CN109081701A - A kind of 3D printing pen ceramic material - Google Patents

A kind of 3D printing pen ceramic material Download PDF

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Publication number
CN109081701A
CN109081701A CN201811053175.3A CN201811053175A CN109081701A CN 109081701 A CN109081701 A CN 109081701A CN 201811053175 A CN201811053175 A CN 201811053175A CN 109081701 A CN109081701 A CN 109081701A
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parts
nano
powder
mass fraction
includes following
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CN201811053175.3A
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Chinese (zh)
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李培成
刘永欣
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Jiangsu Tianze Education Consulting Co Ltd
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Jiangsu Tianze Education Consulting Co Ltd
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Priority to CN201811053175.3A priority Critical patent/CN109081701A/en
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    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/71—Ceramic products containing macroscopic reinforcing agents
    • C04B35/78—Ceramic products containing macroscopic reinforcing agents containing non-metallic materials
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  • Chemical & Material Sciences (AREA)
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  • Ceramic Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)

Abstract

The invention discloses a kind of 3D printing pen ceramic materials, it is mixed by component A and B component according to mass ratio 1:1-3, wherein A includes following components according to the mass fraction: 20-30 parts of nano kaoline, 35-50 parts of nano silica, 15-18 parts of barium titanate powder, 6-12 parts of nano-titanium dioxide, 15-18 parts of nano dye, 15-25 parts of modified landplaster, 10-15 parts of nanometer calcium carbonate, 10-15 parts of nano metal material, 6-9 parts of polyisocyanates, 5-8 parts of zirconium boride, 2-4 parts of stabilizer, 6-8 parts of coupling agent；B component includes following components according to the mass fraction: 5-10 parts of magnesia, 3-6 parts of alumina silicate, 5-7 parts of calcirm-fluoride, 8-16 parts of silicon nitride, 3-6 parts of zinc stearate, 1-2 parts of beryllium oxide, 5-10 parts of barium sulfate, 20-25 parts of graphite microparticles, 6-8 parts of aluminum oxide, 2-4 parts of aluminium borate whisker, 0.5-2 parts of nano rare earth.

Description

A kind of 3D printing pen ceramic material
Technical field
The present invention relates to a kind of 3D printing pen ceramic materials.
Background technique
With the development of 3D printing technique, various corresponding products also come out gradually, such as 3D printing pen, and existing 3D is beaten Print pen substantially uses ABS plastic material, relatively simple, and the universal service life is not high under intensive work environment, through high temperature And damage easy to crack under long term wear, as life is continuously improved, the various quality to printing pen also proposed higher and higher It is required that needing a kind of new material, good high-intensitive, toughness and heat-resisting quantity are made it have.
Summary of the invention
The technical problem to be solved by the present invention is to provide a kind of 3D printing for the above disadvantage of the existing technology Pen uses ceramic material.
The technical solution that the present invention solves the above technical problem is: a kind of 3D printing pen ceramic material, by component A and B Component is mixed according to mass ratio 1:1-3, and wherein A includes following components according to the mass fraction: 20-30 parts of nano kaoline, 35-50 parts of nano silica, 15-18 parts of barium titanate powder, 6-12 parts of nano-titanium dioxide, 15-18 parts of nano dye, modified stone 15-25 parts of cream powder, 10-15 parts of nanometer calcium carbonate, 10-15 parts of nano metal material, 6-9 parts of polyisocyanates, zirconium boride 5-8 Part, 2-4 parts of stabilizer, 6-8 parts of coupling agent；
B component includes following components according to the mass fraction: 5-10 parts of magnesia, 3-6 parts of alumina silicate, 5-7 parts of calcirm-fluoride, silicon nitride 8-16 parts, 3-6 parts of zinc stearate, 1-2 parts of beryllium oxide, 5-10 parts of barium sulfate, 20-25 parts of graphite microparticles, aluminum oxide 6-8 Part, 2-4 parts of aluminium borate whisker, 0.5-2 parts of nano rare earth.
The technical solution that the present invention further limits is:
A above-mentioned includes following components according to the mass fraction: 20 parts of nano kaoline, 35 parts of nano silica, barium titanate powder 15 parts, 6 parts of nano-titanium dioxide, 15 parts of nano dye, 15 parts of modified landplaster, 10 parts of nanometer calcium carbonate, nano metal material 10 parts, 6 parts of polyisocyanates, 5 parts of zirconium boride, 2 parts of stabilizer, 6 parts of coupling agent；
B component includes following components according to the mass fraction: 5 parts of magnesia, 3 parts of alumina silicate, 5 parts of calcirm-fluoride, 8 parts of silicon nitride, hard 3 parts of resin acid zinc, 1 part of beryllium oxide, 5 parts of barium sulfate, 20 parts of graphite microparticles, 6 parts of aluminum oxide, 2 parts of aluminium borate whisker, Nano Rare 0.5 part of soil.
A above-mentioned includes following components according to the mass fraction: 25 parts of nano kaoline, 40 parts of nano silica, metatitanic acid 16 parts of barium powder, 9 parts of nano-titanium dioxide, 16 parts of nano dye, 20 parts of modified landplaster, 12 parts of nanometer calcium carbonate, nano metal 12 parts of material, 8 parts of polyisocyanates, 7 parts of zirconium boride, 3 parts of stabilizer, 7 parts of coupling agent；
B component includes following components according to the mass fraction: 8 parts of magnesia, 4 parts of alumina silicate, 6 parts of calcirm-fluoride, 13 parts of silicon nitride, hard 4 parts of resin acid zinc, 1.5 parts of beryllium oxide, 8 parts of barium sulfate, 23 parts of graphite microparticles, 7 parts of aluminum oxide, aluminium borate whisker 3 part, nanometer 1 part of rare earth.
A above-mentioned includes following components according to the mass fraction: 30 parts of nano kaoline, 45 parts of nano silica, metatitanic acid 18 parts of barium powder, 11 parts of nano-titanium dioxide, 16 parts of nano dye, 25 parts of modified landplaster, 14 parts of nanometer calcium carbonate, nano metal 13 parts of material, 9 parts of polyisocyanates, 7 parts of zirconium boride, 4 parts of stabilizer, 8 parts of coupling agent；
B component includes following components according to the mass fraction: 9 parts of magnesia, 6 parts of alumina silicate, 7 parts of calcirm-fluoride, 15 parts of silicon nitride, hard 5 parts of resin acid zinc, 2 parts of beryllium oxide, 10 parts of barium sulfate, 25 parts of graphite microparticles, 7.5 parts of aluminum oxide, 3.5 parts of aluminium borate whisker, 1.5 parts of nano rare earth.
Nano metal material above-mentioned include 15-20 parts of nanometer aluminium powder, 6-10 parts of nanometer zirconium powder, 8-11 parts of nano zinc powder, 13-18 parts of nanometer iron powder, 5-7 parts of nano-nickel powder, 2-6 parts of nanometer chromium powder, 3-5 parts of nanometer manganese powder, 1-3 parts of copper nanoparticle, nanometer 3-6 parts of tungsten powder.
Stabilizer above-mentioned is antimony organic.
Coupling agent above-mentioned is silane coupling agent.
Nano rare earth above-mentioned is that cerium oxide, lanthana and lithia are mixed according to 2:-5:1 proportion.
The beneficial effects of the present invention are: the present invention use above-mentioned material preparation printing pen, have high intensity, toughness, firmly Degree and heat-resisting quantity can fill up the defect between nano metal material wherein nano rare earth is added, and crystal grain is hindered to grow up, and have There is crystallization particulate, keeps dendritic network relatively sharp, so as to improve the thermoplasticity of cermet, the introducing of nano rare earth, Corrosion resistance and high temperature oxidation resistance tool to cermet material improve, while also improving intensity and toughness, It can also make heat stabilizer simultaneously and organic tin stabilizer cooperates, make its material that there is excellent processability, weatherability, initial stage Coloring, photostability；It adds graphite microparticles and improves the service life of product so that material is even closer；Present invention addition is received Rice metal material can increase intensity, improve texture, add nano dye, be able to solve the problem of product colour uniformity difference, Bending strength of the present invention can be reached for 200-260MPa, and hardness can reach 550MPa or more, it can be resistant to 1100 DEG C in air High temperature, there is good bending strength, fracture toughness, heat-resisting quantity has longer service life, overcome traditional ceramics The easy to crack of mold materials, poor toughness and the deficiency for causing service life short.
Specific embodiment
Embodiment 1
The present embodiment provides a kind of 3D printing pen ceramic materials, are mixed by component A and B component according to mass ratio 1:1.5, Wherein A includes following components according to the mass fraction: 20 parts of nano kaoline, 15 parts of barium titanate powder, is received 35 parts of nano silica Rice 6 parts of titanium dioxide, 15 parts of nano dye, 15 parts of modified landplaster, 10 parts of nanometer calcium carbonate, 10 parts of nano metal material are more 6 parts of isocyanates, 5 parts of zirconium boride, 2 parts of antimony organic, 6 parts of silane coupling agent, wherein nano metal material includes nanometer aluminium powder 15 Part, 6 parts of nanometer zirconium powder, 8 parts of nano zinc powder, 13 parts of nanometer iron powder, 3 parts of 5 part, nanometer chromium powder of nano-nickel powder, 2 part, nanometer manganese powder, 1 part of copper nanoparticle, 3 parts of nano-tungsten powder；
B component includes following components according to the mass fraction: 5 parts of magnesia, 3 parts of alumina silicate, 5 parts of calcirm-fluoride, 8 parts of silicon nitride, hard 3 parts of resin acid zinc, 1 part of beryllium oxide, 5 parts of barium sulfate, 20 parts of graphite microparticles, 6 parts of aluminum oxide, 2 parts of aluminium borate whisker, Nano Rare 0.5 part of soil, wherein nano rare earth is that cerium oxide, lanthana and lithia are mixed according to 2:3:1 proportion.
Embodiment 2
The present embodiment provides a kind of 3D printing pen ceramic materials, are mixed by component A and B component according to mass ratio 1:2, Middle A includes following components according to the mass fraction: 25 parts of nano kaoline, 40 parts of nano silica, barium titanate powder 16 part, nanometer 9 parts of titanium dioxide, 16 parts of nano dye, 20 parts of modified landplaster, 12 parts of nanometer calcium carbonate, 12 parts of nano metal material, polyisocyanate 8 parts of cyanate, 7 parts of zirconium boride, 3 parts of antimony organic, 7 parts of silane coupling agent, wherein nano metal material include 18 parts of nanometer aluminium powder, 8 parts of zirconium powder of nanometer, 15 parts of nanometer iron powder, 4 parts of 6 part, nanometer chromium powder of nano-nickel powder, 4 part, nanometer manganese powder, is received 10 parts of nano zinc powder Rice 5 parts of copper powder, 4 parts of nano-tungsten powder；
B component includes following components according to the mass fraction: 8 parts of magnesia, 4 parts of alumina silicate, 6 parts of calcirm-fluoride, 13 parts of silicon nitride, hard 4 parts of resin acid zinc, 1.5 parts of beryllium oxide, 8 parts of barium sulfate, 23 parts of graphite microparticles, 7 parts of aluminum oxide, aluminium borate whisker 3 part, nanometer 1 part of rare earth.
Embodiment 3
The present embodiment provides a kind of 3D printing pen ceramic materials, are mixed by component A and B component according to mass ratio 1:3, Middle A includes following components according to the mass fraction: 30 parts of nano kaoline, 45 parts of nano silica, barium titanate powder 18 part, nanometer 11 parts of titanium dioxide, 16 parts of nano dye, 25 parts of modified landplaster, 14 parts of nanometer calcium carbonate, 13 parts of nano metal material, polyisocyanate 9 parts of cyanate, 7 parts of zirconium boride, 4 parts of antimony organic, 8 parts of silane coupling agent, wherein nano metal material include 20 parts of nanometer aluminium powder, 10 parts of zirconium powder of nanometer, 16 parts of nanometer iron powder, 5 parts of 7 part, nanometer chromium powder of nano-nickel powder, 6 part, nanometer manganese powder, is received 11 parts of nano zinc powder Rice 3 parts of copper powder, 6 parts of nano-tungsten powder；
B component includes following components according to the mass fraction: 9 parts of magnesia, 6 parts of alumina silicate, 7 parts of calcirm-fluoride, 15 parts of silicon nitride, hard 5 parts of resin acid zinc, 2 parts of beryllium oxide, 10 parts of barium sulfate, 25 parts of graphite microparticles, 7.5 parts of aluminum oxide, 3.5 parts of aluminium borate whisker, 1.5 parts of nano rare earth, wherein nano rare earth is that cerium oxide, lanthana and lithia are mixed according to 2:5:1 proportion.
In addition to the implementation, the present invention can also have other embodiments.It is all to use equivalent substitution or equivalent transformation shape At technical solution, fall within the scope of protection required by the present invention.

Claims (8)

1. a kind of 3D printing pen ceramic material, which is characterized in that mixed and made according to mass ratio 1:1-3 by component A and B component At wherein A includes following components according to the mass fraction: 20-30 parts of nano kaoline, 35-50 parts of nano silica, barium titanate 15-18 parts of powder, 6-12 parts of nano-titanium dioxide, 15-18 parts of nano dye, 15-25 parts of modified landplaster, nanometer calcium carbonate 10- 15 parts, 10-15 parts of nano metal material, 6-9 parts of polyisocyanates, 5-8 parts of zirconium boride, 2-4 parts of stabilizer, 6-8 parts of coupling agent；
B component includes following components according to the mass fraction: 5-10 parts of magnesia, 3-6 parts of alumina silicate, 5-7 parts of calcirm-fluoride, silicon nitride 8-16 parts, 3-6 parts of zinc stearate, 1-2 parts of beryllium oxide, 5-10 parts of barium sulfate, 20-25 parts of graphite microparticles, aluminum oxide 6-8 Part, 2-4 parts of aluminium borate whisker, 0.5-2 parts of nano rare earth.
2. 3D printing pen ceramic material according to claim 1, it is characterised in that: A includes following according to the mass fraction Component: 20 parts of nano kaoline, 35 parts of nano silica, 15 parts of barium titanate powder, 6 parts of nano-titanium dioxide, nano dye 15 Part, 15 parts of modified landplaster, 10 parts of nanometer calcium carbonate, 10 parts of nano metal material, it is 6 parts of polyisocyanates, 5 parts of zirconium boride, steady Determine 2 parts of agent, 6 parts of coupling agent；
B component includes following components according to the mass fraction: 5 parts of magnesia, 3 parts of alumina silicate, 5 parts of calcirm-fluoride, 8 parts of silicon nitride, hard 3 parts of resin acid zinc, 1 part of beryllium oxide, 5 parts of barium sulfate, 20 parts of graphite microparticles, 6 parts of aluminum oxide, 2 parts of aluminium borate whisker, Nano Rare 0.5 part of soil.
3. 3D printing pen ceramic material according to claim 1, it is characterised in that: A includes following according to the mass fraction Component: 25 parts of nano kaoline, 40 parts of nano silica, 16 parts of barium titanate powder, 9 parts of nano-titanium dioxide, nano dye 16 Part, 20 parts of modified landplaster, 12 parts of nanometer calcium carbonate, 12 parts of nano metal material, it is 8 parts of polyisocyanates, 7 parts of zirconium boride, steady Determine 3 parts of agent, 7 parts of coupling agent；
B component includes following components according to the mass fraction: 8 parts of magnesia, 4 parts of alumina silicate, 6 parts of calcirm-fluoride, 13 parts of silicon nitride, hard 4 parts of resin acid zinc, 1.5 parts of beryllium oxide, 8 parts of barium sulfate, 23 parts of graphite microparticles, 7 parts of aluminum oxide, aluminium borate whisker 3 part, nanometer 1 part of rare earth.
4. 3D printing pen ceramic material according to claim 1, it is characterised in that: A includes following according to the mass fraction Component: 30 parts of nano kaoline, 45 parts of nano silica, 18 parts of barium titanate powder, 11 parts of nano-titanium dioxide, nano dye 16 Part, 25 parts of modified landplaster, 14 parts of nanometer calcium carbonate, 13 parts of nano metal material, it is 9 parts of polyisocyanates, 7 parts of zirconium boride, steady Determine 4 parts of agent, 8 parts of coupling agent；
B component includes following components according to the mass fraction: 9 parts of magnesia, 6 parts of alumina silicate, 7 parts of calcirm-fluoride, 15 parts of silicon nitride, hard 5 parts of resin acid zinc, 2 parts of beryllium oxide, 10 parts of barium sulfate, 25 parts of graphite microparticles, 7.5 parts of aluminum oxide, 3.5 parts of aluminium borate whisker, 1.5 parts of nano rare earth.
5. 3D printing pen ceramic material according to claim 1, it is characterised in that: the nano metal material includes receiving 15-20 parts of aluminium powder of rice, 8-11 parts of nano zinc powder, 13-18 parts of nanometer iron powder, 5-7 parts of nano-nickel powder, is received 6-10 parts of nanometer zirconium powder Rice 2-6 parts of chromium powder, 3-5 parts of nanometer manganese powder, 1-3 parts of copper nanoparticle, 3-6 parts of nano-tungsten powder.
6. 3D printing pen ceramic material according to claim 1, it is characterised in that: the stabilizer is antimony organic.
7. 3D printing pen ceramic material according to claim 1, it is characterised in that: the coupling agent is silane coupled Agent.
8. 3D printing pen ceramic material according to claim 1, it is characterised in that: the nano rare earth be cerium oxide, Lanthana and lithia are mixed according to 2:3-5:1 proportion.
CN201811053175.3A 2018-09-10 2018-09-10 A kind of 3D printing pen ceramic material Withdrawn CN109081701A (en)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106045548A (en) * 2016-06-02 2016-10-26 苏州福德龙水产养殖有限公司 High-strength 3D nano ceramic printing material and preparation method thereof
CN107815621A (en) * 2017-12-26 2018-03-20 苏州浩焱精密模具有限公司 A kind of mould high duty metal ceramic material
CN108083685A (en) * 2017-12-31 2018-05-29 芜湖林电子科技有限公司 A kind of high tenacity ceramics 3D printing material and preparation method thereof
CN108503329A (en) * 2018-04-01 2018-09-07 安徽弘泰精密机械科技有限公司 A kind of 3D printing ceramic powder material

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106045548A (en) * 2016-06-02 2016-10-26 苏州福德龙水产养殖有限公司 High-strength 3D nano ceramic printing material and preparation method thereof
CN107815621A (en) * 2017-12-26 2018-03-20 苏州浩焱精密模具有限公司 A kind of mould high duty metal ceramic material
CN108083685A (en) * 2017-12-31 2018-05-29 芜湖林电子科技有限公司 A kind of high tenacity ceramics 3D printing material and preparation method thereof
CN108503329A (en) * 2018-04-01 2018-09-07 安徽弘泰精密机械科技有限公司 A kind of 3D printing ceramic powder material

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Application publication date: 20181225