CN109020018A - A kind of ultrasonic wave and ultraviolet advanced oxidation coupling water purification system and method - Google Patents
A kind of ultrasonic wave and ultraviolet advanced oxidation coupling water purification system and method Download PDFInfo
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- CN109020018A CN109020018A CN201811180721.XA CN201811180721A CN109020018A CN 109020018 A CN109020018 A CN 109020018A CN 201811180721 A CN201811180721 A CN 201811180721A CN 109020018 A CN109020018 A CN 109020018A
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- purification system
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 101
- 230000003647 oxidation Effects 0.000 title claims abstract description 27
- 238000007254 oxidation reaction Methods 0.000 title claims abstract description 27
- 238000000034 method Methods 0.000 title claims abstract description 18
- 238000000746 purification Methods 0.000 title claims abstract description 17
- 230000008878 coupling Effects 0.000 title claims abstract description 6
- 238000010168 coupling process Methods 0.000 title claims abstract description 6
- 238000005859 coupling reaction Methods 0.000 title claims abstract description 6
- 238000006243 chemical reaction Methods 0.000 claims abstract description 20
- 239000011159 matrix material Substances 0.000 claims abstract description 4
- 150000003254 radicals Chemical class 0.000 claims description 12
- 238000005070 sampling Methods 0.000 claims description 12
- 239000010453 quartz Substances 0.000 claims description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 9
- 230000003068 static effect Effects 0.000 claims description 7
- 238000002604 ultrasonography Methods 0.000 claims description 6
- 230000009471 action Effects 0.000 claims description 4
- 230000035939 shock Effects 0.000 claims description 2
- 238000005516 engineering process Methods 0.000 abstract description 12
- 230000001590 oxidative effect Effects 0.000 abstract description 7
- 239000007800 oxidant agent Substances 0.000 abstract description 4
- 230000008569 process Effects 0.000 description 10
- 230000000694 effects Effects 0.000 description 6
- 238000007789 sealing Methods 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 3
- 238000000354 decomposition reaction Methods 0.000 description 3
- 239000003651 drinking water Substances 0.000 description 3
- 235000020188 drinking water Nutrition 0.000 description 3
- 230000004913 activation Effects 0.000 description 2
- 230000002411 adverse Effects 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 239000003814 drug Substances 0.000 description 2
- 239000005416 organic matter Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 239000002957 persistent organic pollutant Substances 0.000 description 2
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 2
- 230000005855 radiation Effects 0.000 description 2
- 238000004659 sterilization and disinfection Methods 0.000 description 2
- 238000009303 advanced oxidation process reaction Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 208000002925 dental caries Diseases 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 239000000645 desinfectant Substances 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- JEGUKCSWCFPDGT-UHFFFAOYSA-N h2o hydrate Chemical compound O.O JEGUKCSWCFPDGT-UHFFFAOYSA-N 0.000 description 1
- 229960002163 hydrogen peroxide Drugs 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 239000013067 intermediate product Substances 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000008239 natural water Substances 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 230000002572 peristaltic effect Effects 0.000 description 1
- JRKICGRDRMAZLK-UHFFFAOYSA-L peroxydisulfate Chemical compound [O-]S(=O)(=O)OOS([O-])(=O)=O JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 1
- -1 polytetrafluoroethylene Polymers 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- 235000019394 potassium persulphate Nutrition 0.000 description 1
- 238000004382 potting Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000000523 sample Substances 0.000 description 1
- 230000026676 system process Effects 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 238000012800 visualization Methods 0.000 description 1
- 238000003911 water pollution Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/72—Treatment of water, waste water, or sewage by oxidation
- C02F1/722—Oxidation by peroxides
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/30—Treatment of water, waste water, or sewage by irradiation
- C02F1/32—Treatment of water, waste water, or sewage by irradiation with ultraviolet light
- C02F1/325—Irradiation devices or lamp constructions
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/34—Treatment of water, waste water, or sewage with mechanical oscillations
- C02F1/36—Treatment of water, waste water, or sewage with mechanical oscillations ultrasonic vibrations
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2201/00—Apparatus for treatment of water, waste water or sewage
- C02F2201/32—Details relating to UV-irradiation devices
- C02F2201/322—Lamp arrangement
- C02F2201/3223—Single elongated lamp located on the central axis of a turbular reactor
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2201/00—Apparatus for treatment of water, waste water or sewage
- C02F2201/32—Details relating to UV-irradiation devices
- C02F2201/322—Lamp arrangement
- C02F2201/3227—Units with two or more lamps
Abstract
The present invention discloses a kind of ultrasonic wave and ultraviolet advanced oxidation coupling water purification system and method, and system includes sequentially connected water tank inlet, centrifugal pump, flowmeter, mixer, first-stage reactor, second reactor and water tank out;Gate valve is provided between centrifugal pump and flowmeter, the feed end of mixer is connect by metering pump with pharmacy jar;First-stage reactor and second reactor are provided with inlet and outlet, and the position of water inlet is lower than the position of water outlet;First-stage reactor and second reactor include mutually matched top plate and cavity, and vibration of ultrasonic wave stick is provided in cavity, and vibration of ultrasonic wave stick two sides are symmetrically arranged with ultraviolet light lamp group.By the way that ultraviolet high-level oxidation technology in conjunction with ultrasonic wave, to be made full use of to the strong oxidizing property of free matrix, oxidant utilization efficiency is improved, reaction rate is improved.
Description
Technical field
The present invention relates to Water purification fields, and in particular to a kind of ultrasonic wave and ultraviolet advanced oxidation coupling water purification system and
Method.
Background technique
Current China water resource is more short, and whole water pollution form is more severe.Conventional water treatment process can only at present
Macromolecule and hydrophobic organic compound are removed, there are toxicity, especially raw water for disinfectant itself or its disinfection by-products (DBPs)
In micro- Organic Pollutants steady chemical structure long half time, conventional water treatment process is difficult to effectively remove it.In raw water water
In the case where matter situation increasingly complexity, drinking water safety is difficult to be protected, and seriously affects quality of water environment and drinking water peace
Entirely.
UV high-level oxidation technology (UV-Advanced Oxidantion Process, UV-AOPs) is to utilize ultraviolet light
(UV) activation decomposes free radical donor and generates a kind of oxygen that high redox potential free radical decomposition water proposes harmful substance
Change method.
High-level oxidation technology based on UV efficient, green, safety can go the spies such as micro- Organic Pollutants in water removal by it
Point is widely applied in drinking water disinfection field, this technology is decomposed free radical donor using the activation of ultraviolet light light and produced
Raw high redox potential free radical, by the organic micro-pollution in the strong oxidizing property decomposition of free radical or even mineralising natural water body
Object.But the ultraviolet high-level oxidation technology technology applied at present is low in the prevalence of free radical donor utilization rate, and high expensive etc. is asked
Topic, also, ultraviolet reactor common at present is mostly intermittent reaction device, and reaction rate is low, and clean-up effect is undesirable.
Summary of the invention
To solve the above-mentioned problems, the present invention discloses a kind of ultrasonic wave and ultraviolet advanced oxidation coupling water purification system and side
Method improves oxidant benefit by the way that ultraviolet high-level oxidation technology in conjunction with ultrasonic wave, to be made full use of to the strong oxidizing property of free matrix
With efficiency, reaction rate is improved.
A kind of ultrasonic wave and ultraviolet advanced oxidation couple water purification system, including sequentially connected water tank inlet, centrifugal pump, stream
Meter, mixer, first-stage reactor, second reactor and water tank out;It is provided with gate valve between the centrifugal pump and flowmeter,
The feed end of the mixer is connect by metering pump with pharmacy jar;The first-stage reactor and second reactor be provided with into
The mouth of a river and water outlet, the position of the water inlet are lower than the position of water outlet;
The first-stage reactor and second reactor include mutually matched top plate and cavity, are provided with ultrasound in the cavity
Wave shock club, vibration of ultrasonic wave stick two sides are symmetrically arranged with ultraviolet light lamp group, and the ultraviolet light lamp group includes multiple ultraviolet
Line fluorescent tube and the quartz socket tube being entirely sleeved on the outside of multiple quartz burners, the ultrasonic vibration stick and ultraviolet light lamp group with
Top plate is detachably connected, and the vibration of ultrasonic wave stick and ultraviolet light lamp group are electrically connected to control centre.
Preferably, the water inlet of the first-stage reactor is provided with the first sampling valve, the water outlet of the first-stage reactor
It is provided with the second sampling valve at mouthful, the water outlet of the second reactor is provided with third sampling valve;
Preferably, it is provided with loophole on the first-stage reactor and second reactor, ultraviolet light intensity is installed at loophole
Spend analyzer;
Preferably, the water inlet is provided with water feeding one-way valve, and the water outlet is provided with out water one-way valve;
Preferably, seal gasket is installed between the top plate and cavity, is provided with movable sealing outside the seal gasket
Device, replaceable reaction cavity of different shapes;
Preferably, lamp tube joint is installed between the ultraviolet light lamp group and top plate, the lamp tube joint and ultraviolet light lamp group it
Between be connected through a screw thread;
Preferably, the vibration of ultrasonic wave stick is made of supersonic generator and ultrasonic wave shake head, the supersonic generator position
In top plate top;
Preferably, the control centre is provided with display and button, for adjusting ultrasonic frequency, power and ultraviolet light intensity
Degree.
Preferably, the control centre use integrated numerically controlled display, uv agent amount, added amount of chemical, ultrasonic power,
Frequency can be controlled separately, individually measure, and process combination operation is more flexible.
Preferably, a kind of process for purifying water coupled using ultrasonic wave and ultraviolet advanced oxidation is also disclosed in the application, specific to walk
It is rapid as follows:
Step 1 will need the raw water purified to be placed in water tank inlet, and free radical donor is placed in pharmacy jar;
Step 2, raw water are pressurizeed through centrifugal pump, are adjusted flow by gate valve and flowmeter, are then flowed into static pipeline mixer, from
Static pipeline mixer is imported after metering pump pressurizes by base donor;
Raw water and free radical donor are uniformly mixed by step 3, static pipeline mixer, and mixed liquor is then delivered to first order reaction
Device opens ultrasonic generator and ultraviolet light lamp group, and the target organic in raw water is in free matrix, ultrasonic wave and ultraviolet light
It is cleaved under double action;
Step 4 flows into second reactor through first-stage reactor treated water, opens ultrasonic generator and ultraviolet light lamp group,
Continue to react;
Step 5, the solution after aoxidizing twice flow out to out water tank, and reaction is completed.
Beneficial effects of the present invention:
(1) present invention couples ultrasonic (US) cavitation oxidation with ultraviolet high-level oxidation technology, the height generated using ultrasonic cavitation bubble
Warm high pressure microenvironment and the high-performance collective effect of ultraviolet light decompose solute molecule and generate energetic free radical (OH, SO4-), mention
The high decomposition efficiency of oxidant accelerates reaction rate and improves object removal rate, at the same to Recalcitrant chemicals have compared with
Good collaboration removal effect;
(2) ultrasound is coupled with ultraviolet high-level oxidation technology in the present invention, can solve conventional ultrasound cavitation oxidation technology high energy consumption
Problem, while can also solve the problems, such as that ultraviolet high-level oxidation technology oxidant utilization is low, and then improve system economy;
(3) present invention will use overflow-type inlet and outlet system, achieve the purpose that actual production is mutually connected with laboratory research.
(4) present invention employs modularized design, replaceable reflection cavitys of different shapes.Comparative study reaction cavity
Influence of the planform to reaction efficiency probes into out most suitable reactor cavity configuration, plays ultraviolet light spoke to greatest extent
The effect of penetrating, improves utilization rate of ultraviolet light.
(5) present invention uses integrated numerically controlled display, and uv agent amount, added amount of chemical, ultrasonic power, frequency can be independent
Control, individually metering, process combination operation are more flexible;
(6) cleaning action that ultrasonic wave generates in the present invention can remove the dirt that quartz socket tube surface is attached to when reaction, improve
The utilization rate of ultraviolet light, and then improve reaction rate.
(7) it present invention employs the tandem of two stage treatment mode ultrasonic wave/ultraviolet reactor, reduces to a certain extent
It is adversely affected caused by short stream in reactor, increases hydraulic detention time.
(8) present invention employs the tandem of two stage treatment form ultrasonic wave/ultraviolet reactor, organic matter passes through first
Concentration significantly reduces after the reaction in stage, is conducive to the progress of second stage reaction, and then improve the removal rate of organic matter, mineralising
Rate reduces reaction bring nocuousness intermediate product.
Detailed description of the invention
In order to illustrate the technical solutions in the embodiments of the present application or in the prior art more clearly, to embodiment or will show below
There is attached drawing needed in technical description to be briefly described, it should be apparent that, the accompanying drawings in the following description is only this
Some embodiments of application for those of ordinary skill in the art without creative efforts, can be with
It obtains other drawings based on these drawings.
Fig. 1 is ultrasonic wave of the present invention and ultraviolet high-level oxidation technology Comprehensive water purifier system process figure;
Fig. 2 is first-stage reactor and second reactor three-dimensional structure diagram;
Fig. 3 is first-stage reactor or second reactor main view;
Fig. 4 is the partial enlarged view of A;
Fig. 5 is first-stage reactor or second reactor left view;
Fig. 6 is first-stage reactor or second reactor top view;
The position Fig. 7 water feeding one-way valve or out water one-way valve sectional structure chart;
In figure: 1. water tank inlets, 2. centrifugal pumps, 3. gate valves, 4. flowmeters, 5. mixers, 6. first sampling valves, 7. level-ones are anti-
Answer device water inlet, 8. first-stage reactors, 9. first order reaction water outlets, 10. second sampling valves, 11. second reactor water inlets,
12. second reactor, 13. second reactor water outlets, 14. sampling valves, 15. go out water tank, 16. pharmacy jars, 17. metering pumps,
18. quartz socket tube, 19. ultraviolet lamp tubes, 20. movable sealing devices, 21. top plates, 22. lamp tube joints, 23. ultrasonic waves occur
Device, 24. loopholes, 25. ultrasonic waves shake head, 26. ultraviolet light lamp groups, 27. ultrasonic power adjusters, 28. ultraviolet light lamp groups switch,
29. cavity, 30. controller displays, 31. control centres, 32. supersonic frequency adjusters, 33, movable sealing device, 34, close
Potting pad.
Specific embodiment
Below in conjunction with the attached drawing in the embodiment of the present application, technical solutions in the embodiments of the present application carries out clear, complete
Whole description, it is clear that described embodiments are only a part of embodiments of the present application, instead of all the embodiments.It is based on
Embodiments herein, every other reality obtained by those of ordinary skill in the art without making creative efforts
Example is applied, shall fall in the protection scope of this application.
As shown in figs. 1-7, water tank inlet 1 connects centrifugal pump 2, and centrifugal pump 2 is connect by gate valve 3 with flowmeter 4, flowmeter
4 are commonly connected to mixer 5 with metering pump 17, and mixer herein is preferably static mixer, and the other end of metering pump 17 connects
Connect pharmacy jar 16, the first-stage reactor water inlet 7 of the other end connection first-stage reactor 8 of mixer 5, the one of first-stage reactor 8
Stage reactor water outlet 9 connects the second reactor water inlet 11 of second reactor 12, the second reactor of second reactor 12
Water outlet 13 is connected to out water tank 15.The first sampling valve 6 is provided between mixer 5 and first-stage reactor water inlet 7,
It is provided with the second sampling valve 10 between the water outlet 9 and second reactor water inlet 11 of first-stage reactor, is gone out in second reactor
Third sampling valve 14 is provided between the mouth of a river 13 and out water tank 15.
It is provided with loophole 24 on first-stage reactor 8 and second reactor 12, ultraviolet light intensity is installed at loophole 24
Analyzer is spent, to measure reactor marginal portion ultraviolet radiation intensity, and then is calculated in reactor according to attenuation coefficient
Portion's ultraviolet radiation strength range.
The inlet and outlet of the first-stage reactor 8 and second reactor 12 use the formula adverse current of prancing of bottom in and top out
Structure is equipped with water feeding one-way valve in water inlet to prevent water flow from flowing back, and is equipped with out water one-way valve in water outlet.Institute
Stating first-stage reactor 8 and second reactor 12 includes mutually matched top plate 21 and cavity 29, is equipped with activity on top plate 21
Formula sealing device 33 is cased with seal gasket 34 on the outside of cavity 29, to guarantee leakproofness, passes through movable sealing device 33 and realizes top
Plate 21 and the sealing installation of cavity 29.29 detachable connection of top plate 21 and cavity, to replace reaction cavity mould of different shapes
Block.
Vibration of ultrasonic wave stick is provided in cavity 29, vibration of ultrasonic wave stick is by the supersonic generator positioned at 21 top of top plate
23 and the ultrasonic wave shake head 25 positioned at 21 lower part of top plate form, frequency of sound wave and power are adjustable, to adapt to different operating conditions
Condition.
Ultrasonic wave shake 25 two sides of head are symmetrically arranged with ultraviolet light lamp group 26, and the ultraviolet light lamp group 26 includes multiple ultraviolet lights
Fluorescent tube 19 and the quartz socket tube 18 for being entirely sleeved on multiple 19 outsides of quartz burner, the quantity of quartz burner is according to ultraviolet lamp
Uv agent amount needed for power, ultraviolet light intensity, time for exposure and pending water determines that ultraviolet lamp group is vertically-mounted.Ultraviolet light
Lamp tube joint is installed between lamp group 26 and top plate 21, is connected through a screw thread between the lamp tube joint and ultraviolet light lamp group 26,
It is convenient for changing, further increases modularization effect.
Vibration of ultrasonic wave head 25 and ultraviolet light lamp group 26 are detachably connected with top plate 21, supersonic generator 23 and ultraviolet
Light lamp group 26 is electrically connected with control centre 31.The control centre 31 is by display screen 30, ultrasonic power adjuster 27, supersonic frequency
Rate adjuster 32, ultraviolet lamp group controller 28 form.The frequency and power of ultrasound shake stick 25 pass through 32,27 controls respectively, and lead to
Cross the visualization of display 30;The opening and closing of ultraviolet lamp group is controlled by 28.
Pharmacy jar 16 uses corrosion resistant polytetrafluoroethylene material, to reduce issuable error in analytic process.Medicine
Hydrogenperoxide steam generator, potassium persulfate solution can be added in agent tank 16, to realize UV/H respectively2O2With the advanced oxygen of UV/persulfate
Change process.Metering pump 17 uses the biggish peristaltic pump of flow adjustment range to optimize experiment condition, seeks optimum condition.Medicament is thrown
Dosage is between 0.5 ~ 10mg/L.
The system work process is as follows:
Raw water is placed in water tank 1, after the pressurization of centrifugal pump 2, adjusts flow, free radical donor by gate valve 3 and flowmeter 4
(H2O2、Or potassium peroxydisulfate) be placed in pharmacy jar 16, main water inlet tube is imported after the pressurization of metering pump 17, then mixed through pipe-line mixer 5
Reacted flowing into first-stage reactor 8 since first-stage reactor water inlet 7 after closing uniformly: target organic in raw water high energy from
By base (OH or SO4-), be cracked into small organic molecule under the double action of ultrasonic wave and ultraviolet light, small part is mineralized
For CO2And H2O;It is flowed out through treated the water of first-stage reactor 8 from the first-stage reactor water outlet 9 on reactor top, then from two
Stage reactor water inlet 11 flow into second reactor 12 continue to react, in the process, reacted through previous step to be formed it is small
Molecular organic and remaining target organic are oxidized to inorganic matter again;Finally, solution after aoxidizing twice is from second level
Reactor water outlet 13 flow to water tank 15, and reaction is completed.Hydraulic detention time is not more than 10min in whole system, and flow velocity is not
Greater than 0.1m/s, uv agent amount is in 200-300mJ/cm2For standard value.
The foregoing description of the disclosed embodiments makes professional and technical personnel in the field can be realized or use the application.
Various modifications to these embodiments will be readily apparent to those skilled in the art, as defined herein
General Principle can be realized in other embodiments without departing from the spirit or scope of the application.Therefore, the application
It is not intended to be limited to the embodiments shown herein, and is to fit to and the principles and novel features disclosed herein phase one
The widest scope of cause.
Claims (9)
1. a kind of ultrasonic wave and ultraviolet advanced oxidation couple water purification system, which is characterized in that including sequentially connected water tank inlet,
Centrifugal pump, flowmeter, mixer, first-stage reactor, second reactor and water tank out;It is set between the centrifugal pump and flowmeter
It is equipped with gate valve, the feed end of the mixer is connect by metering pump with pharmacy jar;The first-stage reactor and second reactor
Inlet and outlet are provided with, the position of the water inlet is lower than the position of water outlet;
The first-stage reactor and second reactor include mutually matched top plate and cavity, are provided with ultrasound in the cavity
Wave shock club, vibration of ultrasonic wave stick two sides are symmetrically arranged with ultraviolet light lamp group, and the ultraviolet light lamp group includes multiple ultraviolet
Line fluorescent tube and the quartz socket tube being entirely sleeved on the outside of multiple quartz burners, the ultrasonic vibration stick and ultraviolet light lamp group with
Top plate is detachably connected, and the top plate top is provided with the ultrasonic generator connecting with vibration of ultrasonic wave stick, the ultrasound
Wave generating device and ultraviolet light lamp group are electrically connected to control centre.
2. a kind of ultrasonic wave as described in claim 1 and ultraviolet advanced oxidation couple water purification system, which is characterized in that described one
The water inlet of stage reactor is provided with the first sampling valve, and the water outlet of the first-stage reactor is provided with the second sampling valve,
The water outlet of the second reactor is provided with third sampling valve.
3. a kind of ultrasonic wave as claimed in claim 2 and ultraviolet advanced oxidation couple water purification system, which is characterized in that described one
It is provided with loophole on stage reactor and second reactor, ultraviolet ray intensity analyzer is installed at loophole.
4. a kind of ultrasonic wave as described in claim 1 and ultraviolet advanced oxidation couple water purification system, which is characterized in that it is described into
Water feeding one-way valve is provided at the mouth of a river, the water outlet is provided with out water one-way valve.
5. a kind of ultrasonic wave as claimed in claim 3 and ultraviolet advanced oxidation couple water purification system, which is characterized in that the top
Seal gasket is installed between plate and cavity, movable attachment device is provided with outside the seal gasket.
6. a kind of ultrasonic wave as claimed in claim 5 and ultraviolet advanced oxidation couple water purification system, which is characterized in that described super
Acoustic wave vibrations stick is made of supersonic generator and ultrasonic wave shake head, and the supersonic generator is located at top plate top.
7. a kind of ultrasonic wave as described in claim 1 and ultraviolet advanced oxidation couple water purification system, which is characterized in that the purple
Lamp tube joint is installed between outer smooth lamp group and top plate, is connected through a screw thread between the lamp tube joint and ultraviolet light lamp group.
8. a kind of ultrasonic wave as described in claim 1 and ultraviolet advanced oxidation couple water purification system, which is characterized in that the control
System is provided centrally with display and button.
9. using the method for ultrasonic wave as described in claim 1 and the coupling water purification system water purification of ultraviolet advanced oxidation, feature
It is, steps are as follows:
Step 1 will need the raw water purified to be placed in water tank inlet, and free radical donor is placed in pharmacy jar;
Step 2, raw water are pressurizeed through centrifugal pump, are adjusted flow by gate valve and flowmeter, are then flowed into static pipeline mixer, from
Static pipeline mixer is imported after metering pump pressurizes by base donor;
Raw water and free radical donor are uniformly mixed by step 3, static pipeline mixer, and mixed liquor is then delivered to first order reaction
Device opens ultrasonic generator and ultraviolet light lamp group, and the target organic in raw water is in free matrix, ultrasonic wave and ultraviolet light
It is cleaved under double action;
Step 4 flows into second reactor through first-stage reactor treated water, opens ultrasonic generator and ultraviolet light lamp group,
Continue to react;
Step 5, the solution after aoxidizing twice flow out to out water tank, and reaction is completed.
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CN104445510A (en) * | 2014-12-09 | 2015-03-25 | 北京科技大学 | Baffled regulable ultrasonic/ultraviolet combined disinfection reactor |
CN205011533U (en) * | 2015-08-10 | 2016-02-03 | 西安建乐建设工程有限公司 | Supersound - photocatalysis allies oneself with uses reaction unit |
CN206142976U (en) * | 2016-09-20 | 2017-05-03 | 深圳泰和环保科技有限公司 | Processing apparatus of fragrant degradation waste water of ultrasonic technique ultraviolet ray |
CN207276380U (en) * | 2017-08-11 | 2018-04-27 | 内蒙古久科康瑞环保科技有限公司 | A kind of waste water advanced oxidization system |
CN107619138A (en) * | 2017-10-29 | 2018-01-23 | 三亚深海鲸电子科技有限公司 | A kind of intelligent water body ultraviolet sterilization device |
CN210974240U (en) * | 2018-10-11 | 2020-07-10 | 山东建筑大学 | Ultrasonic wave and ultraviolet advanced oxidation coupling water purification system |
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