CN108997848A - A kind of inkjet printing surface of aluminum plate coating formula - Google Patents

A kind of inkjet printing surface of aluminum plate coating formula Download PDF

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Publication number
CN108997848A
CN108997848A CN201810805090.XA CN201810805090A CN108997848A CN 108997848 A CN108997848 A CN 108997848A CN 201810805090 A CN201810805090 A CN 201810805090A CN 108997848 A CN108997848 A CN 108997848A
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CN
China
Prior art keywords
parts
inkjet printing
aluminum plate
printing
plate coating
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810805090.XA
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Chinese (zh)
Inventor
李书通
陈朔裕
章以中
张灵生
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Zhejiang Gko New Material Stock Co Ltd
Original Assignee
Zhejiang Gko New Material Stock Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Zhejiang Gko New Material Stock Co Ltd filed Critical Zhejiang Gko New Material Stock Co Ltd
Priority to CN201810805090.XA priority Critical patent/CN108997848A/en
Publication of CN108997848A publication Critical patent/CN108997848A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D123/00Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers
    • C09D123/02Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
    • C09D123/04Homopolymers or copolymers of ethene
    • C09D123/06Polyethene
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide

Abstract

The invention discloses a kind of inkjet printing surface of aluminum plate coating formulas, it according to the mass fraction include following components: 38-42 parts of PE resin, full 7-12 parts of methyl-etherified amino, 30-43 parts of titanium dioxide, 0.5-0.8 parts of levelling agent, 0.2-0.4 parts of defoaming agent, 2-4 parts of adhesion promoter, 1-3 parts of fumed silica, 3-8 parts of butyl ether, 2-4 parts of aromatic hydrocarbon hydrocarbon, 2-5 parts of cyclohexanone.The coating layer aluminium plate produced by the formula, ink adhesive force when printing in the coating layer aluminium plate using paint formulation coating production or printing significantly improves, ink has reached 5B standard in the test of hundred lattice of 1mm × 1mm in the adhesive force on the coating layer aluminium plate, keep better effect after printing or printing true to nature, the inkjet print image of generation is bright in luster, level is abundant, greatly improves product comprehensive performance, improves enterprise product core competitiveness.

Description

A kind of inkjet printing surface of aluminum plate coating formula
Technical field
The present invention relates to aluminum alloy surface process field more particularly to a kind of inkjet printing surface of aluminum plate coating formulas.
Background technique
Inkjet printing is that spray head is drawn probe reagent from microwell plate and moved back to processed support, by temperature-sensitive or Drop is ejected into support surface by the power of the forms injector such as acoustic control, and tiny black or colored ink droplet are ejected by ink-jet Paper.Spray head is drawn probe reagent from microwell plate and is moved back to processed support, is sprayed by forms such as temperature-sensitive or acoustic controls Drop is ejected into support surface by the power of emitter.Tiny black or colored ink droplet are ejected into paper by ink-jet.
Inkjet printing technology is a kind of novel contactless, no pressure, the printing technique without printing plate, is by image information light A kind of image sharpening printing type realized after ink-jet printer is inputted after gated, is widely used at present, and aluminium closes Golden material is applied to aluminium because its excellent mechanical property is favored by the majority of consumers with performance attractive in appearance, by inkjet printing technology In surface treatment, the aluminium alloy covered product of colorful multiplicity is prepared, is necessarily had a vast market foreground, but since technology lacks It falls into, inkjet printing metal product currently on the market is primarily present adhesive force deficiency, and coating and ink affinity are poor, and aesthetics is not The deficiencies of good, needs to carry out technical optimization, realizes being substantially improved for product comprehensive performance, improves the enterprise key market competitiveness.
Summary of the invention
Originally in order to solve the above-mentioned technical problem, the embodiment of the invention provides a kind of inkjet printing surface of aluminum plate coatings to match Side includes following components: 38-42 parts of PE resin according to the mass fraction;Full 7-12 parts of methyl-etherified amino;30-43 parts of titanium dioxide;Stream Flat agent 0.5-0.8 parts;0.2-0.4 parts of defoaming agent;2-4 parts of adhesion promoter;1-3 parts of fumed silica;3-8 parts of butyl ether; 2-4 parts of aromatic hydrocarbon hydrocarbon;2-5 parts of cyclohexanone.
It further, according to the mass fraction include following components: 40 parts of PE resin;Complete 9 parts of amino of methyl-etherified;Titanium dioxide 37 parts;0.6 part of levelling agent;0.3 part of defoaming agent;3 parts of adhesion promoter;2 parts of fumed silica;5 parts of butyl ether;Aromatic hydrocarbon carbon 3 parts of oxygen compound;3 parts of cyclohexanone.
It further, according to the mass fraction include following components: 40 parts of PE resin;Complete 10 parts of amino of methyl-etherified;Titanium dioxide 39 parts;0.65 part of levelling agent;0.35 part of defoaming agent;3 parts of adhesion promoter;2.5 parts of fumed silica;6 parts of butyl ether;Fragrance 3 parts of hydrocarbon hydrocarbon;4 parts of cyclohexanone.
Further, according to the mass fraction include following components:: 38 parts of PE resin;Complete 8 parts of amino of methyl-etherified;Titanium dioxide 32 parts;0.6 part of levelling agent;0.2 part of defoaming agent;3 parts of adhesion promoter;2 parts of fumed silica;3 parts of butyl ether;Aromatic hydrocarbon carbon 3 parts of oxygen compound;3 parts of cyclohexanone.
It further, according to the mass fraction include following components: 42 parts of PE resin;Complete 12 parts of amino of methyl-etherified;Titanium dioxide 43 parts;0.8 part of levelling agent;0.4 part of defoaming agent;4 parts of adhesion promoter;2 parts of fumed silica;8 parts of butyl ether;Aromatic hydrocarbon carbon 4 parts of oxygen compound;5 parts of cyclohexanone.
Further, the levelling agent uses acrylic acid.
Further, the defoaming agent uses acrylate.
Further, the adhesion promoter uses epoxy phosphate ester.
The implementation of the embodiments of the present invention has the following beneficial effects: optimization formulation for coating material, the not no gas of surface of the paint film after film forming Bubble has been not easy secretly to steep, and ink adhesive force when printing in the coating layer aluminium plate using paint formulation coating production or printing is bright Aobvious to improve, ink has reached 5B standard in the test of hundred lattice of 1mm × 1mm in the adhesive force on the coating layer aluminium plate.Use the formula The coating layer aluminium plate of production, coating surface tension are more suitable for pad-ink requirement, keep better effect after printing or printing true to nature.
The inkjet print image of generation is bright in luster, and level is abundant, greatly improves product comprehensive performance, improves enterprise product Core competitiveness.
Specific embodiment
A kind of inkjet printing surface of aluminum plate coating formula of the invention includes following components: PE tree according to the mass fraction 38-42 parts of rouge, 7-12 parts of full methyl-etherified amino is 30-43 parts of titanium dioxide, 0.5-0.8 parts of levelling agent, 0.2-0.4 parts of defoaming agent, attached 2-4 parts of adhesion promoter, 1-3 parts of fumed silica, 3-8 parts of butyl ether, 2-4 parts of aromatic hydrocarbon hydrocarbon, cyclohexanone 2-5 Part.
Embodiment 1:
It according to the mass fraction include following components: 40 parts of PE resin;Complete 9 parts of amino of methyl-etherified;37 parts of titanium dioxide;Acrylic acid 0.6 part;0.3 part of acrylate;3 parts of epoxy phosphate ester;2 parts of fumed silica;5 parts of butyl ether;Aromatic hydrocarbon hydrocarbon 3 Part;3 parts of cyclohexanone.
Embodiment 2:
It according to the mass fraction include following components: 40 parts of PE resin;Complete 10 parts of amino of methyl-etherified;39 parts of titanium dioxide;Propylene 0.65 part of acid;0.35 part of acrylate;3 parts of epoxy phosphate ester;2.5 parts of fumed silica;6 parts of butyl ether;Aromatic hydrocarbon oxidation of coal Close 3 parts of object;4 parts of cyclohexanone.
Embodiment 3:
It according to the mass fraction include following components: 38 parts of PE resin;Complete 8 parts of amino of methyl-etherified;32 parts of titanium dioxide;Acrylic acid 0.6 part;0.2 part of acrylate;3 parts of epoxy phosphate ester;2 parts of fumed silica;3 parts of butyl ether;Aromatic hydrocarbon hydrocarbon 3 Part;3 parts of cyclohexanone.
Embodiment 4:
It according to the mass fraction include following components: 42 parts of PE resin;Complete 12 parts of amino of methyl-etherified;43 parts of titanium dioxide;Propylene 0.8 part of acid;0.4 part of acrylate;4 parts of epoxy phosphate ester;2 parts of fumed silica;8 parts of butyl ether;Aromatic hydrocarbon hydrocarbon 4 Part;5 parts of cyclohexanone.
Embodiment 5:
It according to the mass fraction include following components: 42 parts of PE resin;Complete 12 parts of amino of methyl-etherified;43 parts of titanium dioxide;Propylene 0.8 part of acid;0.4 part of acrylate;2 parts of fumed silica;8 parts of butyl ether;4 parts of aromatic hydrocarbon hydrocarbon;5 parts of cyclohexanone.
Embodiment 6:
It according to the mass fraction include following components: 41 parts of PE resin;Complete 10 parts of amino of methyl-etherified;39 parts of titanium dioxide;Propylene 0.65 part of acid;0.35 part of acrylate;3 parts of epoxy phosphate ester;2.5 parts of fumed silica;6 parts of butyl ether;Aromatic hydrocarbon oxidation of coal Close 3 parts of object;4 parts of cyclohexanone.
Embodiment 7:
It according to the mass fraction include following components: 38 parts of PE resin;Complete 8 parts of amino of methyl-etherified;32 parts of titanium dioxide;Acrylic acid 0.6 part;0.2 part of acrylate;3 parts of epoxy phosphate ester;2 parts of fumed silica;3 parts of butyl ether;Aromatic hydrocarbon hydrocarbon 3 Part;3 parts of cyclohexanone.
Embodiment 8:
It according to the mass fraction include following components: 40 parts of PE resin;Complete 10 parts of amino of methyl-etherified;39 parts of titanium dioxide;Propylene 0.65 part of acid;0.35 part of acrylate;3 parts of epoxy phosphate ester;2.5 parts of fumed silica;6 parts of butyl ether;Aromatic hydrocarbon oxidation of coal Close 5 parts of object;4 parts of cyclohexanone.
Embodiment 9:
It according to the mass fraction include following components: 38 parts of PE resin;Complete 8 parts of amino of methyl-etherified;32 parts of titanium dioxide;Acrylic acid 0.6 part;0.3 part of acrylate;3 parts of epoxy phosphate ester;2 parts of fumed silica;3 parts of butyl ether;Aromatic hydrocarbon hydrocarbon 5 Part;3 parts of cyclohexanone.
Comparative example:
For the common aluminum substrate of printing, and uncoated optimization dope layer.
The adhesive force and articulation index of paint film obtained by above-described embodiment are tested, test result is as follows:
Adhesive force Clarity
Embodiment 1 5B 1
Embodiment 2 5B 1
Embodiment 3 5B 2
Embodiment 4 4B 1
Embodiment 5 3B 2
Embodiment 6 5B 1
Embodiment 7 5B 2
Embodiment 8 4B 1
Embodiment 9 4B 1
Comparative example 2B 3
Adhesion performance test, test result are 0-5B grades, and numerical value is bigger, and adhesion performance is more excellent, and numerical value is smaller, attached It is poorer to put forth effort performance;
Clarity performance test divides 1-5 grades:
1 grade: clear patterns, true to nature, pattern boundaries are clearly demarcated;
2 grades: clear patterns, true to nature, partial pattern obscurity boundary;
3 grades: clear patterns, most of pattern boundaries are fuzzy;
4 grades: dim design, pattern boundaries are smudgy;
5 grades: dim design, pattern non-boundary.
By the above testing result it is found that the coating layer aluminium plate of inventive formulation production, ink are applied using the paint formulation Adhesive force significantly improves when printing or print on the coating layer aluminium plate of cloth production, and adhesive force of the ink on the coating layer aluminium plate exists 5B standard is reached in the test of hundred lattice of 1mm × 1mm, has kept better effect after printing or printing true to nature, the inkjet print image of generation Bright in luster, level is abundant, greatly improves transfer product comprehensive performance, improves enterprise product core competitiveness.
Above disclosed is only a preferred embodiment of the present invention, cannot limit the power of the present invention with this certainly Sharp range, therefore equivalent changes made in accordance with the claims of the present invention, are still within the scope of the present invention.

Claims (8)

1. a kind of inkjet printing surface of aluminum plate coating formula, which is characterized in that according to the mass fraction include following components: PE tree 38-42 parts of rouge;Full 7-12 parts of methyl-etherified amino;30-43 parts of titanium dioxide;0.5-0.8 parts of levelling agent;0.2-0.4 parts of defoaming agent;It is attached 2-4 parts of adhesion promoter;1-3 parts of fumed silica;3-8 parts of butyl ether;2-4 parts of aromatic hydrocarbon hydrocarbon;Cyclohexanone 2-5 Part.
2. inkjet printing according to claim 1 surface of aluminum plate coating formula, which is characterized in that wrap according to the mass fraction Include following components: 40 parts of PE resin;Complete 9 parts of amino of methyl-etherified;37 parts of titanium dioxide;0.6 part of levelling agent;0.3 part of defoaming agent;Attachment 3 parts of power promotor;2 parts of fumed silica;5 parts of butyl ether;3 parts of aromatic hydrocarbon hydrocarbon;3 parts of cyclohexanone.
3. inkjet printing according to claim 1 surface of aluminum plate coating formula, it is characterised in that: wrap according to the mass fraction Include following components: 40 parts of PE resin;Complete 10 parts of amino of methyl-etherified;39 parts of titanium dioxide;0.65 part of levelling agent;0.35 part of defoaming agent; 3 parts of adhesion promoter;2.5 parts of fumed silica;6 parts of butyl ether;3 parts of aromatic hydrocarbon hydrocarbon;4 parts of cyclohexanone.
4. inkjet printing according to claim 1 surface of aluminum plate coating formula, it is characterised in that: wrap according to the mass fraction Include following components: 38 parts of PE resin;Complete 8 parts of amino of methyl-etherified;32 parts of titanium dioxide;0.6 part of levelling agent;0.2 part of defoaming agent;Attachment 3 parts of power promotor;2 parts of fumed silica;3 parts of butyl ether;3 parts of aromatic hydrocarbon hydrocarbon;3 parts of cyclohexanone.
5. inkjet printing according to claim 1 surface of aluminum plate coating formula, it is characterised in that: wrap according to the mass fraction Include following components: 42 parts of PE resin;Complete 12 parts of amino of methyl-etherified;43 parts of titanium dioxide;0.8 part of levelling agent;0.4 part of defoaming agent;It is attached 4 parts of adhesion promoter;2 parts of fumed silica;8 parts of butyl ether;4 parts of aromatic hydrocarbon hydrocarbon;5 parts of cyclohexanone.
6. inkjet printing surface of aluminum plate coating formula described in any one according to claim 1~5, which is characterized in that institute Levelling agent is stated using acrylic acid.
7. inkjet printing surface of aluminum plate coating formula described in any one according to claim 1~5, which is characterized in that institute Defoaming agent is stated using acrylate.
8. inkjet printing surface of aluminum plate coating formula described in any one according to claim 1~5, which is characterized in that institute Adhesion promoter is stated using epoxy phosphate ester.
CN201810805090.XA 2018-07-20 2018-07-20 A kind of inkjet printing surface of aluminum plate coating formula Pending CN108997848A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810805090.XA CN108997848A (en) 2018-07-20 2018-07-20 A kind of inkjet printing surface of aluminum plate coating formula

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Application Number Priority Date Filing Date Title
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Publications (1)

Publication Number Publication Date
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Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0172472A2 (en) * 1984-08-02 1986-02-26 Union Carbide Corporation Novel phosphorylated reaction products and compositions incorporating such products
CN108219633A (en) * 2018-01-20 2018-06-29 新丰惠泽涂料有限公司 A kind of novel dumb light whiting of polyester and its preparation process

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0172472A2 (en) * 1984-08-02 1986-02-26 Union Carbide Corporation Novel phosphorylated reaction products and compositions incorporating such products
CN108219633A (en) * 2018-01-20 2018-06-29 新丰惠泽涂料有限公司 A kind of novel dumb light whiting of polyester and its preparation process

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Application publication date: 20181214

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