CN109065633A - Storage unit and forming method thereof - Google Patents

Storage unit and forming method thereof Download PDF

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Publication number
CN109065633A
CN109065633A CN201810882381.9A CN201810882381A CN109065633A CN 109065633 A CN109065633 A CN 109065633A CN 201810882381 A CN201810882381 A CN 201810882381A CN 109065633 A CN109065633 A CN 109065633A
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CN
China
Prior art keywords
storage unit
layer
floating gate
forming method
word line
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CN201810882381.9A
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Chinese (zh)
Inventor
刘宪周
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Shanghai Huahong Grace Semiconductor Manufacturing Corp
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Shanghai Huahong Grace Semiconductor Manufacturing Corp
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Priority to CN201810882381.9A priority Critical patent/CN109065633A/en
Publication of CN109065633A publication Critical patent/CN109065633A/en
Pending legal-status Critical Current

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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
    • H01L29/40Electrodes ; Multistep manufacturing processes therefor
    • H01L29/41Electrodes ; Multistep manufacturing processes therefor characterised by their shape, relative sizes or dispositions
    • H01L29/423Electrodes ; Multistep manufacturing processes therefor characterised by their shape, relative sizes or dispositions not carrying the current to be rectified, amplified or switched
    • H01L29/42312Gate electrodes for field effect devices
    • H01L29/42316Gate electrodes for field effect devices for field-effect transistors
    • H01L29/4232Gate electrodes for field effect devices for field-effect transistors with insulated gate
    • H01L29/42324Gate electrodes for transistors with a floating gate
    • H01L29/42328Gate electrodes for transistors with a floating gate with at least one additional gate other than the floating gate and the control gate, e.g. program gate, erase gate or select gate
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
    • H01L29/40Electrodes ; Multistep manufacturing processes therefor
    • H01L29/41Electrodes ; Multistep manufacturing processes therefor characterised by their shape, relative sizes or dispositions
    • H01L29/423Electrodes ; Multistep manufacturing processes therefor characterised by their shape, relative sizes or dispositions not carrying the current to be rectified, amplified or switched
    • H01L29/42312Gate electrodes for field effect devices
    • H01L29/42316Gate electrodes for field effect devices for field-effect transistors
    • H01L29/4232Gate electrodes for field effect devices for field-effect transistors with insulated gate
    • H01L29/42324Gate electrodes for transistors with a floating gate
    • H01L29/42332Gate electrodes for transistors with a floating gate with the floating gate formed by two or more non connected parts, e.g. multi-particles flating gate
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
    • H01L29/40Electrodes ; Multistep manufacturing processes therefor
    • H01L29/41Electrodes ; Multistep manufacturing processes therefor characterised by their shape, relative sizes or dispositions
    • H01L29/423Electrodes ; Multistep manufacturing processes therefor characterised by their shape, relative sizes or dispositions not carrying the current to be rectified, amplified or switched
    • H01L29/42312Gate electrodes for field effect devices
    • H01L29/42316Gate electrodes for field effect devices for field-effect transistors
    • H01L29/4232Gate electrodes for field effect devices for field-effect transistors with insulated gate
    • H01L29/42324Gate electrodes for transistors with a floating gate
    • H01L29/42336Gate electrodes for transistors with a floating gate with one gate at least partly formed in a trench
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
    • H01L29/66Types of semiconductor device ; Multistep manufacturing processes therefor
    • H01L29/68Types of semiconductor device ; Multistep manufacturing processes therefor controllable by only the electric current supplied, or only the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched
    • H01L29/76Unipolar devices, e.g. field effect transistors
    • H01L29/772Field effect transistors
    • H01L29/78Field effect transistors with field effect produced by an insulated gate
    • H01L29/788Field effect transistors with field effect produced by an insulated gate with floating gate
    • H01L29/7881Programmable transistors with only two possible levels of programmation

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  • Engineering & Computer Science (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Ceramic Engineering (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Computer Hardware Design (AREA)
  • Semiconductor Memories (AREA)
  • Non-Volatile Memory (AREA)

Abstract

The present invention provides a kind of storage unit and forming method thereof, the storage unit includes FGS floating gate structure, control grid structure and word line structure, and the FGS floating gate structure has tip towards the side of the word line structure.In storage unit provided by the invention and forming method thereof, there is tip towards the side of word line structure in FGS floating gate structure, pass through the point effect at tip, electrons when wiping device in FGS floating gate structure are shifted by tip to word line structure, efficiency of erasing when effective raising erasing operation, to improve the performance of storage unit.

Description

Storage unit and forming method thereof
Technical field
The present invention relates to technical field of integrated circuits, in particular to a kind of storage unit and forming method thereof.
Background technique
Memory can be used for storing a large amount of digital information, and presently, there are the memories of numerous types, as RAM is (random Memory), DRAM (dynamic RAM), ROM (read-only memory), EPROM (Erasable Programmable Read Only Memory EPROM), FLASH (flash memory) etc..
In the prior art, floating gate type flash memory is as a kind of nonvolatile storage, as shown in Figure 1, floating gate type flash memory is deposited Storage unit suffers from similar original unit framework, they have the gate structure of stacking, which includes FGS floating gate structure 1, at least partly cover floating gate control grid structure 2 and word line structure 3, wherein control grid structure 2 can be controlled by coupling it is floating The storage and release of electronics in grid structure 1.When the electric field between control grid structure 2 and word line structure 3 is sufficiently high, floating gate knot Electronics in structure 1 is drawn out between FGS floating gate structure 1 and word line structure 3, to realize the erasing operation of storage unit.
Therefore, how to provide a kind of storage unit with better erasing effect is that those skilled in the art are urgently to be resolved A technical problem.
Summary of the invention
The purpose of the present invention is to provide a kind of storage units and forming method thereof, to improve storage unit in the prior art Erasing effect.
In order to solve the above technical problems, the present invention provides a kind of storage unit, the storage unit includes FGS floating gate structure, control Grid structure processed and word line structure, the FGS floating gate structure have tip towards the side of the word line structure.
Optionally, in the storage unit, the control gate structure is towards the FGS floating gate structure and towards the word The side of cable architecture has an ono dielectric layer.
Optionally, in the storage unit, the thickness of silicon oxide layer is all in the ono dielectric layerIts Middle silicon nitride layer with a thickness of
Optionally, in the storage unit, the FGS floating gate structure and the control grid structure are far from described offline The side of structure has sidewall structure.
The present invention also provides a kind of forming method of storage unit, the forming method of the storage unit includes:
One substrate is provided, there is the first polycrystalline silicon medium layer on the substrate, have on the first polycrystalline silicon medium layer First polysilicon layer;
Barrier structure is formed on first polysilicon layer;
First polysilicon layer is performed etching, forms slope in the position close to the barrier structure;
The second polycrystalline silicon medium layer is formed on first polysilicon layer, is formed on the second polycrystalline silicon medium layer Second polysilicon layer;
It etches second polysilicon and forms control grid structure, then etch first polysilicon layer and retain floating gate knot out Structure region;
The barrier structure is removed, first polysilicon is performed etching in the position on the slope to be formed with tip FGS floating gate structure.
Optionally, in the forming method of the storage unit, on first polysilicon layer and the blocking junction The second polycrystalline silicon medium layer is formed simultaneously on the two sides of structure.
Optionally, in the forming method of the storage unit, second polysilicon layer is ono dielectric layer.
Optionally, in the forming method of the storage unit, the thickness of silicon oxide layer is all in the ono dielectric layerWherein silicon nitride layer with a thickness of
Optionally, in the forming method of the storage unit, the material of the barrier structure includes silicon nitride.
Optionally, in the forming method of the storage unit, further includes: in the FGS floating gate structure and the control gate Structure forms sidewall structure far from the side of word line structure, and the material of the sidewall structure includes silicon nitride.
In conclusion in storage unit provided by the invention and forming method thereof, in FGS floating gate structure towards word line structure Side there is tip, by the point effect at tip, electrons when wipe device in FGS floating gate structure pass through tip to word Cable architecture transfer effectively improves efficiency of erasing when erasing operation, to improve the performance of storage unit.
Detailed description of the invention
Fig. 1 is the structural schematic diagram of the storage unit of the prior art;
Fig. 2 is the flow diagram of the forming method of the storage unit of the embodiment of the present invention;
Fig. 3-9 is structural schematic diagram of the storage unit of the embodiment of the present invention in forming process;
Wherein, 1,32- FGS floating gate structure, 2,61- control grid structure, 3,70- word line structure, 10- substrate, 20- first Polycrystalline silicon medium layer, the first polysilicon layer of 30-, the slope 31-, 40- barrier structure, 50- the second polycrystalline silicon medium layer, 60- Second polysilicon layer, 80- sidewall structure.
Specific embodiment
In order to keep objects, features and advantages of the present invention more obvious and easy to understand, attached drawing is please referred to.It should be clear that this explanation Book structure depicted in this specification institute accompanying drawings, ratio, size etc., only to cooperate the revealed content of specification, for being familiar with this The personage of technology understands and reads, and is not intended to limit the invention enforceable qualifications, therefore does not have technical essence meaning Justice, the modification of any structure, the change of proportionate relationship or the adjustment of size are not influencing the effect of present invention can be generated and institute Under the purpose that can reach, should all still it fall in the range of disclosed technology contents obtain and can cover.
As shown in figure 9, the present invention provides a kind of storage unit, the storage unit includes FGS floating gate structure 32, control gate knot Structure 61 and word line structure 70, the FGS floating gate structure 32 towards the word line structure 70 side have tip, storage unit it is whole It is close with the floating gate type flash memory in prior art in body structure, but subtle improvement has been done for the shape of FGS floating gate structure, pass through Towards word line structure side formed tip to promote erasing operation when FGS floating gate structure in electronics transfer, tip can also work as Make protrusion or part outstanding.
It is corresponding with the structure of storage unit, as shown in Fig. 2, the present invention also provides a kind of formation sides of storage unit The forming method of method, the storage unit includes:
Step S10: as shown in figure 3, providing a substrate 10, there is the first polycrystalline silicon medium layer 20, institute on the substrate 10 Stating has the first polysilicon layer 30 on the first polycrystalline silicon medium layer 20, the material of the first polycrystalline silicon medium layer includes silica, Foundation structure in embodiment only for storage unit is described, for other active structures such as source/drain and gold Belonging to connection (CT, Contact) etc. can refer to prior art processing;
Step S20: as shown in figure 4, forming barrier structure 40 on first polysilicon layer 30, barrier structure 40 can be Barrier effect is played in the formation of subsequent other structures, can form corresponding film layer on the first polysilicon layer, etch away and do not need Region i.e. obtain the barrier structure, optionally, the material of the barrier structure 40 includes silicon nitride;
Step S30: as shown in figure 5, being performed etching to first polysilicon layer 30, close to the barrier structure 40 Position forms slope 31, namely can all be formed centainly in two sides under the influence of the position close to barrier structure is in etch rate The pattern of the gradient, such as gradient size can be 10 degree~80 degree;
Step S40: as shown in fig. 6, then, the second polycrystalline silicon medium layer 50 is formed on first polycrystal layer 30, The second polysilicon layer 60 is formed on the second polycrystalline silicon medium layer 50;
Step S50: as shown in fig. 7, then, etching second polysilicon 60 and forming control grid structure 61, can control Then first polysilicon layer 30 is etched on the basis of grid structure 61 and retains FGS floating gate structure region out, at this point, FGS floating gate structure is also It is unformed so only retain the region out, in the present embodiment, for ease of description, in etching technics for may relate to To photoresist and its graphical and removal photoetching the specific steps such as lack and have not been described in detail, and be situated between for the first polysilicon The redundance of matter layer and the second polycrystalline silicon medium layer is removed, further for other dielectric materials that are related to (as aoxidized Silicon) filling and removal and chemical mechanical grinding etc., those skilled in the art can be implemented by using the prior art in each step The structure of required formation;
Step S60: as shown in figure 8, followed by, the barrier structure 40 is removed, it can be complete in such a way that wet process removes Barrier structure is got rid of, performs etching that form tool cuspidated floating to first polysilicon layer 30 in the position on the slope 31 Grid structure 32, that is, continue the first polysilicon layer 30 of etching downwards after barrier structure 40 removes, it will be in the position on slope 31 It sets to form tip (part with reference to shown in the virtual coil A in attached drawing), it is last as shown in figure 9, in control grid structure 61 and floating gate knot Structure 32 can carry out being formed the technique of word line structure 70 after being formed, that is, deposit wordline polysilicon after forming tunneling oxide layer Layer.
In the storage unit of the present embodiment, the control grid structure 61 is towards the FGS floating gate structure 32 and towards described The side of word line structure 70 has an ONO (Oxide-Nitride-Oxide) dielectric layer, that is, control grid structure 61 and floating gate Between structure 32 and same ono dielectric layer is formed between control grid structure 61 and word line structure 70 to be isolated.Corresponding to depositing In the forming method of storage unit, is formed simultaneously on first polysilicon layer 30 and on the two sides of the barrier structure 40 Two polycrystalline silicon medium layers 50, can be simultaneously on the first polysilicon layer 30 and barrier structure 40 by modes such as chemical meteorology depositions Two sides form the second polycrystalline silicon medium layer 50.In the present embodiment, second polysilicon layer 50 is ono dielectric layer.Optionally, The thickness of silicon oxide layer is all in the ono dielectric layerWherein silicon nitride layer with a thickness of? Same thickness range can be used in two layers of silicon oxide layer in ono dielectric layer formation process, but the thickness of two layers of silicon oxide layer is not It is required that consistent.
In storage unit in the present embodiment, refering to what is shown in Fig. 9, the FGS floating gate structure 32 and the control grid structure 61 have sidewall structure 80 in the side far from the word line structure 70, that is, can form sidewall structure in two sides, can pass through Sidewall structure carries out electrical protection to FGS floating gate structure and control grid structure.The formation side of storage unit in corresponding the present embodiment In method, sidewall structure 80 is formed far from the side of word line structure 70 in the FGS floating gate structure and the control grid structure 61, It is exactly that can distinguish each formation sidewall structure 80 in two sides after forming word line structure 70, the material of the sidewall structure 80 includes Silicon nitride.
Compared with the prior art, in the forming step of storage unit of the invention after forming the first polysilicon layer with regard to shape At barrier structure, the second polycrystalline silicon medium layer and the second polysilicon layer are formed under the barrier effect of barrier structure.It is existing It is used in technology and sequentially forms the first polycrystalline silicon medium layer, the first polysilicon layer, the second polycrystalline silicon medium layer and the second polysilicon Layer, is subsequently formed word line structure, finally completes FGS floating gate structure and control grid structure.And corresponding in the solution of the present invention, first shape At FGS floating gate structure and control grid structure, word line structure is eventually formed.
In conclusion in storage unit provided by the invention and forming method thereof, in FGS floating gate structure towards word line structure Side there is tip, by the point effect at tip, electrons when wipe device in FGS floating gate structure pass through tip to word Cable architecture transfer effectively improves efficiency of erasing when erasing operation, to improve the performance of storage unit.
Foregoing description is only the description to present pre-ferred embodiments, not to any restriction of the scope of the invention, this hair Any change, the modification that the those of ordinary skill in bright field does according to the disclosure above content, belong to the protection of claims Range.

Claims (10)

1. a kind of storage unit, which is characterized in that the storage unit includes FGS floating gate structure, controls grid structure and word line structure, The FGS floating gate structure has tip towards the side of the word line structure.
2. storage unit according to claim 1, which is characterized in that the control gate structure towards the FGS floating gate structure and Side towards the word line structure has an ono dielectric layer.
3. storage unit according to claim 2, which is characterized in that the thickness of silicon oxide layer is all in the ono dielectric layerWherein silicon nitride layer with a thickness of
4. storage unit described in any one of -3 according to claim 1, which is characterized in that the FGS floating gate structure and described Controlling grid structure has sidewall structure in the side far from the word line structure.
5. a kind of forming method of storage unit, which is characterized in that the forming method of the storage unit includes:
One substrate is provided, there is the first polycrystalline silicon medium layer on the substrate, have first on the first polycrystalline silicon medium layer Polysilicon layer;
Barrier structure is formed on first polysilicon layer;
First polysilicon layer is performed etching, forms slope in the position close to the barrier structure;
The second polycrystalline silicon medium layer is formed on first polysilicon layer, forms second on the second polycrystalline silicon medium layer Polysilicon layer;
It etches second polysilicon layer and forms control grid structure, then etch first polysilicon layer and retain FGS floating gate structure out Region;
The barrier structure is removed, performs etching that form tool cuspidated floating to first polysilicon in the position on the slope Grid structure.
6. the forming method of storage unit according to claim 5, which is characterized in that on first polysilicon layer and The second polycrystalline silicon medium layer is formed simultaneously on the two sides of the barrier structure.
7. the forming method of storage unit according to claim 6, which is characterized in that second polysilicon layer is ONO Jie Matter layer.
8. the forming method of storage unit according to claim 7, which is characterized in that silicon oxide layer in the ono dielectric layer Thickness be allWherein silicon nitride layer with a thickness of
9. according to the forming method of storage unit described in any one of claim 5-8, which is characterized in that the blocking junction The material of structure includes silicon nitride.
10. according to the forming method of storage unit described in any one of claim 5-8, which is characterized in that the storage is single The forming method of member further include: form side wall far from the side of word line structure in the FGS floating gate structure and the control grid structure Structure, the material of the sidewall structure include silicon nitride.
CN201810882381.9A 2018-08-06 2018-08-06 Storage unit and forming method thereof Pending CN109065633A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110085592A (en) * 2019-04-30 2019-08-02 上海华虹宏力半导体制造有限公司 Flash memory fabrication method

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20110248328A1 (en) * 2010-04-09 2011-10-13 Taiwan Semiconductor Manufacturing Company, Ltd. Stucture for flash memory cells
CN103050446A (en) * 2012-12-20 2013-04-17 上海宏力半导体制造有限公司 Split-gate flash memory and forming method thereof
TW201508753A (en) * 2013-08-29 2015-03-01 Chrong-Jung Lin Memory cell, memory array and operation method thereof
CN104538367A (en) * 2014-12-30 2015-04-22 上海华虹宏力半导体制造有限公司 Mirror image split gate flash memory and forming method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20110248328A1 (en) * 2010-04-09 2011-10-13 Taiwan Semiconductor Manufacturing Company, Ltd. Stucture for flash memory cells
CN103050446A (en) * 2012-12-20 2013-04-17 上海宏力半导体制造有限公司 Split-gate flash memory and forming method thereof
TW201508753A (en) * 2013-08-29 2015-03-01 Chrong-Jung Lin Memory cell, memory array and operation method thereof
CN104538367A (en) * 2014-12-30 2015-04-22 上海华虹宏力半导体制造有限公司 Mirror image split gate flash memory and forming method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110085592A (en) * 2019-04-30 2019-08-02 上海华虹宏力半导体制造有限公司 Flash memory fabrication method

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