CN109052983A - A kind of production method of imitation wood line, marble glass brick - Google Patents

A kind of production method of imitation wood line, marble glass brick Download PDF

Info

Publication number
CN109052983A
CN109052983A CN201811173513.7A CN201811173513A CN109052983A CN 109052983 A CN109052983 A CN 109052983A CN 201811173513 A CN201811173513 A CN 201811173513A CN 109052983 A CN109052983 A CN 109052983A
Authority
CN
China
Prior art keywords
glass
brick
coating
production method
imitation wood
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201811173513.7A
Other languages
Chinese (zh)
Inventor
程忠付
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
DUYUN DEVELOPMENT ZONE FUTIAN CHEMICAL Co Ltd
Original Assignee
DUYUN DEVELOPMENT ZONE FUTIAN CHEMICAL Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by DUYUN DEVELOPMENT ZONE FUTIAN CHEMICAL Co Ltd filed Critical DUYUN DEVELOPMENT ZONE FUTIAN CHEMICAL Co Ltd
Priority to CN201811173513.7A priority Critical patent/CN109052983A/en
Publication of CN109052983A publication Critical patent/CN109052983A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/006Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B27/00Tempering or quenching glass products
    • C03B27/04Tempering or quenching glass products using gas
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/28Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material
    • C03C17/30Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material with silicon-containing compounds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Thermal Sciences (AREA)
  • Composite Materials (AREA)
  • Physics & Mathematics (AREA)
  • Printing Methods (AREA)
  • Decoration By Transfer Pictures (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)

Abstract

The invention belongs to ornament materials preparation technical field, the production method of especially a kind of imitation wood line, marble glass brick specifically includes following procedure: (1) pretreatment of glass, the preparation of (2) glass coating;(3) glass coating;(4) preparation of heat transfer;(5) thermal transfer;(6) stopping off paints.The present invention is handled glass using ultrasonic wave during glass coating, the absorption property of glass surface can be improved, the surface of glass block is set preferably to bond with figure layer, to make glass block surface more closely be combined with heat transfer, sublimable ink on heat-transferring printing paper can preferably be adsorbed on glass block surface, be beneficial to improve the three-dimensional sense of image;The back side that heat transfer is smeared using the hydrophobic coating being mixed by organic siliconresin and acetone can prevent image color caused by sublimable ink is reversely spread during thermal transfer light since hydrophobic coating has heat resistance, hydrophobicity, increases oiliness.

Description

A kind of production method of imitation wood line, marble glass brick
Technical field
The invention belongs to ornament materials preparation technical field, especially a kind of production of imitation wood line, marble glass brick Method.
Background technique
Glass block is the bulk being pressed into transparent or coloured glass material or hollow box-like, the biggish glassware of body, Have many advantages, such as daylighting, high intensity, antistatic, environmental protection, corrosion-resistant, acid and alkali-resistance, be not afraid of water logging knife cut, it is easy to clean health, it is wide It is general to be used for ornament materials.Currently, glass block in the market is broadly divided into two kinds: sand is cut glass brick, stained glass bricks, and work is produced Skill is all first to stick at dedicated gummed paper on glass block face, profile is carved out further according to patterning requirement, then according to actual production need It asks, figure needed for being sprayed with dry powder sand-blasting machine finally uses color spray rifle paint color on the pattern of glass block.This production work The glass block that skill obtains there are dim pattern, it is out of shape, opaque, three-dimensional sense is bad the disadvantages of, and automation degree is low, labour is strong Degree is big, production efficiency is low.
In order to solve problem above, relevant report proposes a kind of caloric transfer printing technology, it is first that design is good, then make Ink is uniformly coated to form pattern on thermal transfer film by the targeted graphical with coating machine according to setting, then passes through thermal transfer Machinery is transferred to pattern on glass.File if number of patent application is CN201110410452.3 discloses a kind of hollow glass Brick thermal transfer coating and caloric transfer printing technology, manufacture craft include: to carry out high-light transparent coating and white on hollow glass surface The coating of coating utilizes aluminium foil bag, silicon with heat sublimation ink in paper substrates or polymeric membrane substrate or press figure image Adhesive tape vacuumize encapsulation need the hollow glass block of thermal transfer in conjunction with print or printed substrate with heated baking equipment come Carry out the transfer of image;By to hollow brick glass carry out high adhesion, good weatherability, low energy consumption thermal transfer coating painting Dress, then with the technology mode of thermal transfer by full-color digital image transfer to hollow glass block, it can be by the pattern on transfer paper It improves and is transferred on glass block;But during thermal transfer, the ink of pattern is by natural sublimation transfer to hollow glass On brick, it cannot be fully adsorbed on glass surface, three-dimensional sense is poor, and is easy to happen colour fading.
Summary of the invention
In order to solve the above technical problems existing in the prior art, the present invention provides a kind of imitation wood lines, marble grain The manufacturing method of brick is realized particular by following technical scheme:
A kind of production method of imitation wood line, marble grain brick, specifically includes the following steps:
(1) pretreatment of glass: taking glass, is cut, edging, cleaning, drying, obtains plate glass brick;It will put down again Glass sheet brick carries out tempering and obtains tempered glass brick;
(2) glass coating is prepared: transparent glass priming paint, curing agent, diluent being mixed and made into clear dope, by white glass Glass priming paint, curing agent, diluent are mixed and made into white coating;
(3) glass coating: transparent on silk-screen after the resulting tempered glass brick ultrasonication 10-15min of step (1) Coating, it is dry, form clear coat;Then dry in clear coat surface silk-screen white coating, form white coating;
(4) preparation of heat transfer: design wood grain, marble grain image, with heat sublimation ink by image printing or printing One layer of hydrophobic coating is coated onto paper substrate, then at the back side of paper substrate, 10-15min is stood, obtains heat transfer;
(5) thermal transfer: turning heat figure and be closely attached on the white coating of tempered glass brick, after keeping smooth with heatproof without Trace adhesive tape fixes glass and thermal transfer drawing;Then start thermal transfer furnace, according to the thickness of glass block set thermal transfer temperature, After the thermal transfer time, glass block is placed on siege, furnace center is sent into and starts hot pressing;
(6) stopping off: protection is coated at normal temperature after examining product qualified to glass, cooling is taken out to hot pressing time Layer paint is to get imitation wood line, marble glass brick.
Preferably, the tempering of the plate glass brick is that plate glass brick is placed in heating furnace to be heated to 650 DEG C or so, Then glass is taken out, then high pressure cold air is blowed to the two sides of glass with bull nozzle, be cooled to it rapidly and uniformly Room temperature.
Preferably, the step (3), the frequency of ultrasonic wave are 80-100kHz.
Preferably, the step (2), the transparent glass priming paint is epoxy gloss oil, white glass priming paint is ring Oxygen paint, curing agent are paint curing agent, diluent is dilution slow curing water.
Preferably, the clear dope is mixed by transparent glass paint, curing agent, diluent by the mass ratio of 2:1:1.2 It is made.Transparent glass paint, curing agent, diluent three proportion are improper, will lead to that adsorption capacity of the pattern on glass be strong, hardness It is not high with finish.The present invention by related experiment find, transparent glass paint, curing agent, diluent ratio be 2:1:1.2 For optimal selection.
Preferably, the white coating is mixed by white glass paint, curing agent, diluent by the mass ratio of 3:1:1.3 It is made.White glass paint, curing agent, diluent three proportion are improper, will lead to that coloring effect of the pattern on glass be poor, figure line Unintelligible distinct, lines are not fine, three-dimensional sense is not strong etc..The present invention by related experiment find, white glass paint, curing agent, The ratio of diluent is that 3:1:1.3 is optimal selection.
Preferably, the step (4), the hydrophobic coating are to form organic siliconresin and acetone high-speed stirred, Wherein the mass ratio of organic siliconresin and acetone is 1:5-6.
Preferably, the step (5), glass block with a thickness of 5-15mm, thermal transfer temperature is 155-240 DEG C, and heat turns The print time is 220-960s, pressure 0.3-0.8Mpa.The present invention is found through experiments that the thickness of glass is different, and heat turns temperature Degree, print time, pressure are also different, 155-240 DEG C of the architectural grade glass required temperature of general 5-15mm thickness, hot pressing time 220-960s, pressure 0.3-0.8Mpa.
Preferably, protective layer paint is common neutral paint.
Preferably, the imitation wood line, marble glass brick can use decorative floor tiles and wall brick.
The beneficial effects of the present invention are: tempering processing is carried out to glass block, its intensity can not only be enhanced, moreover it is possible to eliminate it The defect on surface makes its surface have better absorption property;The glass block of tempering is ultrasonically treated, can be further improved The absorption property on its surface;Therefore, after by tempering, ultrasonic treatment, glass block can preferably be glued with clear coat, white coating It closes, and then glass block and heat-transferring printing paper are closer in combination, the sublimable ink on heat-transferring printing paper can preferably be adsorbed on glass block Surface is beneficial to improve the three-dimensional sense of image.The hydrophobic coating that organic siliconresin and acetone are mixed has heat resistance, hates Aqueous, increasing oiliness, the back side of heat transfer is smeared using it, can prevent sublimable ink during thermal transfer from reversely spreading and causing Image color it is light.During thermal transfer, thermal transfer time, temperature are arranged according to the thickness of glass block, glass has been taken into account and has added The uniformity and the validity of time of heat, it is ensured that the coloring effect of thermal transfer glass.Imitation wood line, the marble grain that the present invention makes Glass ceramic tile, figure line is clear, the lines flow smoothly finely, three-dimensional sense is strong, and texture is felt rich in sense of movement and variation, and anti-oxidant effect Fruit, not fugitive color.
Detailed description of the invention
Fig. 1 is the structure of glass block, and 1 is glass, and 2 be clear coat, and 3 be white figure layer, and 4 be wood grain, marble grain, 5 For protective layer.
Fig. 2 is imitation wood line glass brick product prepared by the present invention.
Fig. 3 is marbling glass brick product prepared by the present invention.
Specific embodiment
It is limited below with reference to specific embodiment technical solution of the present invention is further, but claimed Range is not only limited to made description.
1 glass coating of embodiment
Clear dope, white coating are prepared by the weight of table 1.
Table 1
2 imitation wood line glass block of embodiment
Production method:
(1) pretreatment of glass: taking glass, is cut, edging, cleaning, drying, obtains plate glass brick;It will put down again Glass sheet brick is placed in heating furnace and is heated to 650 DEG C or so, then takes out glass, then is blowed to high pressure cold air with bull nozzle The two sides of glass, is cooled to room temperature it rapidly and uniformly, obtains with a thickness of the tempered glass brick of 5,8,10,12,15mm;
(2) glass coating: after the resulting tempered glass brick ultrasonication 10min of step (1), silk-screen embodiment 1 is made Standby clear dope, it is dry, form clear coat;Then the white coating prepared in clear coat surface silk-screen embodiment 1 is done It is dry, form white coating;Wherein, the frequency of ultrasonic wave is 100kHz
(3) preparation of heat transfer: design wood grain image by image printing or prints to paper substrate with heat sublimation ink On, then at the back side of paper substrate coat one layer of hydrophobic coating, 10min is stood, heat transfer is obtained;Wherein the hydrophobic applies Material is formed by 100g organic siliconresin, 500g acetone high-speed stirred;
(4) thermal transfer: turning heat figure and be closely attached on the white coating of tempered glass brick, after keeping smooth with heatproof without Trace adhesive tape fixes glass and thermal transfer drawing;Then start thermal transfer furnace, according to the thickness of glass block set thermal transfer temperature, It is specific that glass block is placed on siege as shown in table 2 after the thermal transfer time, it is sent into the pressure of furnace center 0.3-0.8MPa Power hot pressing;
(5) it stopping off: is coated at normal temperature after examining product qualified common to hot pressing time to glass, cooling is taken out Neutrality paint is to get imitation wood line glass block.
2 thermal transfer temperature of table, hot pressing time table
Thickness of glass (mm) Thermal transfer temperature (DEG C) Hot pressing time (s)
5 155~165 220~280
8 165~180 300~350
10 170~185 430~520
12 175~190 480~600
15 180~240 630~960
3 marbling glass block of embodiment
Production method:
(1) pretreatment of glass: taking glass, is cut, edging, cleaning, drying, is obtained with a thickness of plate glass brick; Plate glass brick is placed in heating furnace again and is heated to 650 DEG C or so, then takes out glass, then with bull nozzle by the cold sky of high pressure Air-blowing is cooled to room temperature it rapidly and uniformly to the two sides of glass, obtains the tempered glass brick of 5,8,10,12,15mm;
(2) glass coating: after the resulting tempered glass brick ultrasonication 15min of step (1), silk-screen embodiment 1 is made Standby clear dope, it is dry, form clear coat;Then the white coating prepared in clear coat surface silk-screen embodiment 1 is done It is dry, form white coating;Wherein, the frequency of ultrasonic wave is 80kHz;
(3) preparation of heat transfer: design wood grain image by image printing or prints to paper substrate with heat sublimation ink On, then at the back side of paper substrate coat one layer of hydrophobic coating, 15min is stood, heat transfer is obtained;Wherein the hydrophobic applies Material is formed by 100g organic siliconresin, 600g acetone high-speed stirred;
(4) thermal transfer: turning heat figure and be closely attached on the white coating of tempered glass brick, after keeping smooth with heatproof without Trace adhesive tape fixes glass and thermal transfer drawing;Then start thermal transfer furnace, according to the thickness of glass block set thermal transfer temperature, It is specific that glass block is placed on siege as shown in table 2 after the thermal transfer time, it is sent into the pressure of furnace center 0.3-0.8MPa Power hot pressing;
(5) it stopping off: is coated at normal temperature after examining product qualified common to hot pressing time to glass, cooling is taken out The glass block that neutrality is painted to get marbling.
It is important to point out that, above embodiments and test example are only limitted to do further technical solution of the present invention herein Elaboration and understanding, should not be understood as it is further to technical solution of the present invention limited, what those skilled in the art made The innovation and creation of non-protruding essential characteristics and marked improvement still fall within protection category of the invention.

Claims (10)

1. the production method of a kind of imitation wood line, marble grain brick, specifically includes the following steps:
(1) pretreatment of glass: taking glass, is cut, edging, cleaning, drying, obtains plate glass brick;Again by plate glass Glass brick carries out tempering and obtains tempered glass brick;
(2) glass coating is prepared: transparent glass priming paint, curing agent, diluent being mixed and made into clear dope, by white glass bottom Paint, curing agent, diluent are mixed and made into white coating;
(3) glass coating: after the resulting tempered glass brick ultrasonication 10-15min of step (1), clear dope on silk-screen, It is dry, form clear coat;Then dry in clear coat surface silk-screen white coating, form white coating;
(4) preparation of heat transfer: design wood grain, marble grain image by image printing or print to paper with heat sublimation ink It on substrate processed, then at the back side of paper substrate coats one layer of hydrophobic coating, stands 10-15min, obtain heat transfer;
(5) thermal transfer: turning figure for heat and be closely attached on the white coating of tempered glass brick, uses the seamless glue of heatproof after keeping smooth Band fixes glass and thermal transfer drawing;Then start thermal transfer furnace, thermal transfer temperature is set according to the thickness of glass block, heat turns After printing the time, glass block is placed on siege, furnace center is sent into and starts hot pressing;
(6) stopping off paints: coating protection at normal temperature after examining product qualified to glass, cooling is taken out to hot pressing time Layer paint is to get imitation wood line, marble glass brick.
2. the production method of imitation wood line as described in claim 1, marble grain brick, which is characterized in that the plate glass The tempering of brick is that plate glass brick is placed in heating furnace to be heated to 650 DEG C or so, then takes out glass, then will with bull nozzle High pressure cold air blows to the two sides of glass, is cooled to room temperature it rapidly and uniformly.
3. the production method of imitation wood line as described in claim 1, marble grain brick, which is characterized in that the step (3), The frequency of ultrasonic wave is 80-100kHz.
4. the production method of imitation wood line as described in claim 1, marble grain brick, which is characterized in that the step (2), The transparent glass priming paint is epoxy gloss oil, white glass priming paint is epoxy paint, curing agent is paint curing agent, dilute Agent is released as dilution slow curing water.
5. the production method of imitation wood line as described in claim 1, marble grain brick, which is characterized in that the clear dope It is mixed by transparent glass paint, curing agent, diluent by the mass ratio of 2:1:1.2.
6. the production method of imitation wood line as described in claim 1, marble grain brick, which is characterized in that the white coating It is mixed by white glass paint, curing agent, diluent by the mass ratio of 3:1:1.3.
7. the production method of imitation wood line as described in claim 1, marble grain brick, which is characterized in that the step (4), The hydrophobic coating is to form organic siliconresin and acetone high-speed stirred, and wherein the mass ratio of organic siliconresin and acetone is 1:5-6。
8. the production method of imitation wood line as described in claim 1, marble grain brick, which is characterized in that the step (5), Glass block with a thickness of 5-15mm, thermal transfer temperature is 155-240 DEG C, and the thermal transfer time is 220-960s, pressure 0.3- 0.8MPa。
9. the production method of imitation wood line as described in claim 1, marble grain brick, which is characterized in that the protective layer oil Paint is common neutral paint.
10. the production method of imitation wood line as described in claim 1, marble grain brick, which is characterized in that the imitation wood line, Marble glass brick can be used for decorative floor tiles and wall brick.
CN201811173513.7A 2018-10-09 2018-10-09 A kind of production method of imitation wood line, marble glass brick Pending CN109052983A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201811173513.7A CN109052983A (en) 2018-10-09 2018-10-09 A kind of production method of imitation wood line, marble glass brick

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201811173513.7A CN109052983A (en) 2018-10-09 2018-10-09 A kind of production method of imitation wood line, marble glass brick

Publications (1)

Publication Number Publication Date
CN109052983A true CN109052983A (en) 2018-12-21

Family

ID=64764509

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201811173513.7A Pending CN109052983A (en) 2018-10-09 2018-10-09 A kind of production method of imitation wood line, marble glass brick

Country Status (1)

Country Link
CN (1) CN109052983A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111807715A (en) * 2020-07-23 2020-10-23 长虹美菱股份有限公司 Wood-grain-like touch glass panel for refrigerator and manufacturing process thereof

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101125736A (en) * 2006-08-15 2008-02-20 刘松坡 Method for manufacturing wood grain and marble glass
CN103158384A (en) * 2011-12-12 2013-06-19 李彦坡 Hollow glass brick thermal transfer coating and thermal transfer process
CN103722965A (en) * 2014-01-07 2014-04-16 张相如 Preparation method of thermal transfer printing glass
CN103879134A (en) * 2014-03-17 2014-06-25 殷殿荣 Continuous heat transfer printing technology suitable for single glass block and special device
CN103992044A (en) * 2014-04-30 2014-08-20 安徽宏宇玻璃有限公司 Preparation method for pattern decoration glass
CN105667016A (en) * 2016-03-23 2016-06-15 东莞市森泰玻璃制品有限公司 Marble glass plate and production process thereof
CN106739610A (en) * 2016-12-27 2017-05-31 安徽星光标识系统有限公司 A kind of manufacture craft for printing label

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101125736A (en) * 2006-08-15 2008-02-20 刘松坡 Method for manufacturing wood grain and marble glass
CN103158384A (en) * 2011-12-12 2013-06-19 李彦坡 Hollow glass brick thermal transfer coating and thermal transfer process
CN103722965A (en) * 2014-01-07 2014-04-16 张相如 Preparation method of thermal transfer printing glass
CN103879134A (en) * 2014-03-17 2014-06-25 殷殿荣 Continuous heat transfer printing technology suitable for single glass block and special device
CN103992044A (en) * 2014-04-30 2014-08-20 安徽宏宇玻璃有限公司 Preparation method for pattern decoration glass
CN105667016A (en) * 2016-03-23 2016-06-15 东莞市森泰玻璃制品有限公司 Marble glass plate and production process thereof
CN106739610A (en) * 2016-12-27 2017-05-31 安徽星光标识系统有限公司 A kind of manufacture craft for printing label

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
吴敏,王睿编著: "《个性化开店指南 热转印开店》", 30 June 2013, 印刷工业出版社 *
王多明,孔烔主编: "《中国广告大词典》", 31 December 2008, 中国广播电视出版社 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111807715A (en) * 2020-07-23 2020-10-23 长虹美菱股份有限公司 Wood-grain-like touch glass panel for refrigerator and manufacturing process thereof

Similar Documents

Publication Publication Date Title
CN110104960B (en) Environment-friendly decorative glass and preparation method thereof
WO2022141832A1 (en) Digitally printed plate, manufacturing method, and application
CN102372423A (en) Hot bending furnace for colored glazing glass, method for preparing colored glazing toughened hot-bent glass and colored glazing toughened hot-bent glass
CN109824384A (en) The ceramics preparation method and decal method of fluorescence embossment marble paper
CN106007800B (en) A kind of preparation method of background wall brick and the preparation method of wall
CN107793028A (en) The local glaze embossment ceramic and preparation technology of once-firing
CN108909082A (en) A kind of reflective insulation Flexible decorative sheet and its manufacturing method
CN108000692B (en) A kind of porcelain embryo glazing equipment and porcelain embryo's glazing method using the equipment
CN109052983A (en) A kind of production method of imitation wood line, marble glass brick
CN107673616A (en) The collocation method of the Ceramic Tiles of glaze containing isolation, manufacturing process and product gray scale
CN102677479A (en) Method for manufacturing artificial leathers capable of changing color with temperature
CN101096167A (en) Carved porcelain ware production technique
CN106431504A (en) Multi-colored peacock feather grain decoration ceramic tile and preparation method
CN105691022A (en) Cold transfer printing method and cold transfer printing film thereof
CN105034670A (en) Method for printing patterns on inorganic board through heat transfer
WO2021189501A1 (en) Non-pvc substrate-type 3d printed flooring and preparation method therefor
CN109162417B (en) Method for manufacturing stone-like colorful coating
CN115745665A (en) Ink-jet printing baking-free decorative light ceramic plate and preparation method thereof
CN106590166A (en) Heat transfer printing hollow glass brick and preparation method thereof
EP1604960A4 (en) Method for producing glass sheet coated with titanium oxide thin film
CN202344965U (en) Environment-friendly colorful plate film
CN110978839B (en) Waterproof and antifouling thermal transfer paper, preparation method and printing stock
CN106985589A (en) A kind of covering surface technique that PVA water transfer printing films are transferred to base material workpiece
CN105604277A (en) Light shock-resisting environment-friendly decorative sheet
CN202493002U (en) High-simulation elastic wood veneer of outer wall

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication

Application publication date: 20181221

RJ01 Rejection of invention patent application after publication