CN109082496A - A kind of method of whole process hypoxemia position smelting suprelow carbon steel - Google Patents

A kind of method of whole process hypoxemia position smelting suprelow carbon steel Download PDF

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Publication number
CN109082496A
CN109082496A CN201810902063.4A CN201810902063A CN109082496A CN 109082496 A CN109082496 A CN 109082496A CN 201810902063 A CN201810902063 A CN 201810902063A CN 109082496 A CN109082496 A CN 109082496A
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furnace
oxygen
carbon steel
hypoxemia
converter
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邹春锋
韩蕾蕾
吕晓锋
陈彬
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Shandong Iron and Steel Group Co Ltd SISG
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Shandong Iron and Steel Group Co Ltd SISG
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    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21CPROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
    • C21C5/00Manufacture of carbon-steel, e.g. plain mild steel, medium carbon steel or cast steel or stainless steel
    • C21C5/28Manufacture of steel in the converter
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D11/00Continuous casting of metals, i.e. casting in indefinite lengths
    • B22D11/16Controlling or regulating processes or operations
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21CPROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
    • C21C5/00Manufacture of carbon-steel, e.g. plain mild steel, medium carbon steel or cast steel or stainless steel
    • C21C5/28Manufacture of steel in the converter
    • C21C5/36Processes yielding slags of special composition
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21CPROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
    • C21C7/00Treating molten ferrous alloys, e.g. steel, not covered by groups C21C1/00 - C21C5/00
    • C21C7/0006Adding metallic additives
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21CPROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
    • C21C7/00Treating molten ferrous alloys, e.g. steel, not covered by groups C21C1/00 - C21C5/00
    • C21C7/04Removing impurities by adding a treating agent
    • C21C7/06Deoxidising, e.g. killing
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21CPROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
    • C21C7/00Treating molten ferrous alloys, e.g. steel, not covered by groups C21C1/00 - C21C5/00
    • C21C7/04Removing impurities by adding a treating agent
    • C21C7/068Decarburising
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21CPROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
    • C21C7/00Treating molten ferrous alloys, e.g. steel, not covered by groups C21C1/00 - C21C5/00
    • C21C7/10Handling in a vacuum

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Mechanical Engineering (AREA)
  • Carbon Steel Or Casting Steel Manufacturing (AREA)
  • Treatment Of Steel In Its Molten State (AREA)

Abstract

The invention discloses a kind of methods of whole hypoxemia position smelting suprelow carbon steel.The chemical component mass percent of the invention ultra-low-carbon steel are as follows: C≤0.0030%;Si 0.01%;Mn 0.08~0.18%;P≤0.015%;S≤0.010%;Alsol0.015~0.055%, it uses KR stirring desulphurization-top and bottom combined blown converter-RH vacuum refining furnace-slab caster technique and smelts production.The present invention is using converter terminal hypoxemia full iron low with slag modification, the decarburization of RH furnace hypoxemia locating depth, conticaster full guard argon envelope and tundish ventilating seat brick Argon mode; full iron control is within 5% after slag modification; the control of terminal oxygen is in 350ppm or so after RH furnace depth decarburization; slab oxygen controls within 20ppm; field trash zero level ratio reaches 97% or more; RH furnace aim carbon controls within 20ppm, and conticaster even draws furnace number to reach 10 heats.The pourability and slab quality for ensuring the Ultra-low carbons steel grade such as DDQ grades of cold-rolled steels, improve steel inclusion quantity and form controlled level, effectively increase slab qualification rate.

Description

A kind of method of whole process hypoxemia position smelting suprelow carbon steel
Technical field
The invention belongs to field of steel metallurgy, and in particular to a kind of method of whole process hypoxemia position smelting suprelow carbon steel.
Background technique
The market of steel product will be used wider and wider, to the reliability of its quality, the stability of performance and special The requirement of index also becomes more urgent.Be to require with Molten Steel Cleanliness index, the quantity of nonmetallic inclusionsin steel, form and Size distribution need to be effectively controlled, avoid steel generate raw edges, performance do not conform to, the mass defects such as crackle.It is traditional with molten steel Ingredient is to smelt purpose technique not obviously being able to satisfy steel product quality requirement.
As steel mill is to the development & production of DDQ grades of deep-draw steel, quantity, continuous irrigatation castability, the stocking matter of foreign substance in molten steel Amount is the key technology difficulty faced.Because such steel grade requires endpoint carbon content general control in 50ppm hereinafter, even lower, System Absent measures difficulty is caused to increase.First is that converter smelting endpoint is difficult to control, it is high often to there is converter carbon hypoxemia high carbon-oxygen product Situations such as, for converter terminal carbon 0.03% or so, oxygen content reaches 1000ppm or so, causes slag beneficiation strong, ladle top slag Full iron reaches 20% or more, brings difficulty to the modification of ladle top slag;Second is that RH furnace is for deep decarburization, process Control for Oxygen Content In hyperoxia position, the Control for Oxygen Content that enters the station Control for Oxygen Content after 500-600ppm or more, deep decarburization is high in 450-500ppm or more Oxygen position is controlled to steel quality and continuous irrigatation castability, is produced bigger effect;Third is that in conticaster casting process molten steel secondary oxygen Change expands this influence.Practice have shown that whole hyperoxia position control causes the subcutaneous pin hole of continuous casting sprue dross, slab, stocking raw edges etc. Problems, slab qualification rate are lower.
Therefore, a kind of smelting, casting method that can overcome drawbacks described above, Improving The Quality of Products stability are needed.
Summary of the invention
The object of the present invention is to provide a kind of methods of whole hypoxemia position smelting suprelow carbon steel.Present invention ensures that DDQ The pourability and slab quality problem of the Ultra-low carbons steel grades such as grade cold-rolled steel improve steel inclusion quantity and form control water It is flat, effectively increase slab qualification rate.
To achieve the goals above, the invention adopts the following technical scheme:
First is that converter procedure improves the control of terminal all iron content and the modification effect of terminal clinker;Second is that RH vacuum fine Furnace controls deep decarbonizing process molten steel total oxygen, and the polyoxy of crossing for reducing molten steel exists, and is further reduced foreign substance in molten steel It generates;Third is that pouring molten steel process carries out full guard strict control, pressed from both sides using inert gas argon gas-sealed and argon bottom-blowing removal Miscellaneous form further promotes Molten Steel Cleanliness.
Specifically, the method for a kind of whole hypoxemia position smelting suprelow carbon steel, the described method comprises the following steps:
1) converter reduces slag beneficiation, and carbon oxygen product controlled level is 0.0021~0.0024%, terminal Control for Oxygen Content In 500-600ppm;
2) converter terminal is added 300~400kg/ of modification agent furnace and carries out slag modification;
3) RH furnace smelting process:
1. thermometric determines oxygen after 2~4min of circulation, when oxygen content: when between 450~550ppm, natural decarburization;Work as oxygen content Less than 400ppm, 20~40Nm of oxygen blast3Carry out pressure decarburization;When oxygen content is greater than 600ppm, carbon dust deoxidation is added;Deoxygenation The control of molten steel oxygen is in 340~360ppm before aurification;
2. after RH furnace is pressed again, 20~30kg aluminum shot and 150~200kg modification agent is added in the ladle top of the slag;
4) continuous casting process:
1. the big water-coating port argon envelope flow control of ladle is in 100~120L/min;
2. tundish ventilating seat brick flow is 10-15L/min;
3. tundish immersed nozzle argon jacket flow control is in 15~20L/min;
4. coverture covering is added uniformly, tightly in Metal in Tundish face, secondary oxidation of steel is reduced.
Preferably, the chemical component mass percent of the ultra-low-carbon steel are as follows: C≤0.0030%;Si 0.01%;Mn 0.08~0.18%;P≤0.015%;S≤0.010%;Alsol0.015~0.055%.
Preferably, converter smelting control furnace bottom amount of increase is no more than 100mm, it is ensured that bottom-blowing of converter effect.
Preferably, continuous casting tundish is poured using carbon-free tundish, and ultra-low-carbon steel casting control is in the tundish longevity Life early period (pouring time the 13rd stokehold), reduces resistance to material and corrodes and pollute to molten steel.
Preferably, the modification agent matches by mass percentage are as follows: aluminum shot 30%, lime 10%, pre-melted slag 60% Mixing match.
More specifically, a kind of method based on above-mentioned whole hypoxemia position smelting suprelow carbon steel, the method includes following steps It is rapid:
1, converter procedure, the method that (1) rationally controls furnace bottom amount of increase, improves bottom blowing effect.Control furnace bottom amount of increase is no more than 100mm, it is ensured that bottom-blowing of converter effect.Dynamic grasps bottom blowing gas effect, judges whether bottom blowing effect meets by exposed quantity It is required that.(2) optimization converter ultra-low-carbon steel smelts mode.High basicity slag is made in a converter.Lime adding amount is enough, and basicity control exists 3.5-4.B uses high-silicon high temperature molten iron, it is ensured that converter operates heat affluence, and process ore additional amount reaches 5 tons or more, it is ensured that complete Journey slugging effect.A collection of lime is added before c terminal, is thickened clinker.TSO is measured in advance before d terminal, is adjusted and is supplied according to TSO temperature Oxygen amount guarantees that converter terminal temperature at 1710 DEG C or so, guarantees to meet production requirement into RH temperature.Converter reduces slag oxidation Property, carbon oxygen product controlled level is between 0.0021~0.0024%, and terminal Control for Oxygen Content is between 500-600ppm, aim carbon Content is controlled in 0.04-0.05%, guarantees that oxygen content is met the requirements;(3) converter terminal be added 300~400kg/ of modification agent furnace into Row slag modification, modification agent are matched according to mass percent are as follows: the mixing of aluminum shot 30%, lime 10%, pre-melted slag 60% Proportion;
2, RH process, 1. thermometric determines oxygen after circulation 3min, when oxygen content: when between 450~550ppm, natural decarburization;When Oxygen content is less than 400ppm, 20~40Nm of oxygen blast3Carry out pressure decarburization;When oxygen content is greater than 600ppm, carbon dust is added and sloughs Extra oxygen, 10kg carbon dust take off 100ppm oxygen.The control of molten steel oxygen is in 350ppm or so before deoxidation alloying;After 2. RH furnace is pressed again, The top of the slag is added 20~30kg aluminum shot and 150~200kg modification agent, modification agent and matches according to mass percent are as follows: aluminum shot 30%, The mixing match of grain lime 10%, pre-melted slag 60%;3. outlet temperature controls between 1595~1600 DEG C;
3) continuous casting working procedure, 1. the envelope flow control of ladle big water-coating port argon is in 100~120L/min, 2. tundish ventilating seat brick Flow be 10-15L/min 3. the flow control of tundish immersed nozzle argon jacket in 15~20L/min;4. Metal in Tundish face Coverture covering is added uniformly, tightly, reduces secondary oxidation of steel;5. basket pouring temperature control 1562-1572 DEG C it Between.
Present invention employs KR stirring desulphurization-top and bottom combined blown converter-RH vacuum refining furnace-slab caster technique smeltings Refining production.The present invention uses converter terminal hypoxemia full iron low with slag modification, the hypoxemia locating depth decarburization of RH furnace and conticaster all risk insurance Protect argon envelope and tundish ventilating seat brick mode, it is ensured that the pourability and slab quality of the Ultra-low carbons steel grade such as DDQ grades of cold-rolled steels, Steel inclusion quantity and form controlled level are improved, slab qualification rate is effectively increased.
The present invention uses converter terminal hypoxemia full iron low with slag modification, the decarburization of RH furnace hypoxemia locating depth, conticaster full guard Argon seals and tundish ventilating seat brick Argon mode, and full iron control is within 5% after slag modification, terminal oxygen control after RH furnace depth decarburization System controls within 20ppm in 350ppm or so, slab oxygen, and field trash zero level ratio reaches 97% or more, RH furnace aim carbon control For system within 20ppm, conticaster even draws furnace number to reach 10 heats.
The present invention is suitable for all mild steel and the production of ultra-low-carbon steel is smelted.
Specific embodiment
Any feature is disclosed to obtain in this specification, it unless specifically stated, can be equivalent or with similar purpose by other Alternative features are replaced.Unless specifically stated, each feature is an example in a series of equivalent or similar characteristics ?.It is described to understand the present invention just for the sake of help, it should not be considered as to concrete restriction of the invention.
Each case study on implementation of the present invention executes according to the following steps:
1, converter procedure: the method for 1. rationally controlling furnace bottom amount of increase, improving bottom blowing effect.Control furnace bottom amount of increase is no more than 100mm, it is ensured that bottom-blowing of converter effect.Dynamic grasps bottom blowing gas effect, judges whether bottom blowing effect meets by exposed quantity It is required that.2. optimizing converter ultra-low-carbon steel smelts mode.High basicity slag is made in a converter.Lime adding amount is enough, and basicity is controlled in 3.5- 4.B uses high-silicon high temperature molten iron, it is ensured that converter operates heat affluence, and process ore additional amount reaches 5 tons or more, it is ensured that full range Slag effect.A collection of lime is added before c terminal, is thickened clinker.TSO is measured in advance before d terminal, and oxygen-supplying amount is adjusted according to TSO temperature, Guarantee that converter terminal temperature at 1710 DEG C or so, guarantees to meet production requirement into RH temperature.Converter reduces slag beneficiation, carbon oxygen Product controlled level is between 0.0021~0.0024%, and terminal Control for Oxygen Content is between 500-600ppm, endpoint carbon content control System guarantees that oxygen content is met the requirements in 0.04-0.05%;3. terminal is added 300~400kg/ of modification agent furnace and carries out slag modification, Modification agent is matched according to mass percent are as follows: aluminum shot 30%, lime 10%, pre-melted slag 60% mixing match;
2, RH process: 1. thermometric determines oxygen after circulation 3min, when oxygen content: when between 450~550ppm, natural decarburization;When Oxygen content is less than 400ppm, 20~40m of oxygen blast3Carry out pressure decarburization;When oxygen content is greater than 600ppm, addition carbon dust is sloughed more Remaining oxygen, 10kg carbon dust take off 100ppm oxygen.The control of molten steel oxygen is in 350ppm or so before deoxidation alloying;After 2. RH furnace is pressed again, in slag 20~30kg aluminum shot+150~200kg modification agent is added in face, and modification agent is matched according to mass percent are as follows: aluminum shot 30%, particle The mixing match of lime 10%, pre-melted slag 60%;3. outlet temperature controls between 1595~1600 DEG C.
3, continuous casting working procedure: 1. the envelope flow control of ladle big water-coating port argon is in 100~120L/min, 2. tundish ventilating seat brick Flow is that 3. tundish immersed nozzle argon seals flow control in 15~20L/min to 10-15L/min;4. Metal in Tundish face Coverture covering is added uniformly, tightly, reduces secondary oxidation of steel;5. basket pouring temperature control 1562-1572 DEG C it Between.
Continuous casting tundish is poured using carbon-free tundish, and ultra-low-carbon steel casting control is in tundish work life early period (pouring time the 13rd stokehold) is reduced resistance to material and is corroded and pollute to molten steel.
Ladle slag modification situation is as shown in table 1;Oxygen content and aim carbon situation such as table 2 before RH vacuum refining furnace alloying It is shown;Hypoxemia position smelting suprelow carbon steel Specifications are as shown in table 3;
1 slag modification effect of table
Oxygen content and aim carbon situation before table 2RH vacuum refining furnace alloying
3 hypoxemia position smelting suprelow carbon steel Specifications of table
Using smelting process method of the present invention, full iron control is within 5% after slag modification, terminal oxygen after RH furnace depth decarburization Control controls within 20ppm in 350ppm or so, slab oxygen, and field trash zero level ratio reaches 97% or more, RH furnace aim carbon Within 20ppm, conticaster even draws furnace number to reach 10 heats for control.
From the above results, using this smelting, casting method, molten steel composition can satisfy Ultra-low carbon steel grade requirement, together When realize from converter-RH furnace-conticaster whole process hypoxemia position production model, foreign substance in molten steel significantly reduces, pourability of molten steel It significantly improves, slab, mill bar quality are preferable, and performance is stablized.
Technological parameter (such as temperature, time) section bound value of the invention and interval value can realize this law, Embodiment numerous to list herein.
Ordinary skill in the art knowledge can be used in the unspecified content of the present invention.
It should be noted last that the above examples are only used to illustrate the technical scheme of the present invention and are not limiting.Although ginseng It is described the invention in detail according to embodiment, it will be apparent to an ordinarily skilled person in the art that technical side of the invention Case is modified or replaced equivalently, and without departure from the spirit and scope of technical solution of the present invention, should all be covered in the present invention Scope of the claims in.

Claims (5)

1. a kind of method of whole process hypoxemia position smelting suprelow carbon steel, the described method comprises the following steps:
1) converter reduces slag beneficiation, and 0.0021~0.0024%, terminal Control for Oxygen Content exists carbon oxygen product controlled level 500-600ppm;
2) converter terminal is added 300~400kg/ of modification agent furnace and carries out slag modification;
3) RH furnace smelting process:
1. thermometric determines oxygen after 2~4min of circulation, when oxygen content: when between 450~550ppm, natural decarburization;When oxygen content is less than 400ppm, 20~40Nm of oxygen blast3Carry out pressure decarburization;When oxygen content is greater than 600ppm, carbon dust deoxidation is added;Deoxidation alloying Preceding molten steel oxygen control is in 340~360ppm;
2. after RH furnace is pressed again, 20~30kg aluminum shot and 150~200kg modification agent is added in the ladle top of the slag;
4) continuous casting process:
1. the big water-coating port argon envelope flow control of ladle is in 100~120L/min;
2. tundish ventilating seat brick flow is 10-15L/min;
3. tundish immersed nozzle argon jacket flow control is in 15~20L/min;
4. coverture covering is added uniformly, tightly in Metal in Tundish face, secondary oxidation of steel is reduced.
2. a kind of method of whole hypoxemia position smelting suprelow carbon steel according to claim 1, which is characterized in that described ultralow The chemical component mass percent of carbon steel are as follows: C≤0.0030%;Si 0.01%;Mn 0.08~0.18%;P≤0.015%;S ≤ 0.010%;Alsol0.015~0.055%.
3. a kind of method of whole hypoxemia position smelting suprelow carbon steel according to claim 1, which is characterized in that converter smelting It controls furnace bottom amount of increase and is no more than 100mm, it is ensured that bottom-blowing of converter effect.
4. a kind of method of whole hypoxemia position smelting suprelow carbon steel according to claim 1, which is characterized in that in conticaster Between packet be poured using carbon-free tundish, ultra-low-carbon steel casting control is in tundish work life early period.
5. a kind of method of whole hypoxemia position smelting suprelow carbon steel according to claim 1, which is characterized in that the modification Agent matches by mass percentage are as follows: aluminum shot 30%, lime 10%, pre-melted slag 60% mixing match.
CN201810902063.4A 2018-08-09 2018-08-09 A kind of method of whole process hypoxemia position smelting suprelow carbon steel Pending CN109082496A (en)

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Cited By (9)

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CN109439843A (en) * 2018-12-29 2019-03-08 首钢集团有限公司 A kind of ultra-low-carbon steel smelting control method
CN109735677A (en) * 2018-12-10 2019-05-10 北京首钢股份有限公司 A kind of smelting process reducing high-aluminum steel nozzle blocking probability
CN109837361A (en) * 2019-04-01 2019-06-04 山东钢铁集团日照有限公司 A kind of RH simply connected technique of the anti-wadding stream of low-carbon unskilled steel
CN110079724A (en) * 2019-06-12 2019-08-02 中天钢铁集团有限公司 A kind of Ultra Low-oxygen middle low carbon steel smelting process
CN112626312A (en) * 2020-12-14 2021-04-09 山东钢铁集团日照有限公司 Low-carbon aluminum killed steel Al for reducing RH single process2O3Method of inclusion
CN113862428A (en) * 2021-08-19 2021-12-31 山东钢铁集团日照有限公司 Ultra-low carbon steel smelting method
CN113862424A (en) * 2021-08-23 2021-12-31 山东钢铁集团日照有限公司 Method for reducing ultra-low carbon steel water gap
CN115141904A (en) * 2022-07-05 2022-10-04 江苏省沙钢钢铁研究院有限公司 Continuous casting billet for preparing low-carbon cold-rolled substrate and smelting process thereof
CN115305411A (en) * 2022-08-15 2022-11-08 马鞍山钢铁股份有限公司 Method for efficiently producing ultra-deep drawing cold-rolled enamel steel

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Publication number Priority date Publication date Assignee Title
CN109735677A (en) * 2018-12-10 2019-05-10 北京首钢股份有限公司 A kind of smelting process reducing high-aluminum steel nozzle blocking probability
CN109439843A (en) * 2018-12-29 2019-03-08 首钢集团有限公司 A kind of ultra-low-carbon steel smelting control method
CN109837361A (en) * 2019-04-01 2019-06-04 山东钢铁集团日照有限公司 A kind of RH simply connected technique of the anti-wadding stream of low-carbon unskilled steel
CN110079724A (en) * 2019-06-12 2019-08-02 中天钢铁集团有限公司 A kind of Ultra Low-oxygen middle low carbon steel smelting process
CN112626312A (en) * 2020-12-14 2021-04-09 山东钢铁集团日照有限公司 Low-carbon aluminum killed steel Al for reducing RH single process2O3Method of inclusion
CN112626312B (en) * 2020-12-14 2022-09-20 山东钢铁集团日照有限公司 Low-carbon aluminum killed steel Al for reducing RH single process 2 O 3 Method of inclusion
CN113862428A (en) * 2021-08-19 2021-12-31 山东钢铁集团日照有限公司 Ultra-low carbon steel smelting method
CN113862424A (en) * 2021-08-23 2021-12-31 山东钢铁集团日照有限公司 Method for reducing ultra-low carbon steel water gap
CN115141904A (en) * 2022-07-05 2022-10-04 江苏省沙钢钢铁研究院有限公司 Continuous casting billet for preparing low-carbon cold-rolled substrate and smelting process thereof
CN115141904B (en) * 2022-07-05 2023-09-22 江苏省沙钢钢铁研究院有限公司 Continuous casting blank for preparing low-carbon cold-rolled substrate and smelting process thereof
CN115305411A (en) * 2022-08-15 2022-11-08 马鞍山钢铁股份有限公司 Method for efficiently producing ultra-deep drawing cold-rolled enamel steel
CN115305411B (en) * 2022-08-15 2024-02-06 马鞍山钢铁股份有限公司 Method for efficiently producing ultra-deep drawing cold-rolled enamel steel

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