CN109049883A

CN109049883A - A kind of suction wave composite plate and its application

Info

Publication number: CN109049883A
Application number: CN201811000908.7A
Authority: CN
Inventors: 赵若红; 梅超; 徐安; 傅继阳; 刘爱荣; 吴玖荣
Original assignee: Guangzhou University
Current assignee: Guangzhou University
Priority date: 2018-08-29
Filing date: 2018-08-29
Publication date: 2018-12-21
Anticipated expiration: 2038-08-29
Also published as: CN109049883B

Abstract

The invention discloses a kind of suction wave composite plate and its applications, the suction wave composite plate is from outward appearance to inner essence successively arranged Electromgnetically-transparent layer, electromagnetic wave depletion layer and reflection of electromagnetic wave layer, the Electromgnetically-transparent layer includes Electromgnetically-transparent composite material, and the electromagnetic wave depletion layer includes electromagnetic wave loss composite material.The Electromgnetically-transparent layer has very high electromagnetic wave tansmittivity, electromagnetic wave is set to be easy to be incident on the inside for inhaling wave composite plate, and then it is consumed and absorbs by electromagnetic wave depletion layer, the remaining electromagnetic wave for penetrating electromagnetic wave depletion layer can be reflected on the surface of reflection of electromagnetic wave layer, and consume absorption again by electromagnetic wave depletion layer.Suction wave composite plate of the invention has excellent electro-magnetic wave absorption drain performance and mechanical property, it is able to satisfy the requirement of building structure, for being electromagnetically shielded field, good effectiveness can be reached, effectively prevent local electromagnetism leak and region outside electromagnetic intrusion interference, had a good application prospect in places such as MRI system scanning rooms.

Description

A kind of suction wave composite plate and its application

Technical field

The present invention relates to a kind of electromagnetic wave absorption structure more particularly to a kind of suction wave composite plate and its applications.

Background technique

With the development of science and technology with the raising of human knowledge's level, the approach of electromagnetic wave application is more and more, range is more next It is wider.Now, no matter in communication field, medical treatment & health field or food hygiene, electromagnetic wave has all obtained extremely wide General application.But studies have shown that Working Life under the conditions of electromagnetic radiation for a long time, can cause to endanger to the physical and mental health of people Evil.In addition, electromagnetic radiation can generate interference to e-machine, so that e-machine malfunction is occurred, influence the normal work of machine, very To there is major accident and harm, the reception of broadcast, TV also will affect, generate information leakage, serious information security occur Problem.Therefore, in certain building structure, it need to consider shielding electromagnetic waves problem.Such as the electromagnetism of the MRI system scanning room of hospital It shields the normal operation for guaranteeing equipment and protection surrounding enviroment plays a significant role, MRI system equipment position is necessary Guarantee both not external interference effect magnetic field's regularities and normal operation in operation, also to guarantee the safety of related personnel It is not influenced by the magnetic field with the function of other sensitive equipments.And general electromagnetic wave absorbent material mostly due to it is expensive, The reasons such as poor mechanical property, intensity is low and can not in practical architectural engineering large-scale use.The cement for this purpose, someone begins one's study Base wave-absorbing material.Cement-based absorption material is some with electromagnetism generally by being directly added into the normal concrete of cement base Made of the material of wave absorption function comes, but cement-based absorption material is low to the absorptivity of electromagnetic wave, the reason is that, cement base itself Compact structure, porosity is low, be easy to cause the impedance matching with free space unbalance, and most of electromagnetic wave is caused to be inhaled in cement base The surface of wave material has just been reflected, in addition structure design of the cement-based absorption material in building structure is single, usually Only single layer structure.Therefore, it needs to develop a kind of suitable for building structure and with the electromagnetic wave of preferable electromagnetic wave absorption performance Absorbing material.

For promoted electromagnetic-wave absorbent absorbing property, in addition to select have good absorbing property material other than, to material The structure design of material can also be obviously improved the wave-absorbing effect of material by the way of multilayered structure.It is made with different materials multiple Layer, keeps the function of each layer different, can the utmostly low wave absorbtion for promoting absorbing material under all layers of collective effect Energy.

Summary of the invention

To solve above-mentioned shortcoming and defect existing in the prior art, it is suitable for building the purpose of the present invention is to provide one kind Building structure and the suction wave composite plate with good electromagnetic wave absorption performance.Suction wave composite plate of the invention is from outward appearance to inner essence successively arranged Electromgnetically-transparent layer, electromagnetic wave depletion layer and reflection of electromagnetic wave layer, the Electromgnetically-transparent layer have very high Electromgnetically-transparent Rate can make electromagnetic wave incident to the electromagnetic wave depletion layer, and then be consumed absorption, and remaining electromagnetic wave can be by the electromagnetic wave Reflecting layer is reflected back in the electromagnetic wave depletion layer and is absorbed by consumption again.Suction wave composite plate of the invention has excellent electricity Electro-magnetic wave absorption drain performance, preparation cost is low, and intensity is high, and excellent in mechanical performance is able to satisfy the requirement of building structure.

To solve its technical problem, the technical solution adopted by the present invention are as follows:

A kind of suction wave composite plate, including the Electromgnetically-transparent layer, electromagnetic wave depletion layer and electromagnetism from outward appearance to inner essence set gradually Wave reflection layer, the Electromgnetically-transparent layer include Electromgnetically-transparent composite material, and the electromagnetic wave depletion layer includes electromagnetic wave damage Consume composite material.

The preparation method of the Electromgnetically-transparent composite material includes the following steps: that asphalt mixtures modified by epoxy resin 1. is added in sodium bicarbonate In rouge glue, it is uniformly mixed, obtains mixture A；2. silane coupling agent is added in the mixture A, it is uniformly mixed, is then added Expanded polystyrene particle is uniformly mixed, and after the surface of granules of polystyrene to be foamed is wet completely, alkali-activated slag is added Cementitious material is uniformly mixed, obtains mixture B；3. being vibrated before the mixture B initial set, to separate particle, general Grain heating water bath, is then allowed to stand, obtains modified foaming granules of polystyrene；4. by alkali-activated slag cementitious material and the modification Expanded polystyrene particle is uniformly mixed, and then sequentially adds foam stabilizer and foaming agent, is uniformly mixed, is then quickly charged with mold In, demoulding after sizing obtains test block；5. the test block is carried out steam pressure, maintenance to get the Electromgnetically-transparent composite material.

Inventor has found that expanded polystyrene particle has hydrophobicity under study for action, it is difficult to it is uniformly dispersed in water, it is also difficult Together with being closely attached with cementitious material, and its intensity is low, bulk density is small, in the stirring for preparing Electromgnetically-transparent composite material It is easy to float in the process.For this purpose, the present invention pre-processes expanded polystyrene particle, using silane coupling agent to foaming Granules of polystyrene is modified, and so that it is changed into hydrophily by original hydrophobicity, while also having added bicarbonate with preparatory The epoxide-resin glue and alkali-activated slag cementitious material at sodium powder end form crust on the surface of expanded polystyrene particle, such as This, overcomes expanded polystyrene particle and is easy the problem of floating, to also improve foaming polyphenyl in stirring since bulk density is small The intensity of ethylene particle.Before cure at the beginning of cementitious material, the present invention is also to through above-mentioned pretreated expanded polystyrene particle Heating water bath is carried out, in this way, intragranular sodium bicarbonate can be made because being generated carbon dioxide gas by thermal decomposition, to make granulated At porous structure, the more conducively transmission of electromagnetic wave.Compared with expanded polystyrene particle, modified foaming polyphenyl produced by the present invention Ethylene particle not only increases bulk density, will not float in stirring, and surface is hydrophily, is easy to be uniformly dispersed in water, It is easy to be closely attached together with cementitious material, particle generally porous structure, Electromgnetically-transparent performance is good, and intensity is high.This The modified foaming granules of polystyrene is added in alkali-activated slag cementitious material for invention, and foam stabilizer and foaming agent is added, Electromgnetically-transparent composite material is made.Foaming agent generate it is a series of between each other it is independent, disconnected and be in air-tight state Bubble can allow composite material formed porous structure.Meanwhile the bubble that foam stabilizer can allow foaming agent to generate is more stable, to make The porosity of composite material obtained is stablized, and Electromgnetically-transparent performance is stronger.

1. the preparation method of the electromagnetic wave loss composite material, includes the following steps: nickel coated copper powder and sodium bicarbonate It is uniformly mixed, is then added in epoxide-resin glue, be uniformly mixed, obtain complex colloid；2. the complex colloid is dripped dropwise Enter in glycerol, stands solidification, the colloidal solid hardened；3. the colloidal solid is heated in a water bath, it is then allowed to stand, obtains To porous colloidal solid；4. alkali-activated slag cementitious material and the porous colloidal solid are uniformly mixed, it is then charged into mold In, it then vibrates, conserve, demoulding, being conserved again to get electromagnetic wave loss composite material.

Inventor has found under study for action, although nickel coated copper powder has excellent electric conductivity and electromagnetic wave drain performance, Be nickel coated copper powder particle it is smaller, density is very big, if being directly added into material, will disperse uneven.For this purpose, the present invention is to nickel packet Copper powder is pre-processed.It is to mix nickel coated copper powder with sodium bicarbonate powder first, epoxy resin then is added in mixture It in glue, stirs evenly, complex colloid is made, then complex colloid is instilled in glycerol, since epoxide-resin glue does not dissolve in glycerol, because This, drip to the drops in glycerol complex colloid can wherein setting and hardening at colloidal solid, be formed by colloidal solid by Epoxy resin, nickel coated copper powder and sodium bicarbonate collectively form.Then, heating water bath then to colloidal solid is carried out, on colloidal solid Epoxide-resin glue can soften into when heated thick, and sodium bicarbonate can decompose generation carbon dioxide gas when heated, The two collective effect makes colloidal solid form porous structure, so that porous colloidal solid be made.In this way, not only solving nickel packet Copper powder disperses non-uniform technical problem since particle is small, density is big in the material, and porous colloidal solid obtained Electromagnetic wave drain performance is stronger.The porous colloidal solid is added in alkali-activated slag cementitious material, electromagnetic wave loss is made Composite material, in this way, the electromagnetic wave drain performance of electromagnetic wave loss composite material can not only be enhanced, moreover it is possible to enhance electromagnetic wave loss The mechanical property of composite material.

As the preferred embodiment of the present invention for inhaling wave composite plate, the preparation side of the alkali-activated slag cementitious material Method are as follows: flyash is uniformly mixed with slag, mixing grey body is obtained, alkali-activator then is added into the mixing grey body, mix It closes uniformly to get the alkali-activated slag cementitious material.

The present invention is reacted with alkali-activator and alkali-activated slag cementitious material is made using flyash and slag, using as electromagnetism Wave transmits the base material of composite material and electromagnetic wave loss composite material.In this way, not only to slag, flyash these Industry Wastes Gurry is efficiently used, and the harm with trade waste to environment is reduced resource waste, and greatly reduces suction of the present invention The preparation cost of wave composite plate, and using alkali-activated slag cementitious material as Electromgnetically-transparent composite material made of base material With the excellent in mechanical performance of electromagnetic wave loss composite material, compact structure is good, and compression strength is high, frost resistance and corrosion resistance It is good, it is not easy to collapse, porosity is stablized, and preparation process is environment friendly and pollution-free, is able to satisfy the requirement of building structure.In addition, containing in slag There is metal etc. that there is the ingredient of loss function to electromagnetic wave, in this way, the alkali-activated slag cementitious material as base material can be made The electromagnetic wave for absorbing part can be consumed.

The preferred embodiment of preparation method as alkali-activated slag cementitious material of the present invention, is counted in mass ratio, Flyash: slag=(7:5)~(10:3).Inventor is by serial experiment the study found that with the flyash and slag of the proportion The comprehensive performance for the cementitious material being prepared is more excellent.Preparation method as alkali-activated slag cementitious material of the present invention Most preferred embodiment is counted in mass ratio, flyash: slag=7:3.Inventor is by serial experiment the study found that being matched with this The comprehensive performance for the cementitious material that the flyash and slag of ratio are prepared is optimal.

The preferred embodiment of preparation method as alkali-activated slag cementitious material of the present invention, is counted in mass ratio, Mix grey body: alkali-activator=1:(0.3~0.5).

The more preferable embodiment of preparation method as alkali-activated slag cementitious material of the present invention, in mass ratio Meter mixes grey body: alkali-activator=1:(0.4~0.5).

The more preferable embodiment of preparation method as alkali-activated slag cementitious material of the present invention, in mass ratio Meter mixes grey body: alkali-activator=1:(0.3~0.35).

The preferred embodiment of preparation method as alkali-activated slag cementitious material of the present invention, the alkali-activator The preparation method comprises the following steps: water, waterglass and sodium hydroxide are uniformly mixed, be then allowed to stand for 24 hours to get the alkali-activator.

The preferred embodiment of preparation method as alkali-activator of the present invention, is counted in mass ratio, water: waterglass: Sodium hydroxide=(45~55): 1:2.Inventor passes through serial experiment the study found that alkali-activated carbonatite made from raw material with the proportion The better performances of agent, it is more excellent to the stimulation effect for the material that is excited.

The most preferred embodiment of preparation method as alkali-activator of the present invention, is counted in mass ratio, water: water glass Glass: sodium hydroxide=50:1:2.Inventor passes through serial experiment the study found that alkali-activator made from raw material with the proportion Performance is best, optimal to the stimulation effect for the material that is excited.

As the preferred embodiment of the present invention for inhaling wave composite plate, the preparation side of the Electromgnetically-transparent composite material The step of method 1. in, based on mass volume ratio, sodium bicarbonate: epoxide-resin glue=2~3g:20~30mL；Inventor is by system Column experimental studies have found that, the performance for the mixture A being prepared with the sodium bicarbonate and epoxide-resin glue of the proportion is more excellent, Yu Fa The package effect of foamed polystyrene particle surface is preferable, to keep the performance of modified foaming granules of polystyrene obtained more excellent. Preferably, the step of preparation method of the Electromgnetically-transparent composite material 1. in, based on mass volume ratio, sodium bicarbonate: ring Oxygen resin glue=2.5g:25mL；Inventor is by serial experiment the study found that with the sodium bicarbonate and epoxide-resin glue of the proportion The best performance for the mixture A being prepared, the package effect in expanded polystyrene particle surface is best, to make obtained The best performance of modified foaming granules of polystyrene.

As the preferred embodiment of the present invention for inhaling wave composite plate, the preparation side of the Electromgnetically-transparent composite material The step of method 2. in, silane coupling agent, mixture A, expanded polystyrene particle and alkali-activated slag cementitious material proportion be, Silane coupling agent: mixture A: expanded polystyrene particle: alkali-activated slag cementitious material=1~1.5mL:10~12mL:10 ~11mL:18~22g.Inventor obtains by series further investigation, poly- with the silane coupling agent of the proportion, mixture A, foaming When styrene pellets and alkali-activated slag cementitious material prepare modified foaming granules of polystyrene, the modified foaming polyphenyl can be made Ethylene particle forms ideal shell.The dosage accounting of expanded polystyrene particle is excessive or alkali-activated slag cementitious material Dosage accounting is too small, can all lead to not form ideal shell on the surface of expanded polystyrene particle.

As the most preferred embodiment of the present invention for inhaling wave composite plate, the preparation of the Electromgnetically-transparent composite material The step of method 2. in, the proportion of silane coupling agent, mixture A, expanded polystyrene particle and alkali-activated slag cementitious material For silane coupling agent: mixture A: expanded polystyrene particle: alkali-activated slag cementitious material=1mL:10mL:10mL:20g.

As the preferred embodiment of the present invention for inhaling wave composite plate, the preparation side of the Electromgnetically-transparent composite material The step of method 2. in, expanded polystyrene particle is before use, being first washed with deionized water and drying.As suction of the present invention The step of preferred embodiment of wave composite plate, the preparation method of the Electromgnetically-transparent composite material 2. in, foam polyphenyl second Alkene particle is before use, be first washed with deionized 2~3 times, then in drying in oven.Preferably, the temperature of the drying It is 60~70 DEG C, time 12h.

As the preferred embodiment of the present invention for inhaling wave composite plate, the preparation side of the Electromgnetically-transparent composite material The step of method 3. in, particle is heated into 10~15min in 65~75 DEG C of water-bath, is then allowed to stand for 24 hours, the modified hair is obtained Foamed polystyrene particle.Inventor obtains by series further investigation, carries out water with particle of the water bath condition to Separation by vibration When bath heating, the modified foaming granules of polystyrene with preferable porous structure can be obtained.

As the preferred embodiment of the present invention for inhaling wave composite plate, the preparation side of the Electromgnetically-transparent composite material The concrete operations of the step of method 4. are as follows: alkali-activated slag cementitious material is mixed with modified foaming granules of polystyrene, and is stirred Uniformly, foam stabilizer and foaming agent are then sequentially added, is stirred evenly, is then quickly charged in mold, makes mixed material in mold Crust is prescinded after middle molding, then demoulding, obtain test block.Preferably, the stirring carries out in net slurry blender.

As the preferred embodiment of the present invention for inhaling wave composite plate, the preparation side of the Electromgnetically-transparent composite material The step of method 4. in, count in mass ratio, alkali-activated slag cementitious material: modified foaming granules of polystyrene=(4~6): 1.Hair Bright people obtains by series further investigation, and alkali-activated slag cementitious material and modified foaming granules of polystyrene are with proportion mixing When, resulting composite material had not only had excellent Electromgnetically-transparent performance, but also had excellent mechanical property.If alkali-activated slag The dosage accounting of cementitious material is excessive, will affect the Electromgnetically-transparent performance of composite material；If modified foaming granules of polystyrene Dosage accounting it is excessive, will affect the mechanical properties such as the intensity of composite material.

As the most preferred embodiment of the present invention for inhaling wave composite plate, the preparation of the Electromgnetically-transparent composite material The step of method 4. in, count in mass ratio, alkali-activated slag cementitious material: modified foaming granules of polystyrene=5:1.Inventor It is obtained by series further investigation, when alkali-activated slag cementitious material and modified foaming granules of polystyrene are with proportion mixing, The comprehensive performance of resulting composite material is optimal.

As the preferred embodiment of the present invention for inhaling wave composite plate, the preparation side of the Electromgnetically-transparent composite material The step of method 4. in, the proportion of foam stabilizer, foaming agent and modified foaming granules of polystyrene is foam stabilizer: foaming agent: modified hair Foamed polystyrene particle=2~4g:5~7mL:40~50g.

As the most preferred embodiment of the present invention for inhaling wave composite plate, the preparation of the Electromgnetically-transparent composite material The step of method 4. in, the proportion of foam stabilizer, foaming agent and modified foaming granules of polystyrene is foam stabilizer: foaming agent: modified Expanded polystyrene particle=2g:5mL:44g.

As the preferred embodiment of the present invention for inhaling wave composite plate, the preparation side of the Electromgnetically-transparent composite material The step of method 4. in, foam stabilizer is gum arabic powder.

As the preferred embodiment of the present invention for inhaling wave composite plate, the preparation side of the Electromgnetically-transparent composite material The step of method 4. in, foaming agent be the agent of FP-180 animal foaming.FP-180 animal foaming agent used in the present invention is purchased from mountain Thailand of Dong Yi section builds New technical use Co., Ltd, and the present invention is not construed as limiting it, implements all in protection scope of the present invention Within.

As the preferred embodiment of the present invention for inhaling wave composite plate, the preparation side of the Electromgnetically-transparent composite material The step of method 5. in, test block is put into still kettle, steam pressure 8h at 175~185 DEG C, is then placed in curing box and conserves 3 days, i.e., Obtain the Electromgnetically-transparent composite material.Preferably, the temperature of the curing box be 20 DEG C, humidity 95%.Inventor passes through Series further investigation obtains, and when carrying out steam pressure processing to test block with the autoclaved condition, obtained composite material has preferable more Pore structure.

As the preferred embodiment of the present invention for inhaling wave composite plate, the preparation side of the electromagnetic wave loss composite material The step of method 1. in, based on mass volume ratio, nickel coated copper powder: sodium bicarbonate: epoxide-resin glue=8~12g:2~3g:18~ 22mL.Inventor obtains by series further investigation, and nickel coated copper powder, sodium bicarbonate and epoxide-resin glue are mixed with the proportion When complex colloid, the porous structure of resulting porous colloidal solid is preferable.

As the most preferred embodiment of the present invention for inhaling wave composite plate, the preparation of the electromagnetic wave loss composite material The step of method 1. in, based on mass volume ratio, nickel coated copper powder: sodium bicarbonate: epoxide-resin glue=10g:2.5g:20mL.Hair Bright people obtains by series further investigation, and nickel coated copper powder, sodium bicarbonate and epoxide-resin glue are mixed with epoxy glue with the proportion When body, the porous structure of resulting porous colloidal solid is best.

As the preferred embodiment of the present invention for inhaling wave composite plate, the preparation side of the electromagnetic wave loss composite material The step of method 3. in, colloidal solid is heated into 10~15min in 65~75 DEG C of water-bath, is then allowed to stand for 24 hours, obtains porous glue Body particle.Inventor obtains by series further investigation, when carrying out heating water bath with colloidal solid of the water bath condition to hardening, It can obtain the porous colloidal solid with preferable porous structure.

As the preferred embodiment of the present invention for inhaling wave composite plate, the preparation side of the electromagnetic wave loss composite material The concrete operations of the step of method 4. are as follows: alkali-activated slag cementitious material and the porous colloidal solid are uniformly mixed, then filled Enter in mold, vibrate 15~20s, is then placed in curing box and conserves demoulding for 24 hours, maintenance 3 days is continued to the material after demoulding, Composite material is lost up to the electromagnetic wave.Preferably, the maintenance is under the environmental condition that temperature is 20 DEG C, humidity is 95% It carries out.

As the preferred embodiment of the present invention for inhaling wave composite plate, the preparation side of the electromagnetic wave loss composite material The step of method 4. in, count in mass ratio, alkali-activated slag cementitious material: porous colloidal solid=8:1~10:1.Inventor passes through Series further investigation obtains, and alkali-activated slag cementitious material and porous colloidal solid are mixed with resulting composite wood with the proportion Material had not only had the function of excellent electro-magnetic wave absorption loss, but also had excellent mechanical property.If the dosage of porous colloidal solid accounts for Than too small, the electromagnetic wave loss function of will lead to gained composite material can not be maximized, if the dosage accounting of porous colloidal solid It is excessive, it will lead to the electromagnetic wave loss function reduction of gained composite material.

As the preferred embodiment of the present invention for inhaling wave composite plate, the reflection of electromagnetic wave layer includes metal plate.

In addition, the object of the invention is also to provide a kind of purposes for inhaling wave composite plate, the specifically described suction wave is multiple Application of the plywood in wave-absorbing material applied to buildings field.In addition, the object of the invention is also to provide a kind of suction wave composite plates Purposes, the specifically described application for inhaling wave composite plate in nuclear magnetic resonance room electromagnetic shielding.

Compared with prior art, the invention has the benefit that

1. Electromgnetically-transparent layer of the invention is the Electromgnetically-transparent composite material of porous structure, the Electromgnetically-transparent is multiple Condensation material has very high electromagnetic wave tansmittivity, also has excellent mechanical property, and compression strength is high, frost resistance and corrosion resistance Good, porosity is stablized, and preparation cost is low, environment friendly and pollution-free, can effectively improve the impedance operator of Electromgnetically-transparent layer surface, allows more More electromagnetic wave incidents substantially reduces Electromgnetically-transparent layer surface to the reflectivity of electromagnetic wave to the inside for inhaling wave composite plate.

2. electromagnetic wave depletion layer of the invention is that composite material is lost in electromagnetic wave, the electromagnetic wave loss composite material has Excellent electro-magnetic wave absorption loss function and mechanical property, compression strength is high, and compact structure is good, is not easy the electromagnetic wave that leaks, greatly The integral thickness and weight for reducing absorbent structure greatly, keeps absorbent structure integrally frivolous, improves its safety in utilization.

3. suction wave composite plate of the invention is from outward appearance to inner essence successively arranged Electromgnetically-transparent layer, electromagnetic wave depletion layer and electromagnetic wave Reflecting layer, the Electromgnetically-transparent layer have very high electromagnetic wave tansmittivity, and electromagnetic wave is made to be easy to be incident on suction wave composite plate Inside, and then consumed and absorb by electromagnetic wave depletion layer, the remaining electromagnetic wave for penetrating electromagnetic wave depletion layer can be in reflection of electromagnetic wave layer Surface reflected, and absorption is consumed by electromagnetic wave depletion layer again.Suction wave composite plate of the invention has excellent electromagnetic wave Absorption loss performance can reach good effectiveness for being electromagnetically shielded field, effectively prevent local electromagnetism leak and Electromagnetic intrusion interference outside region.Suction wave composite plate of the invention also has excellent mechanical property, is able to satisfy building structure It is required that being had a good application prospect in the place that MRI system scanning room etc. need to be electromagnetically shielded.

Detailed description of the invention

Fig. 1 is the structural schematic diagram of the present invention for inhaling wave composite plate；

Fig. 2 is the material of embodiment 1, comparative example 1 and comparative example 2 with the reflection of electromagnetic wave Dissipation change figure of frequency；

Fig. 3 is the material of embodiment 5, comparative example 3 and comparative example 4 with the electro-magnetic wave absorption Dissipation change figure of frequency；

Fig. 4 is that composite material is lost with the electromagnetic wave of frequency in the suction wave composite plate of embodiment 10 and the electromagnetic wave of embodiment 5 Absorption loss variation diagram.

Specific embodiment

More clearly to state technical solution of the present invention, further illustrate combined with specific embodiments below, but cannot use In the limitation present invention, this is only section Example of the invention.Unless otherwise instructed, side used by the embodiment of the present invention Method is existing conventional method.The raw materials used in the present invention can be commercially available by commercial sources, and the present invention is not construed as limiting it.

The embodiment of the present invention provides a kind of suction wave composite plate, as shown in Figure 1, the suction wave composite plate is from outward appearance to inner essence successively set There are Electromgnetically-transparent layer 1, electromagnetic wave depletion layer 2 and reflection of electromagnetic wave layer 3, the Electromgnetically-transparent layer 1 is answered by Electromgnetically-transparent Condensation material composition, the electromagnetic wave depletion layer 2 are made of electromagnetic wave loss composite material, and the reflection of electromagnetic wave layer 3 is by metal Board group at.

The preparation method of the Electromgnetically-transparent composite material includes the following steps:

(1) it prepares alkali-activator: water, waterglass and sodium hydroxide being mixed, is stirred evenly, is then allowed to stand for 24 hours, obtains alkali Exciting agent；It counts in mass ratio, water: waterglass: sodium hydroxide=(45~55): 1:2；

(2) it prepares the first alkali-activated slag cementitious material: flyash and slag is added in net slurry blender, stirring is equal It is even, mixing grey body is obtained, alkali-activator is then added, stirs evenly, obtains the first alkali-activated slag cementitious material；By quality Than meter, flyash: slag=(7:5)~(10:3) mixes grey body: alkali-activator=1:(0.4~0.5)；

(3) sodium bicarbonate is added in epoxide-resin glue, stirs evenly, obtains mixture A；Based on mass volume ratio, carbon Sour hydrogen sodium: epoxide-resin glue=2~3g:20~30mL；

(4) expanded polystyrene particle is first washed with deionized 2~3 times, is then dried in 60~70 DEG C of baking oven It is dry, drying time 12h；

(5) silane coupling agent is added in mixture A, is uniformly mixed, the foaming polyphenyl handled through step (4) is then added Ethylene particle, is then stirred evenly with blender, after the surface of granules of polystyrene to be foamed is wet completely, adds first Kind alkali-activated slag cementitious material, and stirred evenly in net slurry blender, obtain mixture B；Silane coupling agent, mixture A, The proportion of expanded polystyrene particle and the first alkali-activated slag cementitious material is silane coupling agent: mixture A: foaming is poly- Styrene pellets: the first alkali-activated slag cementitious material=1~1.5mL:10~12mL:10~11mL:18~22g；

(6) it before mixture B initial set, pours them onto a vinyl disc, then puts Separation by vibration particle on a vibration table, Particle after vibration is heated into 10~15min in 65~75 DEG C of water-bath, is then allowed to stand for 24 hours, modified foaming polyphenyl second is obtained Alkene particle；

(7) it prepares second of alkali-activated slag cementitious material: flyash and slag is added in net slurry blender, stirring is equal It is even, mixing grey body is obtained, alkali-activator is then added, stirs evenly, obtains second of alkali-activated slag cementitious material；By quality Than meter, flyash: slag=(7:5)~(10:3)；It counts in mass ratio, mixes grey body: alkali-activator=1:(0.3~0.35)；

(8) second of alkali-activated slag cementitious material and modified foaming granules of polystyrene are added in net slurry blender, It stirs evenly, then sequentially adds foam stabilizer and foaming agent, stir evenly, be then quickly charged in mold, mixed material is made to exist Crust is prescinded after die for molding, then demoulding, obtain test block；It counts in mass ratio, second of alkali-activated slag cementitious material: Modified foaming granules of polystyrene=(4~6): 1；The proportion of foam stabilizer, foaming agent and modified foaming granules of polystyrene is, surely Infusion: foaming agent: modified foaming granules of polystyrene=2~4g:5~7mL:40~50g；Foam stabilizer is gum arabic powder, Foaming agent is the agent of FP-180 animal foaming；

(9) test block is put into still kettle, steam pressure 8h at 175~185 DEG C, is then placed in that temperature is 20 DEG C, humidity is It is conserved 3 days in 95% curing box, obtains Electromgnetically-transparent composite material.

The preparation method of the electromagnetic wave loss composite material includes the following steps:

(2) it prepares alkali-activated slag cementitious material: flyash and slag being added in net slurry blender, stirs evenly, obtains To mixing grey body, alkali-activator is then added, stirs evenly, obtains alkali-activated slag cementitious material；It counts in mass ratio, fine coal Ash: slag=(7:5)~(10:3) mixes grey body: alkali-activator=1:(0.3~0.35)；

(3) nickel coated copper powder and sodium bicarbonate are mixed, and is stirred evenly in net slurry blender, be then added to asphalt mixtures modified by epoxy resin It in rouge glue, is stirred evenly with high-speed mixer, obtains complex colloid；Based on mass volume ratio, nickel coated copper powder: sodium bicarbonate: ring Oxygen resin glue=8~12g:2~3g:18~22mL；

(4) complex colloid is instilled in glycerol with the common buret of 25mL dropwise, is then allowed to stand for 24 hours, obtained hard The colloidal solid of change；The amount of every drop complex colloid is about 0.05mL；

(5) colloidal solid is heated to 10~15min in 65~75 DEG C of water-bath, is then allowed to stand for 24 hours, porous colloid is obtained Particle；

(6) the alkali-activated slag cementitious material and the porous colloidal solid are mixed, and is stirred in net slurry blender Mix uniformly, be then charged into mold, and in the 15~20s that vibrates on platform that vibrates, be then placed in curing box, temperature be 20 DEG C, Demoulding for 24 hours is conserved under the environmental condition that humidity is 95%, maintenance 3 is continued under identical environmental condition to the material after demoulding Composite material is lost to get the electromagnetic wave in it；It counts in mass ratio, alkali-activated slag cementitious material: porous colloidal solid=8:1 ~10:1.

Embodiment 1

The present embodiment 1 provides a kind of Electromgnetically-transparent composite material, and preparation method includes the following steps:

(1) it prepares alkali-activator: water, waterglass and sodium hydroxide is mixed, stir 8~10min, be then allowed to stand for 24 hours, obtain To alkali-activator；It counts in mass ratio, water: waterglass: sodium hydroxide=50:1:2；

(2) it prepares the first alkali-activated slag cementitious material: flyash and slag is added in net slurry blender, stirring 120~150s obtains mixing grey body, alkali-activator is then added, stirs 4~5min, obtains the gelling of the first alkali-activated slag Material；Count in mass ratio, flyash: slag=7:3 mixes grey body: alkali-activator=1:0.4；

(3) sodium bicarbonate is added in epoxide-resin glue, stirs 3~5min, obtains mixture A；Based on mass volume ratio, Sodium bicarbonate: epoxide-resin glue=1g:10mL；

(4) expanded polystyrene particle is first washed with deionized 2~3 times, is then dried in 65 DEG C of baking oven, dried The dry time is 12h；

(5) silane coupling agent of 10mL is added in the mixture A of 100mL, is uniformly mixed, is then added through step (4) Then the expanded polystyrene particle 100mL of processing stirs 4~5min, the surface of granules of polystyrene to be foamed with blender After being wet completely, the first alkali-activated slag cementitious material of 200g is added, and stirs 30~35s in net slurry blender, Obtain mixture B；

(6) it before mixture B initial set, pours them onto the vinyl disc that a diameter is 30cm, then puts on a vibration table Particle after vibration is heated in 70 DEG C of water-bath 10~15min, is then allowed to stand for 24 hours by 30~45s of vibration to separate particle, Obtain modified foaming granules of polystyrene；

(7) it prepares second of alkali-activated slag cementitious material: net slurry blender is added in 140g flyash and 60g slag In, 120~150s is stirred, mixing grey body is obtained, 64g alkali-activator is then added, stir 4~5min, second of alkali is obtained and swashs Send out slag gel material；

(8) net slurry is added in second of alkali-activated slag cementitious material of 200g and 40g modified foaming granules of polystyrene to stir It mixes in machine, stirs 4~5min, be uniformly mixed it, then sequentially add 2g gum arabic powder and 5mL FP-180 animality Foaming agent stirs 20~25s, is then fitted into mold and stands 3h for the material being stirred rapidly, prescind crust after molding, Then demoulding obtains test block；

(9) test block is put into still kettle, steam pressure 8h at 180 DEG C, be then placed in temperature be 20 DEG C, humidity be 95% support It is conserved 3 days in protecting box, obtains the Electromgnetically-transparent composite material.

Embodiment 2

The present embodiment 2 provides a kind of Electromgnetically-transparent composite material, and preparation method includes the following steps:

(1) it prepares alkali-activator: water, waterglass and sodium hydroxide is mixed, stir 8~10min, be then allowed to stand for 24 hours, obtain To alkali-activator；It counts in mass ratio, water: waterglass: sodium hydroxide=45:1:2；

(2) it prepares the first alkali-activated slag cementitious material: flyash and slag is added in net slurry blender, stirring 120~150s obtains mixing grey body, alkali-activator is then added, stirs 4~5min, obtains the gelling of the first alkali-activated slag Material；Count in mass ratio, flyash: slag=7:5 mixes grey body: alkali-activator=1:0.45；

(3) sodium bicarbonate is added in epoxide-resin glue, stirs 3~5min, obtains mixture A；Based on mass volume ratio, Sodium bicarbonate: epoxide-resin glue=2g:30mL；

(4) expanded polystyrene particle is first washed with deionized 2~3 times, is then dried in 60 DEG C of baking oven, dried The dry time is 12h；

(5) silane coupling agent of 12mL is added in the mixture A of 110mL, is uniformly mixed, is then added through step (4) Then the expanded polystyrene particle 105mL of processing stirs 4~5min, the surface of granules of polystyrene to be foamed with blender After being wet completely, the first alkali-activated slag cementitious material of 180g is added, and stirs 30~35s in net slurry blender, Obtain mixture B；

(6) it before mixture B initial set, pours them onto the vinyl disc that a diameter is 30cm, then puts on a vibration table Particle after vibration is heated in 65 DEG C of water-bath 10~15min, is then allowed to stand for 24 hours by 30~45s of vibration to separate particle, Obtain modified foaming granules of polystyrene；

(7) it prepares second of alkali-activated slag cementitious material: net slurry blender is added in 140g flyash and 100g slag In, 120~150s is stirred, mixing grey body is obtained, 72g alkali-activator is then added, stir 4~5min, second of alkali is obtained and swashs Send out slag gel material；

(8) net slurry is added in second of alkali-activated slag cementitious material of 200g and 50g modified foaming granules of polystyrene to stir It mixes in machine, stirs 4~5min, be uniformly mixed it, then sequentially add 3g gum arabic powder and 6mL FP-180 animality Foaming agent stirs 20~25s, is then fitted into mold and stands 3h for the material being stirred rapidly, prescind crust after molding, Then demoulding obtains test block；

(9) test block is put into still kettle, steam pressure 8h at 175 DEG C, be then placed in temperature be 20 DEG C, humidity be 95% support It is conserved 3 days in protecting box, obtains the Electromgnetically-transparent composite material.

Embodiment 3

The present embodiment 3 provides a kind of Electromgnetically-transparent composite material, and preparation method includes the following steps:

(1) it prepares alkali-activator: water, waterglass and sodium hydroxide is mixed, stir 8~10min, be then allowed to stand for 24 hours, obtain To alkali-activator；It counts in mass ratio, water: waterglass: sodium hydroxide=55:1:2；

(2) it prepares the first alkali-activated slag cementitious material: flyash and slag is added in net slurry blender, stirring 120~150s obtains mixing grey body, alkali-activator is then added, stirs 4~5min, obtains the gelling of the first alkali-activated slag Material；Count in mass ratio, flyash: slag=10:3 mixes grey body: alkali-activator=1:0.5；

(3) sodium bicarbonate is added in epoxide-resin glue, stirs 3~5min, obtains mixture A；Based on mass volume ratio, Sodium bicarbonate: epoxide-resin glue=3g:20mL；

(4) expanded polystyrene particle is first washed with deionized 2~3 times, is then dried in 70 DEG C of baking oven, dried The dry time is 12h；

(5) silane coupling agent of 15mL is added in the mixture A of 120mL, is uniformly mixed, is then added through step (4) Then the expanded polystyrene particle 110mL of processing stirs 4~5min, the surface of granules of polystyrene to be foamed with blender After being wet completely, the first alkali-activated slag cementitious material of 220g is added, and stirs 30~35s in net slurry blender, Obtain mixture B；

(6) it before mixture B initial set, pours them onto the vinyl disc that a diameter is 30cm, then puts on a vibration table Particle after vibration is heated in 75 DEG C of water-bath 10~15min, is then allowed to stand for 24 hours by 30~45s of vibration to separate particle, Obtain modified foaming granules of polystyrene；

(7) it prepares second of alkali-activated slag cementitious material: net slurry blender is added in 200g flyash and 60g slag In, 120~150s is stirred, mixing grey body is obtained, 91g alkali-activator is then added, stir 4~5min, second of alkali is obtained and swashs Send out slag gel material；

(8) net slurry is added in second of alkali-activated slag cementitious material of 240g and 40g modified foaming granules of polystyrene to stir It mixes in machine, stirs 4~5min, be uniformly mixed it, then sequentially add 4g gum arabic powder and 7mL FP-180 animality Foaming agent stirs 20~25s, is then fitted into mold and stands 3h for the material being stirred rapidly, prescind crust after molding, Then demoulding obtains test block；

(9) test block is put into still kettle, steam pressure 8h at 185 DEG C, be then placed in temperature be 20 DEG C, humidity be 95% support It is conserved 3 days in protecting box, obtains the Electromgnetically-transparent composite material.

Embodiment 4

The present embodiment 4 provides a kind of Electromgnetically-transparent composite material, and preparation method includes the following steps:

(1) it prepares alkali-activator: water, waterglass and sodium hydroxide is mixed, stir 8~10min, be then allowed to stand for 24 hours, obtain To alkali-activator；It counts in mass ratio, water: waterglass: sodium hydroxide=48:1:2；

(2) it prepares the first alkali-activated slag cementitious material: flyash and slag is added in net slurry blender, stirring 120~150s obtains mixing grey body, alkali-activator is then added, stirs 4~5min, obtains the gelling of the first alkali-activated slag Material；Count in mass ratio, flyash: slag=8:3 mixes grey body: alkali-activator=1:0.4；

(5) silane coupling agent of 13mL is added in the mixture A of 110mL, is uniformly mixed, is then added through step (4) Then the expanded polystyrene particle 108mL of processing stirs 4~5min, the surface of granules of polystyrene to be foamed with blender After being wet completely, the first alkali-activated slag cementitious material of 210g is added, and stirs 30~35s in net slurry blender, Obtain mixture B；

(7) it prepares second of alkali-activated slag cementitious material: net slurry blender is added in 170g flyash and 80g slag In, 120~150s is stirred, mixing grey body is obtained, 80g alkali-activator is then added, stir 4~5min, second of alkali is obtained and swashs Send out slag gel material；

(8) net slurry is added in second of alkali-activated slag cementitious material of 220g and 40g modified foaming granules of polystyrene to stir It mixes in machine, stirs 4~5min, be uniformly mixed it, then sequentially add 3.5g gum arabic powder and 6.5mL FP-180 is dynamic Physical property foaming agent stirs 20~25s, is then fitted into mold and stands 3h for the material being stirred rapidly, prescind face after molding Packet header, then demoulding, obtains test block；

Embodiment 5

The present embodiment 5 provides a kind of electromagnetic wave loss composite material, and preparation method includes the following steps:

(1) it prepares alkali-activator: water, waterglass and sodium hydroxide is mixed, and stir 10~15min, keep its mixing equal It is even, it is then allowed to stand for 24 hours, obtains alkali-activator；It counts in mass ratio, water: waterglass: sodium hydroxide=50:1:2；

(2) it prepares alkali-activated slag cementitious material: 700g flyash and 300g slag is added in net slurry blender, stirring 120~150s is uniformly mixed it, obtains mixing grey body, 320g alkali-activator is then added, stir 4~5min, make its mixing Uniformly, alkali-activated slag cementitious material is obtained；

(3) 100g nickel coated copper powder and 25g sodium bicarbonate are mixed, and stirs 15~20s in net slurry blender, keep it mixed It closes uniformly, is then added in the epoxide-resin glue of 200mL, stir 3~4min with high-speed mixer, mix it uniformly Close colloid；

(4) complex colloid is instilled into glycerol (every drop is about 0.05mL) dropwise with the common buret of 25mL, so After stand the colloidal solid for 24 hours, hardened；

(5) colloidal solid for taking out setting and hardening in glycerol, colloidal solid heats to 10 in 70 DEG C of water-bath~ 15min is then allowed to stand for 24 hours, obtains porous colloidal solid；

(6) 1000g alkali-activated slag cementitious material and the porous colloidal solid of 125g are mixed, and is stirred in net slurry blender 4~5min is mixed, it is uniformly mixed, is then charged into mold, and in the 15~20s that vibrates on platform that vibrates, be then placed in curing box In, demoulding for 24 hours is conserved under the environmental condition that temperature is 20 DEG C, humidity is 95%, to the material after demoulding in identical environment Under the conditions of continue maintenance 3 days to get the electromagnetic wave be lost composite material.

Embodiment 6

The present embodiment 6 provides a kind of electromagnetic wave loss composite material, and preparation method includes the following steps:

(1) it prepares alkali-activator: water, waterglass and sodium hydroxide is mixed, and stir 10~15min, keep its mixing equal It is even, it is then allowed to stand for 24 hours, obtains alkali-activator；It counts in mass ratio, water: waterglass: sodium hydroxide=45:1:2；

(2) it prepares alkali-activated slag cementitious material: 700g flyash and 500g slag is added in net slurry blender, stirring 120~150s is uniformly mixed it, obtains mixing grey body, 360g alkali-activator is then added, stir 4~5min, make its mixing Uniformly, alkali-activated slag cementitious material is obtained；

(3) 100g nickel coated copper powder and 20g sodium bicarbonate are mixed, and stirs 15~20s in net slurry blender, keep it mixed It closes uniformly, is then added in the epoxide-resin glue of 180mL, stir 3~4min with high-speed mixer, mix it uniformly Close colloid；

(5) colloidal solid for taking out setting and hardening in glycerol, colloidal solid heats to 10 in 65 DEG C of water-bath~ 15min is then allowed to stand for 24 hours, obtains porous colloidal solid；

(6) 1100g alkali-activated slag cementitious material and the porous colloidal solid of 120g are mixed, and is stirred in net slurry blender 4~5min is mixed, it is uniformly mixed, is then charged into mold, and in the 15~20s that vibrates on platform that vibrates, be then placed in curing box In, demoulding for 24 hours is conserved under the environmental condition that temperature is 20 DEG C, humidity is 95%, to the material after demoulding in identical environment Under the conditions of continue maintenance 3 days to get the electromagnetic wave be lost composite material.

Embodiment 7

The present embodiment 7 provides a kind of electromagnetic wave loss composite material, and preparation method includes the following steps:

(1) it prepares alkali-activator: water, waterglass and sodium hydroxide is mixed, and stir 10~15min, keep its mixing equal It is even, it is then allowed to stand for 24 hours, obtains alkali-activator；It counts in mass ratio, water: waterglass: sodium hydroxide=55:1:2；

(2) it prepares alkali-activated slag cementitious material: 1000g flyash and 300g slag being added in net slurry blender, stirred 120~150s is mixed, it is uniformly mixed, mixing grey body is obtained, 455g alkali-activator is then added, stir 4~5min, keeps it mixed It closes uniformly, obtains alkali-activated slag cementitious material；

(3) 120g nickel coated copper powder and 30g sodium bicarbonate are mixed, and stirs 15~20s in net slurry blender, keep it mixed It closes uniformly, is then added in the epoxide-resin glue of 220mL, stir 3~4min with high-speed mixer, mix it uniformly Close colloid；

(5) colloidal solid for taking out setting and hardening in glycerol, colloidal solid heats to 10 in 75 DEG C of water-bath~ 15min is then allowed to stand for 24 hours, obtains porous colloidal solid；

(6) 1200g alkali-activated slag cementitious material and the porous colloidal solid of 120g are mixed, and is stirred in net slurry blender 4~5min is mixed, it is uniformly mixed, is then charged into mold, and in the 15~20s that vibrates on platform that vibrates, be then placed in curing box In, demoulding for 24 hours is conserved under the environmental condition that temperature is 20 DEG C, humidity is 95%, to the material after demoulding in identical environment Under the conditions of continue maintenance 3 days to get the electromagnetic wave be lost composite material.

Embodiment 8

The present embodiment 8 provides a kind of electromagnetic wave loss composite material, and preparation method includes the following steps:

(1) it prepares alkali-activator: water, waterglass and sodium hydroxide is mixed, and stir 10~15min, keep its mixing equal It is even, it is then allowed to stand for 24 hours, obtains alkali-activator；It counts in mass ratio, water: waterglass: sodium hydroxide=52:1:2；

(2) it prepares alkali-activated slag cementitious material: 900g flyash and 400g slag is added in net slurry blender, stirring 120~150s is uniformly mixed it, obtains mixing grey body, 416g alkali-activator is then added, stir 4~5min, make its mixing Uniformly, alkali-activated slag cementitious material is obtained；

(3) 96g nickel coated copper powder and 24g sodium bicarbonate are mixed, and stirs 15~20s in net slurry blender, keep it mixed It closes uniformly, is then added in the epoxide-resin glue of 216mL, stir 3~4min with high-speed mixer, mix it uniformly Close colloid；

(6) 1000g alkali-activated slag cementitious material and the porous colloidal solid of 120g are mixed, and is stirred in net slurry blender 4~5min is mixed, it is uniformly mixed, is then charged into mold, and in the 15~20s that vibrates on platform that vibrates, be then placed in curing box In, demoulding for 24 hours is conserved under the environmental condition that temperature is 20 DEG C, humidity is 95%, to the material after demoulding in identical environment Under the conditions of continue maintenance 3 days to get the electromagnetic wave be lost composite material.

Embodiment 9

The present embodiment 9 provides a kind of electromagnetic wave loss composite material, and preparation method includes the following steps:

(1) it prepares alkali-activator: water, waterglass and sodium hydroxide is mixed, and stir 10~15min, keep its mixing equal It is even, it is then allowed to stand for 24 hours, obtains alkali-activator；It counts in mass ratio, water: waterglass: sodium hydroxide=48:1:2；

(2) it prepares alkali-activated slag cementitious material: 800g flyash and 350g slag is added in net slurry blender, stirring 120~150s is uniformly mixed it, obtains mixing grey body, 345g alkali-activator is then added, stir 4~5min, make its mixing Uniformly, alkali-activated slag cementitious material is obtained；

(3) 80g nickel coated copper powder and 20g sodium bicarbonate are mixed, and stirs 15~20s in net slurry blender, keep it mixed It closes uniformly, is then added in the epoxide-resin glue of 200mL, stir 3~4min with high-speed mixer, mix it uniformly Close colloid；

Embodiment 10

The present embodiment 10 provides a kind of suction wave composite plate, as shown in Figure 1, the suction wave composite plate is from outward appearance to inner essence successively arranged Electromgnetically-transparent layer 1, electromagnetic wave depletion layer 2 and reflection of electromagnetic wave layer 3, the Electromgnetically-transparent layer 1 by embodiment 1 electromagnetic wave Composite material composition is transmitted, the electromagnetic wave depletion layer 2 is made of the electromagnetic wave loss composite material of embodiment 5, the electromagnetism Wave reflection layer 3 is made of metal plate.

Embodiment 11

The present embodiment 11 provides a kind of suction wave composite plate, as shown in Figure 1, the suction wave composite plate is from outward appearance to inner essence successively arranged Electromgnetically-transparent layer 1, electromagnetic wave depletion layer 2 and reflection of electromagnetic wave layer 3, the Electromgnetically-transparent layer 1 by embodiment 2 electromagnetic wave Composite material composition is transmitted, the electromagnetic wave depletion layer 2 is made of the electromagnetic wave loss composite material of embodiment 6, the electromagnetism Wave reflection layer 3 is made of metal plate.

Embodiment 12

The present embodiment 12 provides a kind of suction wave composite plate, as shown in Figure 1, the suction wave composite plate is from outward appearance to inner essence successively arranged Electromgnetically-transparent layer 1, electromagnetic wave depletion layer 2 and reflection of electromagnetic wave layer 3, the Electromgnetically-transparent layer 1 by embodiment 3 electromagnetic wave Composite material composition is transmitted, the electromagnetic wave depletion layer 2 is made of the electromagnetic wave loss composite material of embodiment 7, the electromagnetism Wave reflection layer 3 is made of metal plate.

Embodiment 13

The present embodiment 13 provides a kind of suction wave composite plate, as shown in Figure 1, the suction wave composite plate is from outward appearance to inner essence successively arranged Electromgnetically-transparent layer 1, electromagnetic wave depletion layer 2 and reflection of electromagnetic wave layer 3, the Electromgnetically-transparent layer 1 by embodiment 4 electromagnetic wave Composite material composition is transmitted, the electromagnetic wave depletion layer 2 is made of the electromagnetic wave loss composite material of embodiment 8, the electromagnetism Wave reflection layer 3 is made of metal plate.

Embodiment 14

The present embodiment 14 provides a kind of suction wave composite plate, as shown in Figure 1, the suction wave composite plate is from outward appearance to inner essence successively arranged Electromgnetically-transparent layer 1, electromagnetic wave depletion layer 2 and reflection of electromagnetic wave layer 3, the Electromgnetically-transparent layer 1 by embodiment 1 electromagnetic wave Composite material composition is transmitted, the electromagnetic wave depletion layer 2 is made of the electromagnetic wave loss composite material of embodiment 9, the electromagnetism Wave reflection layer 3 is made of metal plate.

Comparative example 1

A kind of alkali-activated slag cementitious material, preparation method include the following steps:

(2) it prepares alkali-activated slag cementitious material: 140g flyash and 60g slag is added in net slurry blender, stirring 120~150s obtains mixing grey body, 64g alkali-activator is then added, stirs 4~5min, obtains alkali-activated slag gelling material Material.

Comparative example 2

A kind of composite material, preparation method include the following steps:

(2) it prepares alkali-activated slag cementitious material: 140g flyash and 60g slag is added in net slurry blender, stirring 120~150s obtains mixing grey body, 64g alkali-activator is then added, stirs 4~5min, obtains alkali-activated slag gelling material Material；

(3) 200g alkali-activated slag cementitious material and 40g expanded polystyrene particle are added in net slurry blender, stirring 4~5min is uniformly mixed it, then sequentially adds 2g gum arabic powder and 5mLFP-180 animal foaming agent, stirring 20 Then the material being stirred is fitted into mold and is stood 3h rapidly, crust prescinded after molding, then demoulding, obtained by~25s Test block；

(4) test block is put into still kettle, steam pressure 8h at 180 DEG C, be then placed in temperature be 20 DEG C, humidity be 95% support It is conserved 3 days in protecting box, obtains composite material.

The expanded polystyrene particle that comparative example 2 uses is the common expanded polystyrene particle of commercially available purchase, and is used It is preceding not make any pretreatment to it.

Comparative example 3

(1) it prepares alkali-activator: water, waterglass and sodium hydroxide is mixed, stir 10~15min, be then allowed to stand for 24 hours, Obtain alkali-activator；It counts in mass ratio, water: waterglass: sodium hydroxide=50:1:2；

(2) it prepares alkali-activated slag cementitious material: 700g flyash and 300g slag is added in net slurry blender, stirring 120~150s obtains mixing grey body, 320g alkali-activator is then added, stirs 4~5min, obtains alkali-activated slag gelling material Material.

Comparative example 4

A kind of composite material, preparation method include the following steps:

(3) 1000g alkali-activated slag cementitious material and 125g nickel coated copper powder are mixed, and stirs 4 in net slurry blender ~5min, is then charged into mold, and in the 15~20s that vibrates on platform that vibrates, is then placed in curing box, temperature be 20 DEG C, Demoulding for 24 hours is conserved under the environmental condition that humidity is 95%, maintenance 3 is continued under identical environmental condition to the material after demoulding It is to get the composite material.

The nickel coated copper powder that comparative example 4 uses does not carry out any pretreatment.

Effect example

One, Electromgnetically-transparent performance test

By the Electromgnetically-transparent composite material of embodiment 1, the alkali-activated slag cementitious material of comparative example 1 and comparative example 2 The template of equivalent specifications is made in composite material, carries out Electromgnetically-transparent performance test.

Test method (arch method): in microwave dark room, pass through from transmitting antenna and reach receiving antenna again with reference to metal plate Electromagnetic wave power be P1, it is P2, the suction wave of absorbing material that reference metal plate, which is changed to, and reaches the power of receiving antenna after template Reflectivity are as follows: the ㏒ of ┏=10 (P1/P2).

Test results are shown in figure 2, and in Fig. 2, A1 is the electricity of template made of the alkali-activated slag cementitious material of comparative example 1 For magnetic wave reflection loss with the change curve of frequency, A2 is the reflection of electromagnetic wave loss of template made of the composite material of comparative example 2 With the change curve of frequency, A3 be template made of the Electromgnetically-transparent composite material of embodiment 1 reflection of electromagnetic wave loss with The change curve of frequency.

Interpretation of result: as can be seen from Figure 2, the electromagnetic wave of template made of the Electromgnetically-transparent composite material with embodiment 1 Transmission performance is best, it can also be seen that, compared with cementitious material, Electromgnetically-transparent composite material of the invention has significantly superior different Electromagnetic transmission performance, also illustrate that modified foaming granules of polystyrene prepared by the present invention can effectively improve the electromagnetism of composite material Transmission performance.

Two, electromagnetic wave drain performance is tested

By the electromagnetic wave loss composite material of embodiment 5, the alkali-activated slag cementitious material of comparative example 3 and comparative example 4 The template of equivalent specifications is made in composite material, carries out the test of electromagnetic wave drain performance.

Test method (arch method): in microwave dark room, pass through from transmitting antenna and reach receiving antenna again with reference to metal plate Electromagnetic wave power be P1, it is P2, the then suction of absorbing material that reference metal plate, which is changed to, and reaches the power of receiving antenna after template Wave reflection rate are as follows: the ㏒ of ┏=10 (P1/P2).

Test results are shown in figure 3, and in Fig. 3, B is the electricity of template made of the alkali-activated slag cementitious material of comparative example 3 Electro-magnetic wave absorption be lost with frequency change curve, C be comparative example 4 composite material made of template electro-magnetic wave absorption loss with The change curve of frequency, D are that the electro-magnetic wave absorption loss of template made of composite material is lost with frequency in the electromagnetic wave of embodiment 5 Change curve.

Interpretation of result: from figure 3, it can be seen that template made of composite material is lost to electromagnetic wave with the electromagnetic wave of embodiment 5 The effect of absorption loss is best, it can also be seen that, compared with cementitious material, electromagnetic wave loss composite material of the invention has obvious Superior electromagnetic absorption drain performance also illustrates that the porous colloidal solid prepared by the present invention containing nickel coated copper powder can effectively improve The electromagnetic absorption drain performance of composite material.

Three, electro-magnetic wave absorption drain performance is tested

The electromagnetic wave of the suction wave composite plate of embodiment 10 and embodiment 5 loss composite material is made to the sample of equivalent specifications Plate carries out the test of electro-magnetic wave absorption drain performance.

Test results are shown in figure 4, and in Fig. 4, A is that the electricity of template made of composite material is lost in the electromagnetic wave of embodiment 5 The change curve with frequency is lost in electro-magnetic wave absorption, and B is the electro-magnetic wave absorption damage for inhaling template made of wave composite plate of embodiment 10 Consume the change curve with frequency.

Interpretation of result: as can be seen from Figure 4, compared with composite material is lost in the electromagnetic wave of single layer structure, three layers of difference are equipped with The suction wave composite plate of functional layer is more preferable to the absorption loss function of electromagnetic wave.

Inventor has also carried out same electro-magnetic wave absorption drain performance to the suction wave composite plate of embodiment 11~14 and has tested, Test result is shown: the electro-magnetic wave absorption drain performance of suction wave composite plate and approaching for embodiment 10 of embodiment 11~14 are said The bright present invention, which prepares resulting suction wave composite plate, has excellent electro-magnetic wave absorption drain performance, the building suitable for electromagnetic shielding Structure.

The embodiment of the present invention is merely illustrative of the technical solution of the present invention rather than its limitations, although referring to above-mentioned implementation Invention is explained in detail for example, it should be understood by those ordinary skilled in the art that: still can be to of the invention Specific embodiment is modified or replaced equivalently, and any modification without departing from spirit and scope of the invention or is equally replaced It changes, is intended to be within the scope of the claims of the invention.

Claims

1. a kind of suction wave composite plate, which is characterized in that Electromgnetically-transparent layer, electromagnetic wave including from outward appearance to inner essence setting gradually are lost Layer and reflection of electromagnetic wave layer, the Electromgnetically-transparent layer includes Electromgnetically-transparent composite material, and the electromagnetic wave depletion layer includes Composite material is lost in electromagnetic wave；

The preparation method of the Electromgnetically-transparent composite material includes the following steps: that epoxide-resin glue 1. is added in sodium bicarbonate In, it is uniformly mixed, obtains mixture A；2. silane coupling agent is added in the mixture A, it is uniformly mixed, foaming is then added Granules of polystyrene is uniformly mixed, and after the surface of granules of polystyrene to be foamed is wet completely, alkali-activated slag gelling is added Material is uniformly mixed, obtains mixture B；3. being vibrated, before the mixture B initial set to separate particle, by particle water Bath heating, is then allowed to stand, obtains modified foaming granules of polystyrene；4. by alkali-activated slag cementitious material and the modified foaming Granules of polystyrene is uniformly mixed, and then sequentially adds foam stabilizer and foaming agent, is uniformly mixed, is then quickly charged in mold, Demoulding after sizing, obtains test block；5. the test block is carried out steam pressure, maintenance to get the Electromgnetically-transparent composite material；

The preparation method of the electromagnetic wave loss composite material includes the following steps: 1. to mix nickel coated copper powder and sodium bicarbonate Uniformly, it is then added in epoxide-resin glue, is uniformly mixed, obtains complex colloid；2. the complex colloid is instilled dropwise sweet In oil, solidification, the colloidal solid hardened are stood；3. the colloidal solid is heated in a water bath, it is then allowed to stand, obtains more Hole colloidal solid；4. alkali-activated slag cementitious material and the porous colloidal solid are uniformly mixed, it is then charged into mold, so After vibrate, conserve, demoulding, conserve composite material is lost to get the electromagnetic wave again.

2. inhaling wave composite plate as described in claim 1, which is characterized in that the preparation method of the alkali-activated slag cementitious material Are as follows: flyash is uniformly mixed with slag, mixing grey body is obtained, alkali-activator then is added into the mixing grey body, mix Uniformly to get the alkali-activated slag cementitious material；

Preferably, it counts in mass ratio, flyash: slag=(7:5)~(10:3)；

Most preferably, it counts in mass ratio, flyash: slag=7:3；

Preferably, it counts in mass ratio, mixes grey body: alkali-activator=1:(0.3~0.5)；

Preferably, it counts in mass ratio, mixes grey body: alkali-activator=1:(0.4~0.5)；

Preferably, it counts in mass ratio, mixes grey body: alkali-activator=1:(0.3~0.35)；

The alkali-activator the preparation method comprises the following steps: water, waterglass and sodium hydroxide are uniformly mixed, be then allowed to stand for 24 hours to get institute State alkali-activator；

Preferably, it counts in mass ratio, water: waterglass: sodium hydroxide=(45~55): 1:2；

Most preferably, it counts in mass ratio, water: waterglass: sodium hydroxide=50:1:2.

3. inhaling wave composite plate as described in claim 1, which is characterized in that the preparation method of the Electromgnetically-transparent composite material The step of 1. in, based on mass volume ratio, sodium bicarbonate: epoxide-resin glue=2~3g:20~30mL；Preferably, the electromagnetism Wave transmit composite material preparation method the step of 1. in, based on mass volume ratio, sodium bicarbonate: epoxide-resin glue=2.5g: 25mL；

The step of preparation method of the Electromgnetically-transparent composite material 2. in, silane coupling agent, mixture A, foaming polyphenyl second The proportion of alkene particle and alkali-activated slag cementitious material is silane coupling agent: mixture A: expanded polystyrene particle: alkali-activated carbonatite Slag gel material=1~1.5mL:10~12mL:10~11mL:18~22g；Preferably, the Electromgnetically-transparent composite wood The step of preparation method of material 2. in, silane coupling agent, mixture A, expanded polystyrene particle and alkali-activated slag are gelled material The proportion of material is silane coupling agent: mixture A: expanded polystyrene particle: alkali-activated slag cementitious material=1mL:10mL: 10mL:20g。

4. inhaling wave composite plate as described in claim 1, which is characterized in that the preparation method of the Electromgnetically-transparent composite material The step of 2. in, expanded polystyrene particle is before use, being first washed with deionized water and drying；

The step of preparation method of the Electromgnetically-transparent composite material 3. in, particle is heated 10 in 65~75 DEG C of water-bath ~15min is then allowed to stand for 24 hours, obtains the modified foaming granules of polystyrene.

5. inhaling wave composite plate as described in claim 1, which is characterized in that the preparation method of the Electromgnetically-transparent composite material The step of 4. in, count in mass ratio, alkali-activated slag cementitious material: modified foaming granules of polystyrene=(4~6): 1；It is preferred that The step of ground, the preparation method of the Electromgnetically-transparent composite material 4. in, count in mass ratio, alkali-activated slag cementitious material: Modified foaming granules of polystyrene=5:1；

The step of preparation method of the Electromgnetically-transparent composite material 4. in, foam stabilizer, foaming agent and modified foaming polyphenyl second The proportion of alkene particle is foam stabilizer: foaming agent: modified foaming granules of polystyrene=2~4g:5~7mL:40~50g；

Preferably, the step of preparation method of the Electromgnetically-transparent composite material 4. in, foam stabilizer, foaming agent and modified foaming The proportion of granules of polystyrene is foam stabilizer: foaming agent: modified foaming granules of polystyrene=2g:5mL:44g；

Preferably, the step of preparation method of the Electromgnetically-transparent composite material 4. in, foam stabilizer is gum arabic powder；

Preferably, the step of preparation method of the Electromgnetically-transparent composite material 4. in, foaming agent be FP-180 animality hair Infusion.

6. inhaling wave composite plate as described in claim 1, which is characterized in that the preparation method of the Electromgnetically-transparent composite material The step of 5. in, test block is put into still kettle, steam pressure 8h at 175~185 DEG C, be then placed in curing box conserve 3 days to get The Electromgnetically-transparent composite material；Preferably, the temperature of the curing box be 20 DEG C, humidity 95%.

7. inhaling wave composite plate as described in claim 1, which is characterized in that the preparation method of the electromagnetic wave loss composite material The step of 1. in, based on mass volume ratio, nickel coated copper powder: sodium bicarbonate: epoxide-resin glue=8~12g:2~3g:18~ 22mL；

Preferably, the step of preparation method of electromagnetic wave loss composite material 1. in, based on mass volume ratio, nickel copper-clad Powder: sodium bicarbonate: epoxide-resin glue=10g:2.5g:20mL；

The step of preparation method of electromagnetic wave loss composite material 4. in, count in mass ratio, alkali-activated slag cementitious material: Porous colloidal solid=8:1~10:1.

8. inhaling wave composite plate as described in claim 1, which is characterized in that the preparation method of the electromagnetic wave loss composite material The step of 3. in, colloidal solid is heated into 10~15min in 65~75 DEG C of water-bath, is then allowed to stand for 24 hours, obtains porous colloid Particle；

The concrete operations of the step of preparation method of the electromagnetic wave loss composite material 4. are as follows: by alkali-activated slag cementitious material It is uniformly mixed, is then charged into mold, vibrate 15~20s, is then placed in curing box and conserves with the porous colloidal solid For 24 hours, demoulding continues maintenance 3 days to the material after demoulding and composite material is lost to get the electromagnetic wave；Preferably, the maintenance It is carried out under the environmental condition that temperature is 20 DEG C, humidity is 95%.

9. suction wave composite plate as described in any one of claims 1 to 8, which is characterized in that the reflection of electromagnetic wave layer includes gold Belong to plate.

10. wave composite plate as described in any one of claims 1 to 9 of inhaling is in the application in wave-absorbing material applied to buildings field.