CN109023094A - A kind of NbV combined microalloying HRB400E reinforcing bar and production technology - Google Patents

A kind of NbV combined microalloying HRB400E reinforcing bar and production technology Download PDF

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CN109023094A
CN109023094A CN201811052750.8A CN201811052750A CN109023094A CN 109023094 A CN109023094 A CN 109023094A CN 201811052750 A CN201811052750 A CN 201811052750A CN 109023094 A CN109023094 A CN 109023094A
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reinforcing bar
nbv
steel
combined microalloying
production technology
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邓建新
贾建平
孙贵平
王建忠
贾明雪
赵晓锋
王晓娣
尹志强
王新路
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Xuanhua Iron and Steel Group Co Ltd
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Xuanhua Iron and Steel Group Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/02Ferrous alloys, e.g. steel alloys containing silicon
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/06Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of rods or wires
    • C21D8/065Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of rods or wires of ferrous alloys
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/06Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of rods or wires
    • C21D8/08Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of rods or wires for concrete reinforcement
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/001Ferrous alloys, e.g. steel alloys containing N
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/002Ferrous alloys, e.g. steel alloys containing In, Mg, or other elements not provided for in one single group C22C38/001 - C22C38/60
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/04Ferrous alloys, e.g. steel alloys containing manganese
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/12Ferrous alloys, e.g. steel alloys containing tungsten, tantalum, molybdenum, vanadium, or niobium
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00Microstructure comprising significant phases
    • C21D2211/002Bainite
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00Microstructure comprising significant phases
    • C21D2211/005Ferrite
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00Microstructure comprising significant phases
    • C21D2211/009Pearlite

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  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Carbon Steel Or Casting Steel Manufacturing (AREA)
  • Treatment Of Steel In Its Molten State (AREA)

Abstract

The invention discloses a kind of NbV combined microalloying HRB400E reinforcing bar and production technologies, the reinforcing bar chemical component composition and mass percentage are as follows: C:0.19-0.21%, Si:0.32-0.38%, Mn:1.33-1.38%, P≤0.041%, S≤0.041%, Nb:0.017-0.019%, V:0.010-0.014%, N:50-70ppm, O≤50ppm, surplus are Fe and inevitable impurity;The production technology includes smelting, continuous casting, rolling process.Reinforcing bar produced by the invention, metallographic structure F+P+B, grain size are 8.0-8.5 grades, and yield point elongation is obvious, and rebar surface is fine and close Fe3O4Tissue, grain structure refinement, the welding performance of reinforcing bar, cold-bending property, fatigue limit performance, antioxygenic property are better than using a kind of performance of alloy of Nb or V merely.

Description

A kind of NbV combined microalloying HRB400E reinforcing bar and production technology
Technical field
The invention belongs to metallurgical technology fields, and in particular to a kind of NbV combined microalloying HRB400E reinforcing bar and production work Skill.
Background technique
National standard GB-T 1499.2-2018 defines the composition control of HRB400E reinforcing bar, but does not do in detail to its production technology Thin regulation, mature technology is produced using Nb V microalloying technique at present, due to vanadium raw materials rise in price, simple vanadium Microalloying higher cost, and merely with Nb-microalloying reinforcing bar yield strength value limit on the lower side and that there are yield point elongations is unconspicuous Problem, niobium vanadium composite micro-alloying can effectively make up the deficiency of these two aspects, not only can guarantee reinforcement property, but also can reduce cost, Good direction is provided for screw-thread steel production.
Although NbV combined microalloying technique has cost+quality-advantage, have no that any steel mill carries out substance Production technology R&D work.
Xuan Gang is dedicated to the production of NbV combined microalloying process exploitation, and actual development process is because of C high 0.23-0.25%, out Now cross the unconspicuous phenomenon of reinforcement property yield point elongation;N content control is higher, occurs causing the big performance of reinforcing bar aging performance low In standard requirements phenomenon, oxygen content height leads to Nb, V alloy absorptivity labile element wild effect;It is united by test of many times Meter analysis has finally determined the narrow composition science control range of carbon, the narrow composition production technology of silicon, manganese, niobium, vanadium, nitrogen, oxygen, product quality Meet standard requirements.
Summary of the invention
The technical problem to be solved in the present invention is to provide a kind of NbV combined microalloying HRB400E reinforcing bar and production technologies.
In order to solve the above technical problems, the technical solution used in the present invention is: a kind of NbV combined microalloying HRB400E reinforcing bar, the reinforcing bar chemical component composition and its mass percentage are as follows: C:0.19-0.21%, Si:0.32- 0.38%, Mn:1.33-1.38%, P≤0.041%, S≤0.041%, Nb:0.017-0.019%, V:0.010-0.014%, N:50- 70ppm, O≤50ppm, surplus are Fe and inevitable impurity.
Reinforcing bar chemical component composition and its mass percentage of the present invention are as follows: C:0.20%, Si:0.35%, Mn: 1.36%, P≤0.036%, S≤0.036%, Nb:0.018%, V:0.013%, N:60ppm, O≤40ppm, surplus are Fe and can not The impurity avoided.
Bar gauge of the present invention is Φ 12-25mm;Metallographic structure is ferrite (F)+pearlite (P)+bainite (B), ferrite+pearlite >=90%, bainite≤10%, grain size are 8.0-8.5 grades.
Reinforcement yielding intensity 430-460MPa of the present invention, tensile strength 590-615MPa, elongation 27-35%, Agt: 13-14%, strong flexor ratio 1.33-1.38, clod wash recurvation are functional.
The present invention also provides a kind of production technology of NbV combined microalloying HRB400E reinforcing bar, the production technology packets Include smelting, continuous casting, rolling process;The smelting procedure, using the top compound converter smelting in bottom, Nb alloying uses 0.27- The FeNb60-B of 0.30kg/t steel, absorptivity 85%, V alloyization use the FeV50-A of 0.16-0.24kg/t steel, absorptivity 90%, Terminal point control uses highcasting speed technique;The rolling process, 970-1000 DEG C of start rolling temperature.
Smelting procedure of the present invention, using the top compound converter smelting in bottom, at converter smelting 720 seconds, bottom blowing system for converter It automatically switches into argon gas and carries out bottom blowing stirring, monolithic brick bottom blowing flow is 40m3/ h, according to the nominal capacity of converter, bottom blowing is ventilative Brick is 4,6,8 pieces.The uniform liquid steel temperature of necessary ladle bottom blowing argon gas and composition, removal of inclusions technique must be taken.
Smelting procedure of the present invention, terminal point control use highcasting speed technique, converter smelting endpoint: C >=0.10%, P≤ 0.030%, S≤0.035%, N:40-50ppm.
Smelting procedure of the present invention, convertor deacidification alloying, carburant use the petroleum coke of 0.70-0.80kg/t steel, Silicomanganization uses the silicomanganese of 19-20kg/t steel, the ferrosilicon of 0.9-1.1kg/t steel;Deoxidier is using 0.5-1.0kg/t steel Si-Al-Ba alloy strontium.Nb alloying is using the FeNb60-B in GB/T 7737-2007 " ferro-niobium ";V alloyization uses GB/T 4139- FeV50-A in 2012 " vanadium iron ".
Continuous casting working procedure of the present invention is continuously poured the packet degree of superheat in heat and controls at 20-30 DEG C, and two furnaces overheat before middle packet Degree control is at 30-50 DEG C.
Rolling process of the present invention, 970-1000 DEG C of start rolling temperature, 900-920 DEG C of temperature on cooling table
Mentality of designing of the present invention:
Using the top compound converter smelting in bottom, converter top and bottom complex blowing uses nitrogen argon switching technique, and terminal point control uses highcasting speed technique, Steel oxygen content in water is reduced, the higher stable absorptivity of C, Si, Mn, Nb, V alloy is effectively guaranteed, to stabilize The performance of composition control and reinforcing bar.
Using+50 vanadium iron proportion scheme of Nb iron, NbV combined microalloying production technology, Si, Mn, V, Nb are used Narrow composition control technique, the control of Si, Mn, Nb, V absorptivity is stablized, and according to Nb and V microalloying technique characteristic, is calculated best Carbon, Control of Nitrogen Content range, given full play to Nb+V Microalloying Effect.
Using the rolling temperature and temperature on cooling table of narrow temperature range, rolling concrete steel bar specification is Φ 12, Φ 14, Φ 16, Φ 18, Φ 20, Φ 22,25 specification straight steel bar of Φ guarantee in conjunction with the narrow composition control range of effective C, Si, Mn, Nb, V, N science Bainite structure in NbV microalloying reinforcing bar is not more than 10%, remaining all ferrite+pearlitic structrure, to guarantee steel The yield point elongation of muscle is obvious and stablizes.
Reinforcing bar temperature on cooling table is controlled at 900-920 DEG C, has given full play to the cold technique of control, and rebar surface is fine and close Fe304, avoid rebar surface Fe203Transition temperature improves the oxidation resistance of reinforcing bar.
NbV combined microalloying HRB400E reinforcing bar product standard of the present invention refers to GB/T 1499.2-2018;Properties of product Detection method canonical reference GB/T 228.1-2010.
The beneficial effects of adopting the technical scheme are that the 1, present invention uses vanadium micro-alloying technology with simple Project plan comparison, yield strength performance, the tensile strength properties using production technology reinforcing bar of the present invention are more stable, continue in vanadium alloy Under the influence of the factor of rise in price, cost reduces >=20 yuan/ton of steel, has the double advantages of quality, cost.2, the present invention uses Nb with simple Micro-alloying technology project plan comparison solves to play Nb Microalloying Effect and uses high start rolling temperature, and yield point elongation is unknown Aobvious problem.3, reinforcing bar produced by the invention, metallographic structure F+P+B, ferrite+pearlite >=90%, bainite≤10% are brilliant Granularity is 8.0-8.5 grades, and yield point elongation is obvious, and rebar surface is fine and close Fe3O4Tissue, grain structure refinement, the welding of reinforcing bar Performance, cold-bending property, fatigue limit performance, antioxygenic property use a kind of performance of alloy of Nb or V better than simple.
Specific embodiment
Present invention will be explained in further detail combined with specific embodiments below.
Embodiment 1
The present embodiment NbV combined microalloying HRB400E bar gauge be tetra- cutting reinforcing bar of Φ 12mm, chemical component composition and Mass percentage are as follows: C:0.21%, Si:0.35%, Mn:1.36%, P:0.028%, S:0.015%, Nb:0.018%, V: 0.012%, N:64ppm, O:43ppm, surplus are Fe and inevitable impurity.
The production technology of the present embodiment NbV combined microalloying HRB400E reinforcing bar includes smelting, continuous casting, rolling process, tool That steps are as follows is described for body technology:
(1) smelting procedure: using the top compound converter smelting in bottom, converter top and bottom complex blowing uses nitrogen argon switching technique;Convertor deacidification closes Aurification, carburant use the petroleum coke of 0.78kg/t steel, alloying using the silicomanganese of 20kg/t steel, 1.0kg/t steel ferrosilicon, The FeV50-A of FeNb60-B, 0.20kg/t steel of 0.28kg/t steel, deoxidier use the Si-Al-Ba alloy strontium of 0.5kg/t steel;Terminal control System uses highcasting speed technique, converter smelting endpoint: C:0.13%, P:0.024%, S:0.014%, N:48ppm;
(2) continuous casting working procedure: the control of the packet degree of superheat is at 25 DEG C in continuous casting heat;
(3) rolling process: 980 DEG C of start rolling temperature, 910 DEG C of temperature on cooling table.
The present embodiment NbV combined microalloying HRB400E reinforcement property index is shown in Table 1, metallographic structure 40%F+52%P+ 8%B。
1 rolling specs Φ of table, 12 4 cutting reinforcement property
Embodiment 2
The present embodiment NbV combined microalloying HRB400E bar gauge be tri- cutting reinforcing bar of Φ 14mm, chemical component composition and Mass percentage are as follows: C:0.20%, Si:0.36%, Mn:1.35%, P:0.032%, S:0.028%, Nb:0.019%, V: 0.011%, N:62ppm, O:45ppm, surplus are Fe and inevitable impurity.
The production technology of the present embodiment NbV combined microalloying HRB400E reinforcing bar includes smelting, continuous casting, rolling process, tool That steps are as follows is described for body technology:
(1) smelting procedure: using the top compound converter smelting in bottom, converter top and bottom complex blowing uses nitrogen argon switching technique;Convertor deacidification closes Aurification, carburant use the petroleum coke of 0.70kg/t steel, alloying using the silicomanganese of 20kg/t steel, 1.0kg/t steel ferrosilicon, The FeV50-A of FeNb60-B, 0.18kg/t steel of 0.30kg/t steel, deoxidier use the Si-Al-Ba alloy strontium of 0.8kg/t steel;Terminal control System uses highcasting speed technique, converter smelting endpoint: C:0.10%, P:0.028%, S:0.025%, N:45ppm;
(2) continuous casting working procedure: the control of the packet degree of superheat is at 30 DEG C in continuous casting heat;
(3) rolling process: 990 DEG C of start rolling temperature, 910 DEG C of temperature on cooling table.
The present embodiment NbV combined microalloying HRB400E reinforcement property index is shown in Table 2, metallographic structure 35%F+58%P+ 7%B。
2 rolling specs Φ of table, 14 3 cutting reinforcement property
Embodiment 3
The present embodiment NbV combined microalloying HRB400E bar gauge be bis- cutting reinforcing bar of Φ 16mm, chemical component composition and Mass percentage are as follows: C:0.21%, Si:0.37%, Mn:1.34%, P:0.029%, S:0.025%, Nb:0.017%, V: 0.013%, N:65ppm, O:41ppm, surplus are Fe and inevitable impurity.
The production technology of the present embodiment NbV combined microalloying HRB400E reinforcing bar includes smelting, continuous casting, rolling process, tool That steps are as follows is described for body technology:
(1) smelting procedure: using the top compound converter smelting in bottom, converter top and bottom complex blowing uses nitrogen argon switching technique;Convertor deacidification closes Aurification, carburant use the petroleum coke of 0.8kg/t steel, alloying using the silicomanganese of 19.5kg/t steel, 1.1kg/t steel ferrosilicon, The FeV50-A of FeNb60-B, 0.22kg/t steel of 0.27kg/t steel, deoxidier use the Si-Al-Ba alloy strontium of 0.5kg/t steel;Terminal control System uses highcasting speed technique, converter smelting endpoint: C:0.12%, P:0.025%, S:0.015%, N:50ppm;
(2) continuous casting working procedure: middle packet is poured the control of the 1st heat degree of superheat at 30 DEG C;
(3) rolling process: 975 DEG C of start rolling temperature, 900 DEG C of temperature on cooling table.
The present embodiment NbV combined microalloying HRB400E reinforcement property index is shown in Table 3, metallographic structure 38%F+55%P+ 7%B。
3 rolling specs Φ of table, 16 2 cutting reinforcement property
Embodiment 4
The present embodiment NbV combined microalloying HRB400E bar gauge be bis- cutting reinforcing bar of Φ 18mm, chemical component composition and Mass percentage are as follows: C:0.20%, Si:0.34%, Mn:1.37%, P:0.036%, S:0.014%, Nb:0.017%, V: 0.011%, N:59ppm, O:40ppm, surplus are Fe and inevitable impurity.
The production technology of the present embodiment NbV combined microalloying HRB400E reinforcing bar includes smelting, continuous casting, rolling process, tool That steps are as follows is described for body technology:
(1) smelting procedure: using the top compound converter smelting in bottom, converter top and bottom complex blowing uses nitrogen argon switching technique;Convertor deacidification closes Aurification, carburant use the petroleum coke of 0.70kg/t steel, alloying using the silicomanganese of 20kg/t steel, 1.0kg/t steel ferrosilicon, The FeV50-A of FeNb60-B, 0.18kg/t steel of 0.27kg/t steel, deoxidier use the Si-Al-Ba alloy strontium of 0.5kg/t steel;Terminal control System uses highcasting speed technique, converter smelting endpoint: C:0.10%, P:0.030%, S:0.012%, N:44ppm;
(2) continuous casting working procedure: the control of the packet degree of superheat is at 28 DEG C in continuous casting heat;
(3) rolling process: 985 DEG C of start rolling temperature, 900 DEG C of temperature on cooling table.
The present embodiment NbV combined microalloying HRB400E reinforcement property index is shown in Table 4, metallographic structure 40%F+55%P+ 5%B。
4 rolling specs Φ of table, 18 2 cutting reinforcement property
Embodiment 5
The present embodiment NbV combined microalloying HRB400E bar gauge be bis- cutting reinforcing bar of Φ 20mm, chemical component composition and Mass percentage are as follows: C:0.21%, Si:0.32%, Mn:1.38%, P:0.025%, S:0.041%, Nb:0.017%, V: 0.014%, N:50ppm, O:20ppm, surplus are Fe and inevitable impurity.
The production technology of the present embodiment NbV combined microalloying HRB400E reinforcing bar includes smelting, continuous casting, rolling process, tool That steps are as follows is described for body technology:
(1) smelting procedure: using the top compound converter smelting in bottom, converter top and bottom complex blowing uses nitrogen argon switching technique;Convertor deacidification closes Aurification, carburant use the petroleum coke of 0.75kg/t steel, alloying using the silicomanganese of 20kg/t steel, 0.9kg/t steel ferrosilicon, The FeV50-A of FeNb60-B, 0.24kg/t steel of 0.27kg/t steel, deoxidier use the Si-Al-Ba alloy strontium of 0.8kg/t steel;Terminal control System uses highcasting speed technique, converter smelting endpoint: C:0.11%, P:0.022%, S:0.035%, N:40ppm;
(2) continuous casting working procedure: the control of the packet degree of superheat is at 20 DEG C in continuous casting heat;
(3) rolling process: 1000 DEG C of start rolling temperature, 900 DEG C of temperature on cooling table.
The present embodiment NbV combined microalloying HRB400E reinforcement property index is shown in Table 5, metallographic structure 40%F+50%P+ 10%B。
5 rolling specs Φ of table, 20 2 cutting reinforcement property
Embodiment 6
The present embodiment NbV combined microalloying HRB400E bar gauge be bis- cutting reinforcing bar of Φ 22mm, chemical component composition and Mass percentage are as follows: C:0.19%, Si:0.38%, Mn:1.33%, P:0.041%, S:0.030%, Nb:0.019%, V: 0.010%, N:70ppm, O:50ppm, surplus are Fe and inevitable impurity.
The production technology of the present embodiment NbV combined microalloying HRB400E reinforcing bar includes smelting, continuous casting, rolling process, tool That steps are as follows is described for body technology:
(1) smelting procedure: using the top compound converter smelting in bottom, converter top and bottom complex blowing uses nitrogen argon switching technique;Convertor deacidification closes Aurification, carburant use the petroleum coke of 0.72kg/t steel, alloying using the silicomanganese of 19.0kg/t steel, 1.1kg/t steel ferrosilicon, The FeV50-A of FeNb60-B, 0.16kg/t steel of 0.30kg/t steel, deoxidier use the Si-Al-Ba alloy strontium of 1.0kg/t steel;Terminal control System uses highcasting speed technique, converter smelting endpoint: C:0.12%, P:0.028%, S:0.027%, N:45ppm;
(2) continuous casting working procedure: middle packet is poured the control of the 2nd heat degree of superheat at 50 DEG C;
(3) rolling process: 970 DEG C of start rolling temperature, 910 DEG C of temperature on cooling table.
The present embodiment NbV combined microalloying HRB400E reinforcement property index is shown in Table 6, metallographic structure 40%F+55%P+ 5%B。
6 rolling specs Φ of table, 22 2 cutting reinforcement property
Embodiment 7
The present embodiment NbV combined microalloying HRB400E bar gauge is Φ 25mm single line reinforcing bar, chemical component composition and matter Measure percentage composition are as follows: C:0.20%, Si:0.35%, Mn:1.36%, P:0.036%, S:0.036%, Nb:0.018%, V:0.013%, N:60ppm, O:40ppm, surplus are Fe and inevitable impurity.
The production technology of the present embodiment NbV combined microalloying HRB400E reinforcing bar includes smelting, continuous casting, rolling process, tool That steps are as follows is described for body technology:
(1) smelting procedure: using the top compound converter smelting in bottom, converter top and bottom complex blowing uses nitrogen argon switching technique;Convertor deacidification closes Aurification, carburant use the petroleum coke of 0.70kg/t steel, alloying using the silicomanganese of 20kg/t steel, 1.0kg/t steel ferrosilicon, The FeV50-A of FeNb60-B, 0.20kg/t steel of 0.29kg/t steel, deoxidier use the Si-Al-Ba alloy strontium of 1.0kg/t steel;Terminal control System uses highcasting speed technique, converter smelting endpoint: C:0.10%, P:0.030%, S:0.032%, N:45ppm;
(2) continuous casting working procedure: the control of the packet degree of superheat is at 24 DEG C in continuous casting heat;
(3) rolling process: 988 DEG C of start rolling temperature, 920 DEG C of temperature on cooling table.
The present embodiment NbV combined microalloying HRB400E reinforcement property index is shown in Table 7, metallographic structure 40%F+60%P.
7 rolling specs Φ of table, 25 single line reinforcement property
The above embodiments are only used to illustrate and not limit the technical solutions of the present invention, although referring to above-described embodiment to the present invention into Go detailed description, those skilled in the art should understand that: it can still modify to the present invention or equally replace It changes, without departing from the spirit or scope of the invention, or any substitutions, should all cover and be wanted in right of the invention It asks in range.

Claims (10)

1. a kind of NbV combined microalloying HRB400E reinforcing bar, which is characterized in that the reinforcing bar chemical component composition and its quality Percentage composition are as follows: C:0.19-0.21%, Si:0.32-0.38%, Mn:1.33-1.38%, P≤0.041%, S≤0.041%, Nb: 0.017-0.019%, V:0.010-0.014%, N:50-70ppm, O≤50ppm, surplus are Fe and inevitable impurity.
2. a kind of NbV combined microalloying HRB400E reinforcing bar according to claim 1, which is characterized in that the reinforcing bar Study and be grouped as and its mass percentage are as follows: C:0.20%, Si:0.35%, Mn:1.36%, P≤0.036%, S≤0.036%, Nb:0.018%, V:0.013%, N:60ppm, O≤40ppm, surplus are Fe and inevitable impurity.
3. a kind of NbV combined microalloying HRB400E reinforcing bar according to claim 1, which is characterized in that the reinforcing bar rule Lattice are Φ 12-25mm;Metallographic structure be ferrite+pearlite+bainite, ferrite+pearlite >=90%, bainite≤10%, Grain size is 8.0~8.5 grades.
4. a kind of NbV combined microalloying HRB400E reinforcing bar according to claim 1, which is characterized in that the reinforcing bar is bent Take intensity 430-460MPa, tensile strength 590-615MPa, elongation 27-35%, Agt:13-14%, strong flexor ratio 1.33-1.38, Clod wash recurvation is functional.
5. based on a kind of production technology of NbV combined microalloying HRB400E reinforcing bar described in claim 1-4 any one, It is characterized in that, the production technology includes smelting, continuous casting, rolling process;The smelting procedure, using the top compound converter smelting in bottom Refining, Nb alloying use the FeNb60-B of 0.27-0.30kg/t steel, absorptivity 85%, and V alloyization uses 0.16-0.24kg/t steel FeV50-A, absorptivity 90%, terminal point control use highcasting speed technique;The rolling process, 970-1000 DEG C of start rolling temperature.
6. a kind of production technology of NbV combined microalloying HRB400E reinforcing bar according to claim 5, which is characterized in that The smelting procedure, using the top compound converter smelting in bottom, at converter smelting 720 seconds, bottom blowing system for converter automatically switches into argon gas Bottom blowing stirring is carried out, monolithic brick bottom blowing flow is 40m3/ h, according to the nominal capacity of converter, 4,6,8 pieces of bottom-blown air brick.
7. a kind of production technology of NbV combined microalloying HRB400E reinforcing bar according to claim 5, which is characterized in that The smelting procedure, terminal point control use highcasting speed technique, converter smelting endpoint: C >=0.10%, P≤0.030%, S≤ 0.035%, N:40-50ppm.
8. a kind of production technology of NbV combined microalloying HRB400E reinforcing bar according to claim 5-7 any one, It is characterized in that, the smelting procedure, convertor deacidification alloying, carburant use the petroleum coke of 0.70-0.80kg/t steel, silicomanganese Alloying uses the silicomanganese of 19-20kg/t steel, the ferrosilicon of 0.9-1.1kg/t steel;Deoxidier uses the sial of 0.5-1.0kg/t steel Barium strontium.
9. a kind of production technology of NbV combined microalloying HRB400E reinforcing bar according to claim 5-7 any one, It is characterized in that, the continuous casting working procedure, is continuously poured the packet degree of superheat in heat and controls at 20-30 DEG C, the two furnace degree of superheat before middle packet Control is at 30-50 DEG C.
10. a kind of production technology of NbV combined microalloying HRB400E reinforcing bar according to claim 5-7 any one, It is characterized in that, the rolling process, 970-1000 DEG C of start rolling temperature, 900-920 DEG C of temperature on cooling table.
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CN110125174A (en) * 2019-03-28 2019-08-16 盐城市联鑫钢铁有限公司 A kind of HRB400E-F valve snail fine grain rolling mill practice method
CN110885952A (en) * 2019-12-16 2020-03-17 本钢板材股份有限公司 400 MPa-grade hot-rolled ribbed steel bar and preparation method thereof
CN111519100A (en) * 2020-01-11 2020-08-11 武钢集团昆明钢铁股份有限公司 Niobium-vanadium microalloyed 400 MPa-grade ultrafine-grain high-toughness anti-seismic reinforcing steel bar and preparation method thereof
CN111876667A (en) * 2020-06-24 2020-11-03 宣化钢铁集团有限责任公司 HRB500E steel bar produced by micro-nitrogen alloy and production process thereof
CN112143967A (en) * 2020-08-26 2020-12-29 盐城市联鑫钢铁有限公司 Low-cost micro-vanadium ultrafine-grained steel bar and rolling process thereof

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Publication number Priority date Publication date Assignee Title
CN110125174A (en) * 2019-03-28 2019-08-16 盐城市联鑫钢铁有限公司 A kind of HRB400E-F valve snail fine grain rolling mill practice method
CN110885952A (en) * 2019-12-16 2020-03-17 本钢板材股份有限公司 400 MPa-grade hot-rolled ribbed steel bar and preparation method thereof
CN111519100A (en) * 2020-01-11 2020-08-11 武钢集团昆明钢铁股份有限公司 Niobium-vanadium microalloyed 400 MPa-grade ultrafine-grain high-toughness anti-seismic reinforcing steel bar and preparation method thereof
CN111876667A (en) * 2020-06-24 2020-11-03 宣化钢铁集团有限责任公司 HRB500E steel bar produced by micro-nitrogen alloy and production process thereof
CN112143967A (en) * 2020-08-26 2020-12-29 盐城市联鑫钢铁有限公司 Low-cost micro-vanadium ultrafine-grained steel bar and rolling process thereof
CN112143967B (en) * 2020-08-26 2021-06-15 盐城市联鑫钢铁有限公司 Low-cost micro-vanadium ultrafine-grained steel bar and rolling process thereof

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