CN109049219A - A kind of wicker modification processing method for braiding - Google Patents
A kind of wicker modification processing method for braiding Download PDFInfo
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- CN109049219A CN109049219A CN201810899576.4A CN201810899576A CN109049219A CN 109049219 A CN109049219 A CN 109049219A CN 201810899576 A CN201810899576 A CN 201810899576A CN 109049219 A CN109049219 A CN 109049219A
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
- B27K3/52—Impregnating agents containing mixtures of inorganic and organic compounds
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K5/00—Treating of wood not provided for in groups B27K1/00, B27K3/00
- B27K5/003—Treating of wood not provided for in groups B27K1/00, B27K3/00 by using electromagnetic radiation or mechanical waves
- B27K5/0055—Radio-waves, e.g. microwaves
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K9/00—Chemical or physical treatment of reed, straw, or similar material
- B27K9/002—Cane, bamboo
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- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Forests & Forestry (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Electromagnetism (AREA)
- Mechanical Engineering (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention discloses a kind of wicker modification processing methods for braiding, belong to wicker processing technology field, comprising the following steps: (1) wicker pre-processes;(2) immersion treatment;(3) radiation treatment;(4) ultra-violet curing is handled.Modification processing method treated wicker has good comprehensive performance through the invention, surface texture is finer and close, and acid and alkali-resistance, anti-corrosion, anti-aging property enhancing, toughness increase, it is easier to the preparation of wicker products, there is good economic benefit and market popularization value.
Description
Technical field
The invention belongs to wicker processing technology fields, and in particular to a kind of wicker modification processing method for braiding.
Background technique
Wicker plaiting article is one of folks of china traditional handicraft product.People are intended only as common daily utility in ancient times, directly
Decades just gradually rise after to 20th century, also the project for becoming selected areas of China foreign exchange earning gradually.The whole nation has three big
Wicker plaiting article production base, Hubei, Shandong, Anhui (in addition Henan also abounds with wicker plaiting article).Wicker soft pliable, thickness are well-balanced, color is high
It is refined, by novel design, natural, handsome in appearance, Portable durable the practical art product of various honesties can be woven into.Its product
It include: crate (packet), meal basket, food basket (circle, ellipse), bamboo strainer, needlework shallow basket made of wicker or thin bamboo strips, kang mat, reed matting etc..
It is natural, handsome in appearance, light can to weave various honesties by novel design for material of the wicker as wicker plaiting article
Just durable practical art product, as industry continues to develop, product is constantly brought forth new ideas, and has the wicker plaiting article of more more tired more Nover practical beauties
Product shows, however since wicker is pure natural plant fiber, humidity and drying, do not cause mechanical property to reduce, and hold
Easily mildew fracture, and infected vulnerable to ultraviolet light, thus aging, these all seriously restrict the further development of product, if
Wicker is pre-processed before establishment, improves its adaptability to external environment, improves mechanical property, improves wicker products
Quality and quality.
Summary of the invention
The purpose of the present invention is being directed to existing problem, a kind of wicker modification processing method for braiding is provided.It is logical
Cross modification processing method of the present invention treated that wicker has good comprehensive performance, surface texture is finer and close, acid and alkali-resistance, anti-
Rotten, anti-aging property enhancing, toughness increase, it is easier to which the preparation of wicker products has good economic benefit and marketing
Value.
The present invention is achieved by the following technical solutions:
A kind of wicker modification processing method for braiding, comprising the following steps:
(1) wicker pre-processes:
A. mud is taken in the rice field of long-term rice cultivation, it is 35-37% that mud and tap water, which are stirred and evenly mixed to moisture content, is obtained
Paste;
B. the surface for the obtained paste of a will be operated being coated to peeling wicker, coating with a thickness of 8-10mm, after the completion of coating
Wicker is placed in 36-40 DEG C of environment and stands 7-9h;
C. wicker surface, the paste of removal wicker performance are washed after rushing operation b processing with tap water, then are placed in 60-70 DEG C of environment
In be dried, it is dry to surface moisture content be 28-34%;
(2) immersion treatment:
The wicker obtained in step (1) after pretreatment is placed in treatment fluid and is impregnated, specific frequency while immersion
Ultrasonic wave is handled, and after immersion treatment 2-3h, it is drained and standby to take out wicker;
(3) radiation treatment:
Wicker after immersion treatment in step (2) is placed in irradiation instrument and carries out radiation treatment, the form of radiation treatment is infrared ray,
The time of radiation treatment is 10-16min;
(4) ultra-violet curing is handled: the wicker after radiation treatment in step (3) being placed in uv curing machine and is carried out at ultra-violet curing
Reason, ultraviolet wavelength are 230-250nm, and the time of ultra-violet curing processing is 40-50min.
Further, the frequency of ultrasonic wave is 45-49kHz in the step (2).
Further, in the step (2) treatment fluid preparation, including following operation:
1) 6-8 parts of 8-10 parts of 18-20 parts of modified nano zinc oxide, bentonite, sulfuric acid holmium, the isoprene of corresponding parts by weight are weighed
3-5 parts, 7-9 parts of nano silica, 6-7 parts of lutecium chloride, 10-12 parts of alpha-terpineol, 8-20 parts of aromatic alcohol, sterile water 1000-
1100 parts spare.
2) 1) weighed material composition will be operated to be collectively disposed in reaction kettle, the pressure control in reaction kettle is 120-130
DEG C, the pressure control in reaction kettle is 0.4-0.5MPa, stir process 50-60min.
Further, the preparation method of modified nano zinc oxide is in the operation 1): by nano zine oxide and modification liquid
It is that 1:4-5 is collectively disposed in agitator tank according to weight ratio, the temperature being kept stirring in tank is 90-100 DEG C, stir process 35-
45min when temperature is down to room temperature in tank to be mixed, takes out nano zine oxide and is placed in baking oven and is dried, dry to be to constant weight
Can, dry the temperature inside the box control is 57-63 DEG C.
Further, the modification liquid is made of following parts by weight of component: 5-6 parts of silane coupling agent, polyethylene glycol 2000
2-4 parts, 4-5 parts of polysorbas20,8-10 parts of glycerol, 3-6 parts of paratoluenesulfonic acid sodium salt, 120-140 parts of sterile water.
Further, the wavelength of infrared ray is 40-50 μm in the step (3).
The present invention provides a kind of wicker modification processing methods for braiding, pre-process first to wicker, by mud
The surface that paste is coated in wicker is made in slurry, decompose to wicker surface using substances such as microorganisms in mud and soft
Change, is conducive to the uniformity for improving surface, is subsequently placed in 60-70 DEG C of environment and is dried, the fiber on wicker surface can be made to rise
It rises, establishes excellent basis for subsequent operation.Then the wicker after pretreatment is placed in treatment fluid and is impregnated, super
Modified nano zinc oxide, bentonite, sulfuric acid holmium, isoprene, nano silica under the synergism of sound wave, in treatment fluid
Etc. effective components and wicker combination it is even closer, wherein modified nano zinc oxide, bentonite, nano silica collaboration are made
With the specific surface area on raising wicker surface enhances the compactness and that corrosivity on wicker surface, forms well on wicker surface
Electrochemical protection and physics radiation shielding action institutional framework, and modified nano zinc oxide and nano silica can
The absorbance on wicker surface is improved, enhances the anti-ultraviolet ability of wicker, extends the service life of wicker;Sulfuric acid holmium, lutecium chloride
It acts synergistically with nano silica, huge network molecular structure can be formed on wicker surface, the machinery of wicker can be made
Performance and weatherability are greatly improved, and the toughness of wicker is enhanced;Isoprene, alpha-terpineol, aromatic alcohol have the work of antibacterial, deinsectization
With wicker insect prevention, mould proof performance can be enhanced well.Wicker is placed in irradiation instrument after immersion treatment, carries out infrared ray
Radiation treatment, infrared ray have transmission capacity, thermal energy can be converted into the intersection for the treatment of fluid and wicker, to promote treatment fluid
In effective component be deep into inside wicker, further improve the performance of modified effect, furthermore can also play dry effect.
Wicker is finally placed in ultraviolet lower carry out curing process, the effective component in treatment fluid absorbs the ultraviolet light of specific wavelength, decomposes
Active group is generated, the polymerization reaction for causing film forming matter occurs, and forms reticular structure, enhances the toughness of wicker, and further
Effective component in treatment fluid is promoted to play a role.
The present invention has the advantage that compared with prior art
Modification processing method treated wicker has good comprehensive performance through the invention, and surface texture is finer and close, resistance to
Soda acid, anti-corrosion, anti-aging property enhancing, toughness increase, it is easier to which the preparation of wicker products has good economic benefit and city
Field promotional value.
Specific embodiment
Embodiment 1
A kind of wicker modification processing method for braiding, comprising the following steps:
(1) wicker pre-processes:
A. mud is taken in the rice field of long-term rice cultivation, it is 35% that mud and tap water, which are stirred and evenly mixed to moisture content, must be pasted
Shape object;
B. the surface for the obtained paste of a will be operated being coated to peeling wicker, coating with a thickness of 8mm, by willow after the completion of coating
Item is placed in 36 DEG C of environment and stands 7h;
C. wicker surface, the paste of removal wicker performance are washed after rushing operation b processing with tap water, then are placed in 60 DEG C of environment
It is dried, drying to surface moisture content is 28%;
(2) immersion treatment:
The wicker obtained in step (1) after pretreatment is placed in treatment fluid and is impregnated, specific frequency while immersion
Ultrasonic wave is handled, and after immersion treatment 2h, it is drained and standby to take out wicker;
(3) radiation treatment:
Wicker after immersion treatment in step (2) is placed in irradiation instrument and carries out radiation treatment, the form of radiation treatment is infrared ray,
The time of radiation treatment is 10min;
(4) ultra-violet curing is handled: the wicker after radiation treatment in step (3) being placed in uv curing machine and is carried out at ultra-violet curing
Reason, ultraviolet wavelength are 230nm, and the time of ultra-violet curing processing is 40min.
Further, the frequency of ultrasonic wave is 45kHz in the step (2).
Further, in the step (2) treatment fluid preparation, including following operation:
1) 6 parts of 8 parts of 18 parts of modified nano zinc oxide, bentonite, sulfuric acid holmium, isoprene 3 part, nanometer of corresponding parts by weight are weighed
7 parts of silica, 6 parts of lutecium chloride, 10 parts of alpha-terpineol, 8 parts of aromatic alcohol, 1000 parts of sterile water it is spare.
2) 1) weighed material composition will be operated to be collectively disposed in reaction kettle, the pressure control in reaction kettle is 120-130
DEG C, the pressure control in reaction kettle is 0.4MPa, stir process 50min.
Further, the preparation method of modified nano zinc oxide is in the operation 1): by nano zine oxide and modification liquid
It is that 1:4 is collectively disposed in agitator tank according to weight ratio, being kept stirring temperature in tank is 90 DEG C, stir process 35min, to be mixed
When temperature is down to room temperature in tank, taking-up nano zine oxide, which is placed in baking oven, to be dried, drying to constant weight, temperature in drying box
Degree control is 57 DEG C.
Further, the modification liquid is made of following parts by weight of component: 5 parts of silane coupling agent, polyethylene glycol 2000 2
Part, 4 parts of polysorbas20,8 parts of glycerol, 3 parts of paratoluenesulfonic acid sodium salt, 120 parts of sterile water.
Further, the wavelength of infrared ray is 40-50 μm in the step (3).
Embodiment 2
A kind of wicker modification processing method for braiding, comprising the following steps:
(1) wicker pre-processes:
A. mud is taken in the rice field of long-term rice cultivation, it is 36% that mud and tap water, which are stirred and evenly mixed to moisture content, must be pasted
Shape object;
B. the surface for the obtained paste of a will be operated being coated to peeling wicker, coating with a thickness of 9mm, by willow after the completion of coating
Item is placed in 38 DEG C of environment and stands 8h;
C. wicker surface, the paste of removal wicker performance are washed after rushing operation b processing with tap water, then are placed in 65 DEG C of environment
It is dried, drying to surface moisture content is 31%;
(2) immersion treatment:
The wicker obtained in step (1) after pretreatment is placed in treatment fluid and is impregnated, specific frequency while immersion
Ultrasonic wave is handled, and after immersion treatment 2.5h, it is drained and standby to take out wicker;
(3) radiation treatment:
Wicker after immersion treatment in step (2) is placed in irradiation instrument and carries out radiation treatment, the form of radiation treatment is infrared ray,
The time of radiation treatment is 13min;
(4) ultra-violet curing is handled: the wicker after radiation treatment in step (3) being placed in uv curing machine and is carried out at ultra-violet curing
Reason, ultraviolet wavelength are 240nm, and the time of ultra-violet curing processing is 45min.
Further, the frequency of ultrasonic wave is 47kHz in the step (2).
Further, in the step (2) treatment fluid preparation, including following operation:
1) 7 parts of 9 parts of 19 parts of modified nano zinc oxide, bentonite, sulfuric acid holmium, isoprene 4 part, nanometer of corresponding parts by weight are weighed
8 parts of silica, 6.5 parts of lutecium chloride, 11 parts of alpha-terpineol, 14 parts of aromatic alcohol, 1050 parts of sterile water it is spare.
2) 1) weighed material composition will be operated to be collectively disposed in reaction kettle, the pressure control in reaction kettle is 125 DEG C, instead
Answering the pressure in kettle to control is 0.45MPa, stir process 55min.
Further, the preparation method of modified nano zinc oxide is in the operation 1): by nano zine oxide and modification liquid
It is that 1:4.5 is collectively disposed in agitator tank according to weight ratio, the temperature being kept stirring in tank is 95 DEG C, stir process 40min, wait stir
When mixing that temperature is down to room temperature in tank, takes out nano zine oxide and be placed in baking oven and is dried, it is dry to constant weight, in drying box
Temperature control is 60 DEG C.
Further, the modification liquid is made of following parts by weight of component: 5.5 parts of silane coupling agent, polyethylene glycol 2000
3 parts, 4.5 parts of polysorbas20,9 parts of glycerol, 4.5 parts of paratoluenesulfonic acid sodium salt, 130 parts of sterile water.
Further, the wavelength of infrared ray is 45 μm in the step (3).
Embodiment 3
A kind of wicker modification processing method for braiding, comprising the following steps:
(1) wicker pre-processes:
A. mud is taken in the rice field of long-term rice cultivation, it is 37% that mud and tap water, which are stirred and evenly mixed to moisture content, must be pasted
Shape object;
B. the surface for the obtained paste of a will be operated being coated to peeling wicker, coating with a thickness of 10mm, will after the completion of coating
Wicker is placed in 40 DEG C of environment and stands 9h;
C. wicker surface, the paste of removal wicker performance are washed after rushing operation b processing with tap water, then are placed in 70 DEG C of environment
It is dried, drying to surface moisture content is 34%;
(2) immersion treatment:
The wicker obtained in step (1) after pretreatment is placed in treatment fluid and is impregnated, specific frequency while immersion
Ultrasonic wave is handled, and after immersion treatment 3h, it is drained and standby to take out wicker;
(3) radiation treatment:
Wicker after immersion treatment in step (2) is placed in irradiation instrument and carries out radiation treatment, the form of radiation treatment is infrared ray,
The time of radiation treatment is 16min;
(4) ultra-violet curing is handled: the wicker after radiation treatment in step (3) being placed in uv curing machine and is carried out at ultra-violet curing
Reason, ultraviolet wavelength are 250nm, and the time of ultra-violet curing processing is 50min.
Further, the frequency of ultrasonic wave is 49kHz in the step (2).
Further, in the step (2) treatment fluid preparation, including following operation:
1) 5 parts of 8 parts of 10 parts of 20 parts of modified nano zinc oxide, bentonite, sulfuric acid holmium, the isoprene of corresponding parts by weight are weighed, is received
Rice 9 parts of silica, 7 parts of lutecium chloride, 12 parts of alpha-terpineol, 8-20 parts of aromatic alcohol, 1100 parts of sterile water it is spare.
2) 1) weighed material composition will be operated to be collectively disposed in reaction kettle, the pressure control in reaction kettle is 130 DEG C, instead
Answering the pressure in kettle to control is 0.5MPa, stir process 60min.
Further, the preparation method of modified nano zinc oxide is in the operation 1): by nano zine oxide and modification liquid
It is that 1:5 is collectively disposed in agitator tank according to weight ratio, the temperature being kept stirring in tank is 100 DEG C, stir process 45min, wait stir
When mixing that temperature is down to room temperature in tank, takes out nano zine oxide and be placed in baking oven and is dried, it is dry to constant weight, in drying box
Temperature control is 63 DEG C.
Further, the modification liquid is made of following parts by weight of component: 6 parts of silane coupling agent, polyethylene glycol 2000 4
Part, 5 parts of polysorbas20,10 parts of glycerol, 6 parts of paratoluenesulfonic acid sodium salt, 140 parts of sterile water.
Further, the wavelength of infrared ray is 50 μm in the step (3).
Comparative example 1
This comparative example 1 compared with Example 2, saves the pretreated whole operation of step (1) wicker, method step in addition to this
It is rapid all the same.
Comparative example 2
This comparative example 2 compared with Example 2, saves the ultrasonication in step (2) immersion treatment, method in addition to this
Step is all the same.
Comparative example 3
This comparative example 3 compared with Example 2, by modified nano zinc oxide changes into treatment fluid in step (2) immersion treatment
Etc. mass parts non-modified nano zine oxide, method and step in addition to this is all the same.
Comparative example 4
This comparative example 4 compared with Example 2, saves the whole operation of step (3) radiation treatment, method and step in addition to this
It is all the same.
Comparative example 5
This comparative example 5 compared with Example 2, saves the whole operation of step (4) ultra-violet curing processing, method in addition to this
Step is all the same.
Control group
Application No. is a kind of nano micro crystal cellulose for wicker plaiting article wicker-silica solution disclosed in 201510739097.2 to increase
Strong pretreating agent and preparation method thereof.
In order to compare effect of the present invention, select with a collection of wicker, then respectively with embodiment 2, comparative example 1, comparison
Embodiment 2, comparative example 3, comparative example 4, comparative example 5 modification processing method handle wicker, while with compare
The inorganic agent of group handles wicker, and after treatment measures the performance of wicker.
Specific experiment correlation data is as shown in table 1 below:
Table 1
Modification processing method treated wicker has good comprehensive performance, surface through the invention it can be seen from upper table 1
Structure is finer and close, and acid and alkali-resistance, anti-corrosion, anti-aging property enhancing, toughness increase, it is easier to which the preparation of wicker products has very
Good economic benefit and market popularization value.
Claims (6)
1. a kind of wicker modification processing method for braiding, which comprises the following steps:
(1) wicker pre-processes:
A. mud is taken in the rice field of long-term rice cultivation, it is 35-37% that mud and tap water, which are stirred and evenly mixed to moisture content, is obtained
Paste;
B. the surface for the obtained paste of a will be operated being coated to peeling wicker, coating with a thickness of 8-10mm, after the completion of coating
Wicker is placed in 36-40 DEG C of environment and stands 7-9h;
C. wicker surface, the paste of removal wicker performance are washed after rushing operation b processing with tap water, then are placed in 60-70 DEG C of environment
In be dried, it is dry to surface moisture content be 28-34%;
(2) immersion treatment:
The wicker obtained in step (1) after pretreatment is placed in treatment fluid and is impregnated, specific frequency while immersion
Ultrasonic wave is handled, and after immersion treatment 2-3h, it is drained and standby to take out wicker;
(3) radiation treatment:
Wicker after immersion treatment in step (2) is placed in irradiation instrument and carries out radiation treatment, the form of radiation treatment is infrared ray,
The time of radiation treatment is 10-16min;
(4) ultra-violet curing is handled: the wicker after radiation treatment in step (3) being placed in uv curing machine and is carried out at ultra-violet curing
Reason, ultraviolet wavelength are 230-250nm, and the time of ultra-violet curing processing is 40-50min.
2. a kind of wicker modification processing method for braiding according to claim 1, which is characterized in that the step (2)
The frequency of middle ultrasonic wave is 45-49kHz.
3. a kind of wicker modification processing method for braiding according to claim 1, which is characterized in that the step (2)
The preparation of middle treatment fluid, including following operation:
1) 6-8 parts of 8-10 parts of 18-20 parts of modified nano zinc oxide, bentonite, sulfuric acid holmium, the isoprene of corresponding parts by weight are weighed
3-5 parts, 7-9 parts of nano silica, 6-7 parts of lutecium chloride, 10-12 parts of alpha-terpineol, 8-20 parts of aromatic alcohol, sterile water 1000-
1100 parts spare.
2) 1) weighed material composition will be operated to be collectively disposed in reaction kettle, the pressure control in reaction kettle is 120-130 DEG C, instead
Answering the pressure in kettle to control is 0.4-0.5MPa, stir process 50-60min.
4. a kind of wicker modification processing method for braiding according to claim 3, which is characterized in that in the operation 1)
The preparation method of modified nano zinc oxide is: nano zine oxide and modification liquid are collectively disposed at stirring according to weight ratio for 1:4-5
In tank, the temperature being kept stirring in tank is 90-100 DEG C, stir process 35-45min, when temperature is down to room temperature in tank to be mixed,
Taking-up nano zine oxide, which is placed in baking oven, to be dried, and dry to constant weight, dry the temperature inside the box control is 57-63 DEG C.
5. a kind of wicker modification processing method for braiding according to claim 4, which is characterized in that the modification liquid,
It is made of following parts by weight of component: 5-6 parts of silane coupling agent, 2-4 parts of polyethylene glycol 2000,4-5 parts of polysorbas20, glycerol 8-10
Part, 3-6 parts of paratoluenesulfonic acid sodium salt, 120-140 parts of sterile water.
6. a kind of wicker modification processing method for braiding according to claim 1, which is characterized in that the step (3)
The wavelength of middle infrared ray is 40-50 μm.
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CN111438779A (en) * | 2020-03-18 | 2020-07-24 | 阜南县大自然工艺品股份有限公司 | Processing method for improving service strength and service life of wicker product |
CN111941566A (en) * | 2020-08-11 | 2020-11-17 | 阜南县德盛隆工艺家具有限公司 | Method for manufacturing wicker handicraft |
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CN111136742B (en) * | 2019-12-31 | 2021-05-04 | 阜南县天亿工艺品有限公司 | Method for improving durability of fast-growing wood furniture |
CN111438779A (en) * | 2020-03-18 | 2020-07-24 | 阜南县大自然工艺品股份有限公司 | Processing method for improving service strength and service life of wicker product |
CN111941566A (en) * | 2020-08-11 | 2020-11-17 | 阜南县德盛隆工艺家具有限公司 | Method for manufacturing wicker handicraft |
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