CN109045931A - A kind of box-like flue gas pollutant cooperation-removal device of horizontal group - Google Patents

A kind of box-like flue gas pollutant cooperation-removal device of horizontal group Download PDF

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Publication number
CN109045931A
CN109045931A CN201811091600.8A CN201811091600A CN109045931A CN 109045931 A CN109045931 A CN 109045931A CN 201811091600 A CN201811091600 A CN 201811091600A CN 109045931 A CN109045931 A CN 109045931A
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CN
China
Prior art keywords
shell
flue gas
removal device
box
absorbing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201811091600.8A
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Chinese (zh)
Inventor
赵玉良
崔冬
庞杭州
张帆
徐鸿钧
徐永华
师浩浩
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China National Heavy Machinery Research Institute Co Ltd
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China National Heavy Machinery Research Institute Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by China National Heavy Machinery Research Institute Co Ltd filed Critical China National Heavy Machinery Research Institute Co Ltd
Priority to CN201811091600.8A priority Critical patent/CN109045931A/en
Publication of CN109045931A publication Critical patent/CN109045931A/en
Pending legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D46/00Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
    • B01D46/30Particle separators, e.g. dust precipitators, using loose filtering material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/04Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/54Nitrogen compounds
    • B01D53/56Nitrogen oxides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/76Gas phase processes, e.g. by using aerosols
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2251/00Reactants
    • B01D2251/10Oxidants
    • B01D2251/104Ozone
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2251/00Reactants
    • B01D2251/10Oxidants
    • B01D2251/106Peroxides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2251/00Reactants
    • B01D2251/20Reductants
    • B01D2251/206Ammonium compounds
    • B01D2251/2062Ammonia
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2251/00Reactants
    • B01D2251/40Alkaline earth metal or magnesium compounds
    • B01D2251/404Alkaline earth metal or magnesium compounds of calcium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2253/00Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10Inorganic adsorbents
    • B01D2253/102Carbon
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/30Sulfur compounds
    • B01D2257/302Sulfur oxides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/40Nitrogen compounds
    • B01D2257/404Nitrogen oxides other than dinitrogen oxide
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/60Heavy metals or heavy metal compounds
    • B01D2257/602Mercury or mercury compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2258/00Sources of waste gases
    • B01D2258/02Other waste gases
    • B01D2258/0283Flue gases

Abstract

A kind of box-like flue gas pollutant cooperation-removal device of horizontal group, including shell, the different zones of shell are each passed through multiple absorbing cabins, the top of absorbing cabin is connect with feeding bin, the bottom of absorbing cabin is connected with discharge bin, and discharge bin connects removal device, is provided with conveyer below removal device;The intermediate position of shell is provided with blowing mouth B and denitration mixer;When use, flue gas enters from the import A of shell, enter second absorbing cabin after first absorbing cabin reduces dust, for demercuration, into desulfurization absorbing cabin scrubbing CO_2, enters blowing area, ammonia or oxidant later and sprayed into via blowing mouth B, pass through ribbon mixer later, mixes ammonia or oxidant and flue gas uniformly.Through entering denitration region after mixed uniformly flue gas, by several absorbing cabins, the outlet C through shell is expelled to rear portion discharge after removing nitrogen oxides;The present invention have reduce absorbent consumption, improve processing specific aim and overall operation economy the advantages of.

Description

A kind of box-like flue gas pollutant cooperation-removal device of horizontal group
Technical field
The invention belongs to environmental technology fields, and in particular to a kind of box-like flue gas pollutant cooperation-removal device of horizontal group.
Technical background
With the fast development of China's economic society, the emission request of each pollutant is also continuously improved.Correspondingly, right The dedusting of industrial smoke, desulphurization and denitration, the requirement of de- dioxin and demercuration are also higher and higher.Currently, having developed for flue gas The many kinds of solids absorbent of improvement, such as particle calcium base and activated coke absorbent.Wherein activated coke is to flue gas desulfurization, denitration, de- The integrative coordinated processing capacity of mercury and de- dioxin is most strong, and therefore the scope of application is also wider, and current application is more universal.But it is right Regular activated coke, since it is limited to the removing ability of Elemental Mercury, it is therefore necessary to the activated coke through special modification is used, by This makes the higher cost using demercuration activated coke.The activated coke for having adsorbed mercury belongs to dangerous solid waste, it is necessary to by professional machine Structure processing, expense are also very high.In view of above-mentioned application characteristic, moving-bed type activated coke desulfurization denitration system currently on the market System, since structure limits, it is necessary to which same batch of activated coke mixing and absorption all contaminants and a batch concentration discharge are bound to cause in this way It purchases and processing cost is larger, economy is bad.In addition, existing system is damaged big there is also absorbent, flue gas fluctuation is fitted Answering property is poor, and the detection and temperaturing lifting abnormality to temperature change handle the problems such as difficult.These so that it can not meet market very well It is required that, it is necessary to the new construction and corresponding process system that exploitation adapts to therewith.
Summary of the invention
In order to overcome the above-mentioned deficiencies of the prior art, dirty it is an object of the invention to propose a kind of box-like flue gas of horizontal group Object cooperation-removal device is contaminated, can aid in reduction operating cost, reduces absorbent consumption, improves the specific aim of processing and whole The economy of running body;Disposition absorbent can be collected separately.
In order to achieve the above object, the technical solution adopted by the present invention are as follows:
A kind of box-like flue gas pollutant cooperation-removal device of horizontal group, including shell 2, the different zones of shell 2 are worn respectively Multiple absorbing cabins 3 are crossed, the top of absorbing cabin 3 is connect with feeding bin 1, and the bottom of absorbing cabin 3 is connected with discharge bin 5, discharge bin 5 Removal device 6 is connected, the lower section of removal device 6 is provided with conveyer 7;The intermediate position of shell 2 is provided with blowing mouth B and denitration mixing Device 8.
The absorbing cabin 3 is cube structure, and the horizontally arranged of absorbing cabin 3 has 2-5 width for 10-20mm Separate cavities 9.
Part of the absorbing cabin 3 inside shell 2 is constituted using netted or shutter steel plate.
Along the vertical direction in absorbent channel, staggeredly welding multi-group hole spaced apart in the absorbing cabin 3 Arc supporting plate 10.
The feeding bin 1 is welded into the working box for being used to store absorbent of sealing using steel plate, working box Top is provided with automatic distributing mechanism.
The shell 2 is arranged in parallel with multiple, and the air inlet of each shell 2 vertically connects inlet manifold 11, each shell The gas outlet of body 2 vertically connects outlet general pipeline 12.
The air inlet of the shell 2 is provided with flue gas even distribution mechanism.
The shell 2 is arranged in the support 4 of steelframe or concrete;The outside of shell 2 is coated using thermal insulation material.
The different parts of 2 length direction of shell are separately installed with temperature, pressure transmitter.
Beneficial effects of the present invention:
The different zones of inventive shell 2 are each passed through multiple absorbing cabins 3, convenient for reasonable Arrangement dedusting, desulfurization, demercuration and Denitration region is also convenient for loading different types of absorbent respectively, improves the specific aim of processing and the economy of overall operation.It is right For the dangerous waste absorbent of demercuration, disposition can be collected separately;It also helps and subregion replacement absorbent is determined according to control target, mention The utilization rate of high-selenium corn agent is equally beneficial for reducing operating cost, reduces absorbent consumption.Dedusting absorbent channel also can be used The absorbent of rest part discharge.
Detailed description of the invention
Fig. 1 is the structural diagram of the present invention.
Fig. 2 is the top view of absorbing cabin of the present invention.
Fig. 3 is the schematic diagram arranged in parallel of inventive shell.
Specific embodiment
The present invention will be further explained below with reference to the attached drawings.
Shown in referring to Fig.1, a kind of box-like flue gas pollutant cooperation-removal device of horizontal group, including shell 2, shell 2 is not Multiple absorbing cabins 3 are each passed through with region, the top of absorbing cabin 3 is connect with feeding bin 1, and the bottom of absorbing cabin 3 is connected with discharge Storehouse 5, discharge bin 5 connect removal device 6, and the lower section of removal device 6 is provided with conveyer 7;The intermediate position of shell 2 is provided with spray ammonia mouth B and denitration mixer 8.The shell 2 is arranged in the support 4 of steelframe or concrete.
Referring to shown in Fig. 2, the absorbing cabin 3 is cube structure, and the horizontally arranged of absorbing cabin 3 has 2-5 a wide Degree is the separate cavities 9 of 10-20mm.It is spaced apart to interlock along the vertical direction in absorbent channel in the absorbing cabin 3 Weld multi-group hole arc support plate 10.
Referring to shown in Fig. 3, shell 2 is arranged in parallel with multiple, and the air inlet of each shell 2 vertically connects inlet manifold 11, The gas outlet of each shell 2 vertically connects outlet general pipeline 12.
The working principle of the invention is for using activated coke:
When work, flue gas enters from the import A of shell 2, posteriorly moves under the action of blower in tail portion.First pass around One absorbing cabin 3.Pollutant effects are removed to reduce dust to rear portion, this storehouse is to carry out powder filtering filtration storehouse using particulate matter. Filtering absorption of agent can be used the absorbent of other absorbing cabin discharges, convenient for reducing the consumption of new absorbent.Flue gas after dedusting into Enter second absorbing cabin 3, loads dedicated demercuration absorbent herein for demercuration.Flue gas is after demercuration, into desulfurization zone, by number A desulfurization absorbing cabin, scrubbing CO_2 enter the area Pen An later.Ammonia is sprayed into via blowing mouth B, passes through thread mixing later Device 8 mixes ammonia and flue gas uniformly.Through entering denitration region after mixed uniformly flue gas, by several absorbing cabins 3, removing Outlet C after nitrogen oxides through shell 2 is expelled to rear portion discharge.
Absorbent in absorbing cabin 3 is provided by feeding bin 1, via each 3 channel of absorbing cabin, periodically or by outlet is polluted Object exit concentration testing result determines efflux time.The absorbent of adsorption saturation via discharge bin 5, removal device 6 and conveyer 7, Regeneration or unified disposition are sent to after centralized collection.Demercuration dangerous waste absorbent centrally disposes after being collected separately.In operational process, such as It detects that any 3 temperature of absorbing cabin is excessively high, can determine whether to take being passed through inert gas or the quickly suction of discharge this part after burning The methods of agent is received to be handled.
When amount of sulfur contenting in smoke is higher, to eliminate influence of the sulfur dioxide to demercuration, can after dedusting next stage absorbing cabin Desulphurizing activated coke is loaded, a part of sulfur dioxide is first deviate from, later, flue gas enters back into demercuration absorbing cabin and carries out demercuration, and demercuration is inhaled Receiving agent can be used such as modified load bromine or carries sulphur activated coke, for carrying out the oxidation and absorption of Elemental Mercury.After adsorption saturation, our department Point dangerous waste activated coke can be handled individually.
The flue gas or leading portion generate to burning natural gas has desulfurizer, big at present such as the sintering machine of steel industry Have been provided with ammonia desulfuration equipment more.It has not needed to carry out desulfurization again for such, can remove present apparatus leading portion dust-removal and desulfurizing section, directly Connect arrangement denitration dark zone and denitration region.To activated coke denitrating system, being blown mouth B is spray ammonia mouth.To calcium-base absorbing agent, penetrating It can be the oxidants such as ozone, hydrogen peroxide, carry out removal of nitrogen oxide by being mixed into denitration region later.
When processing exhaust gas volumn is larger, flue gas is divided equally through inlet manifold 11 in its arrival end and enters each shell 2, in its outlet Discharge is summarized by outlet general pipeline 12 at end., will also be by screening removal fine powder to activated coke to the absorbent of each blowdown discharge, it Regeneration is uniformly sent to afterwards.To calcium-base absorbing agent, sends to and centrally dispose after unified collection.

Claims (9)

1. a kind of box-like flue gas pollutant cooperation-removal device of horizontal group, which is characterized in that including shell (2), shell (2) is no It is each passed through multiple absorbing cabins (3) with region, the top of absorbing cabin (3) is connect with feeding bin (1), and the bottom of absorbing cabin (3) connects It is connected to discharge bin (5), discharge bin (5) connects removal device (6), is provided with conveyer (7) below removal device (6);Shell (2) Intermediate position is provided with spout B and denitration mixer (8).
2. the box-like flue gas pollutant cooperation-removal device of a kind of horizontal group according to claim 1, which is characterized in that described Absorbing cabin (3) be cube structure, absorbing cabin (3) it is horizontally arranged have 2-5 width for 10-20mm separate cavities (9)。
3. the box-like flue gas pollutant cooperation-removal device of a kind of horizontal group according to claim 1, which is characterized in that described Absorbing cabin (3) in the internal part of shell (2) using netted or shutter steel plate composition.
4. the box-like flue gas pollutant cooperation-removal device of a kind of horizontal group according to claim 1, which is characterized in that described Absorbing cabin (3) in along absorbent channel vertical direction, it is spaced apart staggeredly welding multi-group hole arc support plate (10)。
5. the box-like flue gas pollutant cooperation-removal device of a kind of horizontal group according to claim 1, which is characterized in that described Feeding bin (1) using steel plate be welded into sealing for storing the working box of absorbent, the top of working box is provided with Automatic distributing mechanism.
6. the box-like flue gas pollutant cooperation-removal device of a kind of horizontal group according to claim 1, which is characterized in that described Shell (2) be arranged in parallel with multiple, the air inlet of each shell (2) vertically connects inlet manifold (11), each shell (2) Gas outlet vertically connects outlet general pipeline (12).
7. the box-like flue gas pollutant cooperation-removal device of a kind of horizontal group according to claim 1, which is characterized in that described The air inlet of shell (2) be provided with flue gas even distribution mechanism.
8. the box-like flue gas pollutant cooperation-removal device of a kind of horizontal group according to claim 1, which is characterized in that described Shell (2) be arranged in the support (4) of steelframe or concrete;The outside of shell (2) is coated using thermal insulation material.
9. the box-like flue gas pollutant cooperation-removal device of a kind of horizontal group according to claim 1, which is characterized in that described The different parts of shell (2) length direction be separately installed with temperature, pressure transmitter.
CN201811091600.8A 2018-09-19 2018-09-19 A kind of box-like flue gas pollutant cooperation-removal device of horizontal group Pending CN109045931A (en)

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CN201811091600.8A CN109045931A (en) 2018-09-19 2018-09-19 A kind of box-like flue gas pollutant cooperation-removal device of horizontal group

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN117138548A (en) * 2023-09-12 2023-12-01 山东康源环保科技有限公司 Vertical fixed bed desulfurization, denitrification and dust removal equipment and application method thereof

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CN207025002U (en) * 2017-03-14 2018-02-23 上海克龙化工技术有限公司 Shell fills multiple field organic waste gas treatment device in parallel
CN107930259A (en) * 2017-11-08 2018-04-20 当涂县科辉商贸有限公司 A kind of smoke and dust purifier
CN208959574U (en) * 2018-09-19 2019-06-11 中国重型机械研究院股份公司 A kind of box-like flue gas pollutant cooperation-removal device of horizontal group

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CN204619675U (en) * 2015-04-02 2015-09-09 昆山捷斯安环保科技有限公司 Paint spray booth waste gas treatment equipment
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CN206965437U (en) * 2017-07-18 2018-02-06 晋江九鼎除尘烘烤设备有限公司 A kind of cellular activated carbon exhaust-gas treatment cabinet
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CN107930259A (en) * 2017-11-08 2018-04-20 当涂县科辉商贸有限公司 A kind of smoke and dust purifier
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN117138548A (en) * 2023-09-12 2023-12-01 山东康源环保科技有限公司 Vertical fixed bed desulfurization, denitrification and dust removal equipment and application method thereof

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