CN109096684A - A kind of heat-resistant engineering plastic of high tenacity - Google Patents
A kind of heat-resistant engineering plastic of high tenacity Download PDFInfo
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Abstract
The present invention relates to technical field of polymer materials, and in particular to a kind of heat-resistant engineering plastic of high tenacity.The component of engineering plastics includes: ABS resin, heat-resistant filler, composite flame-retardant agent, toughened fiber, coupling agent, anti-aging agent, glyceryl monostearate, the double lauramides of ethylene and triethyl phosphite.Wherein, composite flame-retardant agent is the mixture of aluminium hydroxide, ammonium polyphosphate and antimony oxide；The ingredient of heat-resistant filler includes calcined kaolin, nano aluminium oxide, N-phenylmaleimide and dibutyl tin dilaurate；Anti-aging agent selects anti-aging agent RD or antioxidant A W.Toughened fiber is a kind of special ceramic fibre handled by rough surface with poplar bundles；The use of this toughened fiber is improved, toughness, high temperature resistance and the anti-aging property of the engineering plastics are greatly improved.
Description
Technical field
The present invention relates to technical field of polymer materials, and in particular to a kind of heat-resistant engineering plastic of high tenacity.
Background technique
Engineering plastics refer to the industrial plastics for being used as industrial part or sheathing material, are intensity, impact resistance, heat-resisting
Property, hardness and the excellent plastics of ageing resistance.Japanese industry by it be defined as can be used as construction with and machine components height
Performance plastics, heat resistance are main with industrially at 100 DEG C or more.Conventional engineering plastics type include polycarbonate,
Polyacetals, denaturation polyphenylene oxide, polyester, polyphenylene sulfide etc..Although engineering plastics hardness is big, intensity is high, stress is unlikely to deform, resistance to punching
Hit excellent performance, but engineering plastics generally have the shortcomings that toughness is poor, are easily broken off when by bending power, material fragility compared with
It is high.
In order to promote the toughness of engineering plastics, conventional method is that a small amount of fibre composition is added in resin material, industry
In production, the fiber used is mainly asbestos mineral fiber, polyester fiber, Fypro, vinal, polyacrylonitrile
The inorfils three classes such as the synthetic fibers such as fiber and glass fibre, carbon fiber, the high temperature resistance of most organic fiber
Not as good as inorganic fibers, therefore pass through the inorfils such as addition glass fibre, ceramic fibre, carbon fiber in fire resistant resin
Material.
It is multiple that Chinese invention patent application number CN201610322232.8 discloses a kind of graphene/glass fiber reinforced ABS
Condensation material and preparation method thereof, the technical solution are exactly to be promoted using graphene and glass fibre to the toughness of ABS resin,
Achieve the purpose that enhance mechanical property, processing performance and thermal stability.
The inorfils such as common glass fibre, ceramic bowl, carbon fiber generally have fiber due to the limitation of processing technology
Surface flatness is high, the disadvantage of combination intensity deficiency poor with the compatilizer of reisn base material；Preparing compound resin
Floating fine phenomenon can be generated when material, so that the intensity of composite material, thermal stability and anti-aging property reduce.
Summary of the invention
Aiming at the problems existing in the prior art, the present invention provides a kind of heat-resistant engineering plastic of high tenacity, the engineerings
Plastics are by the use of special toughened fiber, so that the toughness of engineering plastics, high temperature resistance and anti-aging property obtain very
It is big to be promoted.
In order to achieve the above object, the present invention is achieved through the following technical solutions:
A kind of heat-resistant engineering plastic of high tenacity, according to mass fraction, the component of the engineering plastics includes: ABS resin 100-120
Part, it is 15-18 parts of heat-resistant filler, 3-8 parts of composite flame-retardant agent, 3-7 parts of toughened fiber, 2-4 parts of coupling agent, 1-2 parts of anti-aging agent, stearic
Sour monoglyceride 1-2 parts, double 0.5-1.3 parts of the lauramides of ethylene, 0.5-0.8 parts of triethyl phosphite.
Preferably, according to mass fraction, the component of engineering plastics includes: 110-115 parts of ABS resin, heat-resistant filler 16-17
Part, 4-6 parts of composite flame-retardant agent, 5-6 parts of toughened fiber, 2.5-3.5 parts of coupling agent, 1.3-1.7 parts of anti-aging agent, stearic acid list glycerol
1.2-1.6 parts of ester, double 0.8-1.1 parts of the lauramides of ethylene, 0.6-0.7 parts of triethyl phosphite.
It is further preferred that the component of engineering plastics includes: 117 parts of ABS resin, heat-resistant filler according to mass fraction
16.5 parts, 5 parts of composite flame-retardant agent, 5.5 parts of toughened fiber, 3 parts of coupling agent, 1.5 parts of anti-aging agent, 1.4 parts of glyceryl monostearate,
Double 0.9 part of the lauramides of ethylene, 0.7 part of triethyl phosphite.
In the present invention, the preparation method of toughened fiber includes the following steps:
(1) according to mass percent, prepare ceramic raw material: calcium hydroxide 6.5-8.6%, colloidal silicon dioxide 20.5-22.3%, two
Titanium oxide 1.5-2.3%, magnesium sulfate 4.5-6.3%, yttrium carbonate 0.02-0.04%, sodium carbonate 9.4-11.7%, surplus are aluminum nitrate；
Ceramic raw material is added to ball milling mixing in ball mill, obtains required fibrous matter source；
(2) according to mass percent, by the fibrous matter source of 15.3wt%, the polyvinyl alcohol of 9.7wt%, the polycyclic oxygen third of 3.6wt%
Alkane, the lauric monoethanolamide of 0.8wt%, the glycine betaine of 2.8wt%；It is add to deionized water decentralized processing, then to group
It closes and acetic acid is added dropwise in liquid, the pH value for adjusting combination liquid is 3.8-4.5, obtains required fibrous matter liquid；
(3) fibrous matter liquid is added in the liquid storage container of electrospinning device, spinning spout of the fibrous matter liquid from equipment
It projects, is acted on by the high voltage power supply of 15.5-18.0kV, fibrous matter liquid directive collector, the volatile matter in fibrous matter liquid
After volatilization, collection obtains spinning fibre, spinning fibre is sent in high temperature furnace, with 1050-1200 DEG C of high temperature firing 2.5-
3h obtains required ceramic fibre；The diameter of ceramic fibre is 120-150nm；
(4) dry after ceramic fibre being washed with deionized, it is then fed into acidizing corrosion process chamber, acidizing corrosion processing
Interior is full hydrogen chloride steam, and steam pressure 0.8-1.0MPa, the indoor temperature of acidizing corrosion processing is 150-160 DEG C,
Acidizing corrosion handles the time as 4-7s, and after treatment takes out the fiber after acidizing corrosion, with deionized water repeated flushing 3-5
It is secondary, until cleaning solution is in neutrality；
(5) according to mass percent, by the superfine silicon carbide whisker of 13wt%, the polyvinyl butyral of 0.8wt%, 0.6wt%'s
The triethyl phosphate of the pure and mild 2wt% of propionic acid is added in isopropanol solvent, and ultrasonic wave decentralized processing obtains whisker maceration extract, will be upper
The ceramic fibre of step is immersed in whisker maceration extract and handles 10-15min, then takes out ceramic fibre, is sent to high temperature furnace
In, 30-40min is burnt into 480-560 DEG C of temperature, product cooled to room temperature will be burnt into, be chopped into using cutter
Length is the staple fiber of 1-2mm to get required toughened fiber.
Wherein, nitrogen atmosphere is all made of in the high temperature furnace sintering process in step (3) and step (5) to be protected.
The partial size of superfine silicon carbide whisker is 50-55nm in step (5).
Preferably, composite flame-retardant agent is aluminium hydroxide, ammonium polyphosphate and antimony oxide according to the mixed of 5:2:2 mass ratio
Close object.
Preferably, heat-resistant filler is by calcined kaolin, nano aluminium oxide, N-phenylmaleimide and tin dilaurate two
After butyl tin is according to the mass ratio mixing of 20:8:3:5, production that the temperature in mixing kettle with 80-95 DEG C obtains after being stirred to react
Object.
Preferably, anti-aging agent selects anti-aging agent RD or antioxidant A W.
Engineering plastics provided by the invention the preparation method comprises the following steps:
According to mass fraction, by heat-resistant filler, composite flame-retardant agent, toughened fiber, glyceryl monostearate, the double lauramides of ethylene
It is added in batch mixer with triethyl phosphite and 5-7min is mixed；Then by mixture and coupling agent, anti-aging agent, ABS tree
Rouge is added in double screw extruder together, with 180-195 DEG C of temperature extruding pelletization, obtains required engineering plastics.
The present invention have it is following the utility model has the advantages that
The engineering plastics are a kind of ABS composite resin materials, further increase material by the use of heat-resistant filler in engineering plastics
The high temperature resistance of material improves the toughness and thermal stability of resin material by toughened fiber；Stearic acid used in component
Monoglyceride is used as lubricant, and the double lauramides of ethylene are used as dispersing agent, the synergistic effect that the two generates, Ke Yixian
The compatibility and dispersion effect for improving heat-resistant filler and toughened fiber in resin matrix are write, so that the property of resin material is more
It is uniform and stable；Triethyl phosphite is added as stabilizer, so that the heat resistance of ABS resin is higher good, thermal stability is more preferably.
Wherein, toughened fiber used in the present invention is a kind of special fibrous material, this fiber utilization electrostatic spinning
It is prepared with high-temperature roasting technology, is a kind of refractory ceramic fibre；The refractoriness of fiber is very high, and tensile strength is also very excellent
Show is suitble in resin material use as toughened and strengthened dose and heat-resisting reinforcing agent.In order to improve ceramic fibre and ABS resin master
Combination effect between body material is specially roughened fiber surface using atomization corrosion technology, then will receive again
Rice silicon carbide whisker roasting is solidificated in fiber surface, and this coarse poplar bundles structure can make the intensity of ceramic fibre more
Height, and promote the interaction between ceramic fibre and resin matrix and bond strength；So that the toughness of the engineering plastics of preparation,
Tensile strength and thermal stability are significantly improved.
Specific embodiment
Below with reference to embodiment, further description of the specific embodiments of the present invention, and following embodiment is only used for more
Technical solution of the present invention is clearly demonstrated, and not intended to limit the protection scope of the present invention.
In following embodiment, the preparation method of toughened fiber includes the following steps:
(1) according to mass percent, prepare ceramic raw material: calcium hydroxide 7.2%, colloidal silicon dioxide 21.5%, titanium dioxide
1.8%, magnesium sulfate 5.4%, yttrium carbonate 0.03%, sodium carbonate 10.2%, surplus is aluminum nitrate；Ceramic raw material is added in ball mill
Ball milling mixing, obtain required fibrous matter source；
(2) according to mass percent, by the fibrous matter source of 15.3wt%, the polyvinyl alcohol of 9.7wt%, the polycyclic oxygen third of 3.6wt%
Alkane, the lauric monoethanolamide of 0.8wt%, the glycine betaine of 2.8wt%；It is add to deionized water decentralized processing, then to group
It closes and acetic acid is added dropwise in liquid, the pH value for adjusting combination liquid is 4.2, obtains required fibrous matter liquid；
(3) fibrous matter liquid is added in the liquid storage container of electrospinning device, spinning spout of the fibrous matter liquid from equipment
It projects, is acted on by the high voltage power supply of 17.0kV, fibrous matter liquid directive collector, the volatile matter volatilization in fibrous matter liquid
Afterwards, it collects and obtains spinning fibre, spinning fibre is sent in high temperature furnace, 2.7h is burnt into 1100 DEG C of high-temperature, is obtained
Required ceramic fibre；The diameter of ceramic fibre is 120-150nm；
(4) dry after ceramic fibre being washed with deionized, it is then fed into acidizing corrosion process chamber, acidizing corrosion processing
Interior is full hydrogen chloride steam, and steam pressure 0.9MPa, the indoor temperature of acidizing corrosion processing is 155 DEG C, acidizing corrosion
The processing time is 5s, and after treatment takes out the fiber after acidizing corrosion, with deionized water repeated flushing 4 times, until cleaning solution
It is in neutrality；
(5) according to mass percent, by the superfine silicon carbide whisker of 13wt%, the polyvinyl butyral of 0.8wt%, 0.6wt%'s
The triethyl phosphate of the pure and mild 2wt% of propionic acid is added in isopropanol solvent, and ultrasonic wave decentralized processing obtains whisker maceration extract, will be upper
The ceramic fibre of step is immersed in whisker maceration extract and handles 13min, then takes out ceramic fibre, is sent in high temperature furnace,
It is burnt into 35min with 500 DEG C of temperature, product cooled to room temperature will be burnt into, being chopped into length using cutter is 1-2mm
Staple fiber to get required toughened fiber.
Wherein, nitrogen atmosphere is all made of in the high temperature furnace sintering process in step (3) and step (5) to be protected.
The partial size of superfine silicon carbide whisker is 50-55nm in step (5).
Embodiment 1
A kind of heat-resistant engineering plastic of high tenacity, according to mass fraction, the component of the engineering plastics includes: 100 parts of ABS resin,
15 parts of heat-resistant filler, 3 parts of composite flame-retardant agent, 3 parts of toughened fiber, 2 parts of coupling agent, 1 part of anti-aging agent, 1 part of glyceryl monostearate,
Double 0.5 part of the lauramides of ethylene, 0.5 part of triethyl phosphite.
Wherein, composite flame-retardant agent is the mixing of aluminium hydroxide, ammonium polyphosphate and antimony oxide according to 5:2:2 mass ratio
Object.
Heat-resistant filler is by calcined kaolin, nano aluminium oxide, N-phenylmaleimide and dibutyl tin dilaurate
After the mass ratio mixing of 20:8:3:5, the product that is obtained after being stirred to react in mixing kettle with 80 DEG C of temperature.
Anti-aging agent selects anti-aging agent RD.
Engineering plastics provided by the invention the preparation method comprises the following steps:
According to mass fraction, by heat-resistant filler, composite flame-retardant agent, toughened fiber, glyceryl monostearate, the double lauramides of ethylene
It is added in batch mixer with triethyl phosphite and 5min is mixed；Then by mixture and coupling agent, anti-aging agent, ABS resin
It is added in double screw extruder together, with 180 DEG C of temperature extruding pelletization, obtains required engineering plastics.
Embodiment 2
A kind of heat-resistant engineering plastic of high tenacity, according to mass fraction, the component of the engineering plastics includes: 120 parts of ABS resin,
18 parts of heat-resistant filler, 8 parts of composite flame-retardant agent, 7 parts of toughened fiber, 4 parts of coupling agent, 2 parts of anti-aging agent, 2 parts of glyceryl monostearate,
Double 1.3 parts of the lauramides of ethylene, 0.8 part of triethyl phosphite.
Wherein, composite flame-retardant agent is the mixing of aluminium hydroxide, ammonium polyphosphate and antimony oxide according to 5:2:2 mass ratio
Object.
Heat-resistant filler is by calcined kaolin, nano aluminium oxide, N-phenylmaleimide and dibutyl tin dilaurate
After the mass ratio mixing of 20:8:3:5, the product that is obtained after being stirred to react in mixing kettle with 95 DEG C of temperature.
Anti-aging agent selects antioxidant A W.
Engineering plastics provided by the invention the preparation method comprises the following steps:
According to mass fraction, by heat-resistant filler, composite flame-retardant agent, toughened fiber, glyceryl monostearate, the double lauramides of ethylene
It is added in batch mixer with triethyl phosphite and 7min is mixed；Then by mixture and coupling agent, anti-aging agent, ABS resin
It is added in double screw extruder together, with 195 DEG C of temperature extruding pelletization, obtains required engineering plastics.
Embodiment 3
A kind of heat-resistant engineering plastic of high tenacity, according to mass fraction, the component of the engineering plastics includes: 117 parts of ABS resin,
16.5 parts of heat-resistant filler, 5 parts of composite flame-retardant agent, 5.5 parts of toughened fiber, 3 parts of coupling agent, 1.5 parts of anti-aging agent, stearic acid list glycerol
1.4 parts of ester, double 0.9 part of the lauramides of ethylene, 0.7 part of triethyl phosphite.
Wherein, composite flame-retardant agent is the mixing of aluminium hydroxide, ammonium polyphosphate and antimony oxide according to 5:2:2 mass ratio
Object.
Heat-resistant filler is by calcined kaolin, nano aluminium oxide, N-phenylmaleimide and dibutyl tin dilaurate
After the mass ratio mixing of 20:8:3:5, product that the temperature in mixing kettle with 80-95 DEG C obtains after being stirred to react.
Anti-aging agent selects anti-aging agent RD.
Engineering plastics provided by the invention the preparation method comprises the following steps:
According to mass fraction, by heat-resistant filler, composite flame-retardant agent, toughened fiber, glyceryl monostearate, the double lauramides of ethylene
It is added in batch mixer with triethyl phosphite and 6min is mixed；Then by mixture and coupling agent, anti-aging agent, ABS resin
It is added in double screw extruder together, with 190 DEG C of temperature extruding pelletization, obtains required engineering plastics.
Performance test
1, using buy in the market Chongqing Hua Zhong new material Co., Ltd sale the trade mark for ABS-658 resin material as
Control group tests impact strength, elongation, bending strength and the dimension of the plastic grain of the present embodiment and the plastic grain of comparative example
The performance indicators such as card softening point temperature obtain following test data:
Table 1: the performance test results of the present embodiment and control group plastic grain
The experimental results showed that, the performance of the mechanical performances such as impact strength, elongation and bending strength of the type engineering plastics is non-above
Chang Youxiu, shape performance exceed common ABS resin, show better toughness properties；In addition, the heat resistance of the resin material is more
Good, vicat softening temperature is higher, is able to bear higher temperature environment.
The foregoing is only a preferred embodiment of the present invention, is not intended to restrict the invention, although referring to aforementioned reality
Applying example, invention is explained in detail, for those skilled in the art, still can be to aforementioned each implementation
Technical solution documented by example is modified or equivalent replacement of some of the technical features.It is all in essence of the invention
Within mind and principle, any modification, equivalent replacement, improvement and so on be should all be included in the protection scope of the present invention.
Claims (10)
1. a kind of heat-resistant engineering plastic of high tenacity, it is characterised in that: according to mass fraction, the group subpackage of the engineering plastics
It includes: 100-120 parts of ABS resin, 15-18 parts of heat-resistant filler, 3-8 parts of composite flame-retardant agent, 3-7 parts of toughened fiber, coupling agent 2-4
Part, 1-2 parts of anti-aging agent, 1-2 parts of glyceryl monostearate, double 0.5-1.3 parts of the lauramides of ethylene, triethyl phosphite 0.5-
0.8 part.
2. a kind of heat-resistant engineering plastic of high tenacity according to claim 1, it is characterised in that: according to mass fraction, institute
The component for stating engineering plastics includes: 110-115 parts of ABS resin, and 16-17 parts of heat-resistant filler, 4-6 parts of composite flame-retardant agent, toughening is fine
5-6 parts of dimension, 2.5-3.5 parts of coupling agent, 1.3-1.7 parts of anti-aging agent, 1.2-1.6 parts of glyceryl monostearate, the double lauroyl of ethylene
0.8-1.1 parts of amine, 0.6-0.7 parts of triethyl phosphite.
3. a kind of heat-resistant engineering plastic of high tenacity according to claim 2, it is characterised in that: according to mass fraction, institute
The component for stating engineering plastics includes: 117 parts of ABS resin, and 16.5 parts of heat-resistant filler, 5 parts of composite flame-retardant agent, 5.5 parts of toughened fiber,
3 parts of coupling agent, 1.5 parts of anti-aging agent, 1.4 parts of glyceryl monostearate, double 0.9 part of the lauramides of ethylene, triethyl phosphite 0.7
Part.
4. a kind of heat-resistant engineering plastic of high tenacity according to claim 1, it is characterised in that: the system of the toughened fiber
Preparation Method includes the following steps:
(1) according to mass percent, prepare ceramic raw material: calcium hydroxide 6.5-8.6%, colloidal silicon dioxide 20.5-22.3%, two
Titanium oxide 1.5-2.3%, magnesium sulfate 4.5-6.3%, yttrium carbonate 0.02-0.04%, sodium carbonate 9.4-11.7%, surplus are aluminum nitrate；
Ceramic raw material is added to ball milling mixing in ball mill, obtains required fibrous matter source；
(2) according to mass percent, by the fibrous matter source of 15.3wt%, the polyvinyl alcohol of 9.7wt%, the polycyclic oxygen third of 3.6wt%
Alkane, the lauric monoethanolamide of 0.8wt%, the glycine betaine of 2.8wt%；It is add to deionized water decentralized processing, then to group
It closes and acetic acid is added dropwise in liquid, the pH value for adjusting combination liquid is 3.8-4.5, obtains required fibrous matter liquid；
(3) fibrous matter liquid is added in the liquid storage container of electrospinning device, spinning spout of the fibrous matter liquid from equipment
It projects, is acted on by the high voltage power supply of 15.5-18.0kV, fibrous matter liquid directive collector, the volatile matter in fibrous matter liquid
After volatilization, collection obtains spinning fibre, spinning fibre is sent in high temperature furnace, with 1050-1200 DEG C of high temperature firing 2.5-
3h obtains required ceramic fibre；The diameter of ceramic fibre is 120-150nm；
(4) dry after ceramic fibre being washed with deionized, it is then fed into acidizing corrosion process chamber, acidizing corrosion processing
Interior is full hydrogen chloride steam, and steam pressure 0.8-1.0MPa, the indoor temperature of acidizing corrosion processing is 150-160 DEG C,
Acidizing corrosion handles the time as 4-7s, and after treatment takes out the fiber after acidizing corrosion, with deionized water repeated flushing 3-5
It is secondary, until cleaning solution is in neutrality；
(5) according to mass percent, by the superfine silicon carbide whisker of 13wt%, the polyvinyl butyral of 0.8wt%, 0.6wt%'s
The triethyl phosphate of the pure and mild 2wt% of propionic acid is added in isopropanol solvent, and ultrasonic wave decentralized processing obtains whisker maceration extract, will be upper
The ceramic fibre of step is immersed in whisker maceration extract and handles 10-15min, then takes out ceramic fibre, is sent to high temperature furnace
In, 30-40min is burnt into 480-560 DEG C of temperature, product cooled to room temperature will be burnt into, be chopped into using cutter
Length is the staple fiber of 1-2mm to get required toughened fiber.
5. a kind of heat-resistant engineering plastic of high tenacity according to claim 4, it is characterised in that: the step (3) and step
Suddenly nitrogen atmosphere is all made of in the high temperature furnace sintering process in (5) to be protected.
6. a kind of heat-resistant engineering plastic of high tenacity according to claim 4, it is characterised in that: surpass in the step (5)
The partial size of thin silicon carbide whisker is 50-55nm.
7. a kind of heat-resistant engineering plastic of high tenacity according to claim 1, it is characterised in that: the composite flame-retardant agent is
Aluminium hydroxide, ammonium polyphosphate and antimony oxide according to 5:2:2 mass ratio mixture.
8. a kind of heat-resistant engineering plastic of high tenacity according to claim 1, it is characterised in that: the heat-resistant filler be by
Calcined kaolin, nano aluminium oxide, N-phenylmaleimide and dibutyl tin dilaurate according to 20:8:3:5 mass ratio
After mixing, product that the temperature in mixing kettle with 80-95 DEG C obtains after being stirred to react.
9. a kind of heat-resistant engineering plastic of high tenacity according to claim 1, it is characterised in that: the anti-aging agent is selected anti-
Old agent RD or antioxidant A W.
10. a kind of heat-resistant engineering plastic of high tenacity according to claim 1, which is characterized in that the engineering plastics
The preparation method comprises the following steps:
According to mass fraction, by heat-resistant filler, composite flame-retardant agent, toughened fiber, glyceryl monostearate, the double lauramides of ethylene
It is added in batch mixer with triethyl phosphite and 5-7min is mixed；Then by mixture and coupling agent, anti-aging agent, ABS tree
Rouge is added in double screw extruder together, with 180-195 DEG C of temperature extruding pelletization, obtains required engineering plastics.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111073249A (en) * | 2019-12-18 | 2020-04-28 | 佛山科学技术学院 | High-temperature-resistant plastic material |
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| CN102108178A (en) * | 2009-12-28 | 2011-06-29 | 崔贵府 | Flame-retarding reinforced acrylonitrile-butadiene-styrene (ABS) composite containing ceramic fibers and preparation method thereof |
| CN102993621A (en) * | 2011-09-13 | 2013-03-27 | 黑龙江鑫达企业集团有限公司 | Glass fiber reinforced flame-retardant ABS composite material having high impact resistance and high heat resistance, and its preparation technology |
| CN104448685A (en) * | 2014-12-17 | 2015-03-25 | 天津金发新材料有限公司 | Ceramic fiber reinforced flame retardant ABS and preparation method thereof |
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| CN102108179A (en) * | 2009-12-28 | 2011-06-29 | 崔贵府 | Ceramic fiber-containing flame-retardant and reinforced bulk polymerization-prepared acrylonitrile-butadiene-styrene (ABS) complex and preparation method thereof |
| CN102108178A (en) * | 2009-12-28 | 2011-06-29 | 崔贵府 | Flame-retarding reinforced acrylonitrile-butadiene-styrene (ABS) composite containing ceramic fibers and preparation method thereof |
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| CN111073249A (en) * | 2019-12-18 | 2020-04-28 | 佛山科学技术学院 | High-temperature-resistant plastic material |
| CN111073249B (en) * | 2019-12-18 | 2022-03-22 | 佛山科学技术学院 | High-temperature-resistant plastic material |
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Application publication date: 20181228 |