CN108987764A - Flow-field plate and fuel cell including the flow-field plate - Google Patents

Flow-field plate and fuel cell including the flow-field plate Download PDF

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Publication number
CN108987764A
CN108987764A CN201810906856.3A CN201810906856A CN108987764A CN 108987764 A CN108987764 A CN 108987764A CN 201810906856 A CN201810906856 A CN 201810906856A CN 108987764 A CN108987764 A CN 108987764A
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Prior art keywords
flow
field plate
runner
spiral fin
plate according
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CN201810906856.3A
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CN108987764B (en
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尧磊
彭杰
张剑波
张扬军
诸葛伟林
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Tsinghua University
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Tsinghua University
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/02Details
    • H01M8/0202Collectors; Separators, e.g. bipolar separators; Interconnectors
    • H01M8/0258Collectors; Separators, e.g. bipolar separators; Interconnectors characterised by the configuration of channels, e.g. by the flow field of the reactant or coolant
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/02Details
    • H01M8/0202Collectors; Separators, e.g. bipolar separators; Interconnectors
    • H01M8/0247Collectors; Separators, e.g. bipolar separators; Interconnectors characterised by the form
    • H01M8/0254Collectors; Separators, e.g. bipolar separators; Interconnectors characterised by the form corrugated or undulated
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells

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  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Fuel Cell (AREA)

Abstract

The invention discloses flow-field plate and including the fuel cell of the flow-field plate.The flow-field plate includes: matrix, has multiple runners in described matrix;Multiple spiral fins, the multiple spiral fin are distributed in the runner along the length direction of the runner, and the both ends of the spiral fin are bent in the opposite direction respectively.The flow-field plate can be effectively improved flowing of the gas in runner by the way that spiral fin is arranged in runner, and the convection current for enhancing gas in runner transports effect.

Description

Flow-field plate and fuel cell including the flow-field plate
Technical field
The present invention relates to field of fuel cell technology, specifically, the present invention relates to flow-field plate and including the flow-field plate Fuel cell.
Background technique
Proton Exchange Membrane Fuel Cells (PEMFC) has many advantages, such as high efficiency, high-energy density and low pollution, thus by The extensive concern of many area research persons.Wherein energy density is to measure the important indicator of PEMFC performance, to further increase On the one hand the energy density of battery depends on the design of membrane electrode assembly (MEA), on the other hand then depends on reasonable flow-field plate Design.Flow field plate design mainly has following target: guaranteeing that reaction gas is evenly distributed in pipes' analysis, and is conducive to reaction gas Body is transported into gas diffusion layers, while promoting the discharge of cathode reaction generation water.
Flow field plate Geometries traditional at present mainly have parallel fluid channels, serpentine flow path or interdigitated runner, wherein gas Flowing in parallel and serpentine configuration runner is the one-dimensional or quasi one-dimensional flow along flow channel length direction, and the flow-field plate is in big electricity It will appear the phenomenon of local gas insufficient supply under current density, gas concentration polarization increases, and battery performance reduces;In interdigitated stream Flowing in road is two-dimensional flow, while gas is along flow passage, also has under the action of forced convertion and rushes at gas expansion The velocity component of layer is dissipated, which has the pressure loss big, easily occurs the disadvantages of film is dry under low current density.
Thus, the existing flow-field plate for fuel cell still has much room for improvement.
Summary of the invention
The present invention is directed to solve at least some of the technical problems in related technologies.For this purpose, of the invention One purpose is to propose flow-field plate and the fuel cell including the flow-field plate.The flow-field plate in runner by being arranged spiral ribs Piece can be effectively improved flowing of the gas in runner, and the convection current for enhancing gas in runner transports effect.
In one aspect of the invention, the present invention proposes a kind of flow-field plate.According to an embodiment of the invention, the flow field Plate includes: matrix, has multiple runners in described matrix;Multiple spiral fins, the multiple spiral fin is along the runner Length direction is distributed in the runner, and the both ends of the spiral fin are bent in the opposite direction respectively.As a result, when gas is logical When crossing the runner with spiral fin, under the action of spiral fin, gas is flowing while flowing along flow channel length direction Secondary flow will be also carried out in road cross section, make the flowing of gas in entire runner that there is three-dimensional character, to enhance runner The convection current of interior gas transports effect.Flow-field plate of the invention is applied to fuel cell, is on the one hand conducive to reaction gas from stream Road is transmitted into the gas diffusion layers of fuel cell, be on the other hand also beneficial to electrode reaction product from gas diffusion layers to The transmission of runner, this will increase the reacting gas concentration of electrode surface, improve the power generation performance of battery.
In addition, flow-field plate according to the above embodiment of the present invention can also have the following additional technical features:
In some embodiments of the invention, the length direction of the multiple spiral fin and the runner is at an angle Angle be 45 °~135 °.
In some embodiments of the invention, the section of the spiral fin in the longitudinal direction is triangle, rectangle, ladder Shape, parallelogram, semicircle or the quadrangle with fillet.
In some embodiments of the invention, equal spacing in length direction point of multiple spiral fins along the runner Cloth.
In some embodiments of the invention, the cross sectional shape of the runner in the longitudinal direction is semicircle.
In some embodiments of the invention, the ratio between depth of the height of the spiral fin and the runner for 0.2~ 0.4。
In some embodiments of the invention, the runner is parallel fluid channels, serpentine flow path or interdigitated runner.
In some embodiments of the invention, the matrix of the flow-field plate by stainless steel, titanium and titanium alloy at least it One forms.
In some embodiments of the invention, the matrix of the flow-field plate is formed by graphite.
In another aspect of this invention, the invention proposes a kind of fuel cells.According to an embodiment of the invention, the fuel Battery includes: cathode flow field plate and anode flow field board, and at least one of the cathode flow field plate and anode flow field board are above-mentioned The flow-field plate of embodiment.Fuel cell of the invention can make gas in the plate runner of flow field by using the flow-field plate of above-described embodiment The flowing of body has three-dimensional character, so that the convection current for increasing gas in runner transports effect, be on the one hand conducive to reaction gas from Runner is transmitted into the gas diffusion layers of fuel cell, is on the other hand also beneficial to electrode reaction product from gas diffusion layers Transmission to runner, to increase the reacting gas concentration of electrode surface.Fuel cell power generation performance of the invention is more as a result, It is high.
Additional aspect and advantage of the invention will be set forth in part in the description, and will partially become from the following description Obviously, or practice through the invention is recognized.
Detailed description of the invention
Above-mentioned and/or additional aspect of the invention and advantage will become from the description of the embodiment in conjunction with the following figures Obviously and it is readily appreciated that, in which:
Fig. 1 shows the structural schematic diagram of flow-field plate according to an embodiment of the present invention;
Fig. 2 shows the front view of flow-field plate according to an embodiment of the present invention;
Fig. 3 shows the side view of flow-field plate according to an embodiment of the present invention;
Fig. 4 shows the top view of flow-field plate according to an embodiment of the present invention;
Fig. 5 shows the structural schematic diagram of spiral fin according to an embodiment of the present invention;
Fig. 6 shows the structural schematic diagram of fuel cell in embodiment 1;
Fig. 7 shows X in 1 runner of embodiment, change of the tri- direction velocity components of Y, Z along flow channel length direction (Z-direction) Change;
Fig. 8 shows embodiment 1 and comparative example along the oxygen (O of flow channel length direction (Z-direction)2) molar concentration distribution;
Fig. 9 shows embodiment 1 and comparative example along the oxygen (O of runner vertical direction (Y-direction)2) molar concentration distribution.
Specific embodiment
The embodiment of the present invention is described below in detail, examples of the embodiments are shown in the accompanying drawings, wherein from beginning to end Same or similar label indicates same or similar element or element with the same or similar functions.Below with reference to attached The embodiment of figure description is exemplary, it is intended to is used to explain the present invention, and is not considered as limiting the invention.
In the description of the present invention, it is to be understood that, term " length ", " width ", " thickness ", "upper", "lower" etc. refer to The orientation or positional relationship shown is to be based on the orientation or positional relationship shown in the drawings, and is merely for convenience of the description present invention and simplifies Description, rather than the device or element of indication or suggestion meaning must have a particular orientation, constructed and grasped with specific orientation Make, therefore is not considered as limiting the invention.
In the description of the present invention, the meaning of " plurality " is at least two, such as two, three etc., unless otherwise clear It is specific to limit.
In the present invention unless specifically defined or limited otherwise, fisrt feature in the second feature " on " or " down " can be with It is that the first and second features directly contact or the first and second features pass through intermediary mediate contact.Moreover, fisrt feature exists Second feature " on ", " top " and " above " but fisrt feature be directly above or diagonally above the second feature, or be merely representative of First feature horizontal height is higher than second feature.Fisrt feature can be under the second feature " below ", " below " and " below " One feature is directly under or diagonally below the second feature, or is merely representative of first feature horizontal height less than second feature.
In one aspect of the invention, the present invention proposes a kind of flow-field plate.According to an embodiment of the invention, with reference to figure 1~4, which includes: matrix 100 and multiple spiral fins 200.Wherein, there are multiple runners 110 on matrix 100, it is multiple Spiral fin 200 is distributed in runner 110 along the length direction of runner 110, and the both ends of spiral fin 200 are respectively to opposite side To bending.As a result, when gas is by runner with spiral fin, under the action of spiral fin, gas is long along runner While spending direction flowing, secondary flow will be also carried out in flow channel cross-section, and the flowing of gas in entire runner is made to have three Characteristic is tieed up, so that the convection current for enhancing gas in runner transports effect.Flow-field plate of the invention is applied to fuel cell, a side Face is conducive to reaction gas and is transmitted from runner into the gas diffusion layers of fuel cell, and it is anti-to be on the other hand also beneficial to electrode Transmission of the product from gas diffusion layers to runner is answered, this will increase the reacting gas concentration of electrode surface, improve the power generation of battery Performance.
According to an embodiment of the invention, as shown in figure 4, the angle of the length direction of multiple spiral fins 200 and runner 110 α is 45 °~135 °.Gas can be further conducive to as a result, while along the flowing of 110 length direction of runner, it is horizontal in runner 110 Spiral secondary flow occurs in section, so that the convection current for increasing gas in runner 110 transports effect.
According to an embodiment of the invention, as shown in figure 5, the section of spiral fin 200 in the longitudinal direction can be triangle Shape, rectangle, trapezoidal, parallelogram, semicircle or the quadrangle with fillet.Specifically, A is to cut with triangle in Fig. 5 The structural schematic diagram of the spiral fin in face;B is the structural schematic diagram of the spiral fin with rectangular section;C is with trapezoidal section The structural schematic diagram of the spiral fin in face;D is the structural schematic diagram of the spiral fin with parallelogram section;E be with The structural schematic diagram of the spiral fin of semi-circular cross-section;F is the structure of the spiral fin with the quadrangular section with fillet Schematic diagram.In addition, it is necessary to explanation, in Fig. 1~4, the section of spiral fin 200 in the longitudinal direction is triangle.
According to an embodiment of the invention, distribution spacing of multiple spiral fins 200 in runner 110 is not limited especially System, multiple spiral fins 200 can be distributed along the equal spacing in length direction of runner 110 or unequal spacing distribution.In some implementations In example, multiple spiral fins 200 are distributed along the equal spacing in length direction of runner 110, and the spacing of two neighboring spiral fin 200 can To be adjusted in proportion according to the length of runner 110.
According to an embodiment of the invention, the height of spiral fin 200 can be set in proportion according to the depth of runner 110 Meter.According to a particular embodiment of the invention, as shown in Fig. 2, the ratio between the height h of spiral fin 200 and the depth d of runner 110 are 0.2~0.4.Gas can be further conducive to as a result, while along the flowing of 110 length direction of runner, in 110 cross section of runner Interior generation spiral secondary flow, so that the convection current for increasing gas in runner 110 transports effect.When the ratio of h and d it is too small (< 0.2), to transport effect unobvious for the convection current of gas in runner;When the ratio of h and d is too big (> 0.4), under high current density operating condition Spiral fin can hinder to generate the discharge of water.
According to an embodiment of the invention, the cross sectional shape of runner 110 in the longitudinal direction can be semicircle, work as runner When 100 section in the longitudinal direction is semicircle, the depth d of runner 100 is the radius of the section semicircle of runner 100.
According to an embodiment of the invention, above-mentioned runner 110 can be parallel fluid channels, serpentine flow path or interdigitated runner.? I other words can be effectively improved gas by forming spiral fin 200 in parallel fluid channels, serpentine flow path or interdigitated runner and flow Flowing in road, the convection current for enhancing gas in runner transport effect, to improve the power generation with the fuel cell of the flow-field plate Performance.
According to an embodiment of the invention, the material for being used to form flow-field plate matrix 100 is not particularly restricted, this field skill Art personnel can select according to actual needs.In some embodiments, the matrix 100 of flow-field plate can be by stainless steel, titanium It is formed at least one of titanium alloy.Spiral fin 200 can carry out punch forming by the matrix 100 of convection current field plate as a result, Technique is formed in runner 110.In other implementations, the matrix 100 of flow-field plate can be formed by graphite.Spiral ribs as a result, Piece 200 can carry out mechanical processing technique by the matrix 100 of convection current field plate and be formed in runner 110.
In another aspect of this invention, the invention proposes a kind of fuel cells.According to an embodiment of the invention, the fuel Battery includes: cathode flow field plate and anode flow field board, and at least one of the cathode flow field plate and anode flow field board are above-mentioned The flow-field plate of embodiment.Fuel cell of the invention can make gas in the plate runner of flow field by using the flow-field plate of above-described embodiment The flowing of body has three-dimensional character, so that the convection current for increasing gas in runner transports effect, be on the one hand conducive to reaction gas from Runner is transmitted into the gas diffusion layers of fuel cell, is on the other hand also beneficial to electrode reaction product from gas diffusion layers Transmission to runner, to increase the reacting gas concentration of electrode surface.Fuel cell power generation performance of the invention is more as a result, It is high.
It should be noted that it is equally applicable to above-mentioned fuel cell described previously for feature and advantage described in flow-field plate, This is no longer going to repeat them.
Below with reference to specific embodiment, present invention is described, it should be noted that these embodiments are only to describe Property, without limiting the invention in any way.
Embodiment 1
Proton Exchange Membrane Fuel Cells is prepared using flow-field plate of the invention, single channel structure (is schemed as shown in Figure 6 In 6,1- cathode flow channels, the section 2- is the spiral fin of triangle, 3- cathode gas diffusion layer, 4- cathode catalysis layer, 5- proton Exchange membrane, 6- anode catalyst layer, 7- anode gas diffusion layer, 8- anode flow channel), in the present embodiment, cathode flow field plate material Spiral fin is formed in cathode flow channels, cross section of fluid channel is semicircle by carrying out punch forming to cathode flow field plate for stainless steel Shape, radius 0.75mm, flow-field plate with a thickness of 0.1mm, length 100mm.
In cathode flow channels along flow channel length direction Z equidistantly distributed have section be isosceles triangle (30 degree of apex angle, height Spiral fin 2 0.25mm), spiral fin sum are 40, are divided into 2.5mm, and first is 1.5mm apart from flow channel entry point, Last piece is 1mm apart from runner exit.
Cathode flow field plate is contacted with a thickness of the cathode gas diffusion layer 3 (carbon paper) of 200mm, in cathode gas diffusion layer 3 The upper cathode catalysis layer 4 being coated with a thickness of 10mm, proton exchange membrane 5 with a thickness of 30 μm.
Comparative example 1
Proton Exchange Membrane Fuel Cells is prepared according to method substantially the same manner as Example 1, difference is, cathode stream Do not have spiral fin in road.
Comparative example 2
Proton Exchange Membrane Fuel Cells is prepared according to method substantially the same manner as Example 1, difference is, cathode stream Spiral fin in road is vertical with the length direction Z of cathode flow channels (angle α being equivalent in Fig. 2 is 90 degree).
It is calculated to simplify, only considers single channel as shown in FIG. 6 in Proton Exchange Membrane Fuel Cells, by calculating fluid The course of work of fuel cell in mechanical simulation embodiment 1 and comparative example 1 and 2, current density (I) are 1A/cm2, stoichiometry Number is 2.5, and cathode inlet air quality flow is 1.66 × 10-6kg/s.O in cathode catalysis layer 42Consumption beThe production quantity of vapor isδ in formulaCLFor the thickness of cathode catalysis layer, F is Faraday constant,For the molal weight of oxygen,For the molal weight of water.
X in embodiment 1, Y, tri- direction velocity components of Z along flow channel length direction Z variation tendency as shown in fig. 7, in addition to Outside the velocity component of flow channel length direction Z, while X and Y-direction have apparent velocity component.In gas diffusion layers and catalysis O at layer interface2Molar concentration is with the variation of flow channel length direction Z as shown in figure 8, O in embodiment 12Molar concentration is intended to Greater than comparative example 1 and 2.Fig. 9 further illustrates O2Distribution of the molar concentration along runner vertical direction Y, 1 runner bottom of embodiment O2Concentration be less than comparative example 1 and 2, O in part, cathode gas diffusion layer 3 and cathode catalysis layer 4 on 1 runner of embodiment2Mole Concentration will be greater than comparative example 1 and 2.
By result above as can be seen that flowing of the gas in the runner with spiral fin is Three-dimensional Flow, runner The convection current of interior gas transports effect enhancing, is on the one hand conducive to reaction gas and is transmitted from runner into gas diffusion layers, separately On the one hand it is also beneficial to transmission of the reaction product from gas diffusion layers into runner.This is dense by the reaction gas for increasing electrode surface Degree, improves the power generation performance of battery.
In the description of this specification, reference term " one embodiment ", " some embodiments ", " example ", " specifically show The description of example " or " some examples " etc. means specific features, structure, material or spy described in conjunction with this embodiment or example Point is included at least one embodiment or example of the invention.In the present specification, schematic expression of the above terms are not It must be directed to identical embodiment or example.Moreover, particular features, structures, materials, or characteristics described can be in office It can be combined in any suitable manner in one or more embodiment or examples.In addition, without conflicting with each other, the skill of this field Art personnel can tie the feature of different embodiments or examples described in this specification and different embodiments or examples It closes and combines.
Although the embodiments of the present invention has been shown and described above, it is to be understood that above-described embodiment is example Property, it is not considered as limiting the invention, those skilled in the art within the scope of the invention can be to above-mentioned Embodiment is changed, modifies, replacement and variant.

Claims (10)

1. a kind of flow-field plate characterized by comprising
Matrix has multiple runners in described matrix;
Multiple spiral fins, the multiple spiral fin are distributed in the runner along the length direction of the runner, the spiral shell The both ends of rotation fin are bent in the opposite direction respectively.
2. flow-field plate according to claim 1, which is characterized in that the length side of the multiple spiral fin and the runner To angle be 45 °~135 °.
3. flow-field plate according to claim 1, which is characterized in that the section of the spiral fin in the longitudinal direction is three Angular, rectangle, trapezoidal, parallelogram, semicircle or the quadrangle with fillet.
4. described in any item flow-field plates according to claim 1~3, which is characterized in that multiple spiral fins are along the stream The equal spacing in length direction in road is distributed.
5. flow-field plate according to claim 1, which is characterized in that the cross sectional shape of the runner in the longitudinal direction is half It is round.
6. flow-field plate according to claim 5, which is characterized in that the depth of the height of the spiral fin and the runner The ratio between be 0.2~0.4.
7. flow-field plate according to claim 5, which is characterized in that the runner is parallel fluid channels, serpentine flow path or interdigital Type runner.
8. flow-field plate according to claim 1, which is characterized in that the matrix of the flow-field plate is closed by stainless steel, titanium and titanium The formation of at least one of gold.
9. flow-field plate according to claim 1, which is characterized in that the matrix of the flow-field plate is formed by graphite.
10. a kind of fuel cell characterized by comprising cathode flow field plate and anode flow field board, the cathode flow field plate and sun At least one of pole flow-field plate is flow-field plate according to any one of claims 1 to 9.
CN201810906856.3A 2018-08-10 2018-08-10 Flow field plate and fuel cell including the same Active CN108987764B (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112331878A (en) * 2020-11-06 2021-02-05 青岛科技大学 Proton exchange membrane fuel cell
CN111370728B (en) * 2020-03-18 2021-03-09 清华大学 Fuel cell polar plate flow field and fuel cell polar plate
CN113764681A (en) * 2021-08-25 2021-12-07 厦门大学 Self-adaptive flow field regulation and control type fuel cell polar plate structure

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Publication number Priority date Publication date Assignee Title
CN1921206A (en) * 2005-08-26 2007-02-28 比亚迪股份有限公司 Flow field plate for fuel battery
CN201796995U (en) * 2010-03-30 2011-04-13 上海恒劲动力科技有限公司 Plate for fuel cell and fuel cell thereof
CN103413956A (en) * 2013-08-14 2013-11-27 天津大学 Proton exchange membrane fuel cell channel
US20140051005A1 (en) * 2007-06-04 2014-02-20 GM Global Technology Operations LLC Fuel cell stack with improved end cell performance through a diffusion media having lower compressibility

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1921206A (en) * 2005-08-26 2007-02-28 比亚迪股份有限公司 Flow field plate for fuel battery
US20140051005A1 (en) * 2007-06-04 2014-02-20 GM Global Technology Operations LLC Fuel cell stack with improved end cell performance through a diffusion media having lower compressibility
CN201796995U (en) * 2010-03-30 2011-04-13 上海恒劲动力科技有限公司 Plate for fuel cell and fuel cell thereof
CN103413956A (en) * 2013-08-14 2013-11-27 天津大学 Proton exchange membrane fuel cell channel

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111370728B (en) * 2020-03-18 2021-03-09 清华大学 Fuel cell polar plate flow field and fuel cell polar plate
CN112331878A (en) * 2020-11-06 2021-02-05 青岛科技大学 Proton exchange membrane fuel cell
CN112331878B (en) * 2020-11-06 2022-08-26 青岛科技大学 Proton exchange membrane fuel cell
CN113764681A (en) * 2021-08-25 2021-12-07 厦门大学 Self-adaptive flow field regulation and control type fuel cell polar plate structure

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