CN109053084A - A method of coal mine paste filling material is prepared using scrap glass - Google Patents

A method of coal mine paste filling material is prepared using scrap glass Download PDF

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Publication number
CN109053084A
CN109053084A CN201811134314.5A CN201811134314A CN109053084A CN 109053084 A CN109053084 A CN 109053084A CN 201811134314 A CN201811134314 A CN 201811134314A CN 109053084 A CN109053084 A CN 109053084A
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China
Prior art keywords
scrap glass
coal mine
gangue
aggregate
filling material
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CN201811134314.5A
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Chinese (zh)
Inventor
郭育霞
张树峰
戚庭野
杜献杰
李化运
李庆东
王鹏
冉洪宇
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Taiyuan University of Technology
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Taiyuan University of Technology
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Priority to CN201811134314.5A priority Critical patent/CN109053084A/en
Publication of CN109053084A publication Critical patent/CN109053084A/en
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/04Portland cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00724Uses not provided for elsewhere in C04B2111/00 in mining operations, e.g. for backfilling; in making tunnels or galleries
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/70Grouts, e.g. injection mixtures for cables for prestressed concrete

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Processing Of Solid Wastes (AREA)

Abstract

The invention belongs to coal mine filling production technique fields, more particularly to a kind of method for preparing coal mine paste filling material using scrap glass, including scrap glass 10%~20%, gangue 40%~50%, flyash 10%~20%, cement 10%~20%, water 12%~25% finally obtain the coal mine paste filling material that mass concentration is 75%~88%.The invention enables scrap glasses to have obtained sufficient recycling, solves the pollution to environment, the source of filler has been widened simultaneously, reduce filling cost, it lays a good foundation for implementing in full for filling mining technology, scrap glass mixing aggregate can control the further development of coal mine filling lotion crackle, to improve crack resistance.

Description

A method of coal mine paste filling material is prepared using scrap glass
Technical field
The invention belongs to coal mine filling production technique fields, prepare coal mine lotion more particularly to a kind of utilization scrap glass and fill The method of filling chock material.
Background technique
China is main using coal as one of country of non-renewable energy, the basic energy of coal conduct few in number in the world Very important effect is played to the national economic development and progress of human society.But coal mining is caused by ecological environment simultaneously Harm is also growing day by day, and main includes breaking for surface subsidence caused by mining, waste-water from coal mine, gangue and mining area ecological environment Bad, wherein influence of the surface subsidence to environment is particularly acute.Surface subsidence is primarily due to coal mine gob not by closing Caused by the improvement of reason.Cut-and-fill Mining Technology be using with some strength and cheap material filling goaf, both can be with Surface subsidence caused by control is mined, and energy sufficiently back production coal resources, realize resource and environment, safety, Development of Economy Target.
So-called paste body filling is exactly that the gangue of coal tailing hillock, inferior soil and the tailing of power plant flyash etc. is solid The paste slurry that body waste is processed on ground is pumped using high density solid filling and is arrived coal mine filling ointment pumping by pipeline Underground goaf prevents the mining methods of subsidence to support overlying rock.It mainly by mining overburden control theory, Filling system and filler three parts composition, wherein filler is the basis of paste body filling.With filling mining promote with Using filling available raw material such as gangue, tailings etc. and gradually decrease, filling cost also gradually increases therewith, paste body filling The problem of the material deficiency faced becomes increasingly conspicuous.Find filler that is at low cost, meeting fill paste conveying and intensity requirement It is filling mining urgent problem.
With the development of economy with the raising of living standards of the people, garbage problem becomes increasingly conspicuous.668, China city, 2 ∕ 3 It is surrounded by rubbish band.Scrap glass is one kind of house refuse, it not only brought inconvenience to people's production and life, but also to ring Border causes pollution, while also occupying valuable land resource, increases carrying capacity of environment.According to statistics, China generates every year About 4,500,000 ~ 7,500,000 tons of scrap glass, account for 3% ~ 5% or so of domestic waste total amount.How effectively a large amount of scrap glasses It recycles, is a problem to be solved.
In conclusion paste body filling faces the problems such as material is insufficient, at high cost, filling mining technology is made to be difficult to comprehensive reality It applies.And scrap glass recovery utilization rate is low, large area accumulation, causes environmental pollution, if scrap glass preparation can be made full use of full The filler that sufficient coal mine requires, makes scrap glass turn waste into wealth, is a kind of effective method.
Summary of the invention
In view of the above-mentioned problems, the present invention provides a kind of method for preparing coal mine paste filling material using scrap glass, For recycling scrap glass completely, resource is on the one hand saved, environmental pollution is reduced, has been on the other hand coal mine filling Exploitation provides cheap raw material, and the performance of filler is improved while reducing filling cost, is filling technique It implements in full and lays a good foundation.
The present invention is achieved through the following technical solutions: a kind of to prepare coal mine paste filling material using scrap glass Method includes the following steps:
S1. it collects and scrap glass and is crushed, obtaining scrap glass micro mist that partial size is 0~1mm and partial size is 1~5mm's Scrap glass fine aggregate, wherein the two respectively accounts for 50% according to weight ratio and mixed and be sufficiently stirred to obtain scrap glass mixing bone Expect spare;
S2. it collects gangue and is crushed, so that the grain diameter of gangue is no more than 15mm after broken, further to gained Coal gangue particle is sieved, respectively obtain partial size be 0~5mm fine aggregate, partial size be 5~10mm middle aggregate and partial size be The coarse aggregate of 10~15mm;It according to the weight proportion of three is respectively 30%, 35% and 35% by fine aggregate, middle aggregate and coarse aggregate It is stirred to obtain spare after gangue mixture;
S3. it is spare to collect flyash;
S4. take cement with scrap glass mixing aggregate made from above-mentioned steps, gangue mixture, flyash according to certain ratio Water is added after being mixed in example, and further stirs evenly, and finally obtains coal mine paste filling material, wherein coal shared by each component The weight proportion of mine paste filling material are as follows:
Scrap glass 10%~20%
Gangue 40%~50%
Flyash 10%~20%
Cement 10%~20%
Water 12%~25%
The mass concentration of coal mine paste filling material is 75%~88%.
The cement is the ordinary portland cement of label 425.
The jaw crusher that gangue uses is crushed, by broken gangue using vibrating screen progress fine aggregate, The screening of middle aggregate and coarse aggregate, the vibrating screen that wherein screening of fine aggregate is 5mm using mesh diameter, the screening benefit of middle aggregate The vibrating screen for being 10mm with mesh diameter, the vibrating screen that the screening of coarse aggregate is 15mm using mesh diameter, partial size are greater than 15mm Aggregate be put into crusher carry out again be crushed after give over to it is spare.
The novel specified features having of the present invention and beneficial effect are:
The present invention realizes the technology that coal mine paste filling material is prepared using scrap glass, has obtained scrap glass adequately It recycles, solves the pollution to environment, while having widened the source of filler, reduce filling cost, opened for filling Implementing in full for technology is adopted to lay a good foundation;Scrap glass mixing aggregate can control the further hair of coal mine filling lotion crackle Exhibition, to improve crack resistance, simultaneously because the tensile strength of glass is big, elongation percentage is big, make coal mine paste filling material tension, Bending resistance, impact strength and elongation percentage and toughness are improved, and are effectively improved mobility, the elasticity of coal mine paste filling material Modulus, Poisson's ratio and intensity.
Specific embodiment
Come that the present invention will be described in detail below by example, novelty and creativeness possessed by the present invention include but It is not limited to following embodiment.
Embodiment 1:
It collects 30kg scrap glass simultaneously to be crushed, obtaining scrap glass micro mist that partial size is 0~1mm and partial size is 1~5mm's Scrap glass fine aggregate, wherein the two respectively accounts for 50% according to weight ratio and mixed and be sufficiently stirred to obtain scrap glass mixing bone Expect spare;
The gangue for collecting 100kg Strategy of Shanxi Coking Coal Group Xishan coal electricity Du's youngster level ground coal mine, with PE-150 × 250 model jaw crusher It is crushed, so that broken grain diameter is mainly distributed on 15mm hereinafter, broken gangue is used mesh 5 respectively The vibrating screen of mm, 10mm and 15mm screens, the middle aggregate that fine aggregate, partial size that partial size is 0~5mm are 5~10mm is obtained respectively The coarse aggregate for being 10~15mm with partial size, and the coarse aggregate that will be greater than 15mm is put back to crusher and is crushed again;
Take 18Kg marked as 425 ordinary portland cement and 12Kg scrap glass mixing aggregate obtained above, 48Kg bastard coal Stone mixture (aggregate, 16.8Kg gangue coarse aggregate in 14.4Kg gangue fine aggregate, 16.8Kg gangue) and flyash 30Kg water is added after 12Kg stirring, uniformly mixing is to get the coal mine paste filling material for being 75% to concentration.Following table is dense to obtain The test bit for the coal mine paste filling material that degree is 75%:
Embodiment 2:
It collects 30Kg scrap glass simultaneously to be crushed, obtaining scrap glass micro mist that partial size is 0~1mm and partial size is 1~5mm's Scrap glass fine aggregate, wherein the two respectively accounts for 50% according to weight ratio and mixed and be sufficiently stirred to obtain scrap glass mixing bone Expect spare;
The gangue for collecting the new positive coal mine of the Fenxi 100kg group, is crushed with PE-150 × 250 model jaw crusher, is made brokenly Grain diameter after broken is mainly distributed on 15mm hereinafter, with mesh being respectively 5mm, 10mm and 15mm by broken gangue Vibrating screen screening, obtain middle aggregate that fine aggregate, partial size that partial size is 0~5mm are 5~10mm respectively and partial size be 10~ The coarse aggregate of 15mm, and the coarse aggregate that will be greater than 15mm is put back to crusher and is crushed again;
Take 18Kg marked as 425 ordinary portland cement and 15.6kg scrap glass mixing aggregate obtained above, 50.4Kg Gangue mixture (aggregate, 17.64Kg gangue coarse aggregate in 15.12Kg gangue fine aggregate, 17.64Kg gangue) and powder 24Kg water is added after coal ash 12Kg stirring, uniformly mixing is to get the coal mine paste filling material for being 80% to concentration.Following table be To concentration be 80% coal mine paste filling material test bit:
Embodiment 3:
It collects 30Kg scrap glass simultaneously to be crushed, obtaining scrap glass micro mist that partial size is 0~1mm and partial size is 1~5mm's Scrap glass fine aggregate, wherein the two respectively accounts for 50% according to weight ratio and mixed and be sufficiently stirred to obtain scrap glass mixing bone Expect spare;
The gangue for collecting 100kg area of Tong coal corporation in Shanxi group Tashan Mountain coal mine, is crushed with PE-150 × 250 model jaw crusher, So that broken grain diameter is mainly distributed on 15mm hereinafter, by broken gangue respectively with mesh 5mm, 10mm and The vibrating screen of 15mm screens, middle aggregate that fine aggregate, partial size that partial size is 0~5mm are 5~10mm is obtained respectively and partial size is The coarse aggregate of 10~15mm, and the coarse aggregate that will be greater than 15mm is put back to crusher and is crushed again;
Take 18Kg marked as 425 ordinary portland cement and 20.4kg scrap glass mixing aggregate obtained above, 51.6Kg Gangue mixture (aggregate, 18.06Kg gangue coarse aggregate in 15.48Kg gangue fine aggregate, 18.06Kg gangue) and powder 18Kg water is added after coal ash 12Kg stirring, uniformly mixing is to get the coal mine paste filling material for being 85% to concentration.Following table be To concentration be 85% coal mine paste filling material test bit:
Embodiment 4:
It collects 30Kg scrap glass simultaneously to be crushed, obtaining scrap glass micro mist that partial size is 0~1mm and partial size is 1~5mm's Scrap glass fine aggregate, wherein the two respectively accounts for 50% according to weight ratio and mixed and be sufficiently stirred to obtain scrap glass mixing bone Expect spare;
The gangue for collecting 100kg area of Tong coal corporation in Shanxi group Tashan Mountain coal mine, is crushed with PE-150 × 250 model jaw crusher, So that broken grain diameter is mainly distributed on 15mm hereinafter, by broken gangue respectively with mesh 5mm, 10mm and The vibrating screen of 15mm screens, middle aggregate that fine aggregate, partial size that partial size is 0~5mm are 5~10mm is obtained respectively and partial size is The coarse aggregate of 10~15mm, and the coarse aggregate that will be greater than 15mm is put back to crusher and is crushed again;
Take 18Kg marked as 425 ordinary portland cement and 24kg scrap glass mixing aggregate obtained above, 51.6Kg coal Spoil mixture (aggregate, 18.06Kg gangue coarse aggregate in 15.48Kg gangue fine aggregate, 18.06Kg gangue) and fine coal 14.4Kg water is added after grey 12Kg stirring, uniformly mixing is to get the coal mine paste filling material for being 88% to concentration.Following table be To concentration be 88% coal mine paste filling material test bit:

Claims (3)

1. a kind of method for preparing coal mine paste filling material using scrap glass, which comprises the steps of:
S1. it collects and scrap glass and is crushed, obtaining scrap glass micro mist that partial size is 0~1mm and partial size is 1~5mm's Scrap glass fine aggregate, wherein the two respectively accounts for 50% according to weight ratio and mixed and be sufficiently stirred to obtain scrap glass mixing bone Expect spare;
S2. it collects gangue and is crushed, so that the grain diameter of gangue is no more than 15mm after broken, further to gained Coal gangue particle is sieved, respectively obtain partial size be 0~5mm fine aggregate, partial size be 5~10mm middle aggregate and partial size be The coarse aggregate of 10~15mm;It according to the weight proportion of three is respectively 30%, 35% and 35% by fine aggregate, middle aggregate and coarse aggregate It is stirred to obtain spare after gangue mixture;
S3. it is spare to collect flyash;
S4. cement and scrap glass mixing aggregate, gangue mixture, flyash made from above-mentioned steps are taken according to a certain percentage Water is added after mixing, and further stirs evenly, finally obtains coal mine paste filling material, wherein coal mine shared by each component The weight proportion of paste filling material are as follows:
Scrap glass 10%~20%
Gangue 40%~50%
Flyash 10%~20%
Cement 10%~20%
Water 12%~25%
The mass concentration of coal mine paste filling material is 75%~88%.
2. a kind of method for preparing coal mine paste filling material using scrap glass according to claim 1, feature exist In: the cement is the ordinary portland cement of label 425.
3. a kind of method for preparing coal mine paste filling material using scrap glass according to claim 1 or 2, feature Be: the jaw crusher that gangue uses is crushed, and carries out fine aggregate, middle bone using vibrating screen by broken gangue The screening of the screening of material and coarse aggregate, the vibrating screen that wherein screening of fine aggregate is 5mm using mesh diameter, middle aggregate utilizes net The vibrating screen that eye diameter is 10mm, the vibrating screen that the screening of coarse aggregate is 15mm using mesh diameter, partial size are greater than the bone of 15mm Material be put into crusher carry out again be crushed after give over to it is spare.
CN201811134314.5A 2018-09-27 2018-09-27 A method of coal mine paste filling material is prepared using scrap glass Pending CN109053084A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110342891A (en) * 2019-08-01 2019-10-18 西安科技大学 A kind of spoil paste filling material and preparation method thereof for coal mining
CN110671147A (en) * 2019-10-31 2020-01-10 河南理工大学 Construction system and construction process for filling goafs of different scales by using waste concrete
CN114751695A (en) * 2022-04-13 2022-07-15 山东高速集团有限公司创新研究院 Cement stabilized macadam based on waste glass cullet fine aggregate and preparation process thereof

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CN107285702A (en) * 2017-07-28 2017-10-24 固岩科技发展有限公司 A kind of filling slurry of colliery doping discarded concrete aggregate

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Publication number Priority date Publication date Assignee Title
CN101845966A (en) * 2009-12-29 2010-09-29 中国恩菲工程技术有限公司 Process for filling coal mine goaf
US20130098272A1 (en) * 2011-10-20 2013-04-25 Flyanic, Llc Method and compositions for pozzolanic binders derived from non-ferrous smelter slags
CN103570302A (en) * 2013-11-15 2014-02-12 北京新奥混凝土集团有限公司 Concrete doped with waste glass
CN104355579A (en) * 2014-11-10 2015-02-18 汪洋 Method for preparing concrete from abandoned glass and glass particle screening machine used in same
CN107285702A (en) * 2017-07-28 2017-10-24 固岩科技发展有限公司 A kind of filling slurry of colliery doping discarded concrete aggregate

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110342891A (en) * 2019-08-01 2019-10-18 西安科技大学 A kind of spoil paste filling material and preparation method thereof for coal mining
CN110671147A (en) * 2019-10-31 2020-01-10 河南理工大学 Construction system and construction process for filling goafs of different scales by using waste concrete
CN110671147B (en) * 2019-10-31 2024-02-27 河南理工大学 Construction system and construction process for filling goafs of different scales by utilizing waste concrete
CN114751695A (en) * 2022-04-13 2022-07-15 山东高速集团有限公司创新研究院 Cement stabilized macadam based on waste glass cullet fine aggregate and preparation process thereof

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Application publication date: 20181221

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