiment 13-16
According to the dipping solution of formula preparation the embodiment 13-16 and comparative example 2 and comparative example 3 of table 2, each component is uniformly mixed
It can be used.
In embodiment 13 and embodiment 15, fiber skeleton uses Armaid Cord Filament (disactivation type p-aramid fiber long filament, Supreme Being people
Company, 1680dtex/2,315 twists/m), carry out double bath impregnation tests.One bath uses epoxy resin aqueous solution (G1701, Switzerland
EMS-Griltech company), the impregnation formula of liquid that two baths use is shown in Table lattice 2.Gum dipping process, 150 DEG C of a bath drying, 1min；Heat
230 DEG C for the treatment of temperature, 1min.Two 150 DEG C of bath drying, 1min；230 DEG C of heat treatment temperature, 1min.
In embodiment 14 and embodiment 16, fiber skeleton using nylon66 fiber cord fabric thread (refreshing horse industry, 1400dtex/2,300
Twist/m), carry out the test of mono bath impregnation.The impregnation formula of liquid of use is shown in Table 2.
Gum dipping process dries 150 DEG C, 1min；225 DEG C of heat treatment temperature, 2min.
Comparative example 2-3
In comparative example 2, dipping solution is bathed using with identical fibre framework materials in embodiment 13 and one, two baths are using conventional
RFL (Resorcin-Formaldehyde-Latex) formula, gum dipping process are identical as embodiment 13.
In comparative example 3, fiber skeleton uses nylon66 fiber cord fabric thread (refreshing horse industry, 1400dtex/2,300 twists/m), carries out
The test of mono bath impregnation, using conventional RFL (Resorcin-Formaldehyde-Latex), gum dipping process is identical as embodiment 14.
Be tested for the property to embodiment 13-16 and comparative example 2-3, test method: H bonding force presses GB/T2942-2009
Method, power required for measurement single cord is extracted out from vulcanized rubber block, this bonding force is acted in cord-rubber interface
Shear force value, both ends rubber block constitutes likeness in form letter " H " type with the cord structure that connect of centre.Removing surface adhesion is pressed
GB/T 32109-2015 method, by the way that " sandwich " form is made in two layers of sample cord and three layers of rubber, through co-vulcanized
Afterwards, coverage condition of the rubber on cord after Tear strength and the tearing between cord and rubber is investigated.
2 embodiment 13-16 of table and the dipping solution of comparative example 1, comparative example 2 match when test result
Blocked isocyanate a ': caprolactam blocking isocyanate IL-6 (solid content 60%), Switzerland EMS-Griltech
Company；
Self-crosslinking acrylic resin b ': ACRYGEN 61192 (solid content 44%), Shanghai Ou Nuo forensic chemistry Co., Ltd
(OMNOVA)；
C ': Pliocord VP106S of rubber latex (solid content 40%), Shanghai Ou Nuo forensic chemistry Co., Ltd；
Blocked isocyanate d ': diacetylmonoxime blocks blocked isocyanate 6366 (solid content 45%), and Cohan wound polymer has
Limit company.
Self-crosslinking acrylic resin e ': RS-9699 (solid content 50%), Ahmedabad richness company
Rubber latex f ': butadiene-vinylpyridine copylymer latex Pliocord VP106S (solid content 40%, Shanghai Ou Nuo forensic chemistry Co., Ltd)
With styrene-butadiene latex (solid content 40%, Jiangsu Ya Tai Chemical Co., Ltd.) wherein dry weight ratio, butadiene-vinylpyridine copylymer latex/styrene-butadiene latex=7:3.
In table 2, embodiment 13 and peel adhesion, removing binding efficiency grade and H adhesion level in embodiment 15 reach
The level of adhesion of comparative example 2, peel adhesion, removing binding efficiency grade and the H bonding force of embodiment 14 and embodiment 16 are arrived
Index reached the level of comparative example 3.
In conclusion without using harmful substances such as resorcinol, formaldehyde and epoxy resin, leaching of the invention
Glue has reached the level of adhesion of traditional RFL (Resorcin-Formaldehyde-Latex) dipping solution.
The above is only presently preferred embodiments of the present invention, is not intended to limit the invention in any way.It is all according to the present invention
Essence any simple modification, change and equivalence change to the above embodiments, still fall within technical solution of the present invention
In protection scope.
Claims (9)
1. a kind of fibre framework materials dipping solution, it is characterised in that: dipping solution includes blocked isocyanate, rubber latex, from
Cross-linking type acrylic acid resin and water.
2. a kind of fibre framework materials dipping solution according to claim 1, which is characterized in that each group in the dipping solution
Divide and is calculated by weight as: 5-75 parts of blocked isocyanate dry weight, 5-75 parts of self-cross linking type acrylic resin dry weight, rubber latex
20-90 parts of dry weight, remaining is water, impregnation fluid solid content 5-30%.
3. a kind of fibre framework materials dipping solution according to claim 1, which is characterized in that the blocked isocyanate
For aliphatic or aromatic compound containing two or two or more terminal isocyanate groups groups, and the terminal isocyanate groups base
Group is blocked agent sealing end, and end-capping reagent is caprolactam, diacetylmonoxime, phenol or dimethyl pyrazole.
4. a kind of fibre framework materials dipping solution according to claim 1, which is characterized in that the rubber latex is fourth
Pyrrole latex, butadiene latex, styrene-butadiene latex, Heveatex, EPDM latex, binary ethylene propylene rubber latex, NBR latex, carboxylated
One or more of butadiene-vinylpyridine copylymer latex, carboxylated styrene-butadiene latex or carboxylic acrylonitrile butadiene rubber latex.
5. a kind of fibre framework materials dipping solution according to claim 1, which is characterized in that the self-cross linking type propylene
Acid resin is one or more of water-soluble or dispersed acrylic resin.
6. a kind of fibre framework materials dipping solution according to claim 1, which is characterized in that the self-cross linking type propylene
In acid resin containing there are two types of and the two or more functional groups for having respond, functional group be hydroxyl, carboxyl, amide groups, methylol,
Ketone carbonyl, hydrazide group or amido.
7. a kind of fibre framework materials dipping solution according to claim 1, which is characterized in that the self-cross linking type propylene
In the polymer segment of acid resin contain acrylic acid and its derivative, derivative be acrylic acid, methacrylic acid, itaconic acid, bar
One or more of beans acid, cinnamic acid, maleic acid.
8. a kind of application of fibre framework materials dipping solution according to claim 1, which is characterized in that with or without
The processed fibre framework materials of pre-activate are crossed, are impregnated with the dipping solution, then dries and is heat-treated, in 120-200
0.1-10min, 180-250 DEG C of heat treatment 0.1-10min are dried under the conditions of DEG C.
9. a kind of application of fibre framework materials dipping solution according to claim 8, which is characterized in that the fiber bone
Frame material is polyester PET fiber, in polyester PEN fiber, nylon 66 fiber, nylon 6 fiber, rayon fiber, aramid fiber
It is one or more of.
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110804869A (en) * | 2019-10-09 | 2020-02-18 | 安徽华烨特种材料有限公司 | Production method of aramid fiber high-temperature-resistant framework material |
| WO2021004369A1 (en) * | 2019-07-06 | 2021-01-14 | 蔚林新材料科技股份有限公司 | Green environmentally friendly adhesive dipping liquid and method for production thereof |
| CN113957717A (en) * | 2021-11-15 | 2022-01-21 | 安徽华烨特种材料有限公司 | Ultra-high molecular weight polyethylene fiber reinforced material and preparation method thereof |
| CN114293372A (en) * | 2021-12-31 | 2022-04-08 | 青岛天邦线业有限公司 | Adhesive and fiber treated by same, textile fabric product, composite material and product |
| WO2023030423A1 (en) | 2021-09-02 | 2023-03-09 | 北京化工大学 | Environmentally friendly impregnation system for fiber surface treatment, and preparation method and impregnation treatment method therefor |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100999868A (en) * | 2006-12-29 | 2007-07-18 | 东华大学 | Improved impregnation formula for adhesion of terylene tyre cord and rubber and preparation method thereof |
| CN102634985A (en) * | 2012-03-17 | 2012-08-15 | 马鞍山科英合成材料有限公司 | Closed isocyanate adhesive for gumming fiber framework materials of rubber products, composition of closed isocyanate adhesive, preparation method and application |
| CN104532565A (en) * | 2014-12-18 | 2015-04-22 | 湖北久瑞核技术股份有限公司 | Polyester cord fabric impregnating adhesive, preparation method and impregnated polyester cord fabric |
| CN105051284A (en) * | 2013-04-26 | 2015-11-11 | 科赛全球工业丝与帘布工商股份有限公司 | A RFL-free dipping composition providing high performance for cord fabrics |
| CN106084362A (en) * | 2016-06-28 | 2016-11-09 | 江苏太极实业新材料有限公司 | A kind of environmentally friendly fibre framework materials dipping solution and gum dipping process |
| CN108004784A (en) * | 2017-12-14 | 2018-05-08 | 芜湖华烨新材料有限公司 | A kind of dipping solution for improving Polyester Cord quality and preparation method thereof |
-
2018
- 2018-09-10 CN CN201811051109.2A patent/CN109097993A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100999868A (en) * | 2006-12-29 | 2007-07-18 | 东华大学 | Improved impregnation formula for adhesion of terylene tyre cord and rubber and preparation method thereof |
| CN102634985A (en) * | 2012-03-17 | 2012-08-15 | 马鞍山科英合成材料有限公司 | Closed isocyanate adhesive for gumming fiber framework materials of rubber products, composition of closed isocyanate adhesive, preparation method and application |
| CN105051284A (en) * | 2013-04-26 | 2015-11-11 | 科赛全球工业丝与帘布工商股份有限公司 | A RFL-free dipping composition providing high performance for cord fabrics |
| CN104532565A (en) * | 2014-12-18 | 2015-04-22 | 湖北久瑞核技术股份有限公司 | Polyester cord fabric impregnating adhesive, preparation method and impregnated polyester cord fabric |
| CN106084362A (en) * | 2016-06-28 | 2016-11-09 | 江苏太极实业新材料有限公司 | A kind of environmentally friendly fibre framework materials dipping solution and gum dipping process |
| CN108004784A (en) * | 2017-12-14 | 2018-05-08 | 芜湖华烨新材料有限公司 | A kind of dipping solution for improving Polyester Cord quality and preparation method thereof |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2021004369A1 (en) * | 2019-07-06 | 2021-01-14 | 蔚林新材料科技股份有限公司 | Green environmentally friendly adhesive dipping liquid and method for production thereof |
| CN110804869A (en) * | 2019-10-09 | 2020-02-18 | 安徽华烨特种材料有限公司 | Production method of aramid fiber high-temperature-resistant framework material |
| WO2023030423A1 (en) | 2021-09-02 | 2023-03-09 | 北京化工大学 | Environmentally friendly impregnation system for fiber surface treatment, and preparation method and impregnation treatment method therefor |
| CN113957717A (en) * | 2021-11-15 | 2022-01-21 | 安徽华烨特种材料有限公司 | Ultra-high molecular weight polyethylene fiber reinforced material and preparation method thereof |
| CN114293372A (en) * | 2021-12-31 | 2022-04-08 | 青岛天邦线业有限公司 | Adhesive and fiber treated by same, textile fabric product, composite material and product |
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Application publication date: 20181228 |