CN109072139A - 洗涤剂组合物 - Google Patents
洗涤剂组合物 Download PDFInfo
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- 239000000203 mixture Substances 0.000 title claims abstract description 48
- 239000003599 detergent Substances 0.000 title claims abstract description 27
- 239000000344 soap Substances 0.000 claims abstract description 36
- 239000004094 surface-active agent Substances 0.000 claims abstract description 35
- 238000000034 method Methods 0.000 claims abstract description 18
- 238000005406 washing Methods 0.000 claims abstract description 15
- 238000004140 cleaning Methods 0.000 claims description 22
- -1 Saturated fatty acid carboxylate Chemical class 0.000 claims description 16
- 150000001412 amines Chemical class 0.000 claims description 7
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims description 5
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims description 5
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims description 5
- 239000005642 Oleic acid Substances 0.000 claims description 5
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims description 5
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims description 5
- 229940096992 potassium oleate Drugs 0.000 claims description 5
- MLICVSDCCDDWMD-KVVVOXFISA-M potassium;(z)-octadec-9-enoate Chemical group [K+].CCCCCCCC\C=C/CCCCCCCC([O-])=O MLICVSDCCDDWMD-KVVVOXFISA-M 0.000 claims description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 4
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 4
- 239000007788 liquid Substances 0.000 claims description 4
- 229940049964 oleate Drugs 0.000 claims description 3
- QJRVOJKLQNSNDB-UHFFFAOYSA-N 4-dodecan-3-ylbenzenesulfonic acid Chemical class CCCCCCCCCC(CC)C1=CC=C(S(O)(=O)=O)C=C1 QJRVOJKLQNSNDB-UHFFFAOYSA-N 0.000 claims description 2
- 238000007865 diluting Methods 0.000 claims description 2
- 238000003756 stirring Methods 0.000 claims description 2
- 150000003839 salts Chemical class 0.000 claims 2
- 230000003213 activating effect Effects 0.000 claims 1
- 150000004996 alkyl benzenes Chemical class 0.000 claims 1
- 239000003795 chemical substances by application Substances 0.000 claims 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 7
- 239000000194 fatty acid Substances 0.000 description 7
- 229930195729 fatty acid Natural products 0.000 description 7
- 150000004665 fatty acids Chemical class 0.000 description 5
- 150000002500 ions Chemical class 0.000 description 5
- 150000007942 carboxylates Chemical class 0.000 description 4
- 239000004744 fabric Substances 0.000 description 4
- 239000006260 foam Substances 0.000 description 4
- 239000002518 antifoaming agent Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 1
- NPYPAHLBTDXSSS-UHFFFAOYSA-N Potassium ion Chemical compound [K+] NPYPAHLBTDXSSS-UHFFFAOYSA-N 0.000 description 1
- FKNQFGJONOIPTF-UHFFFAOYSA-N Sodium cation Chemical compound [Na+] FKNQFGJONOIPTF-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- SRSXLGNVWSONIS-UHFFFAOYSA-M benzenesulfonate Chemical compound [O-]S(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-M 0.000 description 1
- 229940077388 benzenesulfonate Drugs 0.000 description 1
- 229910001424 calcium ion Inorganic materials 0.000 description 1
- 239000012459 cleaning agent Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 235000013569 fruit product Nutrition 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229910001425 magnesium ion Inorganic materials 0.000 description 1
- 150000004702 methyl esters Chemical class 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 230000008447 perception Effects 0.000 description 1
- 239000001103 potassium chloride Substances 0.000 description 1
- 235000011164 potassium chloride Nutrition 0.000 description 1
- 229910001414 potassium ion Inorganic materials 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 229910001415 sodium ion Inorganic materials 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 229910021653 sulphate ion Inorganic materials 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D10/00—Compositions of detergents, not provided for by one single preceding group
- C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/37—Mixtures of compounds all of which are anionic
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D10/00—Compositions of detergents, not provided for by one single preceding group
- C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
- C11D10/042—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap based on anionic surface-active compounds and soap
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D10/00—Compositions of detergents, not provided for by one single preceding group
- C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
- C11D10/045—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap based on non-ionic surface-active compounds and soap
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/08—Liquid soap, e.g. for dispensers; capsuled
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
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- C11D1/04—Carboxylic acids or salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
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- C11D1/143—Sulfonic acid esters
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
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Abstract
洗涤剂组合物，其包含表面活性剂体系，所述表面活性剂体系是10重量％至70重量％的皂。易于清洗的洗涤剂组合物。使用这样的组合物的洗衣方法。
Description
本发明涉及一种包含表面活性剂体系的洗涤剂，所述表面活性剂体系是至少10重量％的皂和合适地少于70重量％的皂。
当洗涤衣物时，特别是在手洗时，起泡可以是期望的，因为它可以改善清洁和/或增强使用者对功效的感知。如果产品不起泡，用户可能会认为产品不起作用，或者产品添加不足。
然而，在洗涤步骤之后，通常有相当大量的表面活性剂残留在织物纤维中和织物表面上。这可以称为“遗留”。结果，在清洗(rinse)步骤中发生显著量的起泡。这种遗留通常持续多次清洗。这可导致三次、四次或甚至更多次清洗。人们倾向于清洗衣物直到清洗液中具有最小的泡沫、肥皂感或浑浊。
自然，这种反复清洗增加水消耗，引起环境问题，特别是在缺水国家。此外，肥皂水经常被丢弃而没有进一步使用。
因此，期望减少起泡组合物的遗留。
以前解决此问题的尝试包括以下内容。
一种方法使洗涤剂的表面活性剂含量最小化。这减少了清洗步骤过程中的泡沫量，但是以洗涤步骤中的起泡为代价。
另一种方法提供含有清洗剂、抗泡剂和消泡剂的洗涤剂组合物，以减少清洗过程中的起泡。必须仔细确定添加量，以使洗涤步骤过程中的起泡损失最小化。这些额外成分也增加了成本和浪费。
本发明以不同方式解决了更有效地清洗的起泡洗涤剂的问题。
本发明人惊奇地发现，将组合物中皂的相对量增加到显著大于通常添加到洗涤剂中的皂的含量，导致良好起泡的主洗产品，其似乎比常规洗涤剂更容易清洗。
本发明涉及一种洗涤剂组合物，其包含表面活性剂体系，所述表面活性剂体系是至少10重量％的皂和合适地少于70重量％的皂。
如本文所述，术语皂是指脂肪酸的羧酸盐。
因此，在第一方面，本发明可提供一种洗涤剂组合物，其包含表面活性剂体系，所述表面活性剂体系是10重量％至70重量％的皂。
在一些情况下，表面活性剂体系是小于60重量％的皂，例如小于50重量％的皂。
在一些情况下，表面活性剂体系是至少15重量％的皂，例如20重量％的皂或更高，或甚至25重量％或30重量％的皂或更高。
例如，表面活性剂体系可以是20重量％至50重量％的皂，例如30重量％至50重量％。
应理解，如本文所用，表面活性剂体系描述了组合物的总表面活性剂含量。
在一些情况下，表面活性剂体系可占组合物的至多25重量％。
优选地，表面活性剂体系占组合物的至多20重量％，例如占组合物的至多15重量％。
合适地，表面活性剂体系占组合物的至少5重量％。
例如，它可以是至少8重量％或至少12重量％。
合适地，洗涤剂组合物是液体洗涤剂组合物。例如，它可以是配制用于洗衣的洗衣液。表面活性剂体系可占组合物的12重量％至20重量％。洗涤剂组合物可以配制成手洗组合物，用于在水槽中洗涤物品。表面活性剂体系可占组合物的8重量％至20重量％。
皂是脂肪酸的羧酸盐。本发明组合物的皂含量可以由单一皂化合物或皂化合物的混合物组成。在某些情况下，使用单一的脂肪酸羧酸盐。抗衡离子可以是单一抗衡离子或抗衡离子的混合物。
合适的抗衡离子是本领域已知的，包括钾离子和钠离子以及基于有机胺的抗衡离子，例如基于三乙醇胺的抗衡离子。
脂肪酸羧酸盐可以是不饱和的或饱和的。例如，脂肪酸可包含一个或多个双键。优选地，皂是>50％的单不饱和。
脂肪酸可以是C10-30化合物，例如C15-25化合物。
合适的脂肪酸是油酸。在这些情况下，皂是>50重量％的油酸的羧酸盐。例如，它可以是钾盐。换句话说，皂可以是>50重量％的油酸钾。
在一些情况下，皂为>75重量％的油酸的羧酸盐，例如>90重量％或甚至>95重量％。
总表面活性剂的其余部分是非皂表面活性剂。合适的非皂表面活性剂包括直链烷基苯磺酸盐(LAS)，醇硫酸盐如伯醇硫酸盐(PAS)，烷基醚硫酸盐(AES)，氧化胺(AO)，甲酯磺酸盐(MES)和醇乙氧基化物(NI)。
例如，表面活性剂体系可包含直链烷基苯磺酸盐(LAS)，伯醇硫酸盐(PAS)和皂。在一些情况下，量分别为40-45重量％，1-10重量％和40-50重量％。
例如，表面活性剂体系可以是约50重量％的直链烷基苯磺酸盐(LAS)，约45重量％的皂(优选油酸钾)和约5重量％的伯醇硫酸盐。
在其他实例中，表面活性剂体系可包含烷基醚硫酸盐(AES)，氧化胺(AO)和皂。在一些情况下，量分别为72-40重量％，10-30重量％和40-10重量％。
例如，表面活性剂体系可包含约48-55重量％的烷基醚硫酸盐(AES)，约18-22重量％的氧化胺(AO)和约28-35重量％的皂。
例如，表面活性剂体系可包含约48重量％的烷基醚硫酸盐(AES)，约20重量％的氧化胺(AO)和约32重量％的皂。
本发明进一步提供一种洗衣物品的方法，该方法包括通过在水中稀释前述权利要求中任一项所述的组合物而形成洗涤液；然后搅拌浸入所述洗涤液中的物品；然后从所述物品排出所述洗涤液；然后在一个或多个清洗步骤中清洗所述物品。
合适地，物品是织物物品，例如衣服、家用亚麻制品和窗帘，帆布和工业织物。
如本文所述，本发明的组合物可以导致洗衣方法中较少的清洗，因为发明人已经观察到在用于测试组合物的清洗步骤条件下观察到较少的泡沫。
合适地，方法包括三个或更少个清洗步骤。在一些情况下，方法仅包括两个清洗步骤。
这使得本发明的组合物特别适用于手洗洗衣方法。因此，在一些情况下，方法不是在自动洗衣机中。相反，方法可以是在洗涤桶、水槽或类似物中。这可以称为手洗。
实施例
实施例1
根据本发明的组合物包含：
直链烷基苯磺酸钾(K-LAS) 7.5重量％
油酸钾(K-油酸盐) 6.75重量％
伯烷基磺酸钾 0.75重量％
组合物的表面活性剂含量为15重量％。
将其与目前市售的具有以下活性物组成的洗衣液洗涤剂进行比较：Na-LAS，非离子7EO，烷基醚硫酸钠(2EO)，硬化月桂酸的钠盐。
通过将组合物加入水中制备洗涤溶液，得到5克/升的浓度。水含有浓度为0.8毫摩尔的钙离子和浓度为0.04毫摩尔的镁离子。
以相同的方式制备清洗溶液，但是以0.25克/升的浓度添加组合物。
将20ml的每种溶液加入100ml的带塞量筒中。在垂直平面中用手摇动量筒10次。在静置10秒后记录量筒中的泡沫的体积。
本发明的组合物在洗涤步骤中产生类似的起泡，但在较低浓度下(即在清洗步骤中)给出减少的起泡，这意味着可以更容易地清洗衣物。
Claims (13)
1.一种洗涤剂组合物，其包含表面活性剂体系，所述表面活性剂体系是10重量％至70重量％的皂。
2.根据权利要求1所述的洗涤剂组合物，其中所述洗涤剂组合物是液体组合物。
3.根据权利要求1或2所述的洗涤剂组合物，其中所述表面活性剂体系占所述组合物的5重量％至20重量％。
4.根据前述权利要求中任一项所述的洗涤剂组合物，其中所述皂是>50重量％的单不饱和脂肪酸羧酸盐。
5.根据前述权利要求中任一项所述的洗涤剂组合物，其中所述皂是>50重量％的油酸盐，任选地其中所述油酸盐是油酸钾。
6.根据前述权利要求中任一项所述的洗涤剂组合物，其中所述皂是>95重量％的油酸盐，任选地其中所述油酸盐是油酸钾。
7.根据前述权利要求中任一项所述的洗涤剂组合物，其中所述表面活性剂体系是30重量％至50重量％的皂。
8.根据前述权利要求中任一项所述的洗涤剂组合物，其中所述表面活性剂体系包含选自直链烷基苯磺酸盐(LAS)、醇硫酸盐、烷基醚硫酸盐(AES)和氧化胺(AO)的一种或多种表面活性剂。
9.根据前述权利要求中任一项所述的洗涤剂组合物，其中所述表面活性剂体系包含直链烷基苯磺酸盐(LAS)和醇硫酸盐；任选地其中所述表面活性剂体系包含直链烷基苯磺酸盐(LAS)和伯醇硫酸盐(PAS)。
10.根据权利要求1至8中任一项所述的洗涤剂组合物，其中所述表面活性剂体系包含烷基醚硫酸盐(AES)和氧化胺(AO)。
11.一种洗衣物品的方法，所述方法包括：
通过在水中稀释根据前述权利要求中任一项所述的组合物而形成洗涤液；然后
搅拌浸入所述洗涤液中的物品；然后
从所述物品排出所述洗涤液；然后
在一个或多个清洗步骤中清洗所述物品。
12.根据权利要求11所述的方法，其中所述方法包括三个或更少个清洗步骤，任选地其中所述方法仅包括两个清洗步骤。
13.根据权利要求11或12所述的方法，其中所述洗衣物品的方法不是在自动洗衣机中。
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| Application Number | Priority Date | Filing Date | Title |
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| EP16171146.0 | 2016-05-24 | ||
| EP16171146 | 2016-05-24 | ||
| PCT/EP2017/062315 WO2017202796A1 (en) | 2016-05-24 | 2017-05-22 | Detergent compositions |
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| CN109072139A true CN109072139A (zh) | 2018-12-21 |
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| CN201780029429.5A Pending CN109072139A (zh) | 2016-05-24 | 2017-05-22 | 洗涤剂组合物 |
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| US (1) | US20200318033A1 (zh) |
| EP (1) | EP3464540A1 (zh) |
| CN (1) | CN109072139A (zh) |
| AU (1) | AU2017269850B2 (zh) |
| WO (1) | WO2017202796A1 (zh) |
| ZA (1) | ZA201807103B (zh) |
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| CN106232788B (zh) * | 2014-05-20 | 2019-08-20 | 宝洁公司 | 具有改善的起泡特征的低表面活性剂、高碳酸盐液体衣物洗涤剂组合物 |
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2017
- 2017-05-22 AU AU2017269850A patent/AU2017269850B2/en active Active
- 2017-05-22 WO PCT/EP2017/062315 patent/WO2017202796A1/en unknown
- 2017-05-22 US US16/303,574 patent/US20200318033A1/en not_active Abandoned
- 2017-05-22 CN CN201780029429.5A patent/CN109072139A/zh active Pending
- 2017-05-22 EP EP17726244.1A patent/EP3464540A1/en not_active Withdrawn
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2018
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| US4304680A (en) * | 1973-02-05 | 1981-12-08 | Colgate-Palmolive Company | Laundry soap |
| CN1088972A (zh) * | 1992-10-12 | 1994-07-06 | 阿尔布赖特-威尔逊公司 | 新的洗涤制品 |
| WO1998027189A1 (en) * | 1996-12-17 | 1998-06-25 | Colgate-Palmolive Company | Mildly acidic laundry detergent composition |
| EP1120459A1 (en) * | 2000-01-13 | 2001-08-01 | Yplon S.A. | Detergent package |
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| WO2016074142A1 (en) * | 2014-11-11 | 2016-05-19 | The Procter & Gamble Company | Detergent or cleaning compositions with improved sudsing profile |
Also Published As
| Publication number | Publication date |
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| ZA201807103B (en) | 2020-01-29 |
| EP3464540A1 (en) | 2019-04-10 |
| AU2017269850A1 (en) | 2018-11-15 |
| AU2017269850B2 (en) | 2020-03-12 |
| WO2017202796A1 (en) | 2017-11-30 |
| BR112018074224A2 (pt) | 2019-03-06 |
| US20200318033A1 (en) | 2020-10-08 |
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