CN109019842A - A kind of spherical suspending biologic packing material - Google Patents

A kind of spherical suspending biologic packing material Download PDF

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Publication number
CN109019842A
CN109019842A CN201810754557.2A CN201810754557A CN109019842A CN 109019842 A CN109019842 A CN 109019842A CN 201810754557 A CN201810754557 A CN 201810754557A CN 109019842 A CN109019842 A CN 109019842A
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CN
China
Prior art keywords
parts
biologic packing
spherosome
packing material
shell
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810754557.2A
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Chinese (zh)
Inventor
陈宽
陈勇
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Zhejiang World Clean Environment Engineering Co Ltd
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Zhejiang World Clean Environment Engineering Co Ltd
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Publication date
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Priority to CN201810754557.2A priority Critical patent/CN109019842A/en
Publication of CN109019842A publication Critical patent/CN109019842A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/02Aerobic processes
    • C02F3/10Packings; Fillings; Grids
    • C02F3/109Characterized by the shape
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/02Aerobic processes
    • C02F3/10Packings; Fillings; Grids
    • C02F3/105Characterized by the chemical composition
    • C02F3/107Inorganic materials, e.g. sand, silicates
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/02Aerobic processes
    • C02F3/10Packings; Fillings; Grids
    • C02F3/105Characterized by the chemical composition
    • C02F3/108Immobilising gels, polymers or the like
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00Technologies for wastewater treatment
    • Y02W10/10Biological treatment of water, waste water, or sewage

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  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Biodiversity & Conservation Biology (AREA)
  • Microbiology (AREA)
  • Hydrology & Water Resources (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Carbon And Carbon Compounds (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Silicon Compounds (AREA)

Abstract

The invention discloses a kind of spherical suspending biologic packing materials, and the spherosome that can longitudinally rotate also is socketed with including shell spherical in shape, in the shell, be socketed in spherosome can transverse rotation ellipsoid;The hole of hollow out is distributed on the shell, the aperture of hollow out is distributed on the spherosome, fin is distributed on the ellipsoid, through slot is distributed between each fin.A kind of spherical suspending biologic packing material that the present invention obtains, the spherical suspending biologic packing material include shell, spherosome and ellipsoid from outside to inside, and wherein spherosome can longitudinally rotate, and ellipsoid can transverse rotation.By three spheres of setting to increase mobility, especially ellipsoidal fin even more improves the specific surface area of filling ball.In addition the shell, spherosome and ellipsoidal material are any one of modified polypropene or modified poly ethylene, to realize the feature that hydrophily is strong, biofilm is easy.

Description

A kind of spherical suspending biologic packing material
Technical field
The present invention relates to a kind of filler, especially a kind of spherical suspending biologic packing material.
Background technique
It needs to make the organic matter and impurity in sewage by it in processed sewage currently, biologic packing material ball is placed in It is separated from water.That is, organic matter and impurity in water are attached to filling ball when the water with dirt flows through filling ball On, then these organic matters and impurity react with the microorganism on filler, until being broken down into innocuous substance to reach The purpose of purification of water quality, such as: eliminate ammonia, the nitrogen component in water.
But the specific surface area of existing filling ball is smaller and does not allow easy to be filmed, when needing to adhere to more microorganisms It can only be realized by accelerating, increase cost of sewage disposal.
Summary of the invention
A kind of large specific surface area, hydrophily are provided the purpose of the present invention is to solve above-mentioned the deficiencies in the prior art By force, the easy a kind of spherical suspending biologic packing material of biofilm, can enhance wastewater treatment efficiency.
To achieve the goals above, a kind of spherical suspending biologic packing material designed by the present invention, including shell spherical in shape, The spherosome that can longitudinally rotate also is socketed in the shell, be socketed in spherosome can transverse rotation ellipsoid; The hole of hollow out is distributed on the shell, the aperture of hollow out is distributed on the spherosome, fin is distributed on the ellipsoid Through slot is distributed between each fin in piece.
The shell, spherosome and ellipsoidal material are any one of modified polypropene or modified poly ethylene.
The modified polypropene is made by being covered with hydrophilic agent in the painting of polyacrylic surface, and the hydrophilic agent is by weight Including 5-10 parts of nano silica, 10-15 parts of alkyl phenol polyoxyethylene ether, 1-5 parts of carbon nanotube, 10-15 parts of polyvinyl chloride, 50-60 parts of ethyl alcohol, 10-15 parts of isopropanol, 30-40 parts of water.
The modified poly ethylene includes 95 parts of polyethylene and 5 parts of modifying agent by weight, and the modifying agent wraps by weight Include 50-60 parts of polyacrylate, 20-30 parts of polyethylene glycol, 10-15 parts of Kynoar, 5-8 parts of polyurethane, basic zirconium phosphate 2-3 Part, 1-3 parts of rare earth.
The preparation method of the hydrophilic agent is by weight by 5-10 parts of nano silica, alkyl phenol polyoxyethylene ether 10-15 parts, 1-5 parts of carbon nanotube, 10-15 parts of polyvinyl chloride, 50-60 parts of ethyl alcohol, 10-15 parts of isopropanol, 30-40 parts of water mixing After mixing evenly, 24 hours are stood.
The preparation method of the modifying agent is by weight by 50-60 parts of polyacrylate, 20-30 parts of polyethylene glycol, poly- 10-15 parts of vinylidene, 5-8 parts of polyurethane, 2-3 parts of basic zirconium phosphate, 1-3 parts of rare earth be put into 200-240 DEG C of high temperature reaction stove, It heats 1-2h under nitrogen protection, pulverizes after cooling to obtain the final product.
The preparation method of the modified poly ethylene is by weight to add 95 parts of polyethylene and 5 parts of modifying agent in extruder Heat fusing squeezes out, and temperature is 200-220 DEG C.
The spherical suspending biologic packing material includes shell, spherosome and ellipsoid from outside to inside, and wherein spherosome can longitudinally revolve Turn, ellipsoid can transverse rotation.By three spheres of setting to increase the water body flow inside filler, especially ellipsoid Fin, even more improve the specific surface area of filling ball.
The shell, spherosome and ellipsoidal material are any one of modified polypropene or modified poly ethylene.This It is to be unfavorable for the absorption of biomembrane, it is therefore desirable to be modified to it since polypropylene and polyethylene ontology are relative hydrophobics.
The modified polypropene is to be covered with the alkyl that hydrophilic agent is obtained, in the hydrophilic agent by applying on polyacrylic surface Phenol polyethenoxy ether is a kind of nonionic surfactant as main hydrophilic component, it have property stable, acid and alkali-resistance and at This low feature.Intensity can be improved in nano silica and carbon nanotube, and polyvinyl chloride improves hydrophily as auxiliary agent.Second Alcohol, isopropyl alcohol and water are as solvent.
The modified poly ethylene by parts by weight by 95 parts of polyethylene and 5 parts of modifying agent in extruder heating melting squeeze out and , polyacrylate, polyethylene glycol and polyurethane in the modifying agent can improve the hydrophily of polyethylene, polyacrylic acid Contain on the strand of ester there are many ester group, ester group, there is hydrophily.The terminal hydroxy group of polyethylene glycol is hydrophilic, the ehter bond in chain It is hydrophilic.Anti-corrosive properties can be improved in Kynoar, and basic zirconium phosphate then improves intensity, and rare earth improves the parent of modifying agent as catalyst It is aqueous.
A kind of spherical suspending biologic packing material that the present invention obtains, the spherical suspending biologic packing material include from outside to inside shell, Spherosome and ellipsoid, wherein spherosome can longitudinally rotate, and ellipsoid can transverse rotation.By three spheres of setting to increase Mobility, especially ellipsoidal fin, even more improves the specific surface area of filling ball.In addition the shell, spherosome and ellipse The material of circle is any one of modified polypropene or modified poly ethylene, to realize that hydrophily is strong, biofilm is readily special Point.Spherical suspending biologic packing material produced by the present invention, specific gravity 0.92-0.95g/cm3, specific surface area 500-800m2/m3
Detailed description of the invention
Fig. 1 is the structural schematic diagram of the spherical suspending biologic packing material of embodiment 1;
Fig. 2 is ellipsoidal structural schematic diagram in the spherical suspending biologic packing material of embodiment 1.
In figure: shell 1, spherosome 2, ellipsoid 3, hole 4, aperture 5, fin 6, through slot 7.
Specific embodiment
Present invention will be further explained below with reference to the attached drawings and examples.
Embodiment 1:
As Figure 1-Figure 2, a kind of spherical suspending biologic packing material provided in this embodiment, including spherical suspending biologic packing material, packet Shell 1 spherical in shape is included, the spherosome that can longitudinally rotate 2 is also socketed in the shell 1, is socketed in spherosome 2 Can transverse rotation ellipsoid 3;The hole 4 of hollow out is distributed on the shell 1, the small of hollow out is distributed on the spherosome 2 Hole 5 is distributed with fin 6 on the ellipsoid 3, through slot 7 is distributed between each fin 6.
The material of the shell 1, spherosome 2 and ellipsoid 3 is modified polypropene.
The modified polypropene is made by being covered with hydrophilic agent in the painting of polyacrylic surface, and the hydrophilic agent is by weight Including 5 parts of nano silica, 10 parts of alkyl phenol polyoxyethylene ether, 1 part of carbon nanotube, 10 parts of polyvinyl chloride, 50 parts of ethyl alcohol, different 10 parts of propyl alcohol, 30 parts of water.
The preparation method of the hydrophilic agent be by weight by 5 parts of nano silica, 10 parts of alkyl phenol polyoxyethylene ether, 1 part of carbon nanotube, 10 parts of polyvinyl chloride, 50 parts of ethyl alcohol, 10 parts of isopropanol, 30 parts of water be mixed evenly after, stand 24 hours ?.
By testing, spherical suspending biologic packing material made from the present embodiment, specific gravity 0.92-0.95g/cm3, specific surface Product is 500-800m2/m3
Embodiment 2:
A kind of spherical suspending biologic packing material provided in this embodiment, general structure is identical as embodiment, and difference is described The material of shell 1, spherosome 2 and ellipsoid 3 is modified poly ethylene.
The modified poly ethylene includes 95 parts of polyethylene and 5 parts of modifying agent by weight, and the modifying agent wraps by weight Include 50 parts of polyacrylate, 20 parts of polyethylene glycol, 10 parts of Kynoar, 5 parts of polyurethane, 2 parts of basic zirconium phosphate, 1 part of rare earth.
The preparation method of the modifying agent is by weight by 50 parts of polyacrylate, 20 parts of polyethylene glycol, polyvinylidene fluoride 10 parts of alkene, 5 parts of polyurethane, 2 parts of basic zirconium phosphate, 1 part of rare earth be put into 200-240 DEG C of high temperature reaction stove, heated under nitrogen protection 1-2h pulverizes after cooling to obtain the final product.
The preparation method of the modified poly ethylene is by weight to add 95 parts of polyethylene and 5 parts of modifying agent in extruder Heat fusing squeezes out, and temperature is 200-220 DEG C.
By testing, spherical suspending biologic packing material made from the present embodiment, specific gravity 0.92-0.95g/cm3, specific surface Product is 500-800m2/m3
Embodiment 3:
A kind of spherical suspending biologic packing material provided in this embodiment, general structure is identical as embodiment, and difference is described Shell 1, spherosome 2 material be modified polypropene, the material of ellipsoid 3 is modified poly ethylene.
The modified polypropene is made by being covered with hydrophilic agent in the painting of polyacrylic surface, and the hydrophilic agent is by weight Including 10 parts of nano silica, 15 parts of alkyl phenol polyoxyethylene ether, 5 parts of carbon nanotube, 15 parts of polyvinyl chloride, 60 parts of ethyl alcohol, 15 parts of isopropanol, 40 parts of water.
The modified poly ethylene includes 95 parts of polyethylene and 5 parts of modifying agent by weight, and the modifying agent wraps by weight Include 60 parts of polyacrylate, 30 parts of polyethylene glycol, 15 parts of Kynoar, 8 parts of polyurethane, 3 parts of basic zirconium phosphate, 3 parts of rare earth.
By testing, spherical suspending biologic packing material made from the present embodiment, specific gravity 0.92-0.95g/cm3, specific surface Product is 500-800m2/m3

Claims (7)

1. a kind of spherical suspending biologic packing material, including shell (1) spherical in shape, it is characterised in that: be also socketed in the shell (1) Have the spherosome that can longitudinally rotate (2), be socketed in the spherosome (2) can transverse rotation ellipsoid (3);The shell (1) hole (4) of hollow out is distributed on, the aperture (5) of hollow out is distributed on the spherosome (2), divides on the ellipsoid (3) It is furnished with fin (6), through slot (7) is distributed between each fin (6).
2. a kind of spherical suspending biologic packing material according to claim 1, it is characterised in that: the shell (1), spherosome (2) and the material of ellipsoid (3) is any one of modified polypropene or modified poly ethylene.
3. a kind of spherical suspending biologic packing material according to claim 2, it is characterised in that: the modified polypropene is to pass through On polyacrylic surface, painting is covered with hydrophilic agent and is made, and the hydrophilic agent includes 5-10 parts of nano silica, alkyl by weight 10-15 parts of phenol polyethenoxy ether, 1-5 parts of carbon nanotube, 10-15 parts of polyvinyl chloride, 50-60 parts of ethyl alcohol, 10-15 parts of isopropanol, 30-40 parts of water.
4. a kind of spherical suspending biologic packing material according to claim 2, it is characterised in that: the modified poly ethylene is by weight Part includes 95 parts of polyethylene and 5 parts of modifying agent, and the modifying agent includes 50-60 parts of polyacrylate, polyethylene glycol by weight 20-30 parts, 10-15 parts of Kynoar, 5-8 parts of polyurethane, 2-3 parts of basic zirconium phosphate, 1-3 parts of rare earth.
5. a kind of spherical suspending biologic packing material according to claim 3, it is characterised in that: the preparation method of the hydrophilic agent It is by weight by 5-10 parts of nano silica, 10-15 parts of alkyl phenol polyoxyethylene ether, 1-5 parts of carbon nanotube, polyvinyl chloride 10-15 parts, 50-60 parts of ethyl alcohol, 10-15 parts of isopropanol, 30-40 parts of water be mixed evenly after, stand 24 hours.
6. a kind of spherical suspending biologic packing material according to claim 4, it is characterised in that: the preparation method of the modifying agent Be by weight by 50-60 parts of polyacrylate, 20-30 parts of polyethylene glycol, 10-15 parts of Kynoar, 5-8 parts of polyurethane, 2-3 parts of basic zirconium phosphate, 1-3 parts of rare earth be put into 200-240 DEG C of high temperature reaction stove, 1-2h is heated under nitrogen protection, after cooling It pulverizes to obtain the final product.
7. a kind of spherical suspending biologic packing material according to claim 4, it is characterised in that: the preparation of the modified poly ethylene Method is that by 95 parts of polyethylene and 5 parts of modifying agent, heating melting is squeezed out in extruder by weight, and temperature is 200-220 DEG C.
CN201810754557.2A 2018-07-11 2018-07-11 A kind of spherical suspending biologic packing material Pending CN109019842A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111233145A (en) * 2020-01-16 2020-06-05 桂林理工大学 Novel inorganic-organic material synergistic rapid-separation biochemical ball and preparation method thereof
CN111530408A (en) * 2020-03-26 2020-08-14 苏州仕净环保科技股份有限公司 Spherical filler
CN114516703A (en) * 2021-12-29 2022-05-20 盐城工学院 Treatment device and treatment method suitable for rural sewage treatment
CN115504566A (en) * 2022-10-28 2022-12-23 四川龙源智造水处理设备有限公司 Biological strain packing container for sewage treatment

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3110859A1 (en) * 1980-03-25 1982-01-07 Faigle Kunststoffe Gesellschaft mbH, 6971 Hard Multi-purpose element, in particular a filler for installations for exchanging energy and/or mass or for eliminating drops
CN2782667Y (en) * 2005-03-31 2006-05-24 上海中耀环保实业有限公司 Outer cover type arc stack suspension organism carrier
CN101628758A (en) * 2009-08-04 2010-01-20 中国人民解放军后勤工程学院 Modified PVC biologic filler
KR100987130B1 (en) * 2010-04-07 2010-10-11 (주)상록이티씨 Carrier and sewage treatment method using carrier and bioreactor
KR20110010904A (en) * 2009-07-27 2011-02-08 김도선 Fluidized bed media
CN107265913A (en) * 2016-04-08 2017-10-20 南京唯才新能源科技有限公司 A kind of aerogel composite and preparation method thereof

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3110859A1 (en) * 1980-03-25 1982-01-07 Faigle Kunststoffe Gesellschaft mbH, 6971 Hard Multi-purpose element, in particular a filler for installations for exchanging energy and/or mass or for eliminating drops
CN2782667Y (en) * 2005-03-31 2006-05-24 上海中耀环保实业有限公司 Outer cover type arc stack suspension organism carrier
KR20110010904A (en) * 2009-07-27 2011-02-08 김도선 Fluidized bed media
CN101628758A (en) * 2009-08-04 2010-01-20 中国人民解放军后勤工程学院 Modified PVC biologic filler
KR100987130B1 (en) * 2010-04-07 2010-10-11 (주)상록이티씨 Carrier and sewage treatment method using carrier and bioreactor
CN107265913A (en) * 2016-04-08 2017-10-20 南京唯才新能源科技有限公司 A kind of aerogel composite and preparation method thereof

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111233145A (en) * 2020-01-16 2020-06-05 桂林理工大学 Novel inorganic-organic material synergistic rapid-separation biochemical ball and preparation method thereof
CN111530408A (en) * 2020-03-26 2020-08-14 苏州仕净环保科技股份有限公司 Spherical filler
CN114516703A (en) * 2021-12-29 2022-05-20 盐城工学院 Treatment device and treatment method suitable for rural sewage treatment
CN115504566A (en) * 2022-10-28 2022-12-23 四川龙源智造水处理设备有限公司 Biological strain packing container for sewage treatment

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Application publication date: 20181218