CN109054310A - A kind of color master-batch improving polyester fiber vividness and tinting strength, tinting power - Google Patents

A kind of color master-batch improving polyester fiber vividness and tinting strength, tinting power Download PDF

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Publication number
CN109054310A
CN109054310A CN201810800491.6A CN201810800491A CN109054310A CN 109054310 A CN109054310 A CN 109054310A CN 201810800491 A CN201810800491 A CN 201810800491A CN 109054310 A CN109054310 A CN 109054310A
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China
Prior art keywords
tinting
vividness
polyester fiber
batch
color master
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Application number
CN201810800491.6A
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Chinese (zh)
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CN109054310B (en
Inventor
王军
郭福江
葛汉
周兴
江河
俞涛
郭润叶
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Shantou Kecai New Material Co.,Ltd.
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Zhejiang Heng Ye New Mstar Technology Ltd
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Publication of CN109054310A publication Critical patent/CN109054310A/en
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00Processes of treating or compounding macromolecular substances
    • C08J3/20Compounding polymers with additives, e.g. colouring
    • C08J3/22Compounding polymers with additives, e.g. colouring using masterbatch techniques
    • C08J3/226Compounding polymers with additives, e.g. colouring using masterbatch techniques using a polymer as a carrier
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00General methods for the manufacture of artificial filaments or the like
    • D01F1/02Addition of substances to the spinning solution or to the melt
    • D01F1/04Pigments
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00General methods for the manufacture of artificial filaments or the like
    • D01F1/02Addition of substances to the spinning solution or to the melt
    • D01F1/10Other agents for modifying properties
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/88Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds
    • D01F6/92Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds of polyesters
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2367/00Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
    • C08J2367/02Polyesters derived from dicarboxylic acids and dihydroxy compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2423/00Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2423/02Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2423/04Homopolymers or copolymers of ethene
    • C08J2423/08Copolymers of ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2467/00Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
    • C08J2467/02Polyesters derived from dicarboxylic acids and dihydroxy compounds

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Textile Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses a kind of color master-batch for improving polyester fiber vividness and tinting strength, tinting power, and the dispersing agent of the ethylene acrylate copolymer of pigment, 5-10% including 20-30%, 2-5%, surplus is vector resin.A kind of color master-batch improving terylene vividness and tinting strength, tinting power according to the present invention, it has used and has contained pigment and ethylene acrylate copolymer, so that the vividness of the polyester fiber of the color master-batch and tinting strength, tinting power has been used to be improved, so that the vividness of polyester fiber increases 20%, while stability of spinning process is improved, pressure is stablized, the spinning period improves 20%, and during cleaning assembly, and residual is less, cleaning is more convenient, and cost energy consumption reduces obvious.

Description

A kind of color master-batch improving polyester fiber vividness and tinting strength, tinting power
Technical field
The present invention relates to Masterbatch technical field, especially it is a kind of improve polyester fiber vividness and tinting strength, tinting power color masterbatch Grain.
Background technique
Currently, fibrous material has become that global evolution is most fast and one of most active science and technology field, and wherein chemical fibre is led The promotion and industrialization of domain emphasis basic material technology are to push high-performance composite materials, advanced configuration material, new function material The important measure of material, green fiber Materials.Wherein, original liquid coloring fiber is that colorant is added in spinning solution or melt (Masterbatch) obtains colored fibre through spinning, eliminates dyeing process, reduce discharge of wastewater, has outstanding environmental-friendly Feature.Currently, the yield of China's original liquid coloring fiber is about 4,500,000 tons, only account for 10% or so of experimental branch line total amount, future Growth space is huge.The target of [high-quality original liquid coloring fiber development and application] project has 3: first is that with polyester fiber, Buddhist nun Imperial fiber is attached most importance to;Second is that breaking through the key core technologies of each link of industrial chain;Third is that establishing pigment/dye, Masterbatch, fiber Integrated quality and basic color detection method and standards system, establish fiber preparation and application technical specification and database.It encloses Around this 3 targets, the preparation of high-quality original liquid coloring fibre with high-efficiency and high-level application industry technology are developed in breakthrough, promote me State's original liquid coloring fiber industry technological innovation chain integral level, improves the whole competitiveness of industry.Original liquid coloring and traditional dyeing It see the table below compared to the comparison in terms of energy consumption, cost and environmental protection:
Original liquid coloring is compared with traditional dyeing and be see the table below compared in terms of chromatography, bright-colored degree and stability of spinning process:
Conventional is deposited using original liquid coloring polyester fiber used color master-batch in terms of fiber vividness and tinting strength, tinting power In shortcoming.
Summary of the invention
In order to improve the polyester fiber vividness and tinting strength, tinting power of original liquid coloring, it is fine that invention provides a kind of raising terylene Tie up the color master-batch of vividness and tinting strength, tinting power.
In order to solve the above technical problems, the object of the present invention is achieved like this:
A kind of color master-batch improving polyester fiber vividness and tinting strength, tinting power according to the present invention, including 20-30%'s Pigment, the ethylene acrylate copolymer of 5-10%, 2-5% dispersing agent, surplus is vector resin.
As a further illustration of the above scheme, the dispersing agent is polyethylene wax, dimethicone, poly- second two The mixture of one or more of alcohol, ethene-vinyl acetate wax.
As a further illustration of the above scheme, including 25% pigment;5% ethylene acrylate copolymer, 2% Dispersing agent, surplus is vector resin.
As a further illustration of the above scheme, the vector resin is PET.
The beneficial effects of the present invention are: it is according to the present invention it is a kind of improve terylene vividness and tinting strength, tinting power color masterbatch Grain has been used containing pigment and ethylene acrylate copolymer, so that having used the vividness of the polyester fiber of the color master-batch It is improved with tinting strength, tinting power, so that the vividness of polyester fiber increases 20%, while stability of spinning process improves, and pressure is stablized, The spinning period improves 20%, and during cleaning assembly, and residual is less, and cleaning is more convenient, and cost energy consumption reduces obvious.
Specific embodiment
The present invention is further described combined with specific embodiments below.
A kind of color master-batch improving polyester fiber vividness and tinting strength, tinting power according to the present invention, including 20-30%'s Pigment;The dispersing agent of the ethylene acrylate copolymer of 5-10%, 2-5%, surplus is vector resin.Dispersing agent is polyethylene The mixture of one or more of wax, dimethicone, polyethylene glycol, ethene-vinyl acetate wax.Used pigment is outer The colorant of purchase can be the colors such as red, blue.
The color master-batch according to the present invention for improving polyester fiber vividness and tinting strength, tinting power, factory's stoste different from the past Color master-batch used in coloring production in order to increase bright-colored degree, and artificially increases pigment content concentration or searches It seeks using the more higher pigment of high coloring power, price, to meet bright-colored degree requirement in the market.It is the base in existing pigment Ethylene acrylate copolymer has been used on plinth, has improved the vividness of color, reaches addition cost more lower than common market. The low addition advantage of bring is promoted by bright-colored degree, spinning can be made more stable, the period is longer, cleans more clean. Market be can satisfy for the demand of vividness, in the market general lack of the infull phenomenon of chromatography have better supplement.
Embodiment one
A kind of color master-batch improving polyester fiber vividness and tinting strength, tinting power involved in the present embodiment, including 20% Pigment, 5% ethylene acrylate copolymer, 2% dispersing agent, surplus are vector resin.Vector resin is PET.Dispersing agent For obtained by the ratio mixing of polyethylene wax, dimethicone according to 4:1.Ethylene acrylate copolymer both ends have polar group Group, one end can be combined with terylene molecule, and the other end can be combined with pigment.The combination energy of terylene molecule and pigment can be improved Power.
Embodiment two
A kind of color master-batch improving polyester fiber vividness and tinting strength, tinting power involved in the present embodiment, including 25% Pigment, 7% ethylene acrylate copolymer, 3% dispersing agent, surplus are vector resin.Vector resin is PET.Dispersing agent For in ethene-vinyl acetate wax.
Embodiment three
A kind of color master-batch improving polyester fiber vividness and tinting strength, tinting power involved in the present embodiment, including 25% face Material, 5% ethylene acrylate copolymer, 2% dispersing agent, surplus are vector resin.Vector resin is PET.Dispersing agent is Polyethylene glycol and ethene-vinyl acetate wax are mixed according to 1:1 ratio.
Example IV
A kind of color master-batch improving polyester fiber vividness and tinting strength, tinting power involved in the present embodiment, including 30% Pigment, 10% ethylene acrylate copolymer, 5% dispersing agent, surplus are vector resin.Vector resin is PET.Dispersing agent It is mixed for polyethylene wax, polyethylene glycol, three kinds of ethene-vinyl acetate wax according to 1:1:1 ratio.
The preferred embodiment of the present invention has been described in detail above.It should be appreciated that those skilled in the art without It needs creative work according to the present invention can conceive and makes many modifications and variations.Therefore, all technologies in the art Personnel are available by logical analysis, reasoning, or a limited experiment on the basis of existing technology under this invention's idea Technical solution, all should be within the scope of protection determined by the claims.

Claims (4)

1. a kind of color master-batch for improving polyester fiber vividness and tinting strength, tinting power, which is characterized in that the pigment including 20-30%;5- The dispersing agent of 10% ethylene acrylate copolymer, 2-5%, surplus is vector resin.
2. improving the color master-batch of polyester fiber vividness and tinting strength, tinting power as described in claim 1, which is characterized in that described Dispersing agent is the mixture of one or more of polyethylene wax, dimethicone, polyethylene glycol, ethene-vinyl acetate wax.
3. improving the color master-batch of polyester fiber vividness and tinting strength, tinting power as described in claim 1, which is characterized in that including 25% pigment, 5% ethylene acrylate copolymer, 2% dispersing agent, surplus are vector resin.
4. the color master-batch as described in any one of claims 1 to 3 for improving polyester fiber vividness and tinting strength, tinting power, feature exist In the vector resin is PET.
CN201810800491.6A 2018-07-20 2018-07-20 Coloring master batch for improving brilliance and tinting strength of polyester fiber Active CN109054310B (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU2022202903A1 (en) * 2021-12-24 2023-07-13 Taya Canvas (Shanghai) Company Ltd Fabric and manufacturing method thereof

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS638458A (en) * 1986-06-27 1988-01-14 Sumitomo Chem Co Ltd Coloring resin composition
CN1157015A (en) * 1994-06-07 1997-08-13 莱昂德尔石油化学公司 Dyeable polyolefin compositions and method
CN1486338A (en) * 2001-01-16 2004-03-31 �Ϻ���ͨ��ѧ Color concentrates for polyesters
CN103254576A (en) * 2012-02-21 2013-08-21 上海杰事杰新材料(集团)股份有限公司 Modifying master batch used in fiber-reinforced PET engineering plastic, and preparation method thereof
CN103709662A (en) * 2012-09-29 2014-04-09 青岛欣展塑胶有限公司 High-concentration white master batch for polyester, and preparation method thereof
CN106084674A (en) * 2016-06-01 2016-11-09 广东强大新材料科技有限公司 A kind of plastic cement filler parent granule and preparation method thereof
CN106827287A (en) * 2017-02-24 2017-06-13 浙江恒烨新材料科技有限公司 A kind of Masterbatch production technology

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS638458A (en) * 1986-06-27 1988-01-14 Sumitomo Chem Co Ltd Coloring resin composition
CN1157015A (en) * 1994-06-07 1997-08-13 莱昂德尔石油化学公司 Dyeable polyolefin compositions and method
CN1486338A (en) * 2001-01-16 2004-03-31 �Ϻ���ͨ��ѧ Color concentrates for polyesters
CN103254576A (en) * 2012-02-21 2013-08-21 上海杰事杰新材料(集团)股份有限公司 Modifying master batch used in fiber-reinforced PET engineering plastic, and preparation method thereof
CN103709662A (en) * 2012-09-29 2014-04-09 青岛欣展塑胶有限公司 High-concentration white master batch for polyester, and preparation method thereof
CN106084674A (en) * 2016-06-01 2016-11-09 广东强大新材料科技有限公司 A kind of plastic cement filler parent granule and preparation method thereof
CN106827287A (en) * 2017-02-24 2017-06-13 浙江恒烨新材料科技有限公司 A kind of Masterbatch production technology

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
PET纤维着色技术的探讨: "郭群等", 《聚酯工业》 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU2022202903A1 (en) * 2021-12-24 2023-07-13 Taya Canvas (Shanghai) Company Ltd Fabric and manufacturing method thereof

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Address after: 515000 Xiashan Yanglin Chengmei road section, Chaonan District, Shantou City, Guangdong Province

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Applicant before: ZHEJIANG INFINITECOLOR TECHNOLOGY Co.,Ltd.

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