CN108997704A - A kind of alloying pellet and preparation method thereof of the compound PVB material of ABS - Google Patents
A kind of alloying pellet and preparation method thereof of the compound PVB material of ABS Download PDFInfo
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- CN108997704A CN108997704A CN201810660626.3A CN201810660626A CN108997704A CN 108997704 A CN108997704 A CN 108997704A CN 201810660626 A CN201810660626 A CN 201810660626A CN 108997704 A CN108997704 A CN 108997704A
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- alloying pellet
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
- C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/06—Polymer mixtures characterised by other features having improved processability or containing aids for moulding methods
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/08—Polymer mixtures characterised by other features containing additives to improve the compatibility between two polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/20—Recycled plastic
Abstract
The present invention relates to field of alloy material, provide a kind of alloying pellet of compound PVB material of ABS, the raw material including following parts by weight: 130-160 parts of ABS, 45-55 parts of PVB, 4-8 parts of SAN-g-EPDM, 2.2-2.8 parts of ABS high glue powder, 1.5-2.5 parts of White Mineral Oil, 1.5-2.5 parts of antismoke agent；Wherein, PVB is specially the PVB waste material for deriving from production and living.The present invention also provides a kind of preparation methods of the alloying pellet of the compound PVB material of ABS.The present invention has the advantages that ABS and PVB waste material is used cooperatively, and rationally cooperate corresponding lubricant, antismoke agent, toughener, expanding material, makes ABS/PVB modified alloy that there is better comprehensive performance, expand the application range of ABS alloy；In addition, PVB waste material is used in the preparation of ABS alloy particle, moreover it is possible to further mitigate environmental pressure.
Description
Technical field
The present invention relates to the alloying pellets and its preparation side of field of alloy material more particularly to a kind of compound PVB material of ABS
Method.
Background technique
ABS has the structural particularity of two phase composition of plastics phase and rubber phase, which dictates that it is in performance with superior
Property, such as good rigidity, toughness, oil resistant is corrosion-resistant and good processing fluidity etc., and it is each to be widely used in each row such as automobile, household electrical appliances
In industry, but the disadvantage that it is there is also poor heat resistance, not fire-retardant and cost is high compared with general-purpose plastics.Phenyl, cyano in ABS structure etc.
Good condition is provided for the modification of ABS, a large amount of ABS blending and modifying kind has occurred, such as PVC/ABS, PC/ABS, PBT/
ABS and PMMA/ABS etc., they have his own strong points in performance, gradually instead of certain plastics varieties, and appear in the life of people
In work.
Polyvinyl butyral (PVB) is widely used in the safety interlayers glass such as automobile, and there is safety, heat preservation, control to make an uproar
The multiple functions such as sound and isolation ultraviolet.However, a large amount of leftover pieces, Er Qiesui can be generated in the production process of laminated glass
The development of communications, also occur in succession various motor vehicle liquidations and dismounting recycling problem, no matter these problems are to resource, ring
Border, or it is all increasingly serious to economic level.Therefore, if these " waste materials " can be used, product can not only be reduced
Cost improves certain performances of product, moreover it is possible to respond to the call, play the role of energy-saving and environmental protection.
Accordingly, it is badly in need of a kind of ABS alloy particle and preparation method thereof added with PVB waste material, at present to make full use of PVB
Waste material is realized " turning waste into wealth ".
Summary of the invention
Technical problem to be solved by the present invention lies in provide a kind of conjunction of compound PVB material of the ABS added with PVB waste material
Gold particle and preparation method thereof.
The present invention solves above-mentioned technical problem using following technical scheme:
A kind of alloying pellet of the compound PVB material of ABS, the raw material including following parts by weight: ABS130-160 parts, PVB
45-55 parts, 4-8 parts of SAN-g-EPDM, 2.2-2.8 parts of ABS high glue powder, 1.5-2.5 parts of White Mineral Oil, 1.5-2.5 parts of antismoke agent；
Wherein, PVB is specially the PVB waste material for deriving from production and living.
As one of preferred embodiment of the invention, the raw material including following parts by weight: 145 parts of ABS, PVB50 parts,
6 parts of SAN-g-EPDM, 2.5 parts of ABS high glue powder, 2 parts of White Mineral Oil, 2 parts of antismoke agent；Wherein, PVB is specially to derive from production life
PVB waste material living.
As one of preferred embodiment of the invention, the raw material including following parts by weight: 140 parts of ABS, PVB48 parts,
5 parts of SAN-g-EPDM, 2.4 parts of ABS high glue powder, 1.8 parts of White Mineral Oil, 1.8 parts of antismoke agent；Wherein, PVB is specially to derive from life
Generate PVB waste material living.
As one of preferred embodiment of the invention, the raw material including following parts by weight: 150 parts of ABS, PVB53 parts,
7 parts of SAN-g-EPDM, 2.7 parts of ABS high glue powder, 2.3 parts of White Mineral Oil, 2.3 parts of antismoke agent；Wherein, PVB is specially to derive from life
Generate PVB waste material living.
As one of preferred embodiment of the invention, the antismoke agent is specially frerrous chloride or iron chloride.
As one of preferred embodiment of the invention, each raw material is directly purchased from existing circulation market.
A kind of preparation method of the alloying pellet of the compound PVB material of ABS, includes the following steps:
(1) according to above-mentioned parts by weight, ABS and PVB are uniformly mixed；
(2) according to above-mentioned parts by weight, SAN-g-EPDM, ABS high glue powder, White Mineral Oil and antismoke agent are uniformly mixed；
(3) step (1) and step (2) resulting mixture are mixed, obtain bulk material；
(4) treated that material is transported in double screw extruder by agitated, homogenous plasticized through double screw extruder, then
Respective alloy particle is made through pelletizing.
As one of preferred embodiment of the invention, in the step (3), by step (1) and step (2) resulting mixture
Carry out mixing 6-10h.
It further include utilizing pelletizer pair between the step (3) and step (4) as one of preferred embodiment of the invention
The bulk material carries out the step of granular material is made in pelletizing processing.
As one of preferred embodiment of the invention, in the step (4), double screw extruder carries out granular material equal
Even plasticizing forms strip-shaped materials, and strip-shaped materials form alloying pellet through pelletizing processing again.
As one of preferred embodiment of the invention, in the pelletizing processing, pelletizer cutter rotating velocity is 22-24r/min, double
Wrist revolving speed is 12-14r/min.
Each raw material effect:
ABS: the structural particularity with two phase composition of plastics phase and rubber phase has good rigidity, toughness, and oil resistant is resistance to
Corrosion and good processing fluidity；
PVB waste material: mainly laminated glass, PVB film etc. have the characteristics such as heat-resisting, cold-resistant, mechanical strength is high；By its
In preparation for ABS alloy particle, the comprehensive performance of ABS alloy particle not only can be further improved, moreover it is possible to further subtract
Light environmental pressure is realized " turning waste into wealth "；
SAN-g-EPDM: splendid to the compatibilization effect of PVB/PVB system as expanding material；
ABS high glue powder: there is certain toughening effect to PVB/PVB system；
White Mineral Oil: as lubricant, there is lubricating action；
Antismoke agent: frerrous chloride or iron chloride effectively eliminate the smog that each material generates in burning as antismoke agent
With the compound of pernicious gas.
The present invention compared with prior art the advantages of be: ABS and PVB waste material is used cooperatively, and is rationally combined with corresponding
Lubricant, antismoke agent, toughener, expanding material, make final resulting ABS/PVB modified alloy that there are better excellent properties,
The further expansion application range of ABS alloy；It, not only can be in addition, PVB waste material is used in the preparation of ABS alloy particle
Further increase the comprehensive performance of alloying pellet, moreover it is possible to further mitigate environmental pressure, realize " turning waste into wealth ".
Specific embodiment
It elaborates below to the embodiment of the present invention, the present embodiment carries out under the premise of the technical scheme of the present invention
Implement, the detailed implementation method and specific operation process are given, but protection scope of the present invention is not limited to following implementation
Example.
Embodiment 1
A kind of alloying pellet of the compound PVB material of ABS of the present embodiment, the raw material including following parts by weight: ABS 130
Part, 45 parts of PVB, 4 parts of SAN-g-EPDM, 2.2 parts of ABS high glue powder, 1.5 parts of White Mineral Oil, 1.5 parts of frerrous chloride；Wherein, PVB
Specially derive from the PVB waste material of production and living.
Embodiment 2
A kind of alloying pellet of the compound PVB material of ABS of the present embodiment, the raw material including following parts by weight: ABS 160
Part, 55 parts of PVB, 8 parts of SAN-g-EPDM, 2.8 parts of ABS high glue powder, 2.5 parts of White Mineral Oil, 2.5 parts of iron chloride；Wherein, PVB has
Body is the PVB waste material from production and living.
Embodiment 3
A kind of alloying pellet of the compound PVB material of ABS of the present embodiment, the raw material including following parts by weight: ABS 145
Part, 50 parts of PVB, 6 parts of SAN-g-EPDM, 2.5 parts of ABS high glue powder, 2 parts of White Mineral Oil, 2 parts of frerrous chloride；Wherein, PVB is specific
For from the PVB waste material of production and living.
Embodiment 4
A kind of alloying pellet of the compound PVB material of ABS of the present embodiment, the raw material including following parts by weight: ABS 140
Part, 48 parts of PVB, 5 parts of SAN-g-EPDM, 2.4 parts of ABS high glue powder, 1.8 parts of White Mineral Oil, 1.8 parts of iron chloride；Wherein, PVB has
Body is the PVB waste material from production and living.
Embodiment 5
A kind of alloying pellet of the compound PVB material of ABS of the present embodiment, the raw material including following parts by weight: ABS 150
Part, 53 parts of PVB, 7 parts of SAN-g-EPDM, 2.7 parts of ABS high glue powder, 2.3 parts of White Mineral Oil, 2.3 parts of frerrous chloride；Wherein, PVB
Specially derive from the PVB waste material of production and living.
Embodiment 6
The preparation method of the alloying pellet of the compound PVB material of ABS in a kind of above-described embodiment of the present embodiment, including it is as follows
Step:
(1) first ABS and PVB waste material is uniformly mixed by PVB waste recovery according still further to above-mentioned parts by weight；
(2) according to above-mentioned parts by weight, SAN-g-EPDM, ABS high glue powder, White Mineral Oil and antismoke agent are uniformly mixed；
(3) step (1) and step (2) resulting mixture are subjected to mixing 6h, obtain bulk material；
(4) pelletizing processing is carried out to the resulting bulk material of step (3) using pelletizer and granular material is made, wherein
Cutter rotating velocity is 22r/min, and double wrist revolving speeds are 12r/min；
(5) granular material is transported in double screw extruder, granular material is carried out using double screw extruder
Homogenous plasticized formation strip-shaped materials, strip-shaped materials form alloying pellet through pelletizing processing again, wherein cutter rotating velocity 22r/min,
Double wrist revolving speeds are 12r/min.
Embodiment 7
The preparation method of the alloying pellet of the compound PVB material of ABS in a kind of above-described embodiment of the present embodiment, including it is as follows
Step:
(1) first ABS and PVB waste material is uniformly mixed by PVB waste recovery according still further to above-mentioned parts by weight；
(2) according to above-mentioned parts by weight, SAN-g-EPDM, ABS high glue powder, White Mineral Oil and antismoke agent are uniformly mixed；
(3) step (1) and step (2) resulting mixture are subjected to mixing 10h, obtain bulk material；
(4) pelletizing processing is carried out to the resulting bulk material of step (3) using pelletizer and granular material is made, wherein
Cutter rotating velocity is 24r/min, and double wrist revolving speeds are 14r/min；
(5) granular material is transported in double screw extruder, granular material is carried out using double screw extruder
Homogenous plasticized formation strip-shaped materials, strip-shaped materials form alloying pellet through pelletizing processing again, wherein cutter rotating velocity 24r/min,
Double wrist revolving speeds are 14r/min.
Embodiment 8
The preparation method of the alloying pellet of the compound PVB material of ABS in a kind of above-described embodiment of the present embodiment, including it is as follows
Step:
(1) first ABS and PVB waste material is uniformly mixed by PVB waste recovery according still further to above-mentioned parts by weight；
(2) according to above-mentioned parts by weight, SAN-g-EPDM, ABS high glue powder, White Mineral Oil and antismoke agent are uniformly mixed；
(3) step (1) and step (2) resulting mixture are subjected to mixing 8h, obtain bulk material；
(4) pelletizing processing is carried out to the resulting bulk material of step (3) using pelletizer and granular material is made, wherein
Cutter rotating velocity is 23r/min, and double wrist revolving speeds are 13r/min；
(5) granular material is transported in double screw extruder, granular material is carried out using double screw extruder
Homogenous plasticized formation strip-shaped materials, strip-shaped materials form alloying pellet through pelletizing processing again, wherein cutter rotating velocity 23r/min,
Double wrist revolving speeds are 13r/min.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all in essence of the invention
Made any modifications, equivalent replacements, and improvements etc., should all be included in the protection scope of the present invention within mind and principle.
Claims (10)
1. a kind of alloying pellet of the compound PVB material of ABS, which is characterized in that the raw material including following parts by weight: ABS 130-
160 parts, 45-55 parts of PVB, 4-8 parts of SAN-g-EPDM, 2.2-2.8 parts of ABS high glue powder, 1.5-2.5 parts of White Mineral Oil, antismoke agent
1.5-2.5 part；Wherein, PVB is specially the PVB waste material for deriving from production and living.
2. the alloying pellet of the compound PVB material of ABS according to claim 1, which is characterized in that including following parts by weight
Raw material: 145 parts of ABS, 50 parts of PVB, 6 parts of SAN-g-EPDM, 2.5 parts of ABS high glue powder, 2 parts of White Mineral Oil, 2 parts of antismoke agent；
Wherein, PVB is specially the PVB waste material for deriving from production and living.
3. the alloying pellet of the compound PVB material of ABS according to claim 1, which is characterized in that including following parts by weight
Raw material: 140 parts of ABS, 48 parts of PVB, 5 parts of SAN-g-EPDM, 2.4 parts of ABS high glue powder, 1.8 parts of White Mineral Oil, antismoke agent 1.8
Part；Wherein, PVB is specially the PVB waste material for deriving from production and living.
4. the alloying pellet of the compound PVB material of ABS according to claim 1, which is characterized in that including following parts by weight
Raw material: 150 parts of ABS, 53 parts of PVB, 7 parts of SAN-g-EPDM, 2.7 parts of ABS high glue powder, 2.3 parts of White Mineral Oil, antismoke agent 2.3
Part；Wherein, PVB is specially the PVB waste material for deriving from production and living.
5. the alloying pellet of the compound PVB material of ABS according to claim 1 to 4, which is characterized in that the antismoke agent
Specially frerrous chloride or iron chloride.
6. a kind of preparation method of the alloying pellet of the compound PVB material of ABS a method as claimed in any one of claims 1 to 5, feature exist
In including the following steps:
(1) according to above-mentioned parts by weight, ABS and PVB are uniformly mixed；
(2) according to above-mentioned parts by weight, SAN-g-EPDM, ABS high glue powder, White Mineral Oil and antismoke agent are uniformly mixed；
(3) step (1) and step (2) resulting mixture are mixed, obtain bulk material；
(4) treated that material is transported in double screw extruder by agitated, homogenous plasticized through double screw extruder, then through cutting
Respective alloy particle is made in grain.
7. the preparation method of the alloying pellet of the compound PVB material of ABS according to claim 6, which is characterized in that the step
Suddenly in (3), step (1) and step (2) resulting mixture are subjected to mixing 6-10h.
8. the preparation method of the alloying pellet of the compound PVB material of ABS according to claim 6, which is characterized in that the step
It suddenly further include carrying out pelletizing processing to the bulk material using pelletizer granular material is made between (3) and step (4)
Step.
9. the preparation method of the alloying pellet of the compound PVB material of ABS according to claim 8, which is characterized in that the step
Suddenly in (4), double screw extruder carries out homogenous plasticized formation strip-shaped materials to granular material, and strip-shaped materials are handled through pelletizing again
Form alloying pellet.
10. the preparation method of the alloying pellet of the compound PVB material of ABS according to claim 9, which is characterized in that described
In pelletizing processing, pelletizer cutter rotating velocity is 22-24r/min, and double wrist revolving speeds are 12-14r/min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810660626.3A CN108997704A (en) | 2018-06-25 | 2018-06-25 | A kind of alloying pellet and preparation method thereof of the compound PVB material of ABS |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810660626.3A CN108997704A (en) | 2018-06-25 | 2018-06-25 | A kind of alloying pellet and preparation method thereof of the compound PVB material of ABS |
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| Publication Number | Publication Date |
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| CN108997704A true CN108997704A (en) | 2018-12-14 |
Family
ID=64601648
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| CN201810660626.3A Withdrawn CN108997704A (en) | 2018-06-25 | 2018-06-25 | A kind of alloying pellet and preparation method thereof of the compound PVB material of ABS |
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Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0771848A4 (en) * | 1995-04-27 | 1998-12-09 | Polyplastics Co | Thermoplastic resin composition and process for production thereof |
| CN1813027A (en) * | 2003-06-28 | 2006-08-02 | 纳幕尔杜邦公司 | Polyvinylbutyral compositions and blends having enhanced surface properties and articles made therefrom |
-
2018
- 2018-06-25 CN CN201810660626.3A patent/CN108997704A/en not_active Withdrawn
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0771848A4 (en) * | 1995-04-27 | 1998-12-09 | Polyplastics Co | Thermoplastic resin composition and process for production thereof |
| CN1813027A (en) * | 2003-06-28 | 2006-08-02 | 纳幕尔杜邦公司 | Polyvinylbutyral compositions and blends having enhanced surface properties and articles made therefrom |
Non-Patent Citations (2)
| Title |
|---|
| ＢＡＬＡＫＲＩＳＨＮＡＮ Ｓ: ""Ｅｆｆｅｃｔ ｏｆ ｆｕｎｃｔｉｏｎａｌｉｔｙ ｌｅｖｅｌｓ ａｎｄ ｃｏｍｐａｔｉｂｉｌｉｔｙ"", 《Ｊ ＡＰＰＬ ＰＯＬＹＭ ＳＣＩ》 * |
| 汪慧等: "回收聚乙烯醇缩丁醛(PVB)/ABS共混体系的制备及力学性能", 《材料研究与应用》 * |
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Application publication date: 20181214 |