CN109096617A - A kind of uvioresistant rubber antioxidant of novel environment friendly - Google Patents
A kind of uvioresistant rubber antioxidant of novel environment friendly Download PDFInfo
- Publication number
- CN109096617A CN109096617A CN201810769692.4A CN201810769692A CN109096617A CN 109096617 A CN109096617 A CN 109096617A CN 201810769692 A CN201810769692 A CN 201810769692A CN 109096617 A CN109096617 A CN 109096617A
- Authority
- CN
- China
- Prior art keywords
- parts
- accounting
- rubber
- tpa
- terephthalic acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/16—Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/02—Organic and inorganic ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
- C08K5/098—Metal salts of carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
- C08K5/37—Thiols
- C08K5/372—Sulfides, e.g. R-(S)x-R'
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/52—Phosphorus bound to oxygen only
- C08K5/524—Esters of phosphorous acids, e.g. of H3PO3
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L21/00—Compositions of unspecified rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L91/00—Compositions of oils, fats or waxes; Compositions of derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L91/00—Compositions of oils, fats or waxes; Compositions of derivatives thereof
- C08L91/06—Waxes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L93/00—Compositions of natural resins; Compositions of derivatives thereof
- C08L93/04—Rosin
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
Abstract
The invention discloses a kind of uvioresistant rubber antioxidants of novel environment friendly, it is made of according to parts by weight following raw material: 5.5-7.5 parts of clay powder accounting, 4.5-5.6 parts of isproportionated potassium rosinate, 3.2-4 parts of anti-aging agent accounting, 30-40 parts of ethylene propylene diene rubber, 0.8-1.5 parts of phosphite ester accounting, 3.8-7.2 parts of nano zine oxide accounting, 2.5-3.2 parts of phosphorous oxychloride accounting, 2.5-3.5 parts of paraffin accounting, 8.7-12.5 parts of Corvic, 2.4-3.3 parts of terephthalic acid (TPA) aluminium, 4.5-5.5 parts of dithiodipropionic acid dilauryl, 3.4-4.2 parts of acrylic acid accounting, 1.6-2.5 parts of fire retardant accounting, 8-15 parts of xylene formaldehyde resin, 3.5-4.5 parts of mould inhibitor accounting, it is right 0.6-1.2 parts and 4.8-5.7 parts of aromatic naphtha accounting of phthalic acid barium accounting.The features such as a kind of rubber antioxidant of the invention has preferable thermal stability and enduring quality, good with rubber matrix compatibility after use, has stronger antifatigue and anti-ultraviolet property, and anti-aging efficiency is greatly improved than traditional anti-aging agent.
Description
Technical field
The present invention relates to rubber production research and development correlative technology field more particularly to a kind of uvioresistant rubber of novel environment friendly
Anti-aging agent.
Background technique
In use, will receive extraneous factor (such as ozone aging, thermo-oxidative ageing) influences and aging rubber, causes
Its physical mechanical property changes, and rubber is made to follow the string, mechanical performance decline, reduced service life.In order to solve rubber
Problem of aging, it is necessary to suitable adjuvants are added in rubber, to restrain or delay ager process, prolong the service life, it is this
Auxiliary agent for preventing ageing of rubber is anti-aging agent.Rubber antioxidant be it is a kind of be added during rubber production can prolong
Slow ageing of rubber, the chemicals for extending rubber service life.
Anti-aging agent yield and kind occupy first of rubber chemicals.Amines antioxidants is current production rate because anti ageing property is good
One of with the maximum kind of dosage, but contain amino in its molecular structure, is also easy to produce carcinogen, and rubber product can be made to change colour
Or there is bloom phenomenon on surface, therefore use and receive certain limitation, therefore it is anti-old to have investigated a kind of environment-friendly rubber
Agent.
Environmentally-friendly rubber anti-ageing agent has phenols, esters, Thiourea, composite environment-friendly anti-aging agent, and phenol antiager is non-discolouring,
It does not pollute, no blooming, is a kind of pollution-free anti-aging agent.Contain hydroxyl in phenol antiager, the object being harmful to the human body will not be generated
Matter, it can inhibit radical reaction, achieve the purpose that prevent ageing of rubber.The use in vulcanizate of Phosphorus anti-aging agent will not generate
Environmentally hazardous noxious material, it is a kind of environmentally protective anti-aging agent, and the stability of rubber product can be enhanced.
There are a large amount of unoccupied orbital in rare earth anti-aging agent rare earth element, can in conjunction with the free radical generated in oxidation process,
Chain reaction is terminated, the continuation of oxidation reaction is inhibited.Compound anti-aging agent is to compound anti-aging agent, utilizes the association between component
Same-action plays the effect of each anti-aging agent to the maximum extent.
But that there is also thermal stability is poor for current anti-aging agent, and anti-aging low efficiency, persistence is poor, uses rear antifatigue and anti-purple
Outside line performance is poor, and with rubber matrix poor compatibility problem.
Summary of the invention
The purpose of the present invention is to solve disadvantages existing in the prior art, and a kind of anti-purple of the novel environment friendly proposed
Outside line rubber antioxidant.
To achieve the goals above, present invention employs following technical solutions:
A kind of uvioresistant rubber antioxidant of novel environment friendly is made of according to parts by weight following raw material: clay powder accounting 5.5-
7.5 parts, 4.5-5.6 parts of isproportionated potassium rosinate, 3.2-4 parts of anti-aging agent accounting, 30-40 parts of ethylene propylene diene rubber, phosphite ester
0.8-1.5 parts of accounting, 3.8-7.2 parts of nano zine oxide accounting, 2.5-3.2 parts of phosphorous oxychloride accounting, paraffin accounting 2.5-3.5
Part, 8.7-12.5 parts of Corvic, 2.4-3.3 parts of terephthalic acid (TPA) aluminium, dithiodipropionic acid dilauryl 4.5-5.5
Part, 3.4-4.2 parts of acrylic acid accounting, 1.6-2.5 parts of fire retardant accounting, 8-15 parts of xylene formaldehyde resin, mould inhibitor accounting
3.5-4.5 parts, 0.6-1.2 parts of terephthalic acid (TPA) barium accounting and 4.8-5.7 parts of aromatic naphtha accounting.
A kind of uvioresistant rubber antioxidant of above-mentioned novel environment friendly is made of according to parts by weight following raw material: clay
5.5-7.4 parts of powder accounting, 4.5-5.5 parts of isproportionated potassium rosinate, 3.2-3.9 parts of anti-aging agent accounting, ethylene propylene diene rubber 30-39
Part, 0.8-1.4 parts of phosphite ester accounting, 3.8-7.1 parts of nano zine oxide accounting, 2.5-3.1 parts of phosphorous oxychloride accounting, paraffin account for
Than 2.5-3.4 parts, 8.7-12.4 parts of Corvic, 2.4-3.2 parts of terephthalic acid (TPA) aluminium, dithiodipropionic acid dilauryl
4.5-5.4 parts, 3.4-4.1 parts of acrylic acid accounting, 1.6-2.4 parts of fire retardant accounting, 8-14 parts of xylene formaldehyde resin, mould inhibitor
3.5-4.4 parts of accounting, 0.6-1.1 parts of terephthalic acid (TPA) barium accounting and 4.8-5.6 parts of aromatic naphtha accounting.
A kind of uvioresistant rubber antioxidant of above-mentioned novel environment friendly is made of according to parts by weight following raw material: clay
5.6-7.4 parts of powder accounting, 4.6-5.5 parts of isproportionated potassium rosinate, 3.1-3.9 parts of anti-aging agent accounting, ethylene propylene diene rubber 31-39
Part, 0.9-1.4 parts of phosphite ester accounting, 3.9-7.1 parts of nano zine oxide accounting, 2.6-3.1 parts of phosphorous oxychloride accounting, paraffin account for
Than 2.6-3.4 parts, 8.8-12.4 parts of Corvic, 2.5-3.2 parts of terephthalic acid (TPA) aluminium, dithiodipropionic acid dilauryl
4.6-5.4 parts, 3.5-4.1 parts of acrylic acid accounting, 1.7-2.4 parts of fire retardant accounting, 9-14 parts of xylene formaldehyde resin, mould inhibitor
3.6-4.4 parts of accounting, 0.7-1.1 parts of terephthalic acid (TPA) barium accounting and 4.9-5.6 parts of aromatic naphtha accounting.
A kind of uvioresistant rubber antioxidant of above-mentioned novel environment friendly is made of according to parts by weight following raw material: clay
6 parts of powder accounting, 5.05 parts of isproportionated potassium rosinate, 3.6 parts of anti-aging agent accounting, 35 parts of ethylene propylene diene rubber, phosphite ester accounting
1.15 parts, 5.5 parts of nano zine oxide accounting, 2.85 parts of phosphorous oxychloride accounting, 3 parts of paraffin accounting, Corvic 10.06
Part, 2.85 parts of terephthalic acid (TPA) aluminium, 4 parts of dithiodipropionic acid dilauryl, 3.8 parts of acrylic acid accounting, fire retardant accounting 2.05
Part, 11.5 parts of xylene formaldehyde resin, 4 parts of mould inhibitor accounting, 0.9 part of terephthalic acid (TPA) barium accounting and aromatic naphtha accounting 5.25
Part.
Compared with prior art, the invention has the benefit that
A kind of uvioresistant rubber antioxidant of novel environment friendly of the invention has preferable thermal stability and enduring quality, uses
It is good with rubber matrix compatibility afterwards, there is stronger antifatigue and anti-ultraviolet property, anti-aging efficiency is bigger than traditional anti-aging agent
The beneficial effects such as big raising.
Specific embodiment
Embodiment 1
A kind of uvioresistant rubber antioxidant of novel environment friendly is made of according to parts by weight following raw material: clay powder accounting 5.5
Part, 0.8 part of phosphite ester accounting, is received 4.5 parts of isproportionated potassium rosinate, 3.2 parts of anti-aging agent accounting, 30 parts of ethylene propylene diene rubber
3.8 parts of rice zinc oxide accounting, 2.5 parts of phosphorous oxychloride accounting, 2.5 parts of paraffin accounting, 8.7 parts of Corvic, terephthaldehyde
2.4 parts of sour aluminium, 4.5 parts of dithiodipropionic acid dilauryl, 3.4 parts of acrylic acid accounting, 1.6 parts of fire retardant accounting, dimethylamino benzophenone
8 parts of urea formaldehyde, 3.5 parts of mould inhibitor accounting, 0.6 part of terephthalic acid (TPA) barium accounting and 4.8 parts of aromatic naphtha accounting.
Embodiment 2
A kind of uvioresistant rubber antioxidant of above-mentioned novel environment friendly, be made of according to parts by weight following raw material: clay powder accounts for
Than 7.5 parts, 5.6 parts of isproportionated potassium rosinate, 4 parts of anti-aging agent accounting, 40 parts of ethylene propylene diene rubber, 1.5 parts of phosphite ester accounting,
7.2 parts of nano zine oxide accounting, 3.2 parts of phosphorous oxychloride accounting, 3.5 parts of paraffin accounting, 12.5 parts of Corvic, to benzene two
3.3 parts of aluminium triformate, 5.5 parts of dithiodipropionic acid dilauryl, 4.2 parts of acrylic acid accounting, 2.5 parts of fire retardant accounting, dimethylbenzene
15 parts of formaldehyde resin, 4.5 parts of mould inhibitor accounting, 1.2 parts of terephthalic acid (TPA) barium accounting and 5.7 parts of aromatic naphtha accounting.
Embodiment 3
A kind of uvioresistant rubber antioxidant of above-mentioned novel environment friendly, be made of according to parts by weight following raw material: clay powder accounts for
Than 6 parts, 5.05 parts of isproportionated potassium rosinate, 3.6 parts of anti-aging agent accounting, 35 parts of ethylene propylene diene rubber, phosphite ester accounting 1.15
It is part, 5.5 parts of nano zine oxide accounting, 2.85 parts of phosphorous oxychloride accounting, 3 parts of paraffin accounting, 10.06 parts of Corvic, right
2.85 parts of phthalic acid aluminium, 4 parts of dithiodipropionic acid dilauryl, 3.8 parts of acrylic acid accounting, 2.05 parts of fire retardant accounting, two
11.5 parts of toluene formaldehyde resin, 4 parts of mould inhibitor accounting, 0.9 part of terephthalic acid (TPA) barium accounting and 5.25 parts of aromatic naphtha accounting.
The foregoing is only a preferred embodiment of the present invention, but scope of protection of the present invention is not limited thereto,
Anyone skilled in the art in the technical scope disclosed by the present invention, according to the technique and scheme of the present invention and its
Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.
Claims (4)
1. a kind of uvioresistant rubber antioxidant of novel environment friendly, which is characterized in that be made of according to parts by weight following raw material: pottery
5.5-7.5 parts of native powder accounting, 4.5-5.6 parts of isproportionated potassium rosinate, 3.2-4 parts of anti-aging agent accounting, ethylene propylene diene rubber 30-40
Part, 0.8-1.5 parts of phosphite ester accounting, 3.8-7.2 parts of nano zine oxide accounting, 2.5-3.2 parts of phosphorous oxychloride accounting, paraffin account for
Than 2.5-3.5 parts, 8.7-12.5 parts of Corvic, 2.4-3.3 parts of terephthalic acid (TPA) aluminium, dithiodipropionic acid dilauryl
4.5-5.5 parts, 3.4-4.2 parts of acrylic acid accounting, 1.6-2.5 parts of fire retardant accounting, 8-15 parts of xylene formaldehyde resin, mould inhibitor
3.5-4.5 parts of accounting, 0.6-1.2 parts of terephthalic acid (TPA) barium accounting and 4.8-5.7 parts of aromatic naphtha accounting.
2. a kind of uvioresistant rubber antioxidant of novel environment friendly according to claim 1, which is characterized in that according to weight
Part is made of following raw material: 5.5-7.4 parts of clay powder accounting, 4.5-5.5 parts of isproportionated potassium rosinate, anti-aging agent accounting 3.2-
3.9 parts, 30-39 parts of ethylene propylene diene rubber, 0.8-1.4 parts of phosphite ester accounting, 3.8-7.1 parts of nano zine oxide accounting, oxygen chlorine
Change 2.5-3.1 parts of phosphorus accounting, 2.5-3.4 parts of paraffin accounting, 8.7-12.4 parts of Corvic, terephthalic acid (TPA) aluminium 2.4-
3.2 parts, 4.5-5.4 parts of dithiodipropionic acid dilauryl, 3.4-4.1 parts of acrylic acid accounting, 1.6-2.4 parts of fire retardant accounting,
8-14 parts of xylene formaldehyde resin, 3.5-4.4 parts of mould inhibitor accounting, 0.6-1.1 parts of terephthalic acid (TPA) barium accounting and aromatic naphtha account for
Than 4.8-5.6 parts.
3. a kind of uvioresistant rubber antioxidant of novel environment friendly according to claim 1, which is characterized in that according to weight
Part is made of following raw material: 5.6-7.4 parts of clay powder accounting, 4.6-5.5 parts of isproportionated potassium rosinate, anti-aging agent accounting 3.1-
3.9 parts, 31-39 parts of ethylene propylene diene rubber, 0.9-1.4 parts of phosphite ester accounting, 3.9-7.1 parts of nano zine oxide accounting, oxygen chlorine
Change 2.6-3.1 parts of phosphorus accounting, 2.6-3.4 parts of paraffin accounting, 8.8-12.4 parts of Corvic, terephthalic acid (TPA) aluminium 2.5-
3.2 parts, 4.6-5.4 parts of dithiodipropionic acid dilauryl, 3.5-4.1 parts of acrylic acid accounting, 1.7-2.4 parts of fire retardant accounting,
9-14 parts of xylene formaldehyde resin, 3.6-4.4 parts of mould inhibitor accounting, 0.7-1.1 parts of terephthalic acid (TPA) barium accounting and aromatic naphtha account for
Than 4.9-5.6 parts.
4. a kind of uvioresistant rubber antioxidant of novel environment friendly according to claim 1, which is characterized in that according to weight
Part is made of following raw material: 6 parts of clay powder accounting, 5.05 parts of isproportionated potassium rosinate, 3.6 parts of anti-aging agent accounting, EPDM
35 parts of rubber, 1.15 parts of phosphite ester accounting, 5.5 parts of nano zine oxide accounting, 2.85 parts of phosphorous oxychloride accounting, paraffin accounting 3
Part, 10.06 parts of Corvic, 2.85 parts of terephthalic acid (TPA) aluminium, 4 parts of dithiodipropionic acid dilauryl, acrylic acid accounting
3.8 parts, 2.05 parts of fire retardant accounting, 11.5 parts of xylene formaldehyde resin, 4 parts of mould inhibitor accounting, terephthalic acid (TPA) barium accounting 0.9
Part and 5.25 parts of aromatic naphtha accounting.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810769692.4A CN109096617A (en) | 2018-07-13 | 2018-07-13 | A kind of uvioresistant rubber antioxidant of novel environment friendly |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810769692.4A CN109096617A (en) | 2018-07-13 | 2018-07-13 | A kind of uvioresistant rubber antioxidant of novel environment friendly |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109096617A true CN109096617A (en) | 2018-12-28 |
Family
ID=64846401
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810769692.4A Pending CN109096617A (en) | 2018-07-13 | 2018-07-13 | A kind of uvioresistant rubber antioxidant of novel environment friendly |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109096617A (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102532625A (en) * | 2011-12-21 | 2012-07-04 | 宁波顺泽橡胶有限公司 | Environmentally-friendly rubber anti-ageing agent and preparation method thereof |
| CN104592586A (en) * | 2013-10-31 | 2015-05-06 | 青岛旺裕橡胶制品有限公司 | Environment-friendly rubber antioxidant |
| CN106674887A (en) * | 2015-11-05 | 2017-05-17 | 南通市永顺化工有限公司 | Novel rubber anti-aging agent |
| CN107686659A (en) * | 2017-09-05 | 2018-02-13 | 南通凤凰橡胶制品有限公司 | Mildewproof rubber |
-
2018
- 2018-07-13 CN CN201810769692.4A patent/CN109096617A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102532625A (en) * | 2011-12-21 | 2012-07-04 | 宁波顺泽橡胶有限公司 | Environmentally-friendly rubber anti-ageing agent and preparation method thereof |
| CN104592586A (en) * | 2013-10-31 | 2015-05-06 | 青岛旺裕橡胶制品有限公司 | Environment-friendly rubber antioxidant |
| CN106674887A (en) * | 2015-11-05 | 2017-05-17 | 南通市永顺化工有限公司 | Novel rubber anti-aging agent |
| CN107686659A (en) * | 2017-09-05 | 2018-02-13 | 南通凤凰橡胶制品有限公司 | Mildewproof rubber |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102911612B (en) | Fluorescent EVA (Ethylene vinyl acetate) glue film | |
| CN101221836B (en) | Low temperature resistant anti-crack rubber sleeve flexible cable used for wind power generation | |
| CN102504721B (en) | Steel wire rope core body adhesive for steel wire rope core conveyer belt and preparation method thereof | |
| JP5401873B2 (en) | Rubber composition for coating steel cord | |
| CN104194165A (en) | Low-voltage power cable rubber material | |
| CN103524892A (en) | Insulation ethylene-propylene-diene monomer sheath material for rail traffic cable and preparation method thereof | |
| CN103524843A (en) | Sheath material for signal controlling cable and preparation method thereof | |
| CN108467533A (en) | A kind of exposed conveying appliance resinae polymer membranes and preparation method thereof | |
| CN101903451B (en) | UV stabilisation of a cross-linkable polyolefin composition comprising an acidic silanol condensation catalyst | |
| CN102977470A (en) | Whitening ultraviolet-proof cable insulating rubber and manufacturing method thereof | |
| CN109096617A (en) | A kind of uvioresistant rubber antioxidant of novel environment friendly | |
| CN103304954B (en) | Polyoxymethylene plastic plate | |
| CN105542257A (en) | Mud tire sidewall rubber composition and preparation method thereof | |
| CN102816390A (en) | Blending type rubber compound and preparation method thereof | |
| CN104927124A (en) | Antibacterial antistatic and wear-resistant rubber floor | |
| CN101735745A (en) | Solar energy photovoltaic component seal gum and synthesis method thereof | |
| CN104177725A (en) | High-toughness PVC flexible pipe formula | |
| CN103788466A (en) | Flame retardant mine cable sheath material | |
| CN105482174A (en) | Snowfield tire sidewall rubber material composition and preparation method | |
| CN109762216A (en) | A kind of fire-resistant corrosion-resistant rubber | |
| CN103788467A (en) | Ageing-resistant mining cable sheath material | |
| CN103709754A (en) | Abrasion-resistant rectangular ring rubber | |
| KR20180085263A (en) | Rubber composition for tire tread and studded tire manufactured by using the same | |
| KR101658075B1 (en) | Rubber composition for tire tread and tire manufactured by using the same | |
| CN110607031A (en) | Ethylene propylene diene monomer for rubber plate and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20181228 |
|
| RJ01 | Rejection of invention patent application after publication |