CN109090508A - Canned sardines processes the recovery method of amino acid and its application in fish soup waste liquid - Google Patents
Canned sardines processes the recovery method of amino acid and its application in fish soup waste liquid Download PDFInfo
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- CN109090508A CN109090508A CN201810773280.8A CN201810773280A CN109090508A CN 109090508 A CN109090508 A CN 109090508A CN 201810773280 A CN201810773280 A CN 201810773280A CN 109090508 A CN109090508 A CN 109090508A
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- amino acid
- waste liquid
- fish soup
- recovery method
- soup waste
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- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L17/00—Food-from-the-sea products; Fish products; Fish meal; Fish-egg substitutes; Preparation or treatment thereof
- A23L17/20—Fish extracts
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- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L33/00—Modifying nutritive qualities of foods; Dietetic products; Preparation or treatment thereof
- A23L33/10—Modifying nutritive qualities of foods; Dietetic products; Preparation or treatment thereof using additives
- A23L33/17—Amino acids, peptides or proteins
- A23L33/175—Amino acids
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- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Nutrition Science (AREA)
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Food Science & Technology (AREA)
- Polymers & Plastics (AREA)
- Proteomics, Peptides & Aminoacids (AREA)
- Mycology (AREA)
- Marine Sciences & Fisheries (AREA)
- Zoology (AREA)
- Coloring Foods And Improving Nutritive Qualities (AREA)
Abstract
The invention discloses the recovery method of amino acid in a kind of canned sardines processing fish soup waste liquid and its applications, belong to food technology field.The present invention obtains compound amino acid in fish soup waste liquid using ion exchange resin method, with technically simple, advantage easy to industrialized production, the compound amino acid of acquisition is processed into amino acids oral-liquor, or made an addition in the food such as biscuit, bread, cake, flavouring as nutritional ingredient, enhance food nutrition and flavor.The present invention is greatly improved the utilization rate of resource, reduces environmental pollution, and improves the added value of fish soup waste material, increases the profit of enterprise.
Description
Technical field
The invention belongs to food processing technology fields, and in particular to canned sardines processes time of amino acid in fish soup waste liquid
Receiving method and its application.
Background technique
Basic composition unit of the amino acid as protein, directly participates in the intracorporal metabolism of biology and other physiology are living
It is dynamic.Various disease will be caused by lacking certain amino acid in human body fluid, and therefore, amino acid is to the battalion for maintaining and supplementing patient
It supports, the life danger to give emergency treatment to a dying patient has played key effect, is one of nutritional ingredient indispensable in organism.Protein
Amino acid has 20 kinds, and nonprotein amino acid has more than 400 kinds, and the polypeptide kind of derivative and synthesis reaches as many as thousands of kinds.Ammonia
Base acid is widely used in medicine, food, health care, feed, cosmetics, pesticide, fertilizer, process hides, the fields such as scientific research.
Amino acid can be used as nutritional agents in medicine, antibacterial and configure artificial synthesized diet etc. for especial patient, and use
The amino acid for making food flavor has 8 kinds.By adding amino acid in grain to improve the utilization rate of protein, to solution generation
The contradiction of boundary's population and short-commons has far reaching significance.On daily cosmetics, oneself substituted industrial chemicals of amino acid becomes
Gesture, amino acid are nutriments necessary to skin growth, and constitute natural moisturizing factor, collagen and the bullet of human skin
Property albumen important composition ingredient, therefore amino acid can be applied in cosmetics, prepare serial beautifying nourishing skin-protection product.
In marine fishes processing waste material, protein, amino acid, microelement equal size are higher, cheap, are a kind of excellent
Protein sources, the nitrogen source of matter.Currently, China is not mature enough the technologies such as the processing, recycling and storage of fish processing waste material and phase
It is relatively fewer to close research.In the processing mode of dead meal, fish processing waste material is often prepared into minced fillet, feeding fish meal etc.
Product directly abandons, and fish soup waste material is exhausted directly to sewer mostly, causes a large amount of fish processing waste utilization rates lower,
This not only causes the waste of resource, but also causes strong influence to ecological environment.Therefore, fish processing waste material how is realized
Resource height becomes current letter problem to be solved using oneself.With the fast development of modern marine Fishing technology, marine fishes
The development of processing industry is already also come out top.The processing dead meal generated in marine fishes process also increasingly increases, fish
The utilization and its exploitation of Related product of processing dead meal are gradually paid close attention to by people, and the retrofit of fish by-product is to polynary
Change, systematization and high-valued draw close.With being incremented by for population, the shortage of food rationally seems especially heavy using existing resource
It wants.The recycling of marine fishes processing waste is advantageously implemented ocean fishing class processing industry and pollutes to high economic benefit, low environment
Target.
Though sardine is a kind of small-sized low value fish, its yield is higher than other economic fish, and nutritional ingredient is not
Lower than other economic fish, it is the important marine economy fish in the world, is mainly used as eating.The characteristics of sardine flesh of fish is nutrition
Value is high, is easy digestion, this is mainly due to the amino acid of the needed by human body contained by it is more comprehensive, especially containing all 8 kinds
Essential amino acid: Taurine, lysine, leucine, valine, tryptophan, phenylalanine, isoleucine, methionine.Sha Ding
Flesh of fish beauty, is mostly used to be made as tinned food.During canned sardines processing, the fish soup of infusion sardine is usually as useless
Liquid is given up, and not only will increase the economic cost of the processing sewage of enterprise, can also cause greatly to pollute to environment.Therefore, to husky fourth
Fish soup waste material is recycled in canned fish manufacturing process, is extracted the amino acid with high economic value, can not only be improved
The economic benefit of enterprise, it is also significant to environmental protection.
Summary of the invention
The purpose of the present invention is to obtain amino acid, sardine fish soup waste liquid from canned sardines processing fish soup waste liquid first
Degreasing is carried out through n-hexane, the fish soup after degreasing is further deodorized after separating by cation exchange resin, dries, and obtains total
Free amino acid, the amino acid purity of recycling are 95~100%.
Another object of the present invention is to provide the preparation method of the amino acid, is realized by following steps:
(1) n-hexane extraction 2 times of canned sardines processing 2-2.5 times of quality of fish soup waste liquid carry out degreasing, to extraction
Upper solution afterwards recycles n-hexane, and it is stand-by to collect lower aqueous solution extracted;
(2) lower aqueous solution part is added in treated strongly acidic styrene's type cation exchange resin, is first used
Distilled water with 55-65 drop/min flow velocity wash pillar, first wash away the substances such as inorganic salts, heavy metal, when pillar efflux with
When 2% ninhydrin reaction is positive, stopping washing, use eluant, eluent instead and slowly elute, coutroi velocity is 75-85 drop/min, and
Eluent is collected, when the ninhydrin reaction of eluent and 2% is negative, stops elution;
(3) the eluent rotary evaporation for collecting step (2) is concentrated, and removes ammonia and part peculiar smell, obtains concentrate;
(4) deodorant is made using cycloheptaamylose, peculiar smell removing is carried out to above-mentioned concentrate, then filtered, be freeze-dried,
The compound amino acid refined.
Further, the eluant, eluent is the ammonium hydroxide of 3-3.5%.
The concentrate carries out peculiar smell removing method particularly includes: and cycloheptaamylose is added in concentrate and is suspended, gained
Suspension stands 3-3.5h, then filters, and collects filtrate and is freeze-dried, the compound amino acid refined.
The dosage of the cycloheptaamylose is the 4-4.5% of concentrate total amount.
Another object of the present invention is applied to compound amino acid as a kind of nutrition in food.Above-mentioned time
Amino acid obtained by receiving method is powder, is crushed to appropriate mesh number and is applied again.Smashed fish amino acid powder can be made
For nutritional ingredient, be not added or be added food ingredient, food additives auxiliary material, according to phase in requisition for preparation method product is made.
The product include amino acids oral-liquor, biscuit, bread, cake, cookies, cake class, steamed stuffed bun, steamed bun, noodles, bean vermicelli, egg roll,
Fish meal etc..
The invention has the beneficial effects that: the amino acid powder for being rich in amino acid is provided, can be used for food, cosmetics and medicine
On, it is thoroughly mixed together with other food materials, is reprocessed into colourful marine food.The exploitation of fish amino acid can
To reduce the wasting of resources, its economic value and utility value are improved.
Specific embodiment
Below in conjunction with embodiment the substantive content and beneficial effect that present invention be described in more detail, these embodiments are only
For illustrating rather than limitation of the present invention.In addition, after reading the content taught by the present invention, art technology
Personnel can make various changes or modifications the present invention, and such equivalent forms equally fall within the application the appended claims and limited
Fixed range.
Embodiment 1
Canned sardines processes the recovery method of amino acid in fish soup waste liquid:
(1) n-hexane extraction 2 times of canned sardines processing 2 times of quality of fish soup waste liquid carry out degreasing, to extracted
Upper solution recycles n-hexane, and it is stand-by to collect lower aqueous solution extracted;
(2) lower aqueous solution part is added in treated strongly acidic styrene's type cation exchange resin, is first used
Distilled water washs pillar with 60 drops/min flow velocity, the substances such as inorganic salts, heavy metal is first washed away, when the efflux of pillar and 2%
Ninhydrin reaction when being positive, stop washing, use 3% ammonium hydroxide instead and slowly elute, coutroi velocity is 80 drops/min, and is collected
Eluent stops elution when the ninhydrin reaction of eluent and 2% is negative;
(3) the eluent rotary evaporation for collecting step (2) is concentrated, and removes ammonia and part peculiar smell, obtains concentrate;
(4) cycloheptaamylose that its total amount 4% is added in concentrate is suspended, and gained suspension filters after standing 3h, receives
Collection filtrate is simultaneously freeze-dried, the compound amino acid refined.
Embodiment 2
Canned sardines processes the recovery method of amino acid in fish soup waste liquid:
(1) n-hexane extraction 2 times of canned sardines processing 2.5 times of quality of fish soup waste liquid carry out degreasing, after extraction
Upper solution recycle n-hexane, it is stand-by to collect lower aqueous solution extracted;
(2) lower aqueous solution part is added in treated strongly acidic styrene's type cation exchange resin, is first used
Distilled water washs pillar with 55 drops/min flow velocity, the substances such as inorganic salts, heavy metal is first washed away, when the efflux of pillar and 2%
Ninhydrin reaction when being positive, stop washing, use 3.5% ammonium hydroxide instead and slowly elute, coutroi velocity is 75 drops/min, and is received
Collect eluent, when the ninhydrin reaction of eluent and 2% is negative, stops elution;
(3) the eluent rotary evaporation for collecting step (2) is concentrated, and removes ammonia and part peculiar smell, obtains concentrate;
(4) cycloheptaamylose that its total amount 4.5% is added in concentrate is suspended, and gained suspension stands mistake after 3.5h
Filter is collected filtrate and is freeze-dried, the compound amino acid refined.
Embodiment 3
Canned sardines processes the recovery method of amino acid in fish soup waste liquid:
(1) n-hexane extraction 2 times of canned sardines processing 2 times of quality of fish soup waste liquid carry out degreasing, to extracted
Upper solution recycles n-hexane, and it is stand-by to collect lower aqueous solution extracted;
(2) lower aqueous solution part is added in treated strongly acidic styrene's type cation exchange resin, is first used
Distilled water washs pillar with 65 drops/min flow velocity, the substances such as inorganic salts, heavy metal is first washed away, when the efflux of pillar and 2%
Ninhydrin reaction when being positive, stop washing, use 3% ammonium hydroxide instead and slowly elute, coutroi velocity is 85 drops/min, and is collected
Eluent stops elution when the ninhydrin reaction of eluent and 2% is negative;
(3) the eluent rotary evaporation for collecting step (2) is concentrated, and removes ammonia and part peculiar smell, obtains concentrate;
(4) cycloheptaamylose that its total amount 4% is added in concentrate is suspended, and gained suspension filters after standing 3h, receives
Collection filtrate is simultaneously freeze-dried, the compound amino acid refined.
Application examples 1
Application of the gained amino acid of the invention in biscuit
1 amino acid cookie formulation of table
Amino acid cookie formulation is shown in Table 1.Key points for operation: (1) beat biscuit paste: egg cleans decladding, egg liquid, vanilla powder and
250g white granulated sugar is placed in stainless steel circular bottom pot, and heating of getting angry breaks into bulk body with laing eggs, is warmed to 50 DEG C or so and removes fiery continuation
Beat to it is cold when, beat it is thick, 500g flour and 100g amino acid sieving be poured in egg pot, stirred in stopping surface powder, amino acid powder, stirring
Uniformly biscuit paste.(2) it forms, toast: iron baking tray being wiped clean, one layer of vegetable oil is spread, then spreads a level powder and (uses
50g flour is sprinkling upon on baking tray), biscuit paste is packed into the cloth bag with circle mouth, the right hand grabs the suitable for reading of cloth pocket, and left hand pinches cloth
The lower mouth circle mouthpiece of pocket arranges distance by ranks sequence, squeezes on the baking tray for having spread flour, after having squeezed, remaining
50g white granulated sugar is sprinkling upon on the biscuit squeezed one layer, and baking tray is placed in dry place, biscuit is made to dry skin.It is roasting to be sent into 180 DEG C of ovens
10min, biscuit be presented above it is light yellow, i.e., it is ripe, come out of the stove.
Application examples 2
Application of the gained amino acid of the invention in pocket bread
2 amino acid pocket bread formula of table
Amino acid pocket bread formula is shown in Table 2.Make main points: (1) after the mixing of formula more than, stirring to gluten extends rank
Section, dough temperature keep 25 DEG C, substantially fermentation 150min, when being sent to 105min, turn-over is primary, question handler segmentation it is round as a ball after in
Between provocation 25min.It is put into last fermenting cellar after shaping sabot, is then toasted, 200 DEG C of oven temperatures, bakes 30min.I.e.
It is ripe, it comes out of the stove.
Application examples 3
Application of the gained amino acid of the invention in amino acids oral-liquor
3 amino acids oral-liquor of table
Amino acids oral-liquor formula is shown in Table 3.Key points for operation: amino acid powder is added in pure water and is dissolved, until being completely dissolved
Afterwards be added sugar, honey stir evenly, sterilizing encapsulation to get.
Application examples 4
Application of the gained amino acid of the invention in amino acid lotion
Compound amino acid 5%, 1,3-BDO 6.0%, stearic acid 0.4%, glycerol 4.0%, hexadecanol and octadecyl alcolol are mixed
Close object 1.2%, polysorbate60 1.5%, glycerol stearate 1.0%, triethanolamine 0.25%, VE3.0%, mineral oil
5.0%, squalene 3.0%, mountain soya-bean oil 2.0%, sorbitan sesquioleate 0.6%, carboxyl ethylene polymer 0.15%, hexichol
Ketone -9 0.05%, α-bisabolol 0.5%, vitamin B30.5%, sodium hyaluronate 1.0%, collagen 2.0%, preservative is suitable
Amount, Fragrance qs, deionized water add to 100%, obtain amino acid lotion.
Claims (10)
1. the recovery method that canned sardines processes amino acid in fish soup waste liquid, it is characterised in that: canned sardines is processed fish
Soup waste liquid carries out degreasing with n-hexane, and the fish soup after degreasing carries out separation and purification by cation exchange resin, is then deodorized, is dry
It is dry to get total free amino acid.
2. the recovery method of amino acid in canned sardines processing fish soup waste liquid according to claim 1, it is characterised in that:
Specific step is as follows:
(1) the n-hexane extraction degreasing of canned sardines processing 2-2.5 times of quality of fish soup waste liquid, to upper solution extracted
N-hexane is recycled, it is stand-by to collect lower aqueous solution extracted;
(2) lower aqueous solution part is added in treated strongly acidic styrene's type cation exchange resin, first with distillation
Water stops washing with 55-65 drop/min flow velocity washing pillar when the ninhydrin reaction of the efflux of pillar and 2% is positive
It washs, uses eluant, eluent instead and slowly elute, coutroi velocity is 75-85 drop/min, and collects eluent, when eluent and 2% ninhydrin
When reaction is negative, stop elution;
(3) the eluent rotary evaporation for collecting step (2) is concentrated, and obtains concentrate;
(4) deodorant is made using cycloheptaamylose, peculiar smell removing is carried out to above-mentioned concentrate, then filtered, be freeze-dried, obtain
The compound amino acid of purification.
3. the recovery method of amino acid in canned sardines processing fish soup waste liquid according to claim 1, it is characterised in that:
The eluant, eluent is the ammonium hydroxide of 3-3.5%.
4. the recovery method of amino acid in canned sardines processing fish soup waste liquid according to claim 1, it is characterised in that:
The concentrate carries out peculiar smell removing method particularly includes: cycloheptaamylose is added in concentrate and is suspended, gained suspension is quiet
3-3.5h is set, is then filtered, filtrate is collected and is freeze-dried, the compound amino acid refined.
5. the recovery method of amino acid in canned sardines processing fish soup waste liquid according to claim 4, it is characterised in that:
The dosage of the cycloheptaamylose is the 4-4.5% of concentrate total amount.
6. the recovery method of amino acid in canned sardines processing fish soup waste liquid according to claim 1, it is characterised in that:
The amino acid purity of recycling is 95 ~ 100%.
7. the amino acid that -5 either method obtain according to claim 1.
8. application of the amino acid as claimed in claim 6 in food.
9. application of the amino acid according to claim 7 in food, it is characterised in that: the amino acid is used to prepare ammonia
Base acid oral solution or amino acid lotion.
10. application of the amino acid according to claim 7 in food, it is characterised in that: the amino acid is as nutrition
Ingredient makes an addition in biscuit, bread, cake, noodles or flavouring.
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CN201810773280.8A CN109090508A (en) | 2018-07-14 | 2018-07-14 | Canned sardines processes the recovery method of amino acid and its application in fish soup waste liquid |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN112225619A (en) * | 2020-10-28 | 2021-01-15 | 沈阳师范大学 | Amino acid-containing water-soluble fertilizer for lawn rejuvenation |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS56118047A (en) * | 1980-02-25 | 1981-09-16 | Musashino Kagaku Kenkyusho:Kk | Preparation of amino acid |
CN101411517A (en) * | 2008-07-02 | 2009-04-22 | 广东海洋大学 | Method for producing Paphia undulata amino acid flavoring food |
CN103966274A (en) * | 2013-02-05 | 2014-08-06 | 中国科学院海洋研究所 | Method for biotransformation production of gamma-aminobutyric acid with aquatic products and processing leftovers thereof as raw materials |
CN104387443A (en) * | 2014-11-26 | 2015-03-04 | 江南大学 | Method for efficiently recycling protein and free amino acid from potato starch processing wastewater |
CN107986994A (en) * | 2017-12-14 | 2018-05-04 | 成都新柯力化工科技有限公司 | A kind of method that arginine food additives are extracted from octopus residue |
-
2018
- 2018-07-14 CN CN201810773280.8A patent/CN109090508A/en not_active Withdrawn
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS56118047A (en) * | 1980-02-25 | 1981-09-16 | Musashino Kagaku Kenkyusho:Kk | Preparation of amino acid |
CN101411517A (en) * | 2008-07-02 | 2009-04-22 | 广东海洋大学 | Method for producing Paphia undulata amino acid flavoring food |
CN103966274A (en) * | 2013-02-05 | 2014-08-06 | 中国科学院海洋研究所 | Method for biotransformation production of gamma-aminobutyric acid with aquatic products and processing leftovers thereof as raw materials |
CN104387443A (en) * | 2014-11-26 | 2015-03-04 | 江南大学 | Method for efficiently recycling protein and free amino acid from potato starch processing wastewater |
CN107986994A (en) * | 2017-12-14 | 2018-05-04 | 成都新柯力化工科技有限公司 | A kind of method that arginine food additives are extracted from octopus residue |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN112225619A (en) * | 2020-10-28 | 2021-01-15 | 沈阳师范大学 | Amino acid-containing water-soluble fertilizer for lawn rejuvenation |
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