CN109096961A - Preparation method for woodgrained paper aqueous binder - Google Patents
Preparation method for woodgrained paper aqueous binder Download PDFInfo
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- CN109096961A CN109096961A CN201810686477.8A CN201810686477A CN109096961A CN 109096961 A CN109096961 A CN 109096961A CN 201810686477 A CN201810686477 A CN 201810686477A CN 109096961 A CN109096961 A CN 109096961A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
- C08F283/10—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polymers containing more than one epoxy radical per molecule
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J151/00—Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
- C09J151/08—Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
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Abstract
The invention discloses the preparation methods for woodgrained paper aqueous binder, comprising: adds water: adding water into reaction kettle；Molten alcohol: by polyvinyl alcohol slowly into reaction kettle, and turn on agitator simultaneously, until being completely dissolved；Add monomer: vinyl acetate, ethyl acrylate, methacrylic acid and epoxy resin, stirring being added into reaction kettle；Emulsification: emulsifier is added into reaction kettle, is carried out fully emulsified；Cause: initiator being divided into 10 aliquots of equivalent, initiator is added into reaction kettle, an aliquot is added in the time at equal intervals, adds in 120-180min；Heat preservation: after adding initiator, heat preservation；It adjusts pH value: reaction kettle being cooled down, pH adjusting agent, propyleneglycoles and antioxidant are sequentially added, obtains milky adhesive.The adhesive of preparation has very high adhesion strength, and the water boiling resistance time is long, uses within the scope of very wide temperature；Method is simple, and controlling is good, and reaction process is mild.
Description
Technical field
The present invention relates to technical field of adhesive, the more particularly, to preparation method of woodgrained paper aqueous binder.
Background technique
Woodgrained paper generally using log slurry brown paper as base stock, then the place of techniques such as is embossed, is dyed on surface again
Reason, is finally just produced with colorful, the different woodgrained paper of decorative pattern.Woodgrained paper is due to high, the practical, sexual valence with ornamental value
Than high characteristic, therefore it is applied to the packaging of every field, especially various product or for decorating, and is used to decorate
If, it is much as furniture decoration or deburring.
And to be generally bonded woodgrained paper with furniture, it is traditional to carry out woodgrained paper if being bonded fixation with furniture,
It is fixed generally by tack, but furniture and woodgrained paper can be destroyed in this way, so that stress defect is both generated,
Destroy its integrality.
The existing adhesive that is usually used carries out fitting fixation, and still, the adhesive of existing preparation method preparation will be wooden
When line paper is bonded with furniture, intensity presence is not high, and the water boiling resistance time is too short, and the temperature range used is narrow, once it is warm
Spend low, woodgrained paper will be detached from furniture, and during the preparation process, since initiator controls bad, make monomer sometimes
Polymerization is not complete enough, and binder molecule amount is too small, and intensity is low, sometimes it also occur that sudden and violent poly-, generates security risk.
Summary of the invention
In view of this, the present invention provides the preparation methods for woodgrained paper aqueous binder.
For the preparation method of woodgrained paper aqueous binder, method and step includes:
Add water: adding water into reaction kettle, heat temperature raising is carried out to reaction kettle, heating rate is 4-8 DEG C/min, is opened
It is condensed back, is heated to 80-85 DEG C；
Molten alcohol: polyvinyl alcohol slowly being added in 4-8min into reaction kettle, and turn on agitator simultaneously, stirring speed
Degree is 40-100r/min, 20-30min is stirred, until being completely dissolved；
Add monomer: temperature of reaction kettle is down to 50-60 DEG C, vinyl acetate, ethyl acrylate, first are added into reaction kettle
Base acrylic acid and epoxy resin stir 15-25min；
Emulsification: emulsifier is added into reaction kettle, is warming up to 64-69 DEG C, stirs 25-35min, is carried out fully emulsified；
Cause: initiator being divided into 10 aliquots of equivalent, initiator is added into reaction kettle, mixing speed is adjusted to
180-260r/min, an aliquot is added in the time at equal intervals, adds in 120-180min；
Heat preservation: after adding initiator, temperature is risen to 84-88 DEG C, keeps the temperature 70-90min；
It adjusts pH value: reaction kettle being cooled to 40-50 DEG C, pH adjusting agent, propyleneglycoles and antioxidant are sequentially added,
3-8min is stirred, milky adhesive is obtained.
Preferably, method and step includes:
Add water: adding water into reaction kettle, heat temperature raising is carried out to reaction kettle, heating rate is 5-7 DEG C/min, is opened
It is condensed back, is heated to 81-84 DEG C；
Molten alcohol: polyvinyl alcohol slowly being added in 5-6min into reaction kettle, and turn on agitator simultaneously, stirring speed
Degree is 55-85r/min, 23-27min is stirred, until being completely dissolved；
Add monomer: temperature of reaction kettle is down to 52-58 DEG C, vinyl acetate, ethyl acrylate, first are added into reaction kettle
Base acrylic acid and epoxy resin stir 17-23min；
Emulsification: emulsifier is added into reaction kettle, is warming up to 65-68 DEG C, stirs 27-33min, is carried out fully emulsified；
Cause: initiator being divided into 10 aliquots of equivalent, initiator is added into reaction kettle, mixing speed is adjusted to
190-240r/min, an aliquot is added in the time at equal intervals, adds in 140-160min；
Heat preservation: after adding initiator, temperature is risen to 85-87 DEG C, keeps the temperature 75-84min；
It adjusts pH value: reaction kettle being cooled to 44-48 DEG C, pH adjusting agent, propyleneglycoles and antioxidant are sequentially added,
4-6min is stirred, milky adhesive is obtained.
Preferably, method and step includes:
Add water: adding water into reaction kettle, heat temperature raising is carried out to reaction kettle, heating rate is 6 DEG C/min, is opened cold
Solidifying reflux, is heated to 83 DEG C；
Molten alcohol: polyvinyl alcohol is slowly added in 5min into reaction kettle, and turn on agitator simultaneously, mixing speed
For 65r/min, 25min is stirred, until being completely dissolved；
Add monomer: temperature of reaction kettle is down to 55 DEG C, vinyl acetate, ethyl acrylate, methyl are added into reaction kettle
Acrylic acid and epoxy resin stir 19min；
Emulsification: emulsifier is added into reaction kettle, is warming up to 67 DEG C, stirs 29min, is carried out fully emulsified；
Cause: initiator being divided into 10 aliquots of equivalent, initiator is added into reaction kettle, mixing speed is adjusted to
220r/min, an aliquot is added in the time at equal intervals, adds in 150min；
Heat preservation: after adding initiator, temperature is risen to 86 DEG C, keeps the temperature 78min；
It adjusts pH value: reaction kettle being cooled to 46 DEG C, pH adjusting agent, propyleneglycoles and antioxidant are sequentially added, stirred
5min is mixed, milky adhesive is obtained.
Preferably, it the method also includes milky adhesive discharges, weighs, packaging.
Preferably, the antioxidant is at least one of diphenylamines, p-phenylenediamine and dihydroquinoline.
Preferably, the pH adjusting agent is one of ammonium chloride, sodium bicarbonate and sodium carbonate.
Preferably, the emulsifier is one in odium stearate, lauryl sodium sulfate and calcium dodecyl benzene sulfonate
Kind.
Preferably, the initiator is one in potassium peroxydisulfate, sodium peroxydisulfate, ammonium persulfate and N- diethylaniline
Kind.
Preferably, the water is deionized water.
Preparation method provided by the invention the present invention provides for woodgrained paper aqueous binder, this method preparation are glued
Mixture is applied between woodgrained paper and furniture, has very high adhesion strength, and the water boiling resistance time is long, can be in very wide temperature
It spends in range and uses；Preparation method is simple, and controlling is good, and reaction process is more mild.
Specific embodiment
Below in conjunction with the embodiment of the present invention, technical scheme in the embodiment of the invention is clearly and completely described,
Obviously, described embodiments are some of the embodiments of the present invention, instead of all the embodiments.Based on the implementation in the present invention
Example, every other embodiment obtained by those of ordinary skill in the art without making creative efforts belong to
The scope of protection of the invention.
It should be appreciated that ought use in this specification and in the appended claims, term " includes " and "comprising" instruction
Described feature, entirety, step, operation, the presence of element and/or component, but one or more of the other feature, whole is not precluded
Body, step, operation, the presence or addition of element, component and/or its set.
It will be further appreciated that the term "and/or" used in description of the invention and the appended claims is
Refer to any combination and all possible combinations of one or more of associated item listed, and including these combinations.
Embodiment 1
For woodgrained paper aqueous binder, by its material component of mass fraction are as follows:
Preparation method are as follows:
Weigh: by the above-mentioned substance of quality weighing: vinyl acetate, ethyl acrylate, methacrylic acid, polyvinyl alcohol,
Epoxy resin, propyleneglycoles, diphenylamines, ammonium chloride, odium stearate, potassium peroxydisulfate and deionized water；
Add deionized water: deionized water is added into reaction kettle, heat temperature raising, heating rate 4 are carried out to reaction kettle
DEG C/min, it opens and is condensed back, be heated to 85 DEG C；
Molten alcohol: polyvinyl alcohol is slowly added in 4min into reaction kettle, and turn on agitator simultaneously, mixing speed
For 40r/min, 30min is stirred, until being completely dissolved；
Add monomer: temperature of reaction kettle is down to 60 DEG C, vinyl acetate, ethyl acrylate, methyl are added into reaction kettle
Acrylic acid and epoxy resin stir 15min；
Emulsification: odium stearate is added into reaction kettle, is warming up to 69 DEG C, stirs 25min, is carried out fully emulsified；
Cause: potassium peroxydisulfate being divided into 10 aliquots of equivalent, potassium peroxydisulfate is added into reaction kettle, by mixing speed tune
To 260r/min, an aliquot is added in the time at equal intervals, is added in 120min；
Heat preservation: after adding potassium peroxydisulfate, temperature is risen to 88 DEG C, keeps the temperature 90min；
It adjusts pH value: reaction kettle being cooled to 40 DEG C, ammonium chloride, propyleneglycoles and diphenylamines are sequentially added, stir
3min obtains milky adhesive；
Packaging: milky adhesive is discharged, and is weighed, packaging.
Embodiment 2
For woodgrained paper aqueous binder, by its material component of mass fraction are as follows:
Preparation method are as follows:
Weigh: by the above-mentioned substance of quality weighing: vinyl acetate, ethyl acrylate, methacrylic acid, polyvinyl alcohol,
Epoxy resin, propyleneglycoles, p-phenylenediamine, sodium bicarbonate, lauryl sodium sulfate, sodium peroxydisulfate and deionized water；
Add deionized water: deionized water is added into reaction kettle, heat temperature raising, heating rate 7 are carried out to reaction kettle
DEG C/min, it opens and is condensed back, be heated to 81 DEG C；
Molten alcohol: polyvinyl alcohol is slowly added in 6min into reaction kettle, and turn on agitator simultaneously, mixing speed
For 55r/min, 27min is stirred, until being completely dissolved；
Add monomer: temperature of reaction kettle is down to 58 DEG C, vinyl acetate, ethyl acrylate, methyl are added into reaction kettle
Acrylic acid and epoxy resin stir 17min；
Emulsification: lauryl sodium sulfate is added into reaction kettle, is warming up to 68 DEG C, stirs 33min, carries out sufficiently cream
Change；
Cause: sodium peroxydisulfate being divided into 10 aliquots of equivalent, sodium peroxydisulfate is added into reaction kettle, by mixing speed tune
To 240r/min, an aliquot is added in the time at equal intervals, is added in 140min；
Heat preservation: after adding sodium peroxydisulfate, temperature is risen to 85 DEG C, keeps the temperature 84min；
It adjusts pH value: reaction kettle being cooled to 48 DEG C, sodium bicarbonate, propyleneglycoles and p-phenylenediamine are sequentially added,
4min is stirred, milky adhesive is obtained；
Packaging: milky adhesive is discharged, and is weighed, packaging.
Embodiment 3
For woodgrained paper aqueous binder, by its material component of mass fraction are as follows:
Preparation method are as follows:
Weigh: by the above-mentioned substance of quality weighing: vinyl acetate, ethyl acrylate, methacrylic acid, polyvinyl alcohol,
Epoxy resin, propyleneglycoles, dihydroquinoline, sodium carbonate, calcium dodecyl benzene sulfonate, ammonium persulfate and deionized water；
Add deionized water: deionized water is added into reaction kettle, heat temperature raising, heating rate 8 are carried out to reaction kettle
DEG C/min, it opens and is condensed back, be heated to 80 DEG C；
Molten alcohol: polyvinyl alcohol is slowly added in 8min into reaction kettle, and turn on agitator simultaneously, mixing speed
For 100r/min, 20min is stirred, until being completely dissolved；
Add monomer: temperature of reaction kettle is down to 50 DEG C, vinyl acetate, ethyl acrylate, methyl are added into reaction kettle
Acrylic acid and epoxy resin stir 25min；
Emulsification: calcium dodecyl benzene sulfonate is added into reaction kettle, is warming up to 64 DEG C, stirs 35min, carries out sufficiently cream
Change；
Cause: ammonium persulfate being divided into 10 aliquots of equivalent, ammonium persulfate is added into reaction kettle, by mixing speed tune
To 180r/min, an aliquot is added in the time at equal intervals, is added in 180min；
Heat preservation: after adding ammonium persulfate, temperature is risen to 84 DEG C, keeps the temperature 70min；
It adjusts pH value: reaction kettle being cooled to 50 DEG C, sodium carbonate, propyleneglycoles and dihydroquinoline are sequentially added, stirred
8min is mixed, milky adhesive is obtained；
Packaging: milky adhesive is discharged, and is weighed, packaging.
Embodiment 4
For woodgrained paper aqueous binder, by its material component of mass fraction are as follows:
Preparation method are as follows:
Weigh: by the above-mentioned substance of quality weighing: vinyl acetate, ethyl acrylate, methacrylic acid, polyvinyl alcohol,
Epoxy resin, propyleneglycoles, dihydroquinoline, sodium bicarbonate, odium stearate, N- diethylaniline and deionized water；
Add deionized water: deionized water is added into reaction kettle, heat temperature raising, heating rate 5 are carried out to reaction kettle
DEG C/min, it opens and is condensed back, be heated to 84 DEG C；
Molten alcohol: polyvinyl alcohol is slowly added in 5min into reaction kettle, and turn on agitator simultaneously, mixing speed
For 85r/min, 23min is stirred, until being completely dissolved；
Add monomer: temperature of reaction kettle is down to 52 DEG C, vinyl acetate, ethyl acrylate, methyl are added into reaction kettle
Acrylic acid and epoxy resin stir 17-23min；
Emulsification: odium stearate is added into reaction kettle, is warming up to 65 DEG C, stirs 27min, is carried out fully emulsified；
Cause: N- diethylaniline being divided into 10 aliquots of equivalent, N- diethylaniline is added into reaction kettle, will be stirred
It mixes speed and is adjusted to 190r/min, an aliquot is added in the time at equal intervals, adds in 160min；
Heat preservation: after adding N- diethylaniline, temperature is risen to 87 DEG C, keeps the temperature 75min；
It adjusts pH value: reaction kettle being cooled to 44 DEG C, sodium bicarbonate, propyleneglycoles and dihydroquinoline are sequentially added,
6min is stirred, milky adhesive is obtained；
Packaging: milky adhesive is discharged, and is weighed, packaging.
Embodiment 5
For woodgrained paper aqueous binder, by its material component of mass fraction are as follows:
Preparation method are as follows:
Weigh: by the above-mentioned substance of quality weighing: vinyl acetate, ethyl acrylate, methacrylic acid, polyvinyl alcohol,
Epoxy resin, propyleneglycoles, diphenylamines and p-phenylenediamine, sodium carbonate, odium stearate, ammonium persulfate and deionized water；
Add deionized water: deionized water is added into reaction kettle, heat temperature raising, heating rate 6 are carried out to reaction kettle
DEG C/min, it opens and is condensed back, be heated to 83 DEG C；
Molten alcohol: polyvinyl alcohol is slowly added in 5min into reaction kettle, and turn on agitator simultaneously, mixing speed
For 65r/min, 25min is stirred, until being completely dissolved；
Add monomer: temperature of reaction kettle is down to 55 DEG C, vinyl acetate, ethyl acrylate, methyl are added into reaction kettle
Acrylic acid and epoxy resin stir 19min；
Emulsification: odium stearate is added into reaction kettle, is warming up to 67 DEG C, stirs 29min, is carried out fully emulsified；
Cause: ammonium persulfate being divided into 10 aliquots of equivalent, ammonium persulfate is added into reaction kettle, by mixing speed tune
To 220r/min, an aliquot is added in the time at equal intervals, is added in 150min；
Heat preservation: after adding ammonium persulfate, temperature is risen to 86 DEG C, keeps the temperature 78min；
Adjust pH value: reaction kettle be cooled to 46 DEG C, by sodium carbonate, propyleneglycoles and diphenylamines and p-phenylenediamine according to
Secondary addition stirs 5min, obtains milky adhesive；
Packaging: milky adhesive is discharged, and is weighed, packaging.
Aqueous binder prepared by embodiment 1-5 preparation method, and in commercially available aqueous binder 1 and aqueous viscous
Mixture 2；Adhesive strength, water boiling resistance and heat resistance test are carried out, test result is as follows:
Can be learnt by above-mentioned table: the adhesive of comparative example 1, comparative example 2 and embodiment 1-5 is all cream
White liquid, the adhesive of embodiment 1-5 compared with comparative example 1,2 in terms of adhesive strength, water boiling resistance and heat resistance all
Have biggish performance advantage, wherein temperature be -10 DEG C, handle 72h, intensity is all in 15Mpa or more；It is -5 DEG C in temperature, place
72h is managed, intensity is all in 20Mpa or more；It is 45 DEG C in temperature, handles 72h, intensity, in 20Mpa or so, the temperature range of application
It can achieve between -10 DEG C of -45 degree；And at normal temperature, adhesion strength is high, and the water boiling resistance time is long.
The steps in the embodiment of the present invention can be sequentially adjusted, merged and deleted according to actual needs.
It is described in detail herein, applies specific case and the principle of the present invention and embodiment are explained
It states, above embodiments are merely used to help understand method and its core concept of the invention；Meanwhile for the general skill of this field
Art personnel, according to the thought of the present invention, there will be changes in the specific implementation manner and application range, in conclusion this
Description should not be construed as limiting the invention.
Claims (9)
1. being used for the preparation method of woodgrained paper aqueous binder, which is characterized in that method and step includes: plus water: add water to
In reaction kettle, heat temperature raising is carried out to reaction kettle, heating rate is 4-8 DEG C/min, opens and is condensed back, is heated to 80-85 DEG C；
Molten alcohol: polyvinyl alcohol is slowly added in 4-8min into reaction kettle, and turn on agitator simultaneously, mixing speed are
40-100r/min stirs 20-30min, until being completely dissolved；
Add monomer: temperature of reaction kettle is down to 50-60 DEG C, vinyl acetate, ethyl acrylate, methyl-prop are added into reaction kettle
Olefin(e) acid and epoxy resin stir 15-25min；
Emulsification: emulsifier is added into reaction kettle, is warming up to 64-69 DEG C, stirs 25-35min, is carried out fully emulsified；
Cause: initiator being divided into 10 aliquots of equivalent, initiator is added into reaction kettle, mixing speed is adjusted to 180-
260r/min, an aliquot is added in the time at equal intervals, adds in 120-180min；
Heat preservation: after adding initiator, temperature is risen to 84-88 DEG C, keeps the temperature 70-90min；
It adjusts pH value: reaction kettle being cooled to 40-50 DEG C, pH adjusting agent, propyleneglycoles and antioxidant are sequentially added, stir
3-8min obtains milky adhesive.
2. preparation method according to claim 1, which is characterized in that method and step includes:
Add water: adding water into reaction kettle, heat temperature raising is carried out to reaction kettle, heating rate is 5-7 DEG C/min, opens condensation
Reflux, is heated to 81-84 DEG C；
Molten alcohol: polyvinyl alcohol is slowly added in 5-6min into reaction kettle, and turn on agitator simultaneously, mixing speed are
55-85r/min stirs 23-27min, until being completely dissolved；
Add monomer: temperature of reaction kettle is down to 52-58 DEG C, vinyl acetate, ethyl acrylate, methyl-prop are added into reaction kettle
Olefin(e) acid and epoxy resin stir 17-23min；
Emulsification: emulsifier is added into reaction kettle, is warming up to 65-68 DEG C, stirs 27-33min, is carried out fully emulsified；
Cause: initiator being divided into 10 aliquots of equivalent, initiator is added into reaction kettle, mixing speed is adjusted to 190-
240r/min, an aliquot is added in the time at equal intervals, adds in 140-160min；
Heat preservation: after adding initiator, temperature is risen to 85-87 DEG C, keeps the temperature 75-84min；
It adjusts pH value: reaction kettle being cooled to 44-48 DEG C, pH adjusting agent, propyleneglycoles and antioxidant are sequentially added, stir
4-6min obtains milky adhesive.
3. preparation method according to claim 2, which is characterized in that method and step includes:
Add water: adding water into reaction kettle, heat temperature raising is carried out to reaction kettle, heating rate is 6 DEG C/min, and unlatching is condensed back to
Stream, is heated to 83 DEG C；
Molten alcohol: polyvinyl alcohol is slowly added in 5min into reaction kettle, and turn on agitator simultaneously, mixing speed are
65r/min stirs 25min, until being completely dissolved；
Add monomer: temperature of reaction kettle is down to 55 DEG C, vinyl acetate, ethyl acrylate, metering system are added into reaction kettle
Acid and epoxy resin stir 19min；
Emulsification: emulsifier is added into reaction kettle, is warming up to 67 DEG C, stirs 29min, is carried out fully emulsified；
Cause: initiator being divided into 10 aliquots of equivalent, initiator is added into reaction kettle, mixing speed is adjusted to 220r/
Min, an aliquot is added in the time at equal intervals, adds in 150min；
Heat preservation: after adding initiator, temperature is risen to 86 DEG C, keeps the temperature 78min；
It adjusts pH value: reaction kettle being cooled to 46 DEG C, pH adjusting agent, propyleneglycoles and antioxidant are sequentially added, stir
5min obtains milky adhesive.
4. preparation method according to claim 1 to 3, it is characterised in that: the method also includes bonding milky
Agent discharges, and weighs, packaging.
5. preparation method according to claim 1 to 3, it is characterised in that: the antioxidant is diphenylamines, to benzene two
At least one of amine and dihydroquinoline.
6. preparation method according to claim 1 to 3, it is characterised in that: the pH adjusting agent is ammonium chloride, carbonic acid
One of hydrogen sodium and sodium carbonate.
7. preparation method according to claim 1 to 3, it is characterised in that: the emulsifier is odium stearate, 12
One of sodium alkyl sulfate and calcium dodecyl benzene sulfonate.
8. preparation method according to claim 1 to 3, it is characterised in that: the initiator is potassium peroxydisulfate, over cure
One of sour sodium, ammonium persulfate and N- diethylaniline.
9. preparation method according to claim 1 to 3, it is characterised in that: the water is deionized water.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810686477.8A CN109096961A (en) | 2018-06-28 | 2018-06-28 | Preparation method for woodgrained paper aqueous binder |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810686477.8A CN109096961A (en) | 2018-06-28 | 2018-06-28 | Preparation method for woodgrained paper aqueous binder |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109096961A true CN109096961A (en) | 2018-12-28 |
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| CN201810686477.8A Withdrawn CN109096961A (en) | 2018-06-28 | 2018-06-28 | Preparation method for woodgrained paper aqueous binder |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115851181A (en) * | 2022-11-30 | 2023-03-28 | 汇胜包装科技有限公司 | Pagoda paper tube adhesive for yarn steaming and preparation method thereof |
-
2018
- 2018-06-28 CN CN201810686477.8A patent/CN109096961A/en not_active Withdrawn
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115851181A (en) * | 2022-11-30 | 2023-03-28 | 汇胜包装科技有限公司 | Pagoda paper tube adhesive for yarn steaming and preparation method thereof |
| CN115851181B (en) * | 2022-11-30 | 2024-04-02 | 汇胜包装科技有限公司 | Pagoda paper tube adhesive for steaming yarns and preparation method thereof |
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Application publication date: 20181228 |