CN108996937A - A method of cement retarder is prepared with industry by-product gypsum - Google Patents
A method of cement retarder is prepared with industry by-product gypsum Download PDFInfo
- Publication number
- CN108996937A CN108996937A CN201810743549.8A CN201810743549A CN108996937A CN 108996937 A CN108996937 A CN 108996937A CN 201810743549 A CN201810743549 A CN 201810743549A CN 108996937 A CN108996937 A CN 108996937A
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- CN
- China
- Prior art keywords
- gypsum
- cement retarder
- industry
- product
- ardealite
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B40/00—Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
- C04B40/0028—Aspects relating to the mixing step of the mortar preparation
- C04B40/0039—Premixtures of ingredients
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
- C04B2103/20—Retarders
- C04B2103/22—Set retarders
Abstract
The present invention provides a kind of method for preparing cement retarder with industry by-product gypsum, and the raw material for preparing cement retarder includes following constituent: titanium gypsum 20 ~ 50%, ardealite 10 ~ 40%, sulphur gypsum 10 ~ 30%, manganese gypsum 5 ~ 10%.The preparation of cement retarder is carried out by using the by-product gypsum generated in industrial production, it consumes by-product gypsum and carries out product manufacturing, and then solve the problems, such as that disorderly row leaves about chemical company's industrial residue, avoid pollution environment, by the industrial waste recycling and reusing of chemical enterprise emission, it solves the problems, such as that enterprise faces, while obtaining certain economic value.
Description
Technical field
The present invention relates to cement retarder preparation field more particularly to a kind of cement retarder is prepared with industry by-product gypsum
Method.
Background technique
The substance of the solid waste sulfur acid calcium discharged in the industrial production is referred to as industrial gypsum, industry by-product gypsum
Ardealite including titanium gypsum, manganese gypsum, citric acid gypsum, boron gypsum and bunt gypsum etc..Under the requirement of environmental protection, how
The industry by-product gypsum for effectively handling bulk deposition has become an extremely urgent problem in China or even world wide.
Current stacking processing method seriously restricts the development of enterprise, has both occupied a large amount of soil, polluted underground water and has left
Huge security risk, and the stacking expense for needing corporate payments high, are unfavorable for the sustainable development of enterprise.
Summary of the invention
In view of the above-mentioned problems of the prior art, preparing water with industry by-product gypsum the object of the present invention is to provide a kind of
The method of mud retarder carries out the preparation of cement retarder by using the by-product gypsum generated in industrial production, consumes by-product
Gypsum carries out product manufacturing, and then solves the problems, such as that disorderly row leaves about chemical company's industrial residue, avoids pollution environment.
The present invention provides a kind of method for preparing cement retarder with industry by-product gypsum, the cement retarder for preparing
Raw material includes following constituent: titanium gypsum 20 ~ 50%, ardealite 10 ~ 40%, sulphur gypsum 10 ~ 30%, manganese gypsum 5 ~ 10%.
Further improvement lies in that: the preparation step is as follows:
Step 1: titanium gypsum, ardealite, sulphur gypsum and manganese gypsum are taken out in proportion spare;
Step 2: it is put into after above-mentioned raw materials are mixed in mechanical device and carries out extrusion forming;
Step 3: primary drying is carried out to the material of extrusion forming;
Step 4: redrying is carried out to the material after primary drying;
Step 5: by the crushing material after drying at powdered, cement retarder is obtained.
Further improvement lies in that: the manganese gypsum content is within the 10% of the total weight of titanium gypsum and ardealite.
Further improvement lies in that: when preparing cement retarder, when ardealite is excessively high containing sour component, stone is added into material
Ash is acid in material to reduce.
The beneficial effects of the present invention are: carrying out the system of cement retarder by using the by-product gypsum generated in industrial production
Standby, consumption by-product gypsum carries out product manufacturing, and then solves the problems, such as that disorderly row leaves about chemical company's industrial residue, avoids pollution ring
The industrial waste recycling and reusing of chemical enterprise emission is solved the problems, such as that enterprise faces by border, while obtaining certain economy
Value.
Specific embodiment
In order to deepen the understanding of the present invention, the present invention will be described in further detail with reference to the examples below, the embodiment
For explaining only the invention, it is not intended to limit the scope of the present invention..
Embodiment one
The present embodiment provides a kind of method for preparing cement retarder with industry by-product gypsum, the original for preparing cement retarder
Material includes following constituent: titanium gypsum 42%, ardealite 30%, sulphur gypsum 22%, manganese gypsum 6%.
The preparation step for preparing the method for cement retarder with industry by-product gypsum is as follows:
Step 1: titanium gypsum, ardealite, sulphur gypsum and manganese gypsum are taken out in proportion spare;
Step 2: it is put into after above-mentioned raw materials are mixed in mechanical device and carries out extrusion forming;
Step 3: primary drying is carried out to the material of extrusion forming;
Step 4: redrying is carried out to the material after primary drying;
Step 5: by the crushing material after drying at powdered, cement retarder is obtained.
The manganese gypsum content is within the 10% of the total weight of titanium gypsum and ardealite.When preparing cement retarder, work as phosphorus
When gypsum is excessively high containing sour component, it is acid in material to reduce that lime is added into material.
Embodiment two
The present embodiment provides a kind of method for preparing cement retarder with industry by-product gypsum, the original for preparing cement retarder
Material includes following constituent: titanium gypsum 50%, ardealite 20%, sulphur gypsum 25%, manganese gypsum 5%.
The preparation step for preparing the method for cement retarder with industry by-product gypsum is as follows:
Step 1: titanium gypsum, ardealite, sulphur gypsum and manganese gypsum are taken out in proportion spare;
Step 2: it is put into after above-mentioned raw materials are mixed in mechanical device and carries out extrusion forming;
Step 3: primary drying is carried out to the material of extrusion forming;
Step 4: redrying is carried out to the material after primary drying;
Step 5: by the crushing material after drying at powdered, cement retarder is obtained.
The manganese gypsum content is within the 10% of the total weight of titanium gypsum and ardealite.When preparing cement retarder, work as phosphorus
When gypsum is excessively high containing sour component, it is acid in material to reduce that lime is added into material.
Embodiment three
The present embodiment provides a kind of method for preparing cement retarder with industry by-product gypsum, the original for preparing cement retarder
Material includes following constituent: titanium gypsum 33%, ardealite 40%, sulphur gypsum 30%, manganese gypsum 7%.
The preparation step for preparing the method for cement retarder with industry by-product gypsum is as follows:
Step 1: titanium gypsum, ardealite, sulphur gypsum and manganese gypsum are taken out in proportion spare;
Step 2: it is put into after above-mentioned raw materials are mixed in mechanical device and carries out extrusion forming;
Step 3: primary drying is carried out to the material of extrusion forming;
Step 4: redrying is carried out to the material after primary drying;
Step 5: by the crushing material after drying at powdered, cement retarder is obtained.
The manganese gypsum content is within the 10% of the total weight of titanium gypsum and ardealite.When preparing cement retarder, work as phosphorus
When gypsum is excessively high containing sour component, it is acid in material to reduce that lime is added into material.
Claims (4)
1. a kind of method for preparing cement retarder with industry by-product gypsum, it is characterised in that: the cement retarder for preparing
Raw material includes following constituent: titanium gypsum 20 ~ 50%, ardealite 10 ~ 40%, sulphur gypsum 10 ~ 30%, manganese gypsum 5 ~ 10%.
2. a kind of method for preparing cement retarder with industry by-product gypsum as described in claim 1, it is characterised in that: described
Preparation step is as follows:
Step 1: titanium gypsum, ardealite, sulphur gypsum and manganese gypsum are taken out in proportion spare;
Step 2: it is put into after above-mentioned raw materials are mixed in mechanical device and carries out extrusion forming;
Step 3: primary drying is carried out to the material of extrusion forming;
Step 4: redrying is carried out to the material after primary drying;
Step 5: by the crushing material after drying at powdered, cement retarder is obtained.
3. a kind of method for preparing cement retarder with industry by-product gypsum as described in claim 1, it is characterised in that: described
Manganese gypsum content is within the 10% of the total weight of titanium gypsum and ardealite.
4. a kind of method for preparing cement retarder with industry by-product gypsum as claimed in claim 2, it is characterised in that: preparation
When cement retarder, when ardealite is excessively high containing sour component, it is acid in material to reduce that lime is added into material.
Priority Applications (1)
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CN201810743549.8A CN108996937A (en) | 2018-07-09 | 2018-07-09 | A method of cement retarder is prepared with industry by-product gypsum |
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CN201810743549.8A CN108996937A (en) | 2018-07-09 | 2018-07-09 | A method of cement retarder is prepared with industry by-product gypsum |
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CN201810743549.8A Pending CN108996937A (en) | 2018-07-09 | 2018-07-09 | A method of cement retarder is prepared with industry by-product gypsum |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111533470A (en) * | 2020-04-24 | 2020-08-14 | 四川省星船城水泥股份有限公司 | Method for producing characteristic retarded cement by using multisource industrial byproduct gypsum |
CN111732361A (en) * | 2020-04-24 | 2020-10-02 | 四川省星船城水泥股份有限公司 | Production method for using multisource industrial by-product gypsum as cement retarder |
CN112430000A (en) * | 2020-11-11 | 2021-03-02 | 中国葛洲坝集团水泥有限公司 | Modified titanium gypsum used as cement retarder and preparation method thereof |
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CN104072003A (en) * | 2014-07-15 | 2014-10-01 | 铜陵化学工业集团有限公司 | Method for preparing cement retarder through titanium gypsum |
CN105293967A (en) * | 2015-01-13 | 2016-02-03 | 江苏国翔环保科技有限公司 | Cement additive production device and manufacturing technique thereof |
KR20160108764A (en) * | 2015-03-06 | 2016-09-20 | 쌍용양회공업(주) | The method of neutralization phospho-gypsum using Fluidized bed boiler Fly ash and use thereof |
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2018
- 2018-07-09 CN CN201810743549.8A patent/CN108996937A/en active Pending
Patent Citations (3)
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CN104072003A (en) * | 2014-07-15 | 2014-10-01 | 铜陵化学工业集团有限公司 | Method for preparing cement retarder through titanium gypsum |
CN105293967A (en) * | 2015-01-13 | 2016-02-03 | 江苏国翔环保科技有限公司 | Cement additive production device and manufacturing technique thereof |
KR20160108764A (en) * | 2015-03-06 | 2016-09-20 | 쌍용양회공업(주) | The method of neutralization phospho-gypsum using Fluidized bed boiler Fly ash and use thereof |
Non-Patent Citations (2)
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徐风广等: "利用锰石膏作水泥缓凝剂的研究", 《新型建筑材料》 * |
郭泰民: "《工业副产石膏应用技术》", 31 January 2010, 中国建材工业出版社 * |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111533470A (en) * | 2020-04-24 | 2020-08-14 | 四川省星船城水泥股份有限公司 | Method for producing characteristic retarded cement by using multisource industrial byproduct gypsum |
CN111732361A (en) * | 2020-04-24 | 2020-10-02 | 四川省星船城水泥股份有限公司 | Production method for using multisource industrial by-product gypsum as cement retarder |
CN112430000A (en) * | 2020-11-11 | 2021-03-02 | 中国葛洲坝集团水泥有限公司 | Modified titanium gypsum used as cement retarder and preparation method thereof |
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Application publication date: 20181214 |