CN108997808A - A kind of water-repellent paint for external wall of building and preparation method thereof and construction method - Google Patents
A kind of water-repellent paint for external wall of building and preparation method thereof and construction method Download PDFInfo
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- CN108997808A CN108997808A CN201810916830.7A CN201810916830A CN108997808A CN 108997808 A CN108997808 A CN 108997808A CN 201810916830 A CN201810916830 A CN 201810916830A CN 108997808 A CN108997808 A CN 108997808A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
- C09D4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/66—Additives characterised by particle size
- C09D7/67—Particle size smaller than 100 nm
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Nanotechnology (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of water-repellent paint for external wall of building and preparation method thereof and construction method, the raw material including following parts by weight: 8-13 parts of tartary buckwheat, 4.4-6.8 parts of nano silica, 5.5-7.2 parts of heavy calcium carbonate, 5-7.8 parts of styrene-acrylic emulsion, 21-26.8 parts of diatomite, 1.6-2.5 parts of hydroquinone, 18.5-24.6 parts of methyl methacrylate, 3.3-5.2 parts of cellulose, 13.5-18.4 parts of propylene glycol and 48-55 parts of water.Raw material sources of the present invention are extensive, by using different preparation processes to different raw materials, obtain different products, different products is mixed again, the finished product of preparation not only has the function of quick-drying, also have good compression strength, glossiness and ultraviolet radiation resisting effect, use scope wide.
Description
Technical field
The present invention relates to building coating field, specifically a kind of water-repellent paint for external wall of building.
Background technique
With the construction that the quickening of Development of China's Urbanization and various regions are built, building trade becomes the popular row in people's eye again
Industry.Building trade is exactly one around the design of building, construction, finishing, management and the industry being unfolded, and urban architecture is building row
The important component of industry, urban architecture pass on culture in its unique way, disseminate the charm of life, constantly permeate
Into in daily life, the spiritual home of one and harmonious peacefulness is built for people.
Building includes external wall of building and interior architectural applications, and external wall of building is located at outside, exposing to the weather is subjected to, to prevent water external
Wall builds the infiltration at certain positions, and people can use waterproof measure, and coating water-repellent paint is exactly a kind of common waterproof measure.Make
With water-repellent paint External Wall building carry out coating after external wall of building and external environment can be isolated, thus prevent because rainwater,
It is lauched corrosion caused by the moisture intrusion external wall of building in equal corrosive liquids and air, extends the service life of external wall of building.
Polymer cement-base waterproof coating be the lotion that is synthesized by a variety of waterborne polymerics with mixed with the excellent of various additives
Matter cement composition, the flexibility of polymer (resin) and the rigidity of cement became one, so that it is in terms of impervious and stability
It is excellent in, but the uvioresistant effect of existing polymer cement-base waterproof coating is bad, is easy under strong ultraviolet light
Cracking, influences waterproof effect, reduces the service life, this is just that the use of people brings inconvenience.
Summary of the invention
The purpose of the present invention is to provide a kind of water-repellent paints for external wall of building, to solve to mention in above-mentioned background technique
Out the problem of.
To achieve the above object, the invention provides the following technical scheme:
A kind of water-repellent paint for external wall of building, the raw material including following parts by weight: 8-13 parts of tartary buckwheat, nano-silica
4.4-6.8 parts of SiClx, 5.5-7.2 parts of heavy calcium carbonate, 5-7.8 parts of styrene-acrylic emulsion, 21-26.8 parts of diatomite, hydroquinone
1.6-2.5 parts, 18.5-24.6 parts of methyl methacrylate, 3.3-5.2 parts of cellulose, 13.5-18.4 parts of propylene glycol and water 48-
55 parts.
As a further solution of the present invention: cellulose includes at least one in methylcellulose and hydroxyethyl cellulose
Kind.
As a further solution of the present invention: the partial size of nano silica is 24-40nm, the partial size of heavy calcium carbonate
For 45-82um.
The preparation method of the water-repellent paint for external wall of building, the specific steps are as follows:
Tartary buckwheat is immersed in 24-28 degrees Celsius of water 1.5-3 hours, then by the tartary buckwheat after immersion by step 1
It is crushed and is sent into reactor tank, complex enzyme is added in the environment of 34-45 degrees Celsius and pH value are 5.1-6.4, enzymatic hydrolysis 5-7 is small
When enzyme deactivation, filtering, centrifugation, separation, obtain tartary buckwheat enzymolysis liquid;
Step 2 diatomite, hydroquinone, methyl methacrylate and tartary buckwheat enzymolysis liquid is added in ball grinder, ball
Mill is uniform and crosses 60-80 mesh, obtains the first mixture;
Step 3 adds water in dispersion cup, and nano silica, styrene-acrylic emulsion and fibre is added thereto while stirring
Dimension element, is uniformly dispersed, then handles 20-30 minutes in the electric field of 620-880V, obtain the second mixture;
Heavy calcium carbonate is added in propylene glycol and mechanical stirring is uniform, obtains third mixture by step 4;
Step 5 turns the first mixture, the second mixture and third mixture in blender with 720-960rpm
Speed stirring 45-70 minutes is then allowed to stand 3-5 hours to get finished product is arrived.
As a further solution of the present invention: the ratio of grinding media to material of step 2 ball grinder is 55-70:1, and ball milling temperature is 50-66
Degree Celsius, rotational speed of ball-mill 90-135rpm.
As a further solution of the present invention: the ultrasonic wave aid dispersion of 15-22KHz is used in step 3.
The application method of the water-repellent paint for external wall of building, the specific steps are as follows: water-repellent paint is used into roller coating
Or the method for blade coating is coated uniformly on external wall of building surface.
Compared with prior art, the beneficial effects of the present invention are: raw material sources of the present invention are extensive, by different raw materials
Using different preparation processes, different products is obtained, then different products is mixed, the finished product of preparation not only has fastly
Dry effect also has good compression strength, glossiness and ultraviolet radiation resisting effect, use scope wide.
Specific embodiment
The technical solution of the patent is explained in further detail With reference to embodiment.
Embodiment 1
A kind of water-repellent paint for external wall of building, the raw material including following parts by weight: 8 parts of tartary buckwheat, nanometer titanium dioxide
4.4 parts of silicon, 5.5 parts of heavy calcium carbonate, 5 parts of styrene-acrylic emulsion, 21 parts of diatomite, 1.6 parts of hydroquinone, methyl methacrylate
18.5 parts, 3.3 parts of cellulose, 13.5 parts of propylene glycol and 48 parts of water.Cellulose uses hydroxyethyl cellulose.
The preparation method of the water-repellent paint for external wall of building, the specific steps are as follows:
Tartary buckwheat is immersed in 26 degrees Celsius of water 2.2 hours by step 1, then that the tartary buckwheat after immersion is broken simultaneously
And be sent into reactor tank, complex enzyme is added in the environment of 37 degrees Celsius and pH value are 5.6, digests 6.4 as a child enzyme deactivations, mistake
Filter, centrifugation, separation, obtain tartary buckwheat enzymolysis liquid;
Step 2 diatomite, hydroquinone, methyl methacrylate and tartary buckwheat enzymolysis liquid is added in ball grinder, ball
The ratio of grinding media to material of grinding jar is 58:1, and ball milling temperature is 54 degrees Celsius, rotational speed of ball-mill 105rpm, ball milling and excessively 60 meshes,
Obtain the first mixture;
Step 3 adds water in dispersion cup, and nano silica, styrene-acrylic emulsion and fibre is added thereto while stirring
Dimension element, is uniformly dispersed, then handles 24 minutes in the electric field of 675V, obtain the second mixture;
Heavy calcium carbonate is added in propylene glycol and mechanical stirring is uniform, obtains third mixture by step 4;
Step 5 stirs the first mixture, the second mixture and third mixture in blender with the revolving speed of 750rpm
It mixes 64 minutes, is then allowed to stand 4.4 hours to get finished product is arrived.
The application method of the water-repellent paint for external wall of building, the specific steps are as follows: water-repellent paint is used into roller coating
Method be coated uniformly on external wall of building surface.
Embodiment 2
A kind of water-repellent paint for external wall of building, the raw material including following parts by weight: 10.2 parts of tartary buckwheat, nano-silica
5.1 parts of SiClx, 6.4 parts of heavy calcium carbonate, 5.9 parts of styrene-acrylic emulsion, 23.5 parts of diatomite, 1.9 parts of hydroquinone, metering system
20.4 parts of sour methyl esters, 4.3 parts of cellulose, 15.6 parts of propylene glycol and 51.7 parts of water.The partial size of nano silica is 32nm, heavy
The partial size of Paris white is 58um.
The preparation method of the water-repellent paint for external wall of building, the specific steps are as follows:
Tartary buckwheat, is immersed in 26 degrees Celsius of water 2 hours by step 1, then by the tartary buckwheat after immersion it is broken and
It is sent into reactor tank, complex enzyme is added in the environment of 40 degrees Celsius and pH value are 6.3, digests 6.5 as a child enzyme deactivations, filter,
Centrifugation, separation, obtain tartary buckwheat enzymolysis liquid;
Step 2 diatomite, hydroquinone, methyl methacrylate and tartary buckwheat enzymolysis liquid is added in ball grinder, ball
Mill is uniform and crosses 80 meshes, obtains the first mixture;
Step 3 adds water in dispersion cup, and nano silica, styrene-acrylic emulsion and fibre is added thereto while stirring
Dimension element, is uniformly dispersed, then handles 26 minutes in the electric field of 840V, obtain the second mixture;
Heavy calcium carbonate is added in propylene glycol and mechanical stirring is uniform, obtains third mixture by step 4;
Step 5 stirs the first mixture, the second mixture and third mixture in blender with the revolving speed of 840rpm
It mixes 55 minutes and is assisted using the ultrasonic wave of 18KHz, be then allowed to stand 3.6 hours to get finished product is arrived.
The application method of the water-repellent paint for external wall of building, the specific steps are as follows: by water-repellent paint using blade coating
Method be coated uniformly on external wall of building surface.
Embodiment 3
A kind of water-repellent paint for external wall of building, the raw material including following parts by weight: 12.4 parts of tartary buckwheat, nano-silica
6.2 parts of SiClx, 6.7 parts of heavy calcium carbonate, 7.3 parts of styrene-acrylic emulsion, 25.5 parts of diatomite, 2.3 parts of hydroquinone, metering system
23.8 parts of sour methyl esters, 4.9 parts of cellulose, 17.8 parts of propylene glycol and 52 parts of water.Cellulose includes that methylcellulose and ethoxy are fine
Tie up the mixture of element.The partial size of nano silica is 33nm, and the partial size of heavy calcium carbonate is 75um.
The preparation method of the water-repellent paint for external wall of building, the specific steps are as follows:
Tartary buckwheat is immersed in 27 degrees Celsius of water 2.8 hours by step 1, then that the tartary buckwheat after immersion is broken simultaneously
And be sent into reactor tank, complex enzyme is added in the environment of 44 degrees Celsius and pH value are 5.6, digests 5 as a child enzyme deactivations, filter,
Centrifugation, separation, obtain tartary buckwheat enzymolysis liquid;
Step 2 diatomite, hydroquinone, methyl methacrylate and tartary buckwheat enzymolysis liquid is added in ball grinder, ball
The ratio of grinding media to material of grinding jar is 66:1, and ball milling temperature is 62 degrees Celsius, rotational speed of ball-mill 135rpm, ball milling and excessively 60 meshes,
Obtain the first mixture;
Step 3 adds water in dispersion cup, and nano silica, styrene-acrylic emulsion and fibre is added thereto while stirring
Dimension element, is uniformly dispersed, then handles 26 minutes in the electric field of 810V, obtain the second mixture;
Heavy calcium carbonate is added in propylene glycol and mechanical stirring is uniform, obtains third mixture by step 4;
Step 5 stirs the first mixture, the second mixture and third mixture in blender with the revolving speed of 960rpm
It mixes 64 minutes, is then allowed to stand 4 hours to get finished product is arrived.
The application method of the water-repellent paint for external wall of building, the specific steps are as follows: by water-repellent paint using blade coating
Method be coated uniformly on external wall of building surface.
Embodiment 4
A kind of water-repellent paint for external wall of building, the raw material including following parts by weight: 13 parts of tartary buckwheat, nanometer titanium dioxide
6.8 parts of silicon, 7.2 parts of heavy calcium carbonate, 7.8 parts of styrene-acrylic emulsion, 26.8 parts of diatomite, 2.5 parts of hydroquinone, methacrylic acid
24.6 parts of methyl esters, 5.2 parts of cellulose, 18.4 parts of propylene glycol and 55 parts of water.Cellulose uses methylcellulose.Nano silica
Partial size be 38nm, the partial size of heavy calcium carbonate is 80um.
The preparation method of the water-repellent paint for external wall of building, the specific steps are as follows:
Tartary buckwheat is immersed in 28 degrees Celsius of water 2.8 hours by step 1, then that the tartary buckwheat after immersion is broken simultaneously
And be sent into reactor tank, complex enzyme is added in the environment of 42 degrees Celsius and pH value are 5.6, digests 7 as a child enzyme deactivations, filter,
Centrifugation, separation, obtain tartary buckwheat enzymolysis liquid;
Step 2 diatomite, hydroquinone, methyl methacrylate and tartary buckwheat enzymolysis liquid is added in ball grinder, ball
The ratio of grinding media to material of grinding jar is 68:1, and ball milling temperature is 65 degrees Celsius, rotational speed of ball-mill 120rpm, ball milling and excessively 70 meshes,
Obtain the first mixture;
Step 3 adds water in dispersion cup, and nano silica, styrene-acrylic emulsion and fibre is added thereto while stirring
Dimension element, is uniformly dispersed, then handles 28 minutes in the electric field of 850V, obtain the second mixture;
Heavy calcium carbonate is added in propylene glycol and mechanical stirring is uniform, obtains third mixture by step 4;
Step 5 stirs the first mixture, the second mixture and third mixture in blender with the revolving speed of 960rpm
It mixes 65 minutes and is assisted using the ultrasonic wave of 21KHz, be then allowed to stand 4.5 hours to get finished product is arrived.
The application method of the water-repellent paint for external wall of building, the specific steps are as follows: water-repellent paint is used into roller coating
Method be coated uniformly on external wall of building surface.
Comparative example 1
Except tartary buckwheat and hydroquinone is not contained, remaining raw material, preparation method and application method are same as Example 2.
Comparative example 2
Using existing water-repellent paint as a comparison case 2.
The product of product and comparative example 1-2 to embodiment 1-4 is tested for the property, and test result is shown in Table 1.
Table 1
From table 1 it follows that the product of embodiment 1-4 shines in rate of drying, compression strength, glossiness and uvioresistant
The product of comparative example 1-2 is superior in the performance penetrated.
This product is digested tartary buckwheat to obtain tartary buckwheat enzymolysis liquid, by tartary buckwheat enzymolysis liquid to diatomite, to benzene two
Phenol, methyl methacrylate are modified, then other raw materials are mixed and obtain different products using different preparation processes, will
Different products are mixed, and obtained finished product has the function of quick-drying, also have good compression strength, glossiness and anti-purple
Outside line radiation.
It is obvious to a person skilled in the art that invention is not limited to the details of the above exemplary embodiments, Er Qie
In the case where without departing substantially from spirit or essential attributes of the invention, the present invention can be realized in other specific forms.Therefore, no matter
From the point of view of which point, the present embodiments are to be considered as illustrative and not restrictive, and the scope of the present invention is by appended power
Benefit requires rather than above description limits, it is intended that all by what is fallen within the meaning and scope of the equivalent elements of the claims
Variation is included within the present invention.
In addition, it should be understood that although this specification is described in terms of embodiments, but not each embodiment is only wrapped
Containing an independent technical solution, this description of the specification is merely for the sake of clarity, and those skilled in the art should
It considers the specification as a whole, the technical solutions in the various embodiments may also be suitably combined, forms those skilled in the art
The other embodiments being understood that.
Claims (7)
1. a kind of water-repellent paint for external wall of building, which is characterized in that the raw material including following parts by weight: tartary buckwheat 8-13
Part, 4.4-6.8 parts of nano silica, 5.5-7.2 parts of heavy calcium carbonate, 5-7.8 parts of styrene-acrylic emulsion, diatomite 21-26.8
Part, 1.6-2.5 parts of hydroquinone, 18.5-24.6 parts of methyl methacrylate, 3.3-5.2 parts of cellulose, propylene glycol 13.5-
18.4 parts and water 48-55 parts.
2. the water-repellent paint according to claim 1 for external wall of building, which is characterized in that the cellulose includes methyl
At least one of cellulose and hydroxyethyl cellulose.
3. the water-repellent paint according to claim 1 for external wall of building, which is characterized in that the nano silica
Partial size is 24-40nm, and the partial size of heavy calcium carbonate is 45-82um.
4. a kind of preparation method of the water-repellent paint a method according to any one of claims 1-3 for external wall of building, which is characterized in that
Specific step is as follows:
Tartary buckwheat is immersed in 24-28 degrees Celsius of water 1.5-3 hours, is then crushed the tartary buckwheat after immersion by step 1
And it is sent into reactor tank, complex enzyme is added in the environment of 34-45 degrees Celsius and pH value are 5.1-6.4, enzymatic hydrolysis 5-7 was as a child
Enzyme deactivation, filtering, centrifugation, separation, obtains tartary buckwheat enzymolysis liquid;
Diatomite, hydroquinone, methyl methacrylate and tartary buckwheat enzymolysis liquid are added in ball grinder step 2, and ball milling is equal
Even and mistake 60-80 mesh, obtains the first mixture;
Step 3 adds water in dispersion cup, and nano silica, styrene-acrylic emulsion and fiber is added thereto while stirring
Element is uniformly dispersed, and then handles 20-30 minutes in the electric field of 620-880V, obtains the second mixture;
Heavy calcium carbonate is added in propylene glycol and mechanical stirring is uniform, obtains third mixture by step 4;
Step 5 stirs the first mixture, the second mixture and third mixture in blender with the revolving speed of 720-960rpm
It mixes 45-70 minutes, is then allowed to stand 3-5 hours to get finished product is arrived.
5. the preparation method of the water-repellent paint according to claim 4 for external wall of building, which is characterized in that the step
The ratio of grinding media to material of two ball grinders is 55-70:1, and ball milling temperature is 50-66 degrees Celsius, rotational speed of ball-mill 90-135rpm.
6. the preparation method of the water-repellent paint according to claim 4 for external wall of building, which is characterized in that the step
The ultrasonic wave aid dispersion of 15-22KHz is used in three.
7. a kind of application method of the water-repellent paint a method according to any one of claims 1-3 for external wall of building, which is characterized in that
Specific step is as follows: water-repellent paint is coated uniformly on external wall of building surface using the method for roller coating or blade coating.
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Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103834244A (en) * | 2013-12-25 | 2014-06-04 | 杨昌富 | Emulsion paint for exterior wall |
CN104927430A (en) * | 2015-06-15 | 2015-09-23 | 张家港市山牧新材料技术开发有限公司 | Waterproof paint |
CN105985684A (en) * | 2015-02-10 | 2016-10-05 | 北新集团建材股份有限公司 | Matte high-weatherability high-hydrophobicity exterior wall emulsion paint and preparation method thereof |
CN107892849A (en) * | 2017-11-22 | 2018-04-10 | 江门市水星涂料科技有限公司 | A kind of reflective heat-insulation paint and preparation method thereof |
-
2018
- 2018-08-13 CN CN201810916830.7A patent/CN108997808A/en active Pending
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103834244A (en) * | 2013-12-25 | 2014-06-04 | 杨昌富 | Emulsion paint for exterior wall |
CN105985684A (en) * | 2015-02-10 | 2016-10-05 | 北新集团建材股份有限公司 | Matte high-weatherability high-hydrophobicity exterior wall emulsion paint and preparation method thereof |
CN104927430A (en) * | 2015-06-15 | 2015-09-23 | 张家港市山牧新材料技术开发有限公司 | Waterproof paint |
CN107892849A (en) * | 2017-11-22 | 2018-04-10 | 江门市水星涂料科技有限公司 | A kind of reflective heat-insulation paint and preparation method thereof |
Non-Patent Citations (1)
Title |
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温辉梁: "《化工助剂》", 31 December 2009, 江西科学技术出版社 * |
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Application publication date: 20181214 |
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RJ01 | Rejection of invention patent application after publication |