CN109022105A - A kind of water-soluble fluorine carbon graphite alkene machine oil and preparation method thereof - Google Patents
A kind of water-soluble fluorine carbon graphite alkene machine oil and preparation method thereof Download PDFInfo
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- CN109022105A CN109022105A CN201810609357.8A CN201810609357A CN109022105A CN 109022105 A CN109022105 A CN 109022105A CN 201810609357 A CN201810609357 A CN 201810609357A CN 109022105 A CN109022105 A CN 109022105A
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
- C10M169/04—Mixtures of base-materials and additives
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M177/00—Special methods of preparation of lubricating compositions; Chemical modification by after-treatment of components or of the whole of a lubricating composition, not covered by other classes
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/04—Elements
- C10M2201/041—Carbon; Graphite; Carbon black
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/02—Hydroxy compounds
- C10M2207/021—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/022—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms containing at least two hydroxy groups
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/04—Ethers; Acetals; Ortho-esters; Ortho-carbonates
- C10M2207/042—Epoxides
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/04—Ethers; Acetals; Ortho-esters; Ortho-carbonates
- C10M2207/046—Hydroxy ethers
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2211/00—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions
- C10M2211/04—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions containing carbon, hydrogen, halogen, and oxygen
- C10M2211/042—Alcohols; Ethers; Aldehydes; Ketones
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/04—Phosphate esters
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2227/00—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions
- C10M2227/06—Organic compounds derived from inorganic acids or metal salts
- C10M2227/061—Esters derived from boron
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/02—Pour-point; Viscosity index
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/30—Anti-misting
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Abstract
The invention discloses a kind of water-soluble fluorine carbon graphite alkene machine oil and preparation method thereof.Its each ingredient containing parts by weight: 0.17-9 parts of fluorocarbon alcohols, 0.023-1.6 parts of graphenes, 29.7-62.3 parts of propylene glycol, 29.7-62.3 parts of ethylene glycol, 29.7-62.3 parts of triethylene glycols, 0.97-5.2 parts of borates, 1EO-9EO parts of ethylene oxide, 0.31-5 parts of phosphates.The water-soluble fluorine carbon graphite alkene machine oil has environmental protection, soluble easily in water, degradable, good lubricating properties, the rising of low pour point viscosity is small, and the decline of higher boiling viscosity is small, without the metallic elements such as zinc and copper, cadmium, nickel, cobalt, there is the advantages of traditional oil pollution environment of change, energy-saving and environment friendly.
Description
Technical field
The present invention relates to machine oil fields more particularly to a kind of water-soluble fluorine carbon graphite alkene machine oil and preparation method thereof.
Background technique
The whole world is mechanical all a large amount of useless using mineral oil as that can generate in the machine oil production process of main raw material(s) with oil at present
Containing metals such as copper, cadmium, nickel and cobalts in slag, waste water and exhaust gas, waste residue, waste water and exhaust gas, processed in machinery production, automobile, wheel
Leakage causes seriously to pollute using mineral oil as the machine oil of main raw material(s) to land resource and water resource in ship use process, right
Natural environment greatly destroys.
Summary of the invention
It is soluble easily in water the purpose of the present invention is to provide a kind of environmental protection, degradable, good lubricating properties, in low pour point viscosity
Rise small, small, the water-soluble fluorine carbon graphite alkene machine oil of the metallic elements such as no zinc and copper, cadmium, nickel, cobalt of higher boiling viscosity decline.The water
Dissolubility fluorine carbon graphite alkene machine oil has the advantages of changing traditional oil pollution environment, energy-saving and environment friendly.
To achieve the above object, the present invention provides a kind of water-soluble fluorine carbon graphite alkene machine oil, which is characterized in that containing following weight
Measure each ingredient of part:
Further, containing each ingredient of following parts by weight:
Further, containing each ingredient of following parts by weight:
Further, preparation method is that, by fluorocarbon alcohol, propylene glycol, ethylene glycol, triethylene glycol three stirs after mixing to be added
Heat, is slowly added to corresponding molal quantity ethylene oxide after being warming up to 80-170 DEG C, reaction was cooled to 60-70 after 120-200 minutes
℃；Preferably, 65 DEG C are cooled to after reacting 180 minutes；Borate, phosphate are added, graphene is adjusted after carrying out esterification
Whole pH value is 6.0-8.0, obtains water-soluble fluorine carbon graphite alkene machine oil.
In ingredient of the invention, fluorocarbon alcohol, propylene glycol, ethylene glycol, triethylene glycol, graphene, fluorocarbon alcohol has extremely strong
Water resistance, powerful steric hindrance and chemical inertness, plays good stability and lubricating action in oil product；Propylene glycol, second
Glycol, good adjusting lubricating oil is in 120-150 DEG C of high temperature viscosity-temperature coefficient stability, triethylene glycol, good adjusting lubricating oil
In -50 DEG C of low temperature resistant viscosity-temperature coefficient stability, guarantee the good starting performance of machine power；Graphene has good wear resistance
And thermal diffusivity, these synthesis change the excellent performance being unreachable to lubricating oil.
The synthetic motor oil and semi-synthetic machine oil that world market uses at present are in 120-150 DEG C of viscosity decline 85%, in this way
In the state of just lose 85% lubricity, viscosity, which is greater than 3000 and is stained with, when at -35 DEG C rises 2200% institute and dynamic is difficult
Starting.Synthetic motor oil and semi-synthetic machine oil that world market uses, machine oil own face tension are difficult between 25-30 simultaneously
Itself viscous pays can only play lubrication by viscosity is adjusted on metal to be adhered on metal.
And water-soluble fluorine carbon machine oil of the invention is good improves the synthetic motor oil and semi-synthetic machine that world market uses
Oily disadvantage, water-soluble fluorine carbon graphite alkene machine oil of the invention are maintained at a 50 viscous left sides in 120-150 DEG C of high temperature viscosity-temperature coefficient stability
The right side declines numerical value less than 35%, and viscosity is stained with no more than 1000 when at -40 DEG C rises the dynamic very easy starting of 60% institute,
Reach good lubricity.Water-soluble fluorine carbon graphite alkene machine oil own face tension of the invention is between 35-45 simultaneously, itself
It being easy to be adhered on metal, powerful affinity adherency on the metal surface, not glued by viscosity is adjusted and be paid in metal,
Reach good lubricity.
Water-soluble fluorine carbon graphite alkene machine oil of the invention is a kind of environment-friendly water-based mechanical lubrication oil, and low high temperature viscosity becomes
Change is very small, is free of volatile organic solvent.The fluorocarbon alcohol has good lubricating properties and stability, and graphene has good
Thermal conductivity and wear resistance are mainly used for aerospace, ship, industrial machinery and machining, new-energy automobile constant temperature lubrication, combustion
Petrol car lubricating oil, constant temperature is cooling, transmission machinery etc..
Water-soluble fluorine carbon graphite alkene machine oil of the invention is compared with the technology of conventional oil-based machine oil, aqueous machine oil tool subzero 50
It spends to 150 degree of superpower stability.It is experimentally confirmed, using water-soluble fluorine carbon graphite alkene machine oil of the invention, automobile is -50
DEG C moment it can start engine.At -50 DEG C, the engine oil viscosity of water-soluble fluorine carbon graphite alkene machine oil of the invention be can guarantee 50
(mm2/s)；At 150 DEG C, the engine oil viscosity of water-soluble fluorine carbon graphite alkene machine oil of the invention be can guarantee in 5 (mm2/s).Lubricity
On, it can only rely on viscosity as the machine oil of primary raw material using mineral oil and be sticked on metal and lubricate, and water-soluble fluorine carbon stone of the invention
Black alkene machine oil is lubricated so may adhere to metal surface without relying on viscosity i.e. due to can be hydrophilic in own molecular structure, so
Water-soluble fluorine carbon graphite alkene machine oil of the invention has good application prospect.
Water-soluble fluorine carbon graphite alkene machine oil rub resistance of the invention, resistance to acid and alkali, ageing resistance, solvent resistance, salt tolerance
And salt spray resistance can wait, and have better Corrosion Protection and lubricity, low reachable -50 degree of pour point, viscosity-temperature coefficient
The characteristics such as spending -40 keeps 1000 to glue, and 120 degree of holdings 50 are viscous.
Specific embodiment
The embodiment of the present invention is described below in detail, the examples of the embodiments are intended to be used to explain the present invention, and cannot
It is interpreted as limitation of the present invention.In the examples where no specific technique or condition is specified, described according to the literature in the art
Technology or conditions or carried out according to product description.Reagents or instruments used without specified manufacturer is that can lead to
Cross the conventional products of commercially available acquisition.
Embodiment 1: the preparation of water-soluble fluorine carbon graphite alkene machine oil
The formula table (parts by weight) of 1 embodiment 1-5 of table
Preparation method: by fluorocarbon alcohol, propylene glycol, ethylene glycol and triethylene glycol three agitating and heating after mixing, heating
Corresponding molal quantity ethylene oxide is slowly added to after to 80 DEG C, reaction cools to 65 DEG C after 180 minutes, adds borate, phosphorus
Acid esters, graphene after carrying out esterification, obtain acid product, then adjusting pH value with ammonium hydroxide is 6.0-8.0, obtains water solubility
Fluorine carbon graphite alkene machine oil.
It is preparation-obtained water-soluble fluorine carbon graphite alkene machine oil rub resistance 20000 hours, resistance to acid and alkali PH3-12, anti-aging
Property 10 years, solvent resistance, salt spray resistance 1000 hours can etc., there is better Corrosion Protection and lubricity, pour point is low can
The characteristics such as up to -50 degree, viscosity-temperature coefficient keeps 1000 to glue in -40 degree, and 120 degree of holdings 50 are viscous.Own face tension 35-45 it
Between.
Embodiment 2: the preparation of water-soluble fluorine carbon graphite alkene machine oil
Formula is shown in Table 1, and the preparation method is the same as that of Example 1.
Preparation method: by fluorocarbon alcohol, propylene glycol, ethylene glycol and triethylene glycol three agitating and heating after mixing, heating
Corresponding molal quantity ethylene oxide is slowly added to after to 170 DEG C, reaction cools to 60 DEG C after 120 minutes, adds borate, phosphorus
Acid esters, graphene after carrying out esterification, obtain acid product, then adjusting pH value with ammonium hydroxide is 6.0-8.0, obtains water solubility
Fluorine carbon graphite alkene machine oil.
It is preparation-obtained water-soluble fluorine carbon graphite alkene machine oil rub resistance 20000 hours, resistance to acid and alkali PH3-12, anti-aging
Property 10 years, solvent resistance, salt spray resistance 1000 hours can etc., there is better Corrosion Protection and lubricity, pour point is low can
The characteristics such as up to -50 degree, viscosity-temperature coefficient keeps 1000 to glue in -40 degree, and 120 degree of holdings 50 are viscous.Own face tension 35-45 it
Between.
Embodiment 3: the preparation of water-soluble fluorine carbon graphite alkene machine oil
Formula is shown in Table 1, and the preparation method is the same as that of Example 1.
Preparation method: by fluorocarbon alcohol, propylene glycol, ethylene glycol and triethylene glycol three agitating and heating after mixing, heating
Corresponding molal quantity ethylene oxide is slowly added to after to 100 DEG C, reaction cools to 70 DEG C after 200 minutes, adds borate, phosphorus
Acid esters, graphene after carrying out esterification, obtain acid product, then adjusting pH value with ammonium hydroxide is 6.0-8.0, obtains water solubility
Fluorine carbon graphite alkene machine oil.
It is preparation-obtained water-soluble fluorine carbon graphite alkene machine oil rub resistance 20000 hours, resistance to acid and alkali PH3-12, anti-aging
Property 10 years, solvent resistance, salt spray resistance 1000 hours can etc., there is better Corrosion Protection and lubricity, pour point is low can
The characteristics such as up to -50 degree, viscosity-temperature coefficient keeps 1000 to glue in -40 degree, and 120 degree of holdings 50 are viscous.Own face tension 35-45 it
Between.
Embodiment 4: the preparation of water-soluble fluorine carbon graphite alkene machine oil
Formula is shown in Table 1, and the preparation method is the same as that of Example 1.
Preparation method: by fluorocarbon alcohol, propylene glycol, ethylene glycol and triethylene glycol three agitating and heating after mixing, heating
Corresponding molal quantity ethylene oxide is slowly added to after to 120 DEG C, reaction cools to 63 DEG C after 150 minutes, adds borate, phosphorus
Acid esters, graphene after carrying out esterification, obtain acid product, then adjusting pH value with ammonium hydroxide is 6.0-8.0, obtains water solubility
Fluorine carbon graphite alkene machine oil.
It is preparation-obtained water-soluble fluorine carbon graphite alkene machine oil rub resistance 20000 hours, resistance to acid and alkali PH3-12, anti-aging
Property 10 years, solvent resistance, salt spray resistance 1000 hours can etc., there is better Corrosion Protection and lubricity, pour point is low can
The characteristics such as up to -50 degree, viscosity-temperature coefficient keeps 1000 to glue in -40 degree, and 120 degree of holdings 50 are viscous.Own face tension 35-45 it
Between.
Embodiment 5: the preparation of water-soluble fluorine carbon graphite alkene machine oil
Formula is shown in Table 1, and the preparation method is the same as that of Example 1.
Preparation method: by fluorocarbon alcohol, propylene glycol, ethylene glycol and triethylene glycol three agitating and heating after mixing, heating
Corresponding molal quantity ethylene oxide is slowly added to after to 150 DEG C, reaction cools to 68 degree after 180 minutes, adds borate, phosphorus
Acid esters, graphene after carrying out esterification, obtain acid product, then adjusting pH value with ammonium hydroxide is 6.0-8.0, obtains water solubility
Fluorine carbon graphite alkene machine oil.
It is preparation-obtained water-soluble fluorine carbon graphite alkene machine oil rub resistance 20000 hours, resistance to acid and alkali PH3-12, anti-aging
Property 10 years, solvent resistance, salt spray resistance 1000 hours can etc., there is better Corrosion Protection and lubricity, pour point is low can
The characteristics such as up to -50 degree, viscosity-temperature coefficient keeps 1000 to glue in -40 degree, and 120 degree of holdings 50 are viscous.Own face tension 35-45 it
Between.
Embodiment 6: compliance test result test
It is experimentally confirmed, buys one test at -40 DEG C of lucky automobile, the water-soluble fluorine carbon graphite of embodiment 1-5 by oneself
The engine oil viscosity of alkene machine oil can guarantee in 50 (mm2/s)；At 150 DEG C, the water-soluble fluorine carbon graphite alkene machine oil of embodiment 1-5
Engine oil viscosity can guarantee in 5 (mm2/s).In lubricity, viscosity can only be relied on by traditional machine oil of primary raw material of mineral oil
It is sticked on metal and lubricates, and water-soluble fluorine carbon graphite alkene machine oil of the invention is due to can be hydrophilic in own molecular structure, so nothing
Viscosity need to be relied on i.e. and may adhere to metal surface lubrication, so water-soluble fluorine carbon graphite alkene machine oil of the invention has good answer
Use prospect.
Although the embodiments of the present invention has been shown and described above, it is to be understood that above-described embodiment is example
Property, it is not considered as limiting the invention, those skilled in the art are not departing from the principle of the present invention and objective
In the case where can make changes, modifications, alterations, and variations to the above described embodiments within the scope of the invention.
Claims (4)
1. a kind of water-soluble fluorine carbon graphite alkene machine oil, which is characterized in that each ingredient containing following parts by weight:
2. water-soluble fluorine carbon graphite alkene machine oil described in claim 1, which is characterized in that each ingredient containing following parts by weight:
3. water-soluble fluorine carbon graphite alkene machine oil described in claim 2, which is characterized in that each ingredient containing following parts by weight:
4. any one of the claim 1-3 water-soluble fluorine carbon graphite alkene machine oil, which is characterized in that preparation method is, by fluorine carbon
Alcohol, propylene glycol, ethylene glycol and triethylene glycol three agitating and heating after mixing are slowly added to opposite after being warming up to 80-170 DEG C
Molal quantity ethylene oxide is answered, reaction was cooled to 60-70 DEG C after 120-200 minutes；Preferably, 65 are cooled to after reacting 180 minutes
℃；Borate is added, phosphate, graphene, adjustment pH value is 6.0-8.0 after carrying out esterification, obtains water-soluble fluorine carbon
Graphene machine oil.
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN110205185A (en) * | 2019-06-11 | 2019-09-06 | 日生能科技(厦门)有限公司 | A kind of rare earth compound lube oil additive manufacturing method |
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