CN109020018A - A kind of ultrasonic wave and ultraviolet advanced oxidation coupling water purification system and method - Google Patents

A kind of ultrasonic wave and ultraviolet advanced oxidation coupling water purification system and method Download PDF

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Publication number
CN109020018A
CN109020018A CN201811180721.XA CN201811180721A CN109020018A CN 109020018 A CN109020018 A CN 109020018A CN 201811180721 A CN201811180721 A CN 201811180721A CN 109020018 A CN109020018 A CN 109020018A
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CN
China
Prior art keywords
ultrasonic wave
water
reactor
ultraviolet
purification system
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201811180721.XA
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Chinese (zh)
Inventor
王永磊
杜振齐
王洪波
贾瑞宝
刘威
孙韶华
宋武昌
周安然
赵亮
刘宇雷
秦尧
鞠玲
李亚男
米记茹
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Shandong Jianzhu University
Original Assignee
Shandong Jianzhu University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shandong Jianzhu University filed Critical Shandong Jianzhu University
Priority to CN201811180721.XA priority Critical patent/CN109020018A/en
Publication of CN109020018A publication Critical patent/CN109020018A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/72Treatment of water, waste water, or sewage by oxidation
    • C02F1/722Oxidation by peroxides
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/30Treatment of water, waste water, or sewage by irradiation
    • C02F1/32Treatment of water, waste water, or sewage by irradiation with ultraviolet light
    • C02F1/325Irradiation devices or lamp constructions
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/34Treatment of water, waste water, or sewage with mechanical oscillations
    • C02F1/36Treatment of water, waste water, or sewage with mechanical oscillations ultrasonic vibrations
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2201/00Apparatus for treatment of water, waste water or sewage
    • C02F2201/32Details relating to UV-irradiation devices
    • C02F2201/322Lamp arrangement
    • C02F2201/3223Single elongated lamp located on the central axis of a turbular reactor
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2201/00Apparatus for treatment of water, waste water or sewage
    • C02F2201/32Details relating to UV-irradiation devices
    • C02F2201/322Lamp arrangement
    • C02F2201/3227Units with two or more lamps

Abstract

The present invention discloses a kind of ultrasonic wave and ultraviolet advanced oxidation coupling water purification system and method, and system includes sequentially connected water tank inlet, centrifugal pump, flowmeter, mixer, first-stage reactor, second reactor and water tank out;Gate valve is provided between centrifugal pump and flowmeter, the feed end of mixer is connect by metering pump with pharmacy jar;First-stage reactor and second reactor are provided with inlet and outlet, and the position of water inlet is lower than the position of water outlet;First-stage reactor and second reactor include mutually matched top plate and cavity, and vibration of ultrasonic wave stick is provided in cavity, and vibration of ultrasonic wave stick two sides are symmetrically arranged with ultraviolet light lamp group.By the way that ultraviolet high-level oxidation technology in conjunction with ultrasonic wave, to be made full use of to the strong oxidizing property of free matrix, oxidant utilization efficiency is improved, reaction rate is improved.

Description

A kind of ultrasonic wave and ultraviolet advanced oxidation coupling water purification system and method
Technical field
The present invention relates to Water purification fields, and in particular to a kind of ultrasonic wave and ultraviolet advanced oxidation coupling water purification system and Method.
Background technique
Current China water resource is more short, and whole water pollution form is more severe.Conventional water treatment process can only at present Macromolecule and hydrophobic organic compound are removed, there are toxicity, especially raw water for disinfectant itself or its disinfection by-products (DBPs) In micro- Organic Pollutants steady chemical structure long half time, conventional water treatment process is difficult to effectively remove it.In raw water water In the case where matter situation increasingly complexity, drinking water safety is difficult to be protected, and seriously affects quality of water environment and drinking water peace Entirely.
UV high-level oxidation technology (UV-Advanced Oxidantion Process, UV-AOPs) is to utilize ultraviolet light (UV) activation decomposes free radical donor and generates a kind of oxygen that high redox potential free radical decomposition water proposes harmful substance Change method.
High-level oxidation technology based on UV efficient, green, safety can go the spies such as micro- Organic Pollutants in water removal by it Point is widely applied in drinking water disinfection field, this technology is decomposed free radical donor using the activation of ultraviolet light light and produced Raw high redox potential free radical, by the organic micro-pollution in the strong oxidizing property decomposition of free radical or even mineralising natural water body Object.But the ultraviolet high-level oxidation technology technology applied at present is low in the prevalence of free radical donor utilization rate, and high expensive etc. is asked Topic, also, ultraviolet reactor common at present is mostly intermittent reaction device, and reaction rate is low, and clean-up effect is undesirable.
Summary of the invention
To solve the above-mentioned problems, the present invention discloses a kind of ultrasonic wave and ultraviolet advanced oxidation coupling water purification system and side Method improves oxidant benefit by the way that ultraviolet high-level oxidation technology in conjunction with ultrasonic wave, to be made full use of to the strong oxidizing property of free matrix With efficiency, reaction rate is improved.
A kind of ultrasonic wave and ultraviolet advanced oxidation couple water purification system, including sequentially connected water tank inlet, centrifugal pump, stream Meter, mixer, first-stage reactor, second reactor and water tank out;It is provided with gate valve between the centrifugal pump and flowmeter, The feed end of the mixer is connect by metering pump with pharmacy jar;The first-stage reactor and second reactor be provided with into The mouth of a river and water outlet, the position of the water inlet are lower than the position of water outlet;
The first-stage reactor and second reactor include mutually matched top plate and cavity, are provided with ultrasound in the cavity Wave shock club, vibration of ultrasonic wave stick two sides are symmetrically arranged with ultraviolet light lamp group, and the ultraviolet light lamp group includes multiple ultraviolet Line fluorescent tube and the quartz socket tube being entirely sleeved on the outside of multiple quartz burners, the ultrasonic vibration stick and ultraviolet light lamp group with Top plate is detachably connected, and the vibration of ultrasonic wave stick and ultraviolet light lamp group are electrically connected to control centre.
Preferably, the water inlet of the first-stage reactor is provided with the first sampling valve, the water outlet of the first-stage reactor It is provided with the second sampling valve at mouthful, the water outlet of the second reactor is provided with third sampling valve;
Preferably, it is provided with loophole on the first-stage reactor and second reactor, ultraviolet light intensity is installed at loophole Spend analyzer;
Preferably, the water inlet is provided with water feeding one-way valve, and the water outlet is provided with out water one-way valve;
Preferably, seal gasket is installed between the top plate and cavity, is provided with movable sealing outside the seal gasket Device, replaceable reaction cavity of different shapes;
Preferably, lamp tube joint is installed between the ultraviolet light lamp group and top plate, the lamp tube joint and ultraviolet light lamp group it Between be connected through a screw thread;
Preferably, the vibration of ultrasonic wave stick is made of supersonic generator and ultrasonic wave shake head, the supersonic generator position In top plate top;
Preferably, the control centre is provided with display and button, for adjusting ultrasonic frequency, power and ultraviolet light intensity Degree.
Preferably, the control centre use integrated numerically controlled display, uv agent amount, added amount of chemical, ultrasonic power, Frequency can be controlled separately, individually measure, and process combination operation is more flexible.
Preferably, a kind of process for purifying water coupled using ultrasonic wave and ultraviolet advanced oxidation is also disclosed in the application, specific to walk It is rapid as follows:
Step 1 will need the raw water purified to be placed in water tank inlet, and free radical donor is placed in pharmacy jar;
Step 2, raw water are pressurizeed through centrifugal pump, are adjusted flow by gate valve and flowmeter, are then flowed into static pipeline mixer, from Static pipeline mixer is imported after metering pump pressurizes by base donor;
Raw water and free radical donor are uniformly mixed by step 3, static pipeline mixer, and mixed liquor is then delivered to first order reaction Device opens ultrasonic generator and ultraviolet light lamp group, and the target organic in raw water is in free matrix, ultrasonic wave and ultraviolet light It is cleaved under double action;
Step 4 flows into second reactor through first-stage reactor treated water, opens ultrasonic generator and ultraviolet light lamp group, Continue to react;
Step 5, the solution after aoxidizing twice flow out to out water tank, and reaction is completed.
Beneficial effects of the present invention:
(1) present invention couples ultrasonic (US) cavitation oxidation with ultraviolet high-level oxidation technology, the height generated using ultrasonic cavitation bubble Warm high pressure microenvironment and the high-performance collective effect of ultraviolet light decompose solute molecule and generate energetic free radical (OH, SO4-), mention The high decomposition efficiency of oxidant accelerates reaction rate and improves object removal rate, at the same to Recalcitrant chemicals have compared with Good collaboration removal effect;
(2) ultrasound is coupled with ultraviolet high-level oxidation technology in the present invention, can solve conventional ultrasound cavitation oxidation technology high energy consumption Problem, while can also solve the problems, such as that ultraviolet high-level oxidation technology oxidant utilization is low, and then improve system economy;
(3) present invention will use overflow-type inlet and outlet system, achieve the purpose that actual production is mutually connected with laboratory research.
(4) present invention employs modularized design, replaceable reflection cavitys of different shapes.Comparative study reaction cavity Influence of the planform to reaction efficiency probes into out most suitable reactor cavity configuration, plays ultraviolet light spoke to greatest extent The effect of penetrating, improves utilization rate of ultraviolet light.
(5) present invention uses integrated numerically controlled display, and uv agent amount, added amount of chemical, ultrasonic power, frequency can be independent Control, individually metering, process combination operation are more flexible;
(6) cleaning action that ultrasonic wave generates in the present invention can remove the dirt that quartz socket tube surface is attached to when reaction, improve The utilization rate of ultraviolet light, and then improve reaction rate.
(7) it present invention employs the tandem of two stage treatment mode ultrasonic wave/ultraviolet reactor, reduces to a certain extent It is adversely affected caused by short stream in reactor, increases hydraulic detention time.
(8) present invention employs the tandem of two stage treatment form ultrasonic wave/ultraviolet reactor, organic matter passes through first Concentration significantly reduces after the reaction in stage, is conducive to the progress of second stage reaction, and then improve the removal rate of organic matter, mineralising Rate reduces reaction bring nocuousness intermediate product.
Detailed description of the invention
In order to illustrate the technical solutions in the embodiments of the present application or in the prior art more clearly, to embodiment or will show below There is attached drawing needed in technical description to be briefly described, it should be apparent that, the accompanying drawings in the following description is only this Some embodiments of application for those of ordinary skill in the art without creative efforts, can be with It obtains other drawings based on these drawings.
Fig. 1 is ultrasonic wave of the present invention and ultraviolet high-level oxidation technology Comprehensive water purifier system process figure;
Fig. 2 is first-stage reactor and second reactor three-dimensional structure diagram;
Fig. 3 is first-stage reactor or second reactor main view;
Fig. 4 is the partial enlarged view of A;
Fig. 5 is first-stage reactor or second reactor left view;
Fig. 6 is first-stage reactor or second reactor top view;
The position Fig. 7 water feeding one-way valve or out water one-way valve sectional structure chart;
In figure: 1. water tank inlets, 2. centrifugal pumps, 3. gate valves, 4. flowmeters, 5. mixers, 6. first sampling valves, 7. level-ones are anti- Answer device water inlet, 8. first-stage reactors, 9. first order reaction water outlets, 10. second sampling valves, 11. second reactor water inlets, 12. second reactor, 13. second reactor water outlets, 14. sampling valves, 15. go out water tank, 16. pharmacy jars, 17. metering pumps, 18. quartz socket tube, 19. ultraviolet lamp tubes, 20. movable sealing devices, 21. top plates, 22. lamp tube joints, 23. ultrasonic waves occur Device, 24. loopholes, 25. ultrasonic waves shake head, 26. ultraviolet light lamp groups, 27. ultrasonic power adjusters, 28. ultraviolet light lamp groups switch, 29. cavity, 30. controller displays, 31. control centres, 32. supersonic frequency adjusters, 33, movable sealing device, 34, close Potting pad.
Specific embodiment
Below in conjunction with the attached drawing in the embodiment of the present application, technical solutions in the embodiments of the present application carries out clear, complete Whole description, it is clear that described embodiments are only a part of embodiments of the present application, instead of all the embodiments.It is based on Embodiments herein, every other reality obtained by those of ordinary skill in the art without making creative efforts Example is applied, shall fall in the protection scope of this application.
As shown in figs. 1-7, water tank inlet 1 connects centrifugal pump 2, and centrifugal pump 2 is connect by gate valve 3 with flowmeter 4, flowmeter 4 are commonly connected to mixer 5 with metering pump 17, and mixer herein is preferably static mixer, and the other end of metering pump 17 connects Connect pharmacy jar 16, the first-stage reactor water inlet 7 of the other end connection first-stage reactor 8 of mixer 5, the one of first-stage reactor 8 Stage reactor water outlet 9 connects the second reactor water inlet 11 of second reactor 12, the second reactor of second reactor 12 Water outlet 13 is connected to out water tank 15.The first sampling valve 6 is provided between mixer 5 and first-stage reactor water inlet 7, It is provided with the second sampling valve 10 between the water outlet 9 and second reactor water inlet 11 of first-stage reactor, is gone out in second reactor Third sampling valve 14 is provided between the mouth of a river 13 and out water tank 15.
It is provided with loophole 24 on first-stage reactor 8 and second reactor 12, ultraviolet light intensity is installed at loophole 24 Analyzer is spent, to measure reactor marginal portion ultraviolet radiation intensity, and then is calculated in reactor according to attenuation coefficient Portion's ultraviolet radiation strength range.
The inlet and outlet of the first-stage reactor 8 and second reactor 12 use the formula adverse current of prancing of bottom in and top out Structure is equipped with water feeding one-way valve in water inlet to prevent water flow from flowing back, and is equipped with out water one-way valve in water outlet.Institute Stating first-stage reactor 8 and second reactor 12 includes mutually matched top plate 21 and cavity 29, is equipped with activity on top plate 21 Formula sealing device 33 is cased with seal gasket 34 on the outside of cavity 29, to guarantee leakproofness, passes through movable sealing device 33 and realizes top Plate 21 and the sealing installation of cavity 29.29 detachable connection of top plate 21 and cavity, to replace reaction cavity mould of different shapes Block.
Vibration of ultrasonic wave stick is provided in cavity 29, vibration of ultrasonic wave stick is by the supersonic generator positioned at 21 top of top plate 23 and the ultrasonic wave shake head 25 positioned at 21 lower part of top plate form, frequency of sound wave and power are adjustable, to adapt to different operating conditions Condition.
Ultrasonic wave shake 25 two sides of head are symmetrically arranged with ultraviolet light lamp group 26, and the ultraviolet light lamp group 26 includes multiple ultraviolet lights Fluorescent tube 19 and the quartz socket tube 18 for being entirely sleeved on multiple 19 outsides of quartz burner, the quantity of quartz burner is according to ultraviolet lamp Uv agent amount needed for power, ultraviolet light intensity, time for exposure and pending water determines that ultraviolet lamp group is vertically-mounted.Ultraviolet light Lamp tube joint is installed between lamp group 26 and top plate 21, is connected through a screw thread between the lamp tube joint and ultraviolet light lamp group 26, It is convenient for changing, further increases modularization effect.
Vibration of ultrasonic wave head 25 and ultraviolet light lamp group 26 are detachably connected with top plate 21, supersonic generator 23 and ultraviolet Light lamp group 26 is electrically connected with control centre 31.The control centre 31 is by display screen 30, ultrasonic power adjuster 27, supersonic frequency Rate adjuster 32, ultraviolet lamp group controller 28 form.The frequency and power of ultrasound shake stick 25 pass through 32,27 controls respectively, and lead to Cross the visualization of display 30;The opening and closing of ultraviolet lamp group is controlled by 28.
Pharmacy jar 16 uses corrosion resistant polytetrafluoroethylene material, to reduce issuable error in analytic process.Medicine Hydrogenperoxide steam generator, potassium persulfate solution can be added in agent tank 16, to realize UV/H respectively2O2With the advanced oxygen of UV/persulfate Change process.Metering pump 17 uses the biggish peristaltic pump of flow adjustment range to optimize experiment condition, seeks optimum condition.Medicament is thrown Dosage is between 0.5 ~ 10mg/L.
The system work process is as follows:
Raw water is placed in water tank 1, after the pressurization of centrifugal pump 2, adjusts flow, free radical donor by gate valve 3 and flowmeter 4 (H2O2、Or potassium peroxydisulfate) be placed in pharmacy jar 16, main water inlet tube is imported after the pressurization of metering pump 17, then mixed through pipe-line mixer 5 Reacted flowing into first-stage reactor 8 since first-stage reactor water inlet 7 after closing uniformly: target organic in raw water high energy from By base (OH or SO4-), be cracked into small organic molecule under the double action of ultrasonic wave and ultraviolet light, small part is mineralized For CO2And H2O;It is flowed out through treated the water of first-stage reactor 8 from the first-stage reactor water outlet 9 on reactor top, then from two Stage reactor water inlet 11 flow into second reactor 12 continue to react, in the process, reacted through previous step to be formed it is small Molecular organic and remaining target organic are oxidized to inorganic matter again;Finally, solution after aoxidizing twice is from second level Reactor water outlet 13 flow to water tank 15, and reaction is completed.Hydraulic detention time is not more than 10min in whole system, and flow velocity is not Greater than 0.1m/s, uv agent amount is in 200-300mJ/cm2For standard value.
The foregoing description of the disclosed embodiments makes professional and technical personnel in the field can be realized or use the application. Various modifications to these embodiments will be readily apparent to those skilled in the art, as defined herein General Principle can be realized in other embodiments without departing from the spirit or scope of the application.Therefore, the application It is not intended to be limited to the embodiments shown herein, and is to fit to and the principles and novel features disclosed herein phase one The widest scope of cause.

Claims (9)

1. a kind of ultrasonic wave and ultraviolet advanced oxidation couple water purification system, which is characterized in that including sequentially connected water tank inlet, Centrifugal pump, flowmeter, mixer, first-stage reactor, second reactor and water tank out;It is set between the centrifugal pump and flowmeter It is equipped with gate valve, the feed end of the mixer is connect by metering pump with pharmacy jar;The first-stage reactor and second reactor Inlet and outlet are provided with, the position of the water inlet is lower than the position of water outlet;
The first-stage reactor and second reactor include mutually matched top plate and cavity, are provided with ultrasound in the cavity Wave shock club, vibration of ultrasonic wave stick two sides are symmetrically arranged with ultraviolet light lamp group, and the ultraviolet light lamp group includes multiple ultraviolet Line fluorescent tube and the quartz socket tube being entirely sleeved on the outside of multiple quartz burners, the ultrasonic vibration stick and ultraviolet light lamp group with Top plate is detachably connected, and the top plate top is provided with the ultrasonic generator connecting with vibration of ultrasonic wave stick, the ultrasound Wave generating device and ultraviolet light lamp group are electrically connected to control centre.
2. a kind of ultrasonic wave as described in claim 1 and ultraviolet advanced oxidation couple water purification system, which is characterized in that described one The water inlet of stage reactor is provided with the first sampling valve, and the water outlet of the first-stage reactor is provided with the second sampling valve, The water outlet of the second reactor is provided with third sampling valve.
3. a kind of ultrasonic wave as claimed in claim 2 and ultraviolet advanced oxidation couple water purification system, which is characterized in that described one It is provided with loophole on stage reactor and second reactor, ultraviolet ray intensity analyzer is installed at loophole.
4. a kind of ultrasonic wave as described in claim 1 and ultraviolet advanced oxidation couple water purification system, which is characterized in that it is described into Water feeding one-way valve is provided at the mouth of a river, the water outlet is provided with out water one-way valve.
5. a kind of ultrasonic wave as claimed in claim 3 and ultraviolet advanced oxidation couple water purification system, which is characterized in that the top Seal gasket is installed between plate and cavity, movable attachment device is provided with outside the seal gasket.
6. a kind of ultrasonic wave as claimed in claim 5 and ultraviolet advanced oxidation couple water purification system, which is characterized in that described super Acoustic wave vibrations stick is made of supersonic generator and ultrasonic wave shake head, and the supersonic generator is located at top plate top.
7. a kind of ultrasonic wave as described in claim 1 and ultraviolet advanced oxidation couple water purification system, which is characterized in that the purple Lamp tube joint is installed between outer smooth lamp group and top plate, is connected through a screw thread between the lamp tube joint and ultraviolet light lamp group.
8. a kind of ultrasonic wave as described in claim 1 and ultraviolet advanced oxidation couple water purification system, which is characterized in that the control System is provided centrally with display and button.
9. using the method for ultrasonic wave as described in claim 1 and the coupling water purification system water purification of ultraviolet advanced oxidation, feature It is, steps are as follows:
Step 1 will need the raw water purified to be placed in water tank inlet, and free radical donor is placed in pharmacy jar;
Step 2, raw water are pressurizeed through centrifugal pump, are adjusted flow by gate valve and flowmeter, are then flowed into static pipeline mixer, from Static pipeline mixer is imported after metering pump pressurizes by base donor;
Raw water and free radical donor are uniformly mixed by step 3, static pipeline mixer, and mixed liquor is then delivered to first order reaction Device opens ultrasonic generator and ultraviolet light lamp group, and the target organic in raw water is in free matrix, ultrasonic wave and ultraviolet light It is cleaved under double action;
Step 4 flows into second reactor through first-stage reactor treated water, opens ultrasonic generator and ultraviolet light lamp group, Continue to react;
Step 5, the solution after aoxidizing twice flow out to out water tank, and reaction is completed.
CN201811180721.XA 2018-10-11 2018-10-11 A kind of ultrasonic wave and ultraviolet advanced oxidation coupling water purification system and method Pending CN109020018A (en)

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Application Number Priority Date Filing Date Title
CN201811180721.XA CN109020018A (en) 2018-10-11 2018-10-11 A kind of ultrasonic wave and ultraviolet advanced oxidation coupling water purification system and method

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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104445510A (en) * 2014-12-09 2015-03-25 北京科技大学 Baffled regulable ultrasonic/ultraviolet combined disinfection reactor
CN205011533U (en) * 2015-08-10 2016-02-03 西安建乐建设工程有限公司 Supersound - photocatalysis allies oneself with uses reaction unit
CN206142976U (en) * 2016-09-20 2017-05-03 深圳泰和环保科技有限公司 Processing apparatus of fragrant degradation waste water of ultrasonic technique ultraviolet ray
CN107619138A (en) * 2017-10-29 2018-01-23 三亚深海鲸电子科技有限公司 A kind of intelligent water body ultraviolet sterilization device
CN207276380U (en) * 2017-08-11 2018-04-27 内蒙古久科康瑞环保科技有限公司 A kind of waste water advanced oxidization system
CN210974240U (en) * 2018-10-11 2020-07-10 山东建筑大学 Ultrasonic wave and ultraviolet advanced oxidation coupling water purification system

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104445510A (en) * 2014-12-09 2015-03-25 北京科技大学 Baffled regulable ultrasonic/ultraviolet combined disinfection reactor
CN205011533U (en) * 2015-08-10 2016-02-03 西安建乐建设工程有限公司 Supersound - photocatalysis allies oneself with uses reaction unit
CN206142976U (en) * 2016-09-20 2017-05-03 深圳泰和环保科技有限公司 Processing apparatus of fragrant degradation waste water of ultrasonic technique ultraviolet ray
CN207276380U (en) * 2017-08-11 2018-04-27 内蒙古久科康瑞环保科技有限公司 A kind of waste water advanced oxidization system
CN107619138A (en) * 2017-10-29 2018-01-23 三亚深海鲸电子科技有限公司 A kind of intelligent water body ultraviolet sterilization device
CN210974240U (en) * 2018-10-11 2020-07-10 山东建筑大学 Ultrasonic wave and ultraviolet advanced oxidation coupling water purification system

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