CN109023570A - A kind of preparation method of composite nanometer particle, composite nanometer particle and sunshade net - Google Patents
A kind of preparation method of composite nanometer particle, composite nanometer particle and sunshade net Download PDFInfo
- Publication number
- CN109023570A CN109023570A CN201810945185.1A CN201810945185A CN109023570A CN 109023570 A CN109023570 A CN 109023570A CN 201810945185 A CN201810945185 A CN 201810945185A CN 109023570 A CN109023570 A CN 109023570A
- Authority
- CN
- China
- Prior art keywords
- parts
- composite nanometer
- particle
- nanometer particle
- preparation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/06—Dyes
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01G—HORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
- A01G13/00—Protecting plants
- A01G13/02—Protective coverings for plants; Coverings for the ground; Devices for laying-out or removing coverings
- A01G13/0206—Canopies, i.e. devices providing a roof above the plants
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/06—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyolefin as constituent
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/16—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one other macromolecular compound obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds as constituent
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Textile Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Environmental Sciences (AREA)
- Artificial Filaments (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a kind of preparation method of composite nanometer particle and the nanoparticles of preparation, for the preparation method of composite nanometer particle the following steps are included: (1) grinds cationic red GTL, aluminium oxide and silica dioxide nano particle, high-temperature calcination obtains nano particle；(2) by 3,4-rthylene dioxythiophene monomer aqueous dispersion, the aqueous dispersion is added in nano particle, ammonium persulfate and hydrochloric acid are added into mixed solution；(3) mixed liquor is centrifuged, obtained washing of precipitate, it is dry, obtain composite nanometer particle.Above-mentioned composite nanometer particle is applied in fiber, and the sunshade net of preparation has color fastness to washing and colour fasteness to sunlight higher.
Description
Technical field
Additive and sunshade net used in sunshade net the present invention relates to agricultural planting, in particular in sunshade net
The dye nanoparticle and sunshade net used.
Background technique
Colored shade net can change radiation spectrum specifically to improve the photosynthesis characteristics of crop, and increase scattering light and change
The illumination condition of kind crop, adjusts the growth of plant.Further, since insect has phobotaxis to specific color, therefore colour hides
Screened postive theoretically also has the function of certain insect prevention.But due to the condition that sunshade net uses, colour fasteness to sunlight is not less than 5
Grade, color fastness to washing are not less than 5 grades.Color fastness to washing is had by the active force between dyestuff and fiber and solubility in water
It closes, when forming insoluble substance between dyestuff and fiber, color fastness to washing will be greatly increased, furthermore molten in addition to dyestuff
Solution property problem also needs the degree that falls off for considering dyestuff, it is desirable that have good compatibility between dyestuff and fibrous matrix.
For product dyed thereby under the irradiation of light, dyestuff absorbs luminous energy, and energy level improves, and molecule is in excited state, dye molecule
Color development system is changed or is destroyed, and causes dyestuff to decompose and discoloration or discolouration phenomena occurs, therefore influence the resistance to day of dyestuff
Bond strength of an important factor for the shining color fastness for the selection of dyestuff and its with fibrous matrix.
Summary of the invention
Goal of the invention: the present invention provides a kind of composite nanometer particles, can be used as the carrier of dyestuff, so that dyestuff and fibre
There is strong binding force between Wiki body.It is a further object of the present invention to provide the colored shades prepared using composite nanometer particle
Net, the sunshade net have high color fastness to washing and high colour fasteness to sunlight.
A kind of technical solution: preparation method of composite nanometer particle of the present invention, comprising the following steps:
It (1) is that 1:1:1-2 cationic red GTL, aluminium oxide and silica dioxide nano particle are ground by mass ratio, in 300-400
DEG C high-temperature calcination 4-8h, obtains nano particle；
(2) 10-15mmol/L 3,4-rthylene dioxythiophene monomer aqueous dispersion is prepared, by the nanometer in step (1)
The aqueous dispersion is added in grain, and ultrasound keeps its evenly dispersed, obtains mixed liquor, and it is 1:1- that molar ratio is added into mixed solution
1.2 ammonium persulfate and hydrochloric acid, is stirred at room temperature 5-6h；
(3) the resulting mixed liquor of step (2) is centrifuged, obtained washing of precipitate is dry, obtains composite nanometer particle.
Preferably, in step (2), mass percentage of the nano particle in mixed solution is 8-10%.
The composite nanometer particle that the preparation method of above-mentioned composite nanometer particle obtains, the composite nanometer particle and cationic red
GTL realizes adsorbed close, and the cationic colourant selected has intensity height, bright in color light, fastness to light good etc. excellent in the present invention
Point.The resulting nano particle for being adsorbed with coloring agent is utilized fabricated in situ by the present invention, so that nano particle periphery is coated with
PEDOT layer structure can to adsorb the dye migration in the nano particle of dyestuff using PEDOT layer structure, improve
The fastness to washing of dyestuff, furthermore PEDOT layer structure can transmit free electron, form ELECTRONIC COVER, can rapidly deplete outer
Electronics transfer caused by the shortwaves such as the ultraviolet light on boundary or the energy in excited state molecule guarantee dyestuff to the length of red spectrum
The enhancing ability of phase.
It can make stock-dye in conjunction in fiber containing acidic-group using cationic red GTL in the present invention
A kind of colored shade net of the present invention, by weight, the sunshade net is prepared by following raw material: 40-50
Part polyethylene, 5-10 parts of polymer electrolyte block polymers of polyurethane, 2-5 parts of PET, 1-2 parts of polyvinyl alcohol, 1-2 parts of sodium alginates,
0.1-0.5 chitosan, 1-3 part coupling agent, 0.5-2 parts of stearic acid, 1-4 parts of titanium dioxide and 4-6 parts of composite nanometer particles.
Preferably, the sunshade net is prepared by following raw material: 45 parts of polyethylene, 8 parts of polymer electrolyte polyurethane blocks copolymerization
Object, 3 parts of PET, 2 parts of polyvinyl alcohol, 1 part of sodium alginate, 0.3 chitosan, 2 parts of coupling agents, 1 part of stearic acid, 2 parts of titanium dioxide with
And 5 parts of composite nanometer particles.
The composite nanometer particle includes the following steps preparation: (1) by mass ratio be 1:1:1-2 cationic red GTL, oxidation
Aluminium and silica dioxide nano particle grinding, in 300-400 DEG C of high-temperature calcination 4-8h, obtain nano particle；(2) 10-15mmol/L is prepared
The aqueous dispersion is added in nano particle in step (1) by 3,4-rthylene dioxythiophene monomer aqueous dispersion, and ultrasound makes
Its is evenly dispersed, obtains mixed liquor, and ammonium persulfate and hydrochloric acid that molar ratio is 1:1-1.2 are added into mixed solution, and room temperature is stirred
Mix 5-6h；(3) the resulting mixed liquor of step (2) is centrifuged, obtained washing of precipitate is dry, obtains composite nanometer particle.
Preferably, the coupling agent is KH-550 or KH-560, and composite nanometer particle can be improved in coupling agent in the present invention
Agent silica inorganic particle and Miscibility.
Preferably, the partial size of the composite nanometer particle is 200-300nm.
Preferably, the titanium dioxide partial size is 50-100nm.
The preparation method of above-mentioned colored shade net comprising the steps of: (1) preparation of composite nanometer particle: by mass ratio
For the grinding of 1:1:1-2 cationic red GTL, aluminium oxide and silica dioxide nano particle, in 300-400 DEG C of high-temperature calcination 4-8h, must receive
Rice grain prepares 10-15mmol/L 3,4-rthylene dioxythiophene monomer aqueous dispersion, the disperse water is added in nano particle
Solution, ultrasound, keep its evenly dispersed, obtain mixed liquor, into mixed solution be added molar ratio be 1:1-1.2 ammonium persulfate and
5-6h is stirred at room temperature in hydrochloric acid, centrifugation, and obtained washing of precipitate is dry, obtains composite nanometer particle；(2) by 40-50 parts of poly- second
Alkene, 5-10 parts of polymer electrolyte block polymers of polyurethane, 2-5 parts of PET, 1-2 parts of polyvinyl alcohol, 1-2 parts of sodium alginates, 0.1-
0.5 chitosan, 1-3 part coupling agent, 0.5-2 parts of stearic acid, 1-4 parts of titanium dioxide and resulting 4-6 parts of step (1) compound receive
Rice grain is added melt blowing machine and is meltblown, prepares composite fibre, be prepared into colored shade net with gained composite fibre.
Unless otherwise indicated, " % " indicates mass percent in the present invention.
The utility model has the advantages that (1) present invention adsorbs dyestuff using inorganic nanoparticles, and coated outside dyestuff by in-situ polymerization
Poly- 3,4-rthylene dioxythiophene film layer improves the color fastness to washing and colour fasteness to sunlight of dyestuff；(2) composite Nano of the present invention
The preparation method of particle is simple, at low cost, is suitble to large-scale production；(3) sunshade net of the invention can be for a long time to red spectrum
With reinforcing effect, can be applied in greenhouse gardening for a long time.
Specific embodiment
One, raw material sources
3,4- ethene dioxythiophene (EDOT) is purchased from Shanghai Aladdin biochemical technology limited liability company；
Polymer electrolyte polyurethane is SN2301 type dispersing agent；
Remaining raw material is commercially available gained.
Two, sample preparation
The preparation of 2.1 composite nanometer particles
It is that 1:1:1 cationic red GTL, aluminium oxide and silica dioxide nano particle are ground by mass ratio, in 350 DEG C of high-temperature calcinations
6h obtains nano particle；10mmol/L 3,4-rthylene dioxythiophene monomer aqueous dispersion is prepared, aqueous dispersion system will be accounted for
The nano particle of total amount 8% is added in aqueous dispersion, ultrasonic under 25KHz frequency, keeps its evenly dispersed, adds into mixed solution
Entering the ammonium persulfate and hydrochloric acid that molar ratio is 1:1, the concentration of ammonium persulfate and hydrochloric acid in dispersion is 30mmol/L,
6h is stirred at room temperature under 300rmp rate, obtained mixed solution is centrifuged, obtained precipitating is washed 3 times, and it is dry, obtain composite Nano
Particle.
2.2 sample preparation
Embodiment 1: by 40 parts of polyethylene, 5 parts of polymer electrolyte block polymers of polyurethane, 2 parts of PET, 1 part of polyvinyl alcohol, 1
Part sodium alginate, 0.1 chitosan, 1 part of coupling agent KH-550,0.5 part of stearic acid, 1 part of titanium dioxide, 4 parts of composite nanometer particles,
Melt blowing machine is added to be meltblown, prepares composite fibre, is prepared into colored shade net with gained composite fibre.
Embodiment 2: by 50 parts of polyethylene, 10 parts of polymer electrolyte block polymers of polyurethane, 5 parts of PET, 2 parts of polyvinyl alcohol,
2 parts of sodium alginates, 0.5 chitosan, 3 parts of coupling agent KH-550,2 parts of stearic acid, 4 parts of titanium dioxide and 6 parts of composite nanometer particles,
Melt blowing machine is added to be meltblown, prepares composite fibre, is prepared into colored shade net with gained composite fibre.
Embodiment 3: by 45 parts of polyethylene, 8 parts of polymer electrolyte block polymers of polyurethane, 3 parts of PET, 2 parts of polyvinyl alcohol, 1
Part sodium alginate, 0.3 part of chitosan, 2 parts of coupling agent KH-550,1 part of stearic acid, 2 parts of titanium dioxide and 5 parts of composite Nanos
Grain is added melt blowing machine and is meltblown, prepares composite fibre, be prepared into colored shade net with gained composite fibre.
Embodiment 4: by 40 parts of polyethylene, 5 parts of polymer electrolyte block polymers of polyurethane, 2 parts of PET, 2 parts of polyvinyl alcohol, 2
6 parts of part sodium alginate, 0.5 chitosan, 3 parts of coupling agent KH-550,2 parts of stearic acid, 4 parts of titanium dioxide and step composite Nanos
Grain is added melt blowing machine and is meltblown, prepares composite fibre, be prepared into colored shade net with gained composite fibre.
Embodiment 5: by 50 parts of polyethylene, 10 parts of polymer electrolyte block polymers of polyurethane, 5 parts of PET, 1 part of polyvinyl alcohol,
4 parts of 1 part of sodium alginate, 0.1 chitosan, 1 part of coupling agent KH-550,0.5 part of stearic acid, 1 part of titanium dioxide and step compound are received
Rice grain is added melt blowing machine and is meltblown, prepares composite fibre, be prepared into colored shade net with gained composite fibre.
Comparative example 1: by 45 parts of polyethylene, 8 parts of polymer electrolyte block polymers of polyurethane, 3 parts of PET, 2 parts of polyvinyl alcohol, 1
Part sodium alginate, 0.3 part of chitosan, 2 parts of coupling agent KH-550,1 part of stearic acid, 2 parts of titanium dioxide and 5 parts of cationic reds
GTL is added melt blowing machine and is meltblown, prepares composite fibre, be prepared into colored shade net with gained composite fibre.
Three, application effect is tested
The test of 3.1 color fastness to washings
Using chlorine washing powder is free of, the additional amount of washing powder is 4 grams per liters, takes 150 grams of aqueous solution dissolved with washing powder, will
The sample cloth of 10X4cm size is put into solution, and solution is arranged 20 DEG C, shakes and washes 30 minutes.Sample cloth must be washed together with a piece of calico
It washs, to detect whether the color under washing.
3.2 colour fasteness to sunlights:
With reference in national standard GB/T8429-1998 " textile color stability tests colour fastness to weathering: atmospheric exposure " standard
Method detects the colour fasteness to sunlight of sunshade net.
The color fastness to washing and colour fasteness to sunlight of the different samples of table 1
| Sample | Color fastness to washing | Colour fasteness to sunlight |
| Embodiment 1 | Seven grades | Seven grades |
| Embodiment 2 | Seven grades | Seven grades |
| Embodiment 3 | Seven grades | Seven grades |
| Embodiment 4 | Seven grades | Seven grades |
| Embodiment 5 | Seven grades | Seven grades |
| Comparative example 1 | Pyatyi | Six grades |
As shown in Table 1, the present invention is good to the adhesion of dyestuff, by it for dyestuff easy to change, due to carrying
The presence of body, so that the fastness to light of the dyestuff is excellent, not fugitive color.In addition, composite nanometer particle preparation method of the invention
Simply, nano particle in aqueous solution can be obtained directly by centrifugation, can rapidly be separated with preparation system, and industrialization is suitble to
Production.
3.3 mechanics performance determining
The sample of 2.2 parts preparation is subjected to Mechanics Performance Testing, the results are shown in Table 2
The different sample mechanics performance determinings of table 2
| Sample | Tensile strength/MPa | Elongation at break/% |
| Embodiment 1 | 83.4 | 37.3 |
| Embodiment 2 | 81.3 | 35.9 |
| Embodiment 3 | 87.9 | 37.4 |
| Embodiment 4 | 86.6 | 34.5 |
| Embodiment 5 | 85.5 | 33.1 |
| Comparative example 1 | 73.2 | 27.8 |
As can be seen from Table 2, since composite nanometer particle can not only increase the sun-resistant color jail of sunshade net in the present invention
The mechanical property of sunshade net is gone back while being increased to degree and color fastness to washing.
Claims (10)
1. a kind of preparation method of composite nanometer particle, which comprises the following steps:
It (1) is that 1:1:1-2 cationic red GTL, aluminium oxide and silica dioxide nano particle are ground by mass ratio, in 300-400 DEG C of height
Temperature calcining 4-8h, obtains nano particle；
(2) 10-15mmol/L 3,4-rthylene dioxythiophene monomer aqueous dispersion is prepared, the nano particle in step (1) is added
Enter the aqueous dispersion, ultrasound keeps its evenly dispersed, obtains mixed liquor, and it is 1:1-1.2's that molar ratio is added into mixed solution
Ammonium persulfate and hydrochloric acid, are stirred at room temperature 5-6h；
(3) the resulting mixed liquor of step (2) is centrifuged, obtained washing of precipitate is dry, obtains composite nanometer particle.
2. the preparation method of composite nanometer particle according to claim 1, it is characterised in that in step (2), the nanometer
Mass percentage of the particle in mixed solution is 8-10%.
3. the composite nanometer particle that the preparation method of any composite nanometer particle according to claim 1 to 2 obtains.
4. a kind of colored shade net, which is characterized in that by weight, the sunshade net is prepared by following raw material: 40-50 parts poly-
Ethylene, 5-10 parts of polymer electrolyte block polymers of polyurethane, 2-5 parts of PET, 1-2 parts of polyvinyl alcohol, 1-2 parts of sodium alginates, 0.1-
0.5 chitosan, 1-3 part coupling agent, 0.5-2 parts of stearic acid, 1-4 parts of titanium dioxide and 4-6 parts of composite nanometer particles.
5. colored shade net according to claim 4, which is characterized in that the sunshade net is prepared by following raw material: 45 parts
Polyethylene, 8 parts of polymer electrolyte block polymers of polyurethane, 3 parts of PET, 2 parts of polyvinyl alcohol, 1 part of sodium alginate, 0.3 chitosan, 2
Part coupling agent, 1 part of stearic acid, 2 parts of titanium dioxide and 5 parts of composite nanometer particles.
6. colored shade net according to claim 4, which is characterized in that the composite nanometer particle includes the following steps system
It is standby:
It (1) is that 1:1:1-2 cationic red GTL, aluminium oxide and silica dioxide nano particle are ground by mass ratio, in 300-400 DEG C of height
Temperature calcining 4-8h, obtains nano particle；
(2) 10-15mmol/L 3,4-rthylene dioxythiophene monomer aqueous dispersion is prepared, the nano particle in step (1) is added
Enter the aqueous dispersion, ultrasound keeps its evenly dispersed, obtains mixed liquor, and it is 1:1-1.2's that molar ratio is added into mixed solution
Ammonium persulfate and hydrochloric acid, are stirred at room temperature 5-6h；
(3) the resulting mixed liquor of step (2) is centrifuged, obtained washing of precipitate is dry, obtains composite nanometer particle.
7. colored shade net according to claim 4, which is characterized in that the coupling agent is KH-550 or KH-560.
8. colored shade net according to claim 4, which is characterized in that the partial size of the composite nanometer particle is 200-
300nm。
9. colored shade net according to claim 4, which is characterized in that the titanium dioxide partial size is 50-100nm.
10. the preparation method of any colored shade net as described in claim 4-9, which is characterized in that comprise the steps of:
(1) preparation of composite nanometer particle: being 1:1:1-2 cationic red GTL, aluminium oxide and silica dioxide nano particle by mass ratio
Grinding obtains nano particle in 300-400 DEG C of high-temperature calcination 4-8h, prepares 10-15mmol/L 3,4-rthylene dioxythiophene monomer
The aqueous dispersion is added in nano particle by aqueous dispersion, and ultrasound keeps its evenly dispersed, obtains mixed liquor, to mixed solution
It is middle that the ammonium persulfate and hydrochloric acid that molar ratio is 1:1-1.2 is added, 5-6h is stirred at room temperature, is centrifuged, obtained washing of precipitate, it is dry,
Obtain composite nanometer particle；
(2) by 40-50 parts of polyethylene, 5-10 parts of polymer electrolyte block polymers of polyurethane, 2-5 parts of PET, 1-2 parts of polyvinyl alcohol,
1-2 parts of sodium alginates, 0.1-0.5 chitosan, 1-3 parts of coupling agents, 0.5-2 parts of stearic acid, 1-4 parts of titanium dioxide and step
(1) resulting 4-6 parts of composite nanometer particle is added melt blowing machine and is meltblown, prepare composite fibre, prepared with gained composite fibre
Obtain colored shade net.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810945185.1A CN109023570A (en) | 2018-08-20 | 2018-08-20 | A kind of preparation method of composite nanometer particle, composite nanometer particle and sunshade net |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810945185.1A CN109023570A (en) | 2018-08-20 | 2018-08-20 | A kind of preparation method of composite nanometer particle, composite nanometer particle and sunshade net |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109023570A true CN109023570A (en) | 2018-12-18 |
Family
ID=64632016
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810945185.1A Pending CN109023570A (en) | 2018-08-20 | 2018-08-20 | A kind of preparation method of composite nanometer particle, composite nanometer particle and sunshade net |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109023570A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110741856A (en) * | 2019-10-31 | 2020-02-04 | 黎业强 | Preparation method of insect-resistant anti-aging sunshade net |
| CN113564743A (en) * | 2021-08-04 | 2021-10-29 | 绿地遮阳有限公司 | Insect-pest-preventing anti-aging sunshade net and preparation method thereof |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101445625A (en) * | 2008-12-26 | 2009-06-03 | 上海新上化高分子材料有限公司 | Colored low smoke, zero halogen and flame retardant polyolefine composition and preparation method thereof |
| CN103469578A (en) * | 2013-09-23 | 2013-12-25 | 青岛大学 | Preparation method of ultraviolet-proof anti-electromagnetic radiation textile fabric |
| CN105821505A (en) * | 2015-11-06 | 2016-08-03 | 菏泽恒泰健身器材制造有限公司 | Anti-ultraviolet and heat-resisting net |
| CN106245136A (en) * | 2016-08-17 | 2016-12-21 | 东华大学 | A kind of coloured superhigh molecular weight polyethylene fibers and preparation method thereof |
| CN108232122A (en) * | 2018-01-22 | 2018-06-29 | 南京大学射阳高新技术研究院 | The preparation method and application of the lithium titanate nano particle of PEDOT claddings |
| CN108314907A (en) * | 2017-12-28 | 2018-07-24 | 万隆化工有限公司 | Organic and inorganic resin coated pigment and preparation method thereof |
-
2018
- 2018-08-20 CN CN201810945185.1A patent/CN109023570A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101445625A (en) * | 2008-12-26 | 2009-06-03 | 上海新上化高分子材料有限公司 | Colored low smoke, zero halogen and flame retardant polyolefine composition and preparation method thereof |
| CN103469578A (en) * | 2013-09-23 | 2013-12-25 | 青岛大学 | Preparation method of ultraviolet-proof anti-electromagnetic radiation textile fabric |
| CN105821505A (en) * | 2015-11-06 | 2016-08-03 | 菏泽恒泰健身器材制造有限公司 | Anti-ultraviolet and heat-resisting net |
| CN106245136A (en) * | 2016-08-17 | 2016-12-21 | 东华大学 | A kind of coloured superhigh molecular weight polyethylene fibers and preparation method thereof |
| CN108314907A (en) * | 2017-12-28 | 2018-07-24 | 万隆化工有限公司 | Organic and inorganic resin coated pigment and preparation method thereof |
| CN108232122A (en) * | 2018-01-22 | 2018-06-29 | 南京大学射阳高新技术研究院 | The preparation method and application of the lithium titanate nano particle of PEDOT claddings |
Non-Patent Citations (4)
| Title |
|---|
| 朱美芳 等: "《中国战略性新兴产业著•新材料 高性能纤维》", 30 November 2017, 中国铁道出版社 * |
| 田恰 等: "《纺织品检验》", 30 June 2006, 中国纺织出版社 * |
| 陈宁 等: "《高等学校专业教材 酶工程》", 30 June 2011, 中国轻工业出版社 * |
| 马世昌: "《基础化学反应》", 31 January 2003, 陕西科学技术出版社 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110741856A (en) * | 2019-10-31 | 2020-02-04 | 黎业强 | Preparation method of insect-resistant anti-aging sunshade net |
| CN113564743A (en) * | 2021-08-04 | 2021-10-29 | 绿地遮阳有限公司 | Insect-pest-preventing anti-aging sunshade net and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Liu et al. | Constructing carbon dots and CdTe quantum dots multi-functional composites for ultrasensitive sensing and rapid degrading ciprofloxacin | |
| CN106750466B (en) | Reversible thermochromic film and preparation method thereof | |
| Abou Elmaaty et al. | One-step green approach for functional printing and finishing of textiles using silver and gold NPs | |
| WO2018095442A1 (en) | Quantum dot and use of composite material thereof in preparing ultraviolet resistant products | |
| CN109023570A (en) | A kind of preparation method of composite nanometer particle, composite nanometer particle and sunshade net | |
| CN105219373B (en) | A kind of carrier granular and preparation method thereof | |
| CN108559485A (en) | A kind of nano-crystal cellulose fluorescence probe and preparation method thereof of detection metal ion | |
| CN105968852A (en) | Anti-ultraviolet radiation lignin-based zinc oxide composite particles and preparation method and application thereof | |
| CN102492428A (en) | Uniform fluorescent microball and preparation method | |
| CN105646765B (en) | A kind of method for the aqueous dispersions for preparing fluorescent polymer microballoon | |
| CN114381261B (en) | Phosphorescent carbon dot-metal organic framework composite material and preparation method and application thereof | |
| CN102796512A (en) | Method for preparing melamine-formaldehyde resin fluorescent microspheres | |
| CN107236297A (en) | A kind of nano modification colours nylon composite materials | |
| Madhi et al. | Bio-based surface modification of wool fibers by chitosan-graphene quantum dots nanocomposites | |
| Mohamed et al. | Color-tunable encapsulated perylene-labeled silica fluorescent hybrid nanoparticles | |
| Yao et al. | Highly transparent, writable and photoluminescent foldable polymer film: When fluorescent dyes or pigments join cellulose-based microgel | |
| CN104947230A (en) | Preparation method of luminescent fiber | |
| CN102206490A (en) | Preparation method for core-shell structure red phosphor, and core-shell structure red phosphor prepared by using the same | |
| Li et al. | Luminescent hydrogels with tunable emission colors and excellent adhesion performance fabricated by lanthanide complexes induced crosslinking and physical interaction | |
| Khalaf et al. | Glass nanofibers as a reinforcement agent to polylactic acid smart plastic window | |
| CN107236298A (en) | A kind of modification of nylon composite materials and color method | |
| CN107629782B (en) | Preparation method of tungsten oxide-mica photochromic pearlescent pigment and dispersion liquid thereof | |
| CN1216187C (en) | Colored cellulosic shaped bodies | |
| CN105061773A (en) | Novel chitosan-modified epoxy-resin-base high-polymer dye and preparation method thereof | |
| CN114213568B (en) | Light conversion microsphere, preparation method and application |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20181218 |
|
| RJ01 | Rejection of invention patent application after publication |