CN109004318A - Detachable aluminium-air cell device - Google Patents

Detachable aluminium-air cell device Download PDF

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Publication number
CN109004318A
CN109004318A CN201810853938.6A CN201810853938A CN109004318A CN 109004318 A CN109004318 A CN 109004318A CN 201810853938 A CN201810853938 A CN 201810853938A CN 109004318 A CN109004318 A CN 109004318A
Authority
CN
China
Prior art keywords
electrolyte
battery pack
battery
reserve tank
stocking system
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810853938.6A
Other languages
Chinese (zh)
Inventor
付超鹏
韩雨峰
蒋敏
张佼
孙宝德
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shanghai Jiaotong University
Original Assignee
Shanghai Jiaotong University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shanghai Jiaotong University filed Critical Shanghai Jiaotong University
Priority to CN201810853938.6A priority Critical patent/CN109004318A/en
Publication of CN109004318A publication Critical patent/CN109004318A/en
Pending legal-status Critical Current

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Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M12/00Hybrid cells; Manufacture thereof
    • H01M12/04Hybrid cells; Manufacture thereof composed of a half-cell of the fuel-cell type and of a half-cell of the primary-cell type
    • H01M12/06Hybrid cells; Manufacture thereof composed of a half-cell of the fuel-cell type and of a half-cell of the primary-cell type with one metallic and one gaseous electrode
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/60Arrangements or processes for filling or topping-up with liquids; Arrangements or processes for draining liquids from casings
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Hybrid Cells (AREA)

Abstract

A kind of detachable aluminium-air cell device, it include: battery pack and the electrolyte stocking system being flexibly connected therewith, the electrolyte stocking system includes: two and imports and exports the electrolyte reserve tank being selectively connected to by electrolyte, one electrolyte reserve tank is connected with battery pack, another electrolyte reserve tank is equipped with electrolyte note row's mouth, when needing battery pack to stop working, open electrolyte inlet and outlet switch, electrolyte flows out battery pack, it flows into electrolyte tank, electrode is separated with electrolyte, stops electric discharge;When battery needs to discharge again, cell apparatus is inverted, electrolyte flows back in battery pack, and realization is discharged again.The present invention simple and quick can be such that electrode and electrolyte separates, and control reaction immediately starts and stops, and improves battery.

Description

Detachable aluminium-air cell device
Technical field
The present invention relates to a kind of technology in aluminium-air cell field, specifically a kind of detachable aluminium-air cell Device.
Background technique
Aluminium-air cell is a kind of novel metal fuel battery, and anode is made of air electrode, and cathode is by fine aluminium or aluminium Composition of alloy, electrolyte is using neutral or alkaline solution.Neutral electrolyte can use sodium chloride solution, alkaline electrolyte Sodium hydroxide or potassium hydroxide solution can be used.Cathode aluminium sheet and electricity can be constantly consumed in aluminium-air cell discharge process Liquid is solved, does not need to recharge after battery discharge, replacing electrode plate and supplementing electrolyte can be realized re-discharge.Aluminium is empty In the stand-by state, self-corrosion can occur for cathode aluminium sheet and electrolyte contacts, and aluminium sheet and electrolyte can be consumed constantly in pneumoelectric pond, cause Make energy loss.
Summary of the invention
The present invention In view of the above shortcomings of the prior art, proposes a kind of detachable aluminium-air cell device, can It is simple and quick to separate electrode and electrolyte, and control reaction immediately starts and stops, and improves battery.
The present invention is achieved by the following technical solutions:
The present invention includes: battery pack and the electrolyte stocking system being flexibly connected therewith, which includes: Two are imported and exported the electrolyte reserve tank being selectively connected to by electrolyte, and an electrolyte reserve tank is connected with battery pack, separately One electrolyte reserve tank is equipped with electrolyte note row's mouth, when needing battery pack to stop working, opens electrolyte inlet and outlet and opens It closes, electrolyte flows out battery pack, flows into electrolyte tank, and electrode is separated with electrolyte, stops electric discharge;When battery needs to put again When electric, cell apparatus is inverted, electrolyte flows back in battery pack, and realization is discharged again.
The electrolyte stocking system is connected by strainer with battery pack, so that the insoluble of generation is put in discharge process Electric collection of products not only can be recycled discharging product and realize resource recycling in filter screen, but also battery work can be improved Make efficiency.
Technical effect
Compared with prior art, electrolyte can be stored in electrolyte tank by the present invention in battery back up, make electrode It is kept completely separate with electrolyte, thoroughly inhibits self discharge, avoid the loss of the energy content of battery, realize the long term storage of battery;The present invention Filling electrolyte and free electrolyte can be fast implemented;Precipitating can be filtered out by installing filter screen, improve battery life with Generating efficiency.
Detailed description of the invention
Fig. 1 is schematic structural view of the invention;
Fig. 2 is that Fig. 1 is inverted schematic diagram;
In figure: 1 battery pack, 2 electrolyte stocking systems, 201 strainers, 202 sector movable baffles, 203 electrolyte inlet and outlet, 204 electrolyte reserve tanks, 205 electrolyte note row's mouth.
Specific embodiment
As shown in Figure 1, for one kind that the present embodiment is related to, wherein including: battery pack 1 and the electrolyte being flexibly connected therewith Stocking system 2, the electrolyte stocking system 2 include: two electrolyte deposits being selectively connected to by electrolyte inlet and outlet 203 Case 204, an electrolyte reserve tank 204 are connected with battery pack 1, another electrolyte reserve tank 204 is equipped with electrolyte note row Mouth 205.
The electrolyte stocking system 2 is connected by strainer 201 with battery pack 1, which is by round stainless steel Outline border and internal double layers intersect stainless steel wire composition in length and breadth, and mesh number is 500 mesh.
The selectivity connection imports and exports the sector movable baffle 202 of 203 sides in fact by being rotatably dispose in electrolyte Existing, the radius of the sector movable baffle 202 is identical as plan radius where electrolyte reserve tank, preferably has resistance to well The property of soda acid and the polyethylene for sealing liquid are made.
As shown in Fig. 2, being first inverted cell apparatus, is infused from electrolyte and inject 4M sodium hydroxide solution 2L, electricity in row's mouth 205 Solution liquid is stored in electrolyte tank.When rotation electrolyte tank 204, open electrolyte inlet and outlet 203, electrolyte is electrolysed from 203 Liquid inlet and outlet outflow, flow into battery pack in discharge, simultaneously close off electrolyte inlet and outlet 203, then by cell apparatus be inverted to Normal operating conditions as shown in Figure 1, the electric discharge work of battery normal continuous.
When battery does not need work, electrolyte inlet and outlet 203 are opened, electrolyte flows back to electrolyte tank under the effect of gravity In, battery stops working.Since electrolyte is isolated with electrode plate, self-discharge of battery is not present, battery can long-term preservation.
When needing to discharge again, battery need to be only inverted, electrolyte will again flow into battery pack, and realization is discharged again. After operating intermittently 1 month, split cell group and electrolyte stocking system, removal filter plate are cleaned, and obtain filtration product 12.3g.Filter screen is once purged, is placed again into cell apparatus, reuses.
Above-mentioned specific implementation can by those skilled in the art under the premise of without departing substantially from the principle of the invention and objective with difference Mode carry out local directed complete set to it, protection scope of the present invention is subject to claims and not by above-mentioned specific implementation institute Limit, each implementation within its scope is by the constraint of the present invention.

Claims (6)

1. a kind of detachable aluminium-air cell device characterized by comprising battery pack and the electrolysis being flexibly connected therewith Liquid stocking system, the electrolyte stocking system include: two and import and export the electrolyte reserve tank being selectively connected to by electrolyte, One electrolyte reserve tank is connected with battery pack, another electrolyte reserve tank is equipped with electrolyte note row's mouth, when needing battery When group stops working, electrolyte inlet and outlet switch is opened, electrolyte flows out battery pack, flows into electrolyte tank, electrode and electrolysis Liquid separation, stops electric discharge;When battery needs to discharge again, cell apparatus is inverted, electrolyte flows back in battery pack, realizes again Secondary electric discharge.
2. the apparatus according to claim 1, characterized in that the electrolyte stocking system passes through strainer and battery pack phase Even, so that in discharge process, the insoluble discharging product of generation is collected in filter screen, and discharging product not only can be recycled and realize resource Recycling, but also battery working efficiency can be improved.
3. the apparatus of claim 2, characterized in that the strainer is by round stainless steel outline border and internal double layers Intersect stainless steel wire composition in length and breadth.
4. the apparatus according to claim 1, characterized in that the selectivity connection, by being rotatably dispose in electrolyte The sector movable baffle for importing and exporting side is realized.
5. device according to claim 4, characterized in that the radius and electrolyte reserve tank of the sector movable baffle Place plan radius is identical.
6. device according to claim 4 or 5, characterized in that the sector movable baffle is made of polyethylene.
CN201810853938.6A 2018-07-30 2018-07-30 Detachable aluminium-air cell device Pending CN109004318A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810853938.6A CN109004318A (en) 2018-07-30 2018-07-30 Detachable aluminium-air cell device

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810853938.6A CN109004318A (en) 2018-07-30 2018-07-30 Detachable aluminium-air cell device

Publications (1)

Publication Number Publication Date
CN109004318A true CN109004318A (en) 2018-12-14

Family

ID=64596243

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201810853938.6A Pending CN109004318A (en) 2018-07-30 2018-07-30 Detachable aluminium-air cell device

Country Status (1)

Country Link
CN (1) CN109004318A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109768353A (en) * 2019-03-06 2019-05-17 铜仁学院 A kind of detachable aluminium-air cell device
CN111224172A (en) * 2020-01-16 2020-06-02 荆门市探梦科技有限公司 Aqueous battery system

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105024111A (en) * 2015-07-14 2015-11-04 北京航空航天大学 Oxygen-metal battery-based rotary electrode-electrolyte separation structure
CN105186067A (en) * 2015-07-14 2015-12-23 北京航空航天大学 Electrode-electrolyte mutual separation structure based on oxygen-metal battery
CN105789737A (en) * 2014-12-19 2016-07-20 中国科学院大连化学物理研究所 Metal/air battery pack
CN108172950A (en) * 2016-12-08 2018-06-15 中国科学院大连化学物理研究所 A kind of metal-air battery system and its operation method of automatic preparation electrolyte

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105789737A (en) * 2014-12-19 2016-07-20 中国科学院大连化学物理研究所 Metal/air battery pack
CN105024111A (en) * 2015-07-14 2015-11-04 北京航空航天大学 Oxygen-metal battery-based rotary electrode-electrolyte separation structure
CN105186067A (en) * 2015-07-14 2015-12-23 北京航空航天大学 Electrode-electrolyte mutual separation structure based on oxygen-metal battery
CN108172950A (en) * 2016-12-08 2018-06-15 中国科学院大连化学物理研究所 A kind of metal-air battery system and its operation method of automatic preparation electrolyte

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109768353A (en) * 2019-03-06 2019-05-17 铜仁学院 A kind of detachable aluminium-air cell device
CN111224172A (en) * 2020-01-16 2020-06-02 荆门市探梦科技有限公司 Aqueous battery system

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Application publication date: 20181214

RJ01 Rejection of invention patent application after publication