CN105462040B - A kind of water-fast fluorescence bamboo-plastic composite material and preparation method thereof - Google Patents

A kind of water-fast fluorescence bamboo-plastic composite material and preparation method thereof Download PDF

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CN105462040B
CN105462040B CN201610007493.0A CN201610007493A CN105462040B CN 105462040 B CN105462040 B CN 105462040B CN 201610007493 A CN201610007493 A CN 201610007493A CN 105462040 B CN105462040 B CN 105462040B
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parts
water
bamboo
resin
composite material
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CN105462040A (en
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彭孝茹
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Xu Haijun
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/06—Polyethene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B7/00—Mixing; Kneading
    • B29B7/74—Mixing; Kneading using other mixers or combinations of mixers, e.g. of dissimilar mixers ; Plant
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B9/00—Making granules
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
    • B29C45/17—Component parts, details or accessories; Auxiliary operations
    • B29C45/76—Measuring, controlling or regulating
    • B29C45/77—Measuring, controlling or regulating of velocity or pressure of moulding material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
    • B29C45/17—Component parts, details or accessories; Auxiliary operations
    • B29C45/76—Measuring, controlling or regulating
    • B29C45/78—Measuring, controlling or regulating of temperature
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2945/00—Indexing scheme relating to injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould
    • B29C2945/76—Measuring, controlling or regulating
    • B29C2945/76494—Controlled parameter
    • B29C2945/76498—Pressure
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2945/00—Indexing scheme relating to injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould
    • B29C2945/76—Measuring, controlling or regulating
    • B29C2945/76494—Controlled parameter
    • B29C2945/76531—Temperature
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2945/00—Indexing scheme relating to injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould
    • B29C2945/76—Measuring, controlling or regulating
    • B29C2945/76494—Controlled parameter
    • B29C2945/76551—Time
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2945/00—Indexing scheme relating to injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould
    • B29C2945/76—Measuring, controlling or regulating
    • B29C2945/76494—Controlled parameter
    • B29C2945/76595—Velocity
    • B29C2945/76605—Velocity rotational movement
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

Abstract

The present invention provides a kind of water-fast fluorescence bamboo-plastic composite material and preparation method thereof.It is prepared by following component：Bamboo powder, zinc sulphide luminescent powder, polyvinyl resin, acrylic resin, vinylidene resin, vinyl acetate resin, 2,6 di-t-butyl, 4 methylphenol, Lauryl Alcohol ester, pentaerythritol oleate, castor oil, polyether sulfone, phthalic acid ester, water.Its preparation method is added in mixer and mixed first to mix all components, is then added mixer mixing, is cooled to room temperature, is ground into particle, finally by pulverized particles through injection molding machine injection molding to obtain the final product.The water-fast fluorescence bamboo-plastic composite material of the present invention, has good water-fast moisture resistance effect, is suitable for working under high humidity environment, while has elasticity and impact resistance well；In addition its preparation process is also relatively simple.

Description

A kind of water-fast fluorescence bamboo-plastic composite material and preparation method thereof
Technical field
The present invention relates to Material Field, and in particular to a kind of water-fast fluorescence bamboo-plastic composite material and preparation method thereof.
Background technology
Bamboo-plastic composite material is using bamboo fibres such as bamboo sawdust, bamboo scraps, bamboo slags as primary raw material, utilizes polymer chemistry interface Merge principle and strengthen the characteristics of filling-modified, be compounded a certain proportion of plastic matrix, be aided with appropriate processing aid, through special A kind of molding new material of the multiple use with Reversible Cycle of process post-processing.Existing many scholars are to it at present Performance, which has carried out research, to be improved, its application range also becomes more and more extensive, and wherein fluorescence bamboo-plastic composite material is just employed In all trades and professions, such as on road instruction, night advertisement, landscaping and public sign.The use of wherein most material Ambient humidity is all higher, or needs to be subjected to exposing to the sun and rain, and therefore, developing a kind of water-fast fluorescence bamboo-plastic composite material can carry significantly The service life of high material, exaggerates its application range, has broad application prospects.
The content of the invention
Technical problems to be solved：The object of the present invention is to provide a kind of water-fast fluorescence bamboo-plastic composite material, has fine Water-fast moisture resistance effect, be suitable for working under high humidity environment, at the same have well elasticity and impact resistance.
Technical solution：A kind of water-fast fluorescence bamboo-plastic composite material, is prepared by following component with parts by weight：Bamboo powder 10- 20 parts, 10-20 parts of zinc sulphide luminescent powder, 20-30 parts of polyvinyl resin, 10-20 parts of acrylic resin, vinylidene resin 10-20 parts, 2-5 parts of vinyl acetate resin, 1-2 parts of 2,6 di tert butyl 4 methyl phenol, 1-2 parts of Lauryl Alcohol ester, season penta 2-5 parts of tetrol oleate, 2-5 parts of castor oil, 1-2 parts of polyether sulfone, 0.5-1 parts of phthalic acid ester, 20-30 parts of water.
It is further preferred that a kind of water-fast fluorescence bamboo-plastic composite material, by following component with prepared by parts by weight and Into：13-17 parts of bamboo powder, 12-18 parts of zinc sulphide luminescent powder, 22-27 parts of polyvinyl resin, 13-18 parts of acrylic resin, inclined dichloro 12-17 parts of vinyl, 3-4 parts of vinyl acetate resin, 1.3-1.7 parts of 2,6 di tert butyl 4 methyl phenol, Lauryl Alcohol 1.2-1.8 parts of ester, 3-4 parts of pentaerythritol oleate, 3-4 parts of castor oil, 1.3-1.7 parts of polyether sulfone, phthalic acid ester 0.6- 0.9 part, 22-27 parts of water.
The preparation method of above-mentioned water-fast fluorescence bamboo-plastic composite material comprises the following steps：
Step 1：All components are mixed, are added in mixer with rotating speed 1400-1500r/min, at 95-105 DEG C of temperature Mixing 10-15 minutes；
Step 2：Feed the mixture into 165-175 DEG C of temperature in mixer, rotating speed 35-45r/min, mixing 20-30 minutes；
Step 3：Step 2 gains are cooled to room temperature, are ground into particle；
Step 4：By pulverized particles through injection molding machine in 165-175 DEG C of injection temperature, back-pressure 6-9MPa, dwell pressure 6- 9MPa, screw speed 70-100r/min, 10-15 seconds cooling time of lower injection molding to obtain the final product.
It is further preferred that rotating speed is 1430-1470r/min in step 1, temperature is 98-102 DEG C, incorporation time 11- 14 minutes.
It is further preferred that mixing temperature is 168-172 DEG C, rotating speed 38-42r/min in step 2, mixing time is 23-27 minutes.
It is further preferred that injection temperature is 168-172 DEG C, back-pressure 7-8MPa, dwell pressure 7- in step 4 8MPa, screw speed 80-90r/min, cooling time are 11-14 seconds.
Beneficial effect：The water absorption rate of the water-fast fluorescence bamboo-plastic composite material of the present invention is relatively low, and the water absorption rate of 15 days is minimum only For 1.69%, expansion rate of water absorption also only has 0.26%, illustrates that the water-fast effect of the present invention is fine, can be very in the larger environment of humidity Work well；Its bending strength is maximum also up to 44.69MPa, to illustrate its elasticity, impact resistance up to 76.2MPa, tensile strength Also preferably, it is a kind of preferably water-fast moisture resistance environmental protection ground composite material.
Embodiment
Embodiment 1
A kind of water-fast fluorescence bamboo-plastic composite material, is prepared by following component with parts by weight：13 parts of bamboo powder, zinc sulphide night 12 parts of light powder, 22 parts of polyvinyl resin, 13 parts of acrylic resin, 12 parts of vinylidene resin, 3 parts of vinyl acetate resin, 1.3 parts of 2,6 di tert butyl 4 methyl phenol, 1.2 parts of Lauryl Alcohol ester, 3 parts of pentaerythritol oleate, 3 parts of castor oil, polyethers 1.3 parts of sulfone, 0.6 part of phthalic acid ester, 22 parts of water.
The preparation method of above-mentioned water-fast fluorescence bamboo-plastic composite material is：First all components are mixed, add mixer in Rotating speed 1430r/min, mixes at 98 DEG C of temperature 11 minutes, then adds 168 DEG C, rotating speed 38r/min of temperature in mixer, mixing 23 minutes, be cooled to room temperature, be ground into particle, finally by pulverized particles through injection molding machine in 168 DEG C of injection temperature, back-pressure 7MPa, dwell pressure 7MPa, screw speed 80r/min, 11 seconds cooling times of lower injection molding to obtain the final product.
Embodiment 2
A kind of water-fast fluorescence bamboo-plastic composite material, is prepared by following component with parts by weight：17 parts of bamboo powder, zinc sulphide night 18 parts of light powder, 27 parts of polyvinyl resin, 18 parts of acrylic resin, 17 parts of vinylidene resin, 4 parts of vinyl acetate resin, 1.7 parts of 2,6 di tert butyl 4 methyl phenol, 1.8 parts of Lauryl Alcohol ester, 4 parts of pentaerythritol oleate, 4 parts of castor oil, polyethers 1.7 parts of sulfone, 0.9 part of phthalic acid ester, 27 parts of water.
The preparation method of above-mentioned water-fast fluorescence bamboo-plastic composite material is：First all components are mixed, add mixer in Rotating speed 1470r/min, mixes at 102 DEG C of temperature 14 minutes, then adds 172 DEG C of temperature in mixer, rotating speed 42r/min, close Refining 27 minutes, be cooled to room temperature, be ground into particle, finally by pulverized particles through injection molding machine in 172 DEG C of injection temperature, back-pressure 8MPa, dwell pressure 8MPa, screw speed 90r/min, 14 seconds cooling times of lower injection molding to obtain the final product.
Embodiment 3
A kind of water-fast fluorescence bamboo-plastic composite material, is prepared by following component with parts by weight：20 parts of bamboo powder, zinc sulphide night 20 parts of light powder, 30 parts of polyvinyl resin, 20 parts of acrylic resin, 20 parts of vinylidene resin, 5 parts of vinyl acetate resin, 2 parts of 2,6 di tert butyl 4 methyl phenol, 2 parts of Lauryl Alcohol ester, 5 parts of pentaerythritol oleate, 5 parts of castor oil, polyether sulfone 2 Part, 1 part of phthalic acid ester, 30 parts of water.
The preparation method of above-mentioned water-fast fluorescence bamboo-plastic composite material is：First all components are mixed, add mixer in Rotating speed 1500r/min, mixes at 105 DEG C of temperature 15 minutes, then adds 175 DEG C of temperature in mixer, rotating speed 45r/min, close Refining 30 minutes, be cooled to room temperature, be ground into particle, finally by pulverized particles through injection molding machine in 175 DEG C of injection temperature, back-pressure 9MPa, dwell pressure 9MPa, screw speed 100r/min, 15 seconds cooling times of lower injection molding to obtain the final product.
Embodiment 4
A kind of water-fast fluorescence bamboo-plastic composite material, is prepared by following component with parts by weight：10 parts of bamboo powder, zinc sulphide night 10 parts of light powder, 20 parts of polyvinyl resin, 10 parts of acrylic resin, 10 parts of vinylidene resin, 2 parts of vinyl acetate resin, 1 part of 2,6 di tert butyl 4 methyl phenol, 1 part of Lauryl Alcohol ester, 2 parts of pentaerythritol oleate, 2 parts of castor oil, polyether sulfone 1 Part, 0.5 part of phthalic acid ester, 20 parts of water.
The preparation method of above-mentioned water-fast fluorescence bamboo-plastic composite material is：First all components are mixed, add mixer in Rotating speed 1400r/min, mixes at 95 DEG C of temperature 10 minutes, then adds 165 DEG C, rotating speed 35r/min of temperature in mixer, mixing 20 minutes, be cooled to room temperature, be ground into particle, finally by pulverized particles through injection molding machine in 165 DEG C of injection temperature, back-pressure 6MPa, dwell pressure 6MPa, screw speed 70r/min, 10 seconds cooling times of lower injection molding to obtain the final product.
Embodiment 5
A kind of water-fast fluorescence bamboo-plastic composite material, is prepared by following component with parts by weight：15 parts of bamboo powder, zinc sulphide night 15 parts of light powder, 25 parts of polyvinyl resin, 15 parts of acrylic resin, 15 parts of vinylidene resin, vinyl acetate resin 3.5 Part, 1.5 parts of 2,6 di tert butyl 4 methyl phenol, 1.5 parts of Lauryl Alcohol ester, 3.5 parts of pentaerythritol oleate, castor oil 3.5 Part, 1.5 parts of polyether sulfone, 0.7 part of phthalic acid ester, 25 parts of water.
The preparation method of above-mentioned water-fast fluorescence bamboo-plastic composite material is：First all components are mixed, add mixer in Rotating speed 1450r/min, mixes at 100 DEG C of temperature 12 minutes, then adds 170 DEG C of temperature in mixer, rotating speed 40r/min, close Refining 25 minutes, be cooled to room temperature, be ground into particle, finally by pulverized particles through injection molding machine in 170 DEG C of injection temperature, back-pressure 7MPa, dwell pressure 7MPa, screw speed 85r/min, 12 seconds cooling times of lower injection molding to obtain the final product.
Comparative example 1
Difference lies in replace acrylic resin with polyvinyl resin with embodiment 5 for the present embodiment.Specifically：
A kind of water-fast fluorescence bamboo-plastic composite material, is prepared by following component with parts by weight：15 parts of bamboo powder, zinc sulphide night 15 parts of light powder, 25 parts of polyvinyl resin, 15 parts of vinylidene resin, 3.5 parts of vinyl acetate resin, 2,6- di-t-butyls- 1.5 parts of 4- methylphenols, 1.5 parts of Lauryl Alcohol ester, 3.5 parts of pentaerythritol oleate, 3.5 parts of castor oil, 1.5 parts of polyether sulfone, 0.7 part of phthalic acid ester, 25 parts of water.
The preparation method of above-mentioned water-fast fluorescence bamboo-plastic composite material is：First all components are mixed, add mixer in Rotating speed 1450r/min, mixes at 100 DEG C of temperature 12 minutes, then adds 170 DEG C of temperature in mixer, rotating speed 40r/min, close Refining 25 minutes, be cooled to room temperature, be ground into particle, finally by pulverized particles through injection molding machine in 170 DEG C of injection temperature, back-pressure 7MPa, dwell pressure 7MPa, screw speed 85r/min, 12 seconds cooling times of lower injection molding to obtain the final product.
Comparative example 2
Difference lies in do not contain Lauryl Alcohol ester and pentaerythritol oleate with embodiment 5 for the present embodiment.Specifically It is：
A kind of water-fast fluorescence bamboo-plastic composite material, is prepared by following component with parts by weight：15 parts of bamboo powder, zinc sulphide night 15 parts of light powder, 25 parts of polyvinyl resin, 15 parts of acrylic resin, 15 parts of vinylidene resin, vinyl acetate resin 3.5 Part, 1.5 parts of 2,6 di tert butyl 4 methyl phenol, 3.5 parts of castor oil, 1.5 parts of polyether sulfone, 0.7 part of phthalic acid ester, water 25 parts.
The preparation method of above-mentioned water-fast fluorescence bamboo-plastic composite material is：First all components are mixed, add mixer in Rotating speed 1450r/min, mixes at 100 DEG C of temperature 12 minutes, then adds 170 DEG C of temperature in mixer, rotating speed 40r/min, close Refining 25 minutes, be cooled to room temperature, be ground into particle, finally by pulverized particles through injection molding machine in 170 DEG C of injection temperature, back-pressure 7MPa, dwell pressure 7MPa, screw speed 85r/min, 12 seconds cooling times of lower injection molding to obtain the final product.
Each embodiment is compared with comparative example, comparing result such as table 1 below：
The performance indicator of table 1 is water-fast fluorescence bamboo-plastic composite material
Name of product Water absorption rate (%) Thickness swelling rate (%) Bending strength（MPa） Tensile strength (MPa)
Embodiment 1 1.74 0.31 75.3 42.93
Embodiment 2 1.69 0.26 76.2 44.69
Embodiment 3 1.71 0.28 75.8 43.91
Embodiment 4 1.77 0.33 75.1 42.87
Embodiment 5 1.73 0.30 75.5 43.32
Comparative example 1 1.81 0.39 69.1 34.15
Comparative example 2 1.93 0.45 73.4 40.93
Note：Water absorption rate and thickness swelling rate minute are 15 days
As known from Table 1, the water absorption rate of embodiment 1-5 is all relatively low, the water absorption rate minimum 1.69% of 15 days, expansion rate of water absorption Also there was only 0.26%, illustrate that the water-fast effect of the present invention is fine；Its bending strength is maximum also reachable up to 76.2MPa, tensile strength 44.69MPa, illustrates its elasticity, and impact resistance is also fine.Compared with comparative example 1, find comparative example 1 water-fast effect slightly under Drop, and bending strength and tensile strength are then significantly reduced, and illustrate to compound resin by polyvinyl resin and acrylic resin Elastic strength uses polyvinyl resin higher than single.Compared with comparative example 2, Lauryl Alcohol ester and pentaerythritol oleate are found All have an impact to 4 listed indexs, wherein water absorption rate improves 0.2 percentage point, and expansion rate of water absorption also increases 0.25 Percentage point, illustrates that Lauryl Alcohol ester and pentaerythritol oleate have obvious action to the water resistance for improving the present invention.From table As a result it will be seen that highly preferred embodiment of the present invention is embodiment 2.

Claims (3)

  1. A kind of 1. water-fast fluorescence bamboo-plastic composite material, it is characterised in that：It is prepared by following component with parts by weight：Bamboo powder 10- 20 parts, 10-20 parts of zinc sulphide luminescent powder, 20-30 parts of polyvinyl resin, 10-20 parts of acrylic resin, vinylidene resin 10-20 parts, 2-5 parts of vinyl acetate resin, 1-2 parts of 2,6 di tert butyl 4 methyl phenol, 1-2 parts of Lauryl Alcohol ester, season penta 2-5 parts of tetrol oleate, 2-5 parts of castor oil, 1-2 parts of polyether sulfone, 0.5-1 parts of phthalic acid ester, 20-30 parts of water, it is prepared Method is as follows：
    Step 1：All components are mixed, are added in mixer with rotating speed 1400-1500r/min, are mixed at 95-105 DEG C of temperature 10-15 minutes；
    Step 2：Feed the mixture into 165-175 DEG C of temperature in mixer, rotating speed 35-45r/min, mixing 20-30 minutes；
    Step 3：Step 2 gains are cooled to room temperature, are ground into particle；
    Step 4：By pulverized particles through injection molding machine in 165-175 DEG C of injection temperature, back-pressure 6-9MPa, dwell pressure 6- 9MPa, screw speed 70-100r/min, 10-15 seconds cooling time of lower injection molding to obtain the final product.
  2. A kind of 2. water-fast fluorescence bamboo-plastic composite material according to claim 1, it is characterised in that：By following component with weight Part is prepared：13-17 parts of bamboo powder, 12-18 parts of zinc sulphide luminescent powder, 22-27 parts of polyvinyl resin, acrylic resin 13-18 Part, 12-17 parts of vinylidene resin, 3-4 parts of vinyl acetate resin, 2,6 di tert butyl 4 methyl phenol 1.3-1.7 Part, 1.2-1.8 parts of Lauryl Alcohol ester, 3-4 parts of pentaerythritol oleate, 3-4 parts of castor oil, 1.3-1.7 parts of polyether sulfone, adjacent benzene two 0.6-0.9 parts of formic acid esters, 22-27 parts of water.
  3. A kind of 3. water-fast fluorescence bamboo-plastic composite material as claimed in claim 1, it is characterised in that：The bamboo powder mesh number is 80- 120 mesh.
CN201610007493.0A 2016-01-07 2016-01-07 A kind of water-fast fluorescence bamboo-plastic composite material and preparation method thereof Active CN105462040B (en)

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CN108948770A (en) * 2018-08-02 2018-12-07 天津市建筑材料科学研究院有限公司 A kind of method that stalk prepares flame retardant type building board

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102031003A (en) * 2009-09-28 2011-04-27 莊丽 Fluorescent wood-plastic and bamboo-plastic new material
CN102702602A (en) * 2012-06-07 2012-10-03 天津聚贤达科技有限公司 Novel wood-plastic composite material
CN103102556A (en) * 2011-11-15 2013-05-15 上海杰事杰新材料(集团)股份有限公司 Bamboo-plastic composite material and preparation method and application thereof
CN103102572A (en) * 2013-02-05 2013-05-15 四川大学 Polyolefin wood-plastic composite material and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102031003A (en) * 2009-09-28 2011-04-27 莊丽 Fluorescent wood-plastic and bamboo-plastic new material
CN103102556A (en) * 2011-11-15 2013-05-15 上海杰事杰新材料(集团)股份有限公司 Bamboo-plastic composite material and preparation method and application thereof
CN102702602A (en) * 2012-06-07 2012-10-03 天津聚贤达科技有限公司 Novel wood-plastic composite material
CN103102572A (en) * 2013-02-05 2013-05-15 四川大学 Polyolefin wood-plastic composite material and preparation method thereof

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