CN108996937A - A method of cement retarder is prepared with industry by-product gypsum - Google Patents

A method of cement retarder is prepared with industry by-product gypsum Download PDF

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Publication number
CN108996937A
CN108996937A CN201810743549.8A CN201810743549A CN108996937A CN 108996937 A CN108996937 A CN 108996937A CN 201810743549 A CN201810743549 A CN 201810743549A CN 108996937 A CN108996937 A CN 108996937A
Authority
CN
China
Prior art keywords
gypsum
cement retarder
industry
product
ardealite
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810743549.8A
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Chinese (zh)
Inventor
王爱武
秦慧荣
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Tongling Ke Ke Industrial Gypsum Comprehensive Utilization Co Ltd
Original Assignee
Tongling Ke Ke Industrial Gypsum Comprehensive Utilization Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Tongling Ke Ke Industrial Gypsum Comprehensive Utilization Co Ltd filed Critical Tongling Ke Ke Industrial Gypsum Comprehensive Utilization Co Ltd
Priority to CN201810743549.8A priority Critical patent/CN108996937A/en
Publication of CN108996937A publication Critical patent/CN108996937A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B40/00Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
    • C04B40/0028Aspects relating to the mixing step of the mortar preparation
    • C04B40/0039Premixtures of ingredients
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2103/00Function or property of ingredients for mortars, concrete or artificial stone
    • C04B2103/20Retarders
    • C04B2103/22Set retarders

Abstract

The present invention provides a kind of method for preparing cement retarder with industry by-product gypsum, and the raw material for preparing cement retarder includes following constituent: titanium gypsum 20 ~ 50%, ardealite 10 ~ 40%, sulphur gypsum 10 ~ 30%, manganese gypsum 5 ~ 10%.The preparation of cement retarder is carried out by using the by-product gypsum generated in industrial production, it consumes by-product gypsum and carries out product manufacturing, and then solve the problems, such as that disorderly row leaves about chemical company's industrial residue, avoid pollution environment, by the industrial waste recycling and reusing of chemical enterprise emission, it solves the problems, such as that enterprise faces, while obtaining certain economic value.

Description

A method of cement retarder is prepared with industry by-product gypsum
Technical field
The present invention relates to cement retarder preparation field more particularly to a kind of cement retarder is prepared with industry by-product gypsum Method.
Background technique
The substance of the solid waste sulfur acid calcium discharged in the industrial production is referred to as industrial gypsum, industry by-product gypsum Ardealite including titanium gypsum, manganese gypsum, citric acid gypsum, boron gypsum and bunt gypsum etc..Under the requirement of environmental protection, how The industry by-product gypsum for effectively handling bulk deposition has become an extremely urgent problem in China or even world wide. Current stacking processing method seriously restricts the development of enterprise, has both occupied a large amount of soil, polluted underground water and has left Huge security risk, and the stacking expense for needing corporate payments high, are unfavorable for the sustainable development of enterprise.
Summary of the invention
In view of the above-mentioned problems of the prior art, preparing water with industry by-product gypsum the object of the present invention is to provide a kind of The method of mud retarder carries out the preparation of cement retarder by using the by-product gypsum generated in industrial production, consumes by-product Gypsum carries out product manufacturing, and then solves the problems, such as that disorderly row leaves about chemical company's industrial residue, avoids pollution environment.
The present invention provides a kind of method for preparing cement retarder with industry by-product gypsum, the cement retarder for preparing Raw material includes following constituent: titanium gypsum 20 ~ 50%, ardealite 10 ~ 40%, sulphur gypsum 10 ~ 30%, manganese gypsum 5 ~ 10%.
Further improvement lies in that: the preparation step is as follows:
Step 1: titanium gypsum, ardealite, sulphur gypsum and manganese gypsum are taken out in proportion spare;
Step 2: it is put into after above-mentioned raw materials are mixed in mechanical device and carries out extrusion forming;
Step 3: primary drying is carried out to the material of extrusion forming;
Step 4: redrying is carried out to the material after primary drying;
Step 5: by the crushing material after drying at powdered, cement retarder is obtained.
Further improvement lies in that: the manganese gypsum content is within the 10% of the total weight of titanium gypsum and ardealite.
Further improvement lies in that: when preparing cement retarder, when ardealite is excessively high containing sour component, stone is added into material Ash is acid in material to reduce.
The beneficial effects of the present invention are: carrying out the system of cement retarder by using the by-product gypsum generated in industrial production Standby, consumption by-product gypsum carries out product manufacturing, and then solves the problems, such as that disorderly row leaves about chemical company's industrial residue, avoids pollution ring The industrial waste recycling and reusing of chemical enterprise emission is solved the problems, such as that enterprise faces by border, while obtaining certain economy Value.
Specific embodiment
In order to deepen the understanding of the present invention, the present invention will be described in further detail with reference to the examples below, the embodiment For explaining only the invention, it is not intended to limit the scope of the present invention..
Embodiment one
The present embodiment provides a kind of method for preparing cement retarder with industry by-product gypsum, the original for preparing cement retarder Material includes following constituent: titanium gypsum 42%, ardealite 30%, sulphur gypsum 22%, manganese gypsum 6%.
The preparation step for preparing the method for cement retarder with industry by-product gypsum is as follows:
Step 1: titanium gypsum, ardealite, sulphur gypsum and manganese gypsum are taken out in proportion spare;
Step 2: it is put into after above-mentioned raw materials are mixed in mechanical device and carries out extrusion forming;
Step 3: primary drying is carried out to the material of extrusion forming;
Step 4: redrying is carried out to the material after primary drying;
Step 5: by the crushing material after drying at powdered, cement retarder is obtained.
The manganese gypsum content is within the 10% of the total weight of titanium gypsum and ardealite.When preparing cement retarder, work as phosphorus When gypsum is excessively high containing sour component, it is acid in material to reduce that lime is added into material.
Embodiment two
The present embodiment provides a kind of method for preparing cement retarder with industry by-product gypsum, the original for preparing cement retarder Material includes following constituent: titanium gypsum 50%, ardealite 20%, sulphur gypsum 25%, manganese gypsum 5%.
The preparation step for preparing the method for cement retarder with industry by-product gypsum is as follows:
Step 1: titanium gypsum, ardealite, sulphur gypsum and manganese gypsum are taken out in proportion spare;
Step 2: it is put into after above-mentioned raw materials are mixed in mechanical device and carries out extrusion forming;
Step 3: primary drying is carried out to the material of extrusion forming;
Step 4: redrying is carried out to the material after primary drying;
Step 5: by the crushing material after drying at powdered, cement retarder is obtained.
The manganese gypsum content is within the 10% of the total weight of titanium gypsum and ardealite.When preparing cement retarder, work as phosphorus When gypsum is excessively high containing sour component, it is acid in material to reduce that lime is added into material.
Embodiment three
The present embodiment provides a kind of method for preparing cement retarder with industry by-product gypsum, the original for preparing cement retarder Material includes following constituent: titanium gypsum 33%, ardealite 40%, sulphur gypsum 30%, manganese gypsum 7%.
The preparation step for preparing the method for cement retarder with industry by-product gypsum is as follows:
Step 1: titanium gypsum, ardealite, sulphur gypsum and manganese gypsum are taken out in proportion spare;
Step 2: it is put into after above-mentioned raw materials are mixed in mechanical device and carries out extrusion forming;
Step 3: primary drying is carried out to the material of extrusion forming;
Step 4: redrying is carried out to the material after primary drying;
Step 5: by the crushing material after drying at powdered, cement retarder is obtained.
The manganese gypsum content is within the 10% of the total weight of titanium gypsum and ardealite.When preparing cement retarder, work as phosphorus When gypsum is excessively high containing sour component, it is acid in material to reduce that lime is added into material.

Claims (4)

1. a kind of method for preparing cement retarder with industry by-product gypsum, it is characterised in that: the cement retarder for preparing Raw material includes following constituent: titanium gypsum 20 ~ 50%, ardealite 10 ~ 40%, sulphur gypsum 10 ~ 30%, manganese gypsum 5 ~ 10%.
2. a kind of method for preparing cement retarder with industry by-product gypsum as described in claim 1, it is characterised in that: described Preparation step is as follows:
Step 1: titanium gypsum, ardealite, sulphur gypsum and manganese gypsum are taken out in proportion spare;
Step 2: it is put into after above-mentioned raw materials are mixed in mechanical device and carries out extrusion forming;
Step 3: primary drying is carried out to the material of extrusion forming;
Step 4: redrying is carried out to the material after primary drying;
Step 5: by the crushing material after drying at powdered, cement retarder is obtained.
3. a kind of method for preparing cement retarder with industry by-product gypsum as described in claim 1, it is characterised in that: described Manganese gypsum content is within the 10% of the total weight of titanium gypsum and ardealite.
4. a kind of method for preparing cement retarder with industry by-product gypsum as claimed in claim 2, it is characterised in that: preparation When cement retarder, when ardealite is excessively high containing sour component, it is acid in material to reduce that lime is added into material.
CN201810743549.8A 2018-07-09 2018-07-09 A method of cement retarder is prepared with industry by-product gypsum Pending CN108996937A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810743549.8A CN108996937A (en) 2018-07-09 2018-07-09 A method of cement retarder is prepared with industry by-product gypsum

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810743549.8A CN108996937A (en) 2018-07-09 2018-07-09 A method of cement retarder is prepared with industry by-product gypsum

Publications (1)

Publication Number Publication Date
CN108996937A true CN108996937A (en) 2018-12-14

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Country Status (1)

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CN (1) CN108996937A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111533470A (en) * 2020-04-24 2020-08-14 四川省星船城水泥股份有限公司 Method for producing characteristic retarded cement by using multisource industrial byproduct gypsum
CN111732361A (en) * 2020-04-24 2020-10-02 四川省星船城水泥股份有限公司 Production method for using multisource industrial by-product gypsum as cement retarder
CN112430000A (en) * 2020-11-11 2021-03-02 中国葛洲坝集团水泥有限公司 Modified titanium gypsum used as cement retarder and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104072003A (en) * 2014-07-15 2014-10-01 铜陵化学工业集团有限公司 Method for preparing cement retarder through titanium gypsum
CN105293967A (en) * 2015-01-13 2016-02-03 江苏国翔环保科技有限公司 Cement additive production device and manufacturing technique thereof
KR20160108764A (en) * 2015-03-06 2016-09-20 쌍용양회공업(주) The method of neutralization phospho-gypsum using Fluidized bed boiler Fly ash and use thereof

Patent Citations (3)

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Publication number Priority date Publication date Assignee Title
CN104072003A (en) * 2014-07-15 2014-10-01 铜陵化学工业集团有限公司 Method for preparing cement retarder through titanium gypsum
CN105293967A (en) * 2015-01-13 2016-02-03 江苏国翔环保科技有限公司 Cement additive production device and manufacturing technique thereof
KR20160108764A (en) * 2015-03-06 2016-09-20 쌍용양회공업(주) The method of neutralization phospho-gypsum using Fluidized bed boiler Fly ash and use thereof

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Title
徐风广等: "利用锰石膏作水泥缓凝剂的研究", 《新型建筑材料》 *
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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111533470A (en) * 2020-04-24 2020-08-14 四川省星船城水泥股份有限公司 Method for producing characteristic retarded cement by using multisource industrial byproduct gypsum
CN111732361A (en) * 2020-04-24 2020-10-02 四川省星船城水泥股份有限公司 Production method for using multisource industrial by-product gypsum as cement retarder
CN112430000A (en) * 2020-11-11 2021-03-02 中国葛洲坝集团水泥有限公司 Modified titanium gypsum used as cement retarder and preparation method thereof

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Application publication date: 20181214