CN108998309A - A kind of environment-friendly cleaning agent - Google Patents

A kind of environment-friendly cleaning agent Download PDF

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Publication number
CN108998309A
CN108998309A CN201810961814.XA CN201810961814A CN108998309A CN 108998309 A CN108998309 A CN 108998309A CN 201810961814 A CN201810961814 A CN 201810961814A CN 108998309 A CN108998309 A CN 108998309A
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China
Prior art keywords
parts
cleaning agent
environment
oil
surfactant
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Pending
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CN201810961814.XA
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Chinese (zh)
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孙冉冉
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Individual
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Individual
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    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D10/00Compositions of detergents, not provided for by one single preceding group
    • C11D10/04Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)

Abstract

The invention discloses a kind of environment-friendly cleaning agent, the cleaning agent is grouped as by following mass fraction group: 5~12 parts of sodium hydroxide solution, 8~18 parts of silicone oil, 12~20 parts of glycerin monostearate, 9~12 parts of sodium citrate, 10~16 parts of ethyl orthosilicate, 3~7 parts of lemon, 4~5 parts of orange oil, 6~9 parts of silicon dioxide gel, 1~2 part of surfactant, 1~3 part of antifreezing agent, 20~35 parts of ethyl alcohol, 60~90 parts of deionized water.The present invention effectively avoids the pollution problem to environment, not will cause the salinization of soil or corrosionization of soil, more environmentally protective, meets the demand of present social sustainable development.

Description

A kind of environment-friendly cleaning agent
Technical field
The present invention relates to environment protection field, specifically a kind of environment-friendly cleaning agent.
Background technique
Cleaning agent is a very big scope, many kinds of, including inorganic cleaning and organic washing two major classes organic washing Briefly, organic washing agent is exactly to contain cleaning agent made of carbon compound, inorganic clear numerous for agent and the difference of inorganic cleaning agent Agent is exactly cleaning agent made of carbon-free compound, therefore they belong to inorganic matter.The classification method of cleaning agent is also very much, respectively State is all not quite similar, we generally fall into water system, half water system, non-water system cleaning agent three categories.
The attention of the requirement to environment of present people more, so that the degree of the requirement to cleaning agent is also higher and higher, For cleaning agent, present cleaning agent is usually present following drawback, first, toxicity caused by corrosivity and corrosion inhibiter decompose is to biology Harm is very big, seriously pollutes environment, it is necessary to discharge again after carrying out water process;Secondly, inevitably generate corrosivity damage pair Equipment causes certain damage.
Summary of the invention
The purpose of the present invention is to provide a kind of environment-friendly cleaning agents, to solve the problems mentioned in the above background technology.
To achieve the above object, the invention provides the following technical scheme:
A kind of environment-friendly cleaning agent, the cleaning agent are grouped as by following mass fraction group: sodium hydroxide solution 5~12 Part, 8~18 parts of silicone oil, 12~20 parts of glycerin monostearate, 9~12 parts of sodium citrate, 10~16 parts of ethyl orthosilicate, lemon 3~7 parts of essential oil, 4~5 parts of orange oil, 6~9 parts of silicon dioxide gel, 1~2 part of surfactant, 1~3 part of antifreezing agent, ethyl alcohol 20 ~35 parts, 60~90 parts of deionized water.The surfactant is alkyl phenol polyoxyethylene ether (0P-10) or detergent alkylate sulphur Sour sodium;The silicone oil is by amino-modified silicone oil, one of polyether modified silicon oil or shuttle base modified silicon oil or several mixing groups At;The antifreezing agent is by fatty acid amide, organic acid esters, alkyl succinimide, and 2-Butoxyethyl acetate is a kind of or several Kind is made after mixing with deionized water.
As a further solution of the present invention: the cleaning agent is grouped as by following mass fraction group: sodium hydroxide solution 6 Part, 8 parts of silicone oil, 12 parts of glycerin monostearate, 9 parts of sodium citrate, 10 parts of ethyl orthosilicate, 3 parts of lemon, 4 parts of orange oil, 6 parts of silicon dioxide gel, 1 part of surfactant, 1 part of antifreezing agent, 22 parts of ethyl alcohol, 84 parts of deionized water.
As a further solution of the present invention: the cleaning agent is grouped as by following mass fraction group: sodium hydroxide solution 11 parts, 17 parts of silicone oil, 19 parts of glycerin monostearate, 12 parts of sodium citrate, 15 parts of ethyl orthosilicate, 7 parts of lemon, orange oil 5 parts, 9 parts of silicon dioxide gel, 2 parts of surfactant, 3 parts of antifreezing agent, 35 parts of ethyl alcohol, 70 parts of deionized water.
As further scheme of the invention: the cleaning agent is grouped as by following mass fraction group: sodium hydroxide is molten 10 parts of liquid, 13 parts of silicone oil, 17 parts of glycerin monostearate, 10 parts of sodium citrate, 13 parts of ethyl orthosilicate, 5 parts of lemon, orange 5 parts, 7 parts of silicon dioxide gel, 2 parts of surfactant, 2 parts of antifreezing agent, 28 parts of ethyl alcohol, 75 parts of deionized water of oil.
The present invention also provides a kind of preparation methods of environment-friendly cleaning agent, include following steps:
1) above-mentioned mass fraction is installed and prepares corresponding material;
2) deionized water is heated to 60~75 DEG C, then the sodium hydroxide solution of corrresponding quality number, monostearate is sweet Grease, sodium citrate, ethyl orthosilicate, lemon, orange oil and ethyl alcohol sequentially add, with 3-5 DEG C/min while stirring It is brought rapidly up to 80-85 DEG C, and requires to be uniformly mixed, to obtain solution A;
3) after above-mentioned solution A being warming up to 90-100 DEG C with the speed of 2-3 DEG C/min again, corrresponding quality number is sequentially added Silicone oil, silicon dioxide gel, surfactant and antifreezing agent be cooled to room temperature after mixing, that is, obtain this Product.
Compared with prior art, the beneficial effects of the present invention are:
The one, present invention can effectively remove the spot on the common materials such as glass, metal, plastics surface, and after air-drying not The marking can be left, the comparison prior art has more excellent cleaning effect;
The specific lower corrosivity standard of the two, present invention, to the equipment particularly with aluminum alloy material, the present invention compares The prior art has apparent low corrosion effect, can greatly reduce the influence to equipment or environment;
Solution three, of the invention can be degradable by soil at 20 days or so, effectively avoids the pollution problem to environment, It not will cause the salinization of soil or corrosionization of soil, it is more environmentally protective, meet the demand of present social sustainable development.
Specific embodiment
The technical scheme in the embodiments of the invention will be clearly and completely described below, it is clear that described implementation Example is only a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, this field is common Technical staff's every other embodiment obtained without making creative work belongs to the model that the present invention protects It encloses.
Embodiment one:
In the embodiment of the present invention, a kind of environment-friendly cleaning agent, the cleaning agent is grouped as by following mass fraction group: hydrogen-oxygen 6 parts of sodium solution of change, 8 parts of silicone oil, 12 parts of glycerin monostearate, 9 parts of sodium citrate, 10 parts of ethyl orthosilicate, lemon 3 Part, 4 parts of orange oil, 6 parts of silicon dioxide gel, 1 part of surfactant, 1 part of antifreezing agent, 22 parts of ethyl alcohol and 84 parts of deionized water.
A kind of preparation method of above-mentioned environment-friendly cleaning agent, includes following steps:
1) above-mentioned mass fraction is installed and prepares corresponding material;
2) deionized water is heated to 70 DEG C, then by the sodium hydroxide solution of corrresponding quality number, glycerin monostearate, Sodium citrate, ethyl orthosilicate, lemon, orange oil and ethyl alcohol sequentially add, and stirring while is brought rapidly up with 3 DEG C/min It to 80 DEG C, and requires to be uniformly mixed, to obtain solution A;
3) after above-mentioned solution A being warming up to 90 DEG C with the speed of 2 DEG C/min again, the silicon of corrresponding quality number is sequentially added Oil, silicon dioxide gel, surfactant and antifreezing agent are cooled to room temperature after mixing, i.e. acquisition this product.
Embodiment two:
In the embodiment of the present invention, a kind of environment-friendly cleaning agent, the cleaning agent is grouped as by following mass fraction group: hydrogen-oxygen 11 parts of sodium solution of change, 17 parts of silicone oil, 19 parts of glycerin monostearate, 12 parts of sodium citrate, 15 parts of ethyl orthosilicate, lemon 7 parts, 5 parts of orange oil, 9 parts of silicon dioxide gel, 2 parts of surfactant, 3 parts of antifreezing agent, 35 parts of ethyl alcohol, 70 parts of deionized water.
A kind of preparation method of above-mentioned environment-friendly cleaning agent, includes following steps:
1) above-mentioned mass fraction is installed and prepares corresponding material;
2) deionized water is heated to 75 DEG C, then by the sodium hydroxide solution of corrresponding quality number, glycerin monostearate, Sodium citrate, ethyl orthosilicate, lemon, orange oil and ethyl alcohol sequentially add, and stirring while is brought rapidly up with 3 DEG C/min It to 83 DEG C, and requires to be uniformly mixed, to obtain solution A;
3) after above-mentioned solution A being warming up to 95 DEG C with the speed of 3 DEG C/min again, the silicon of corrresponding quality number is sequentially added Oil, silicon dioxide gel, surfactant and antifreezing agent are cooled to room temperature after mixing, i.e. acquisition this product.
Embodiment three:
In the embodiment of the present invention, a kind of environment-friendly cleaning agent, the cleaning agent is grouped as by following mass fraction group: hydrogen-oxygen 10 parts of sodium solution of change, 13 parts of silicone oil, 17 parts of glycerin monostearate, 10 parts of sodium citrate, 13 parts of ethyl orthosilicate, lemon 5 parts, 5 parts of orange oil, 7 parts of silicon dioxide gel, 2 parts of surfactant, 2 parts of antifreezing agent, 28 parts of ethyl alcohol, 75 parts of deionized water.
A kind of preparation method of above-mentioned environment-friendly cleaning agent, includes following steps:
1) above-mentioned mass fraction is installed and prepares corresponding material;
2) deionized water is heated to 70 DEG C, then by the sodium hydroxide solution of corrresponding quality number, glycerin monostearate, Sodium citrate, ethyl orthosilicate, lemon, orange oil and ethyl alcohol sequentially add, and stirring while is brought rapidly up with 3 DEG C/min It to 85 DEG C, and requires to be uniformly mixed, to obtain solution A;
3) after above-mentioned solution A being warming up to 100 DEG C with the speed of 3 DEG C/min again, the silicon of corrresponding quality number is sequentially added Oil, silicon dioxide gel, surfactant and antifreezing agent are cooled to room temperature after mixing, i.e. acquisition this product.
Comparative example one:
Certain commercially available glass cleaner, according to the formula of mass parts are as follows: 47 parts of methanol, 32 parts of deionized water, calcium chloride dihydrate 6 Part, 5 parts of dodecyl ether sulfate, 6 parts of sorbierite monopalmitate, 2 parts of sodium citrate, 4 parts of sodium metasilicate.
Comparative example two:
Certain commercially available glass cleaner, according to the formula of parts by weight are as follows: 30 parts of methanol, 8 parts of calcium chloride dihydrate, alkyl phenol polyoxy 6 parts of vinethene, 7 parts of sorbierite monopalmitate, 6 parts of water-soluble silicon oil, 60 parts of deionized water.
One, the cleaning effect of the embodiment of the present invention and comparative example compares:
By the embodiment of the present invention and comparative example in the prior art, with regard to same material, same spot is cleaned Comparison, comparison obtain cleaning effect of the invention;
1) portion's material: sub- Gree plate, material are polyacrylate organic glass;Spot is rainy day roadside sewage;
Clean condition is as shown in table 1:
Table 1
2) portion's material: metal plate, aluminum alloy material;Spot is the greasy dirt in technique production;
Clean condition is as shown in table 2:
Table 2
3) portion's material: plastic plate, PC material;Spot is the ground dust and dirt in life;
Clean condition is as shown in table 3:
Table 3
By above table, it can be concluded that, for the present invention in cleaning operation, practical cleaning effect is outstanding, can effectively clear up table The situation of the spot in face, or even the comparative example two that compares, cleaning effect is even better.
Two, the corrosion condition of solution of the embodiment of the present invention and comparative example itself:
Sheet metal is put into respectively into different solvents and is impregnated for 24 hours, the appearance of sheet metal and quality are subjected to front and back comparison (as shown in table 4);
Table 4
From the above data, it can be seen that of the invention has lower point of corruption compared to comparative example one, two more in the prior art Corrosion, particularly with the equipment of aluminum alloy material, the present invention compares the prior art with apparent low corrosion effect, Neng Gou great The big influence reduced to equipment.
Three, the pollution situation of solution of the embodiment of the present invention and comparative example itself;
The same plants of identical soil in identical glass container, will be transplanted into (this experiment is by taking epipremnum aureum as an example);
It is arrived respectively into the corresponding solution of 10ml, continuous observation 35 days or so, the degradation situation of solution enters 5 institute of table in soil Show;
Table 5
By above data it can be seen that solution of the invention can be degradable by soil at 20 days or so, and the prior art Cleaning solution degradation slowly, or even degradable can leave a question open;The present invention can effectively avoid the pollution problem to environment, will not The salinization of soil or corrosionization of soil are caused, it is more environmentally protective, meet the demand of present social sustainable development.
It is obvious to a person skilled in the art that invention is not limited to the details of the above exemplary embodiments, Er Qie In the case where without departing substantially from spirit or essential attributes of the invention, the present invention can be realized in other specific forms.Therefore, no matter From the point of view of which point, the present embodiments are to be considered as illustrative and not restrictive, and the scope of the present invention is by appended power Benefit requires rather than above description limits, it is intended that all by what is fallen within the meaning and scope of the equivalent elements of the claims Variation is included within the present invention.
In addition, it should be understood that although this specification is described in terms of embodiments, but not each embodiment is only wrapped Containing an independent technical solution, this description of the specification is merely for the sake of clarity, and those skilled in the art should It considers the specification as a whole, the technical solutions in the various embodiments may also be suitably combined, forms those skilled in the art The other embodiments being understood that.

Claims (8)

1. a kind of environment-friendly cleaning agent, which is characterized in that the cleaning agent is grouped as by following mass fraction group: sodium hydroxide is molten 5~12 parts of liquid, 8~18 parts of silicone oil, 12~20 parts of glycerin monostearate, 9~12 parts of sodium citrate, ethyl orthosilicate 10~16 Part, 3~7 parts of lemon, 4~5 parts of orange oil, 6~9 parts of silicon dioxide gel, 1~2 part of surfactant, antifreezing agent 1~3 Part, 20~35 parts of ethyl alcohol, 60~90 parts of deionized water.
2. environment-friendly cleaning agent according to claim 1, which is characterized in that the surfactant is alkyl phenol polyoxy second Alkene ether (0P-10) or neopelex.
3. environment-friendly cleaning agent according to claim 1, which is characterized in that the silicone oil is by amino-modified silicone oil, polyethers One of modified silicon oil or shuttle base modified silicon oil or several mixing composition.
4. environment-friendly cleaning agent according to claim 1, which is characterized in that the antifreezing agent is organic by fatty acid amide Acid esters, alkyl succinimide, 2-Butoxyethyl acetate one or several kinds are made after mixing with deionized water.
5. environment-friendly cleaning agent according to claim 1, which is characterized in that the cleaning agent is by following mass fraction component Composition: 6 parts of sodium hydroxide solution, 8 parts of silicone oil, 12 parts of glycerin monostearate, 9 parts of sodium citrate, 10 parts of ethyl orthosilicate, lemon 3 parts of lemon essential oil, 4 parts of orange oil, 6 parts of silicon dioxide gel, 1 part of surfactant, 1 part of antifreezing agent, 22 parts of ethyl alcohol, deionized water 84 Part.
6. environment-friendly cleaning agent according to claim 1, which is characterized in that the cleaning agent is by following mass fraction component Composition: 11 parts of sodium hydroxide solution, 17 parts of silicone oil, 19 parts of glycerin monostearate, 12 parts of sodium citrate, ethyl orthosilicate 15 Part, 7 parts of lemon, 5 parts of orange oil, 9 parts of silicon dioxide gel, 2 parts of surfactant, 3 parts of antifreezing agent, 35 parts of ethyl alcohol, go from 70 parts of sub- water.
7. environment-friendly cleaning agent according to claim 1, which is characterized in that the cleaning agent is by following mass fraction component Composition: 10 parts of sodium hydroxide solution, 13 parts of silicone oil, 17 parts of glycerin monostearate, 10 parts of sodium citrate, ethyl orthosilicate 13 Part, 5 parts of lemon, 5 parts of orange oil, 7 parts of silicon dioxide gel, 2 parts of surfactant, 2 parts of antifreezing agent, 28 parts of ethyl alcohol, go from 75 parts of sub- water.
8. the preparation method of -7 any environment-friendly cleaning agents according to claim 1, which is characterized in that include following step It is rapid:
1) above-mentioned mass fraction is installed and prepares corresponding material;
2) deionized water is heated to 60~75 DEG C, then by the sodium hydroxide solution of corrresponding quality number, glycerin monostearate, Sodium citrate, ethyl orthosilicate, lemon, orange oil and ethyl alcohol sequentially add, and stirring while is risen rapidly with 3-5 DEG C/min Temperature is uniformly mixed to 80-85 DEG C, to obtain solution A;
3) after above-mentioned solution A being warming up to 90-100 DEG C with the speed of 2-3 DEG C/min again, the silicon of corrresponding quality number is sequentially added Oil, silicon dioxide gel, surfactant and antifreezing agent are cooled to room temperature after mixing, i.e. acquisition this product.
CN201810961814.XA 2018-08-22 2018-08-22 A kind of environment-friendly cleaning agent Pending CN108998309A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112011415A (en) * 2020-08-31 2020-12-01 上海申仰实业有限公司 Kitchen oil stain cleaning agent

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103013197A (en) * 2012-12-19 2013-04-03 江苏博斯腾纳米涂层有限公司 Preparation method of nano anti-fogging agent
CN105431514A (en) * 2012-08-31 2016-03-23 3M创新有限公司 Multi-functional compositions and methods of use
CN105419980A (en) * 2015-12-17 2016-03-23 青岛大方智慧网络科技有限公司 High-efficient antifreeze equipment cleaning solution
CN107674779A (en) * 2017-11-01 2018-02-09 华蓥市第二中学 A kind of high school chemical experiment apparatus cleaning treatment agent

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105431514A (en) * 2012-08-31 2016-03-23 3M创新有限公司 Multi-functional compositions and methods of use
CN103013197A (en) * 2012-12-19 2013-04-03 江苏博斯腾纳米涂层有限公司 Preparation method of nano anti-fogging agent
CN105419980A (en) * 2015-12-17 2016-03-23 青岛大方智慧网络科技有限公司 High-efficient antifreeze equipment cleaning solution
CN107674779A (en) * 2017-11-01 2018-02-09 华蓥市第二中学 A kind of high school chemical experiment apparatus cleaning treatment agent

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112011415A (en) * 2020-08-31 2020-12-01 上海申仰实业有限公司 Kitchen oil stain cleaning agent

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Application publication date: 20181214