CN108977136A - A kind of carpet lawn glue and preparation method thereof - Google Patents
A kind of carpet lawn glue and preparation method thereof Download PDFInfo
- Publication number
- CN108977136A CN108977136A CN201810859413.3A CN201810859413A CN108977136A CN 108977136 A CN108977136 A CN 108977136A CN 201810859413 A CN201810859413 A CN 201810859413A CN 108977136 A CN108977136 A CN 108977136A
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- solvent
- reaction kettle
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J145/00—Adhesives based on homopolymers or copolymers of compounds having no unsaturated aliphatic radicals in a side chain, and having one or more carbon-to-carbon double bonds in a carbocyclic or in a heterocyclic system; Adhesives based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a kind of carpet lawn glue, 4-12% natural rubbers；The poly- a methylstyrene resin of 6-10%；10-15% terpene resin；4-5% high styrene rubber；3-6% aldehyde ketone resin；1-2% White Carbon black；0.15-0.3% antioxidant；50-60% solvent, the present invention have many advantages, such as that cost of material is low, adhesive strength is high, are bonded wilful good, fast drying, environmental protection, ample supply and prompt delivery.
Description
Technical field
The present invention relates to bonding glue fields, more specifically, being a kind of carpet lawn glue and preparation method thereof.
Background technique
Existing lawn carpet glue uses, and is all bonded using traditional neoprene, high production cost, environmentally friendly degree is low, glue
Water solid content is low, and adhesive strength is poor, and especially when neoprene source of goods shortage, the source of goods is nervous, causes raw raising, is unfavorable for enterprise
Production development because production neoprene enterprise, forbids project, high pollution, high-risk enterprise for country.
Summary of the invention
In order to make up the above deficiency, the present invention provides a kind of carpet lawn glue and preparation method thereof.
The scheme of the invention is:
A kind of carpet lawn glue is made of the raw material for including following parts by weight:
The solvent is No. 120 solvent naphthas, ethyl acetate and dimethylbenzene as a preferred technical solution,.
The solvent is made from the following raw materials in parts by weight as a preferred technical solution:
No. 120 solvent naphtha 25-35%；
Ethyl acetate 28-46%；
Dimethylbenzene 4-10%.
As a preferred technical solution, by including that the raw material of following parts by weight is made:
No. 120 solvent naphthas 30%；
Ethyl acetate 30%；
Dimethylbenzene 6%.
As a preferred technical solution,
It as a preferred technical solution, further include antioxygen glue.
The present invention also provides a kind of methods for preparing carpet lawn glue, comprising steps of
1) refining glue；The natural rubber of 4-12% parts by weight is first cut into fritter, then refines eight times, is cut on rubber mixing machine
Small pieces are stand-by；
2) it mixes；The solvent of 50-60% parts by weight is taken to pour into reaction kettle, the natural rubber for then taking step 1) to refine is thrown
Enter in reaction kettle, then into reaction kettle put into 4-5% parts by weight high styrene rubber, stirring and dissolving 18-24 hours, instead
It answers kettle to be warmed to 64-107 DEG C, after waiting the rubber in reaction kettles to be completely dissolved, then puts into the poly- a methylbenzene second of 6-10% parts by weight
The terpene resin of olefine resin, the aldehyde ketone resin of 3-6% parts by weight and 10-15% parts by weight；Stirring 4-6 hours waits it completely mixed
After molten, in the antioxidant for the white carbon black and 0.15-0.3% parts by weight for putting into 1-2% parts by weight into reaction kettle, continue to stir
One hour；
3) it filters, solution made of step 2) is filtered, finished product is obtained.
Poly- a methylstyrene resin, the 3- of 6-10% parts by weight are put into the step 2) as a preferred technical solution,
After the aldehyde ketone resin of 6% parts by weight and the terpene resin of 10-15% parts by weight, then put into the antioxygen glue of 2-3% parts by weight.
The preparation method of the solvent as a preferred technical solution: by No. 120 solvent naphthas of 25-35% parts by weight,
The ethyl acetate of 28-46% parts by weight enters in mixer to be mixed with the dimethylbenzene of 4-10% parts by weight, obtains solvent.
By adopting the above-described technical solution, a kind of carpet lawn glue, 1) refining glue；First the natural rubber of 4-10% parts by weight
Glue is cut into fritter, then refines eight times on rubber mixing machine, cuts into pieces stand-by；2) it mixes；The solvent of 50-60% parts by weight is taken to fall
Enter in reaction kettle, in the natural rubber investment reaction kettle for then taking step 1) to refine, then puts into 4-5% weight into reaction kettle
The high styrene rubber of part is measured, stirring and dissolving 18-24 hours, reaction kettle was warmed to 64-107 DEG C, waited the rubber in reaction kettles complete
After fully dissolved, then put into the aldehyde ketone resin and 10-15% of the poly- a methylstyrene resin of 6-10% parts by weight, 3-6% parts by weight
The terpene resin of parts by weight；Stirring 4-6 hours, after waiting its complete miscibility, in the hard charcoal for putting into 1-2% parts by weight into reaction kettle
The black antioxidant with 0.15-0.3% parts by weight, continues stirring one hour；3) it filters, solution made of step 2) was carried out
Filter, obtains finished product.
Invention advantage: the present invention is with cost of material is low, adhesive strength is high, is bonded wilful good, fast drying, environmental protection, the source of goods
The advantages that sufficient, the present invention not only increases tack and adhesive strength and toughness also enhances hardness and cohesive force, mentions simultaneously
The high functions such as viscosity, high temperature resistant, water-fast, resistance to acid and alkali, the combination of each raw material can be played the role of learning from other's strong points to offset one's weaknesses, can be proper
The balance of three power is played to benefit, initial bonding strength, cohesive force, peeling force, adhesive strength of the present invention is high, being capable of fast rapid-curing cutback after bonding
Change, the hardness after enhancing bonding, can be used in the viscous of the zone materials such as carpet, imitative lawn, timber, paper, flexible plastic and metal
Use is connected, is worked well.
Specific embodiment
In order to make up the above deficiency, the present invention provides a kind of carpet lawn glue and preparation method thereof, to solve above-mentioned back
The problems in scape technology.
A kind of carpet lawn glue is made of the raw material for including following parts by weight:
The solvent is No. 120 solvent naphthas, ethyl acetate and dimethylbenzene as a preferred technical solution,.
The solvent is made from the following raw materials in parts by weight as a preferred technical solution:
No. 120 solvent naphtha 25-35%；
Ethyl acetate 28-46%；
Dimethylbenzene 4-10%.
As a preferred technical solution, by including that the raw material of following parts by weight is made:
No. 120 solvent naphthas 30%；
Ethyl acetate 30%；
Dimethylbenzene 6%.
As a preferred technical solution,
It as a preferred technical solution, further include antioxygen glue.
The present invention also provides a kind of methods for preparing carpet lawn glue, comprising steps of
1) refining glue；The natural rubber of 4-12% parts by weight is first cut into fritter, then refines eight times, is cut on rubber mixing machine
Small pieces are stand-by；
2) it mixes；The solvent of 50-60% parts by weight is taken to pour into reaction kettle, the natural rubber for then taking step 1) to refine is thrown
Enter in reaction kettle, then into reaction kettle put into 4-5% parts by weight high styrene rubber, stirring and dissolving 18-24 hours, instead
It answers kettle to be warmed to 64-107 DEG C, after waiting the rubber in reaction kettles to be completely dissolved, then puts into the poly- a methylbenzene second of 6-10% parts by weight
The terpene resin of olefine resin, the aldehyde ketone resin of 3-6% parts by weight and 10-15% parts by weight；Stirring 4-6 hours waits it completely mixed
After molten, in the antioxidant for the white carbon black and 0.15-0.3% parts by weight for putting into 1-2% parts by weight into reaction kettle, continue to stir
One hour；
3) it filters, solution made of step 2) is filtered, finished product is obtained.
Poly- a methylstyrene resin, the 3- of 6-10% parts by weight are put into the step 2) as a preferred technical solution,
After the aldehyde ketone resin of 6% parts by weight and the terpene resin of 10-15% parts by weight, then put into the antioxygen glue of 2-3% parts by weight.
The preparation method of the solvent as a preferred technical solution: by No. 120 solvent naphthas of 25-35% parts by weight,
The ethyl acetate of 28-46% parts by weight enters in mixer to be mixed with the dimethylbenzene of 4-10% parts by weight, obtains solvent.
In order to be easy to understand the technical means, the creative features, the aims and the efficiencies achieved by the present invention, tie below
Specific embodiment is closed, the present invention is further explained.
Embodiment one:
1) refining glue；The natural rubber of 4% parts by weight is first cut into fritter, then refines eight times, is cut into small on rubber mixing machine
Piece is stand-by；
2) it mixes；The solvent of 50% parts by weight is taken to pour into reaction kettle, the natural rubber investment for then taking step 1) to refine
In reaction kettle, then in the high styrene rubber for putting into 4% parts by weight into reaction kettle, stirring and dissolving 18 hours, reaction kettle added
Temperature is to 65 DEG C, after waiting the rubber in reaction kettles to be completely dissolved, then puts into poly- a methylstyrene resin, 3% weight of 6% parts by weight
Measure the aldehyde ketone resin of part and the terpene resin of 10% parts by weight；Stirring 4 hours, after waiting its complete miscibility, is throwing into reaction kettle
Enter the white carbon black of 1% parts by weight and the antioxidant of 0.15% parts by weight, continues stirring one hour；
3) it filters, solution made of step 2) is filtered, finished product is obtained.
Poly- a methylstyrene resin, 3% weight of 6% parts by weight are put into the step 2) as a preferred technical solution,
After measuring the aldehyde ketone resin of part and the terpene resin of 10% parts by weight, then put into the antioxygen glue of 2% parts by weight.
The preparation method of the solvent as a preferred technical solution: by No. 120 solvent naphthas, 28% of 25% parts by weight
The ethyl acetate of parts by weight enters in mixer to be mixed with the dimethylbenzene of 4% parts by weight, obtains solvent.
Embodiment two:
1) refining glue；The natural rubber of 12% parts by weight is first cut into fritter, then refines eight times, is cut into small on rubber mixing machine
Piece is stand-by；
2) it mixes；The solvent of 60% parts by weight is taken to pour into reaction kettle, the natural rubber investment for then taking step 1) to refine
In reaction kettle, then in the high styrene rubber for putting into 5% parts by weight into reaction kettle, stirring and dissolving 24 hours, reaction kettle added
Temperature is to 77 DEG C, after waiting the rubber in reaction kettles to be completely dissolved, then puts into poly- a methylstyrene resin, 6% weight of 10% parts by weight
Measure the aldehyde ketone resin of part and the terpene resin of 15% parts by weight；Stirring 6 hours, after waiting its complete miscibility, is throwing into reaction kettle
Enter the white carbon black of 2% parts by weight and the antioxidant of 0.3% parts by weight, continues stirring one hour；
3) it filters, solution made of step 2) is filtered, finished product is obtained.
The poly- a methylstyrene resin of 10% parts by weight of investment, 6% in the step 2) as a preferred technical solution,
After the terpene resin of the aldehyde ketone resin of parts by weight and 15% parts by weight, then put into the antioxygen glue of 3% parts by weight.
The preparation method of the solvent as a preferred technical solution: by No. 120 solvent naphthas, 46% of 35% parts by weight
The ethyl acetate of parts by weight enters in mixer to be mixed with the dimethylbenzene of 10% parts by weight, obtains solvent.
Embodiment three:
1) refining glue；The natural rubber of 6% parts by weight is first cut into fritter, then refines eight times, is cut into small on rubber mixing machine
Piece is stand-by；
2) it mixes；The solvent of 55% parts by weight is taken to pour into reaction kettle, the natural rubber investment for then taking step 1) to refine
In reaction kettle, then in the high styrene rubber for putting into 4.5% parts by weight into reaction kettle, stirring and dissolving 20 hours, reaction kettle
70 DEG C are warmed to, after waiting the rubber in reaction kettles to be completely dissolved, then puts into the poly- a methylstyrene resin of 6% parts by weight, 5%
The terpene resin of the aldehyde ketone resin of parts by weight and 12% parts by weight；Stirring 5 hours, after waiting its complete miscibility, into reaction kettle
The white carbon black of 1.5% parts by weight and the antioxidant of 0.2% parts by weight are put into, stirring one hour is continued；
3) it filters, solution made of step 2) is filtered, finished product is obtained.
Poly- a methylstyrene resin, 5% weight of 6% parts by weight are put into the step 2) as a preferred technical solution,
After measuring the aldehyde ketone resin of part and the terpene resin of 12% parts by weight, then put into the antioxygen glue of 2.5% parts by weight.
The preparation method of the solvent as a preferred technical solution: by No. 120 solvent naphthas, 30% of 30% parts by weight
The ethyl acetate of parts by weight enters in mixer to be mixed with the dimethylbenzene of 6% parts by weight, obtains solvent.
The above shows and describes the basic principle, main features and advantages of the invention.The technology of the industry
Personnel are it should be appreciated that the present invention is not limited to the above embodiments, and the above embodiments and description only describe this
The principle of invention, without departing from the spirit and scope of the present invention, various changes and improvements may be made to the invention, these changes
Change and improvement all fall within the protetion scope of the claimed invention.The claimed scope of the invention by appended claims and its
Equivalent circle.
Claims (9)
1. a kind of carpet lawn glue, which is characterized in that be made of the raw material for including following parts by weight:
2. a kind of carpet lawn as described in claim 1 glue, it is characterised in that: the solvent is No. 120 solvent naphthas, acetic acid second
Ester and dimethylbenzene.
3. a kind of carpet lawn glue as claimed in claim 2, which is characterized in that the solvent by following parts by weight raw material system
At:
No. 120 solvent naphtha 25-35%；
Ethyl acetate 28-46%；
Dimethylbenzene 4-10%.
4. a kind of carpet lawn glue as claimed in claim 3, which is characterized in that the solvent by following parts by weight raw material system
At:
No. 120 solvent naphthas 30%；
Ethyl acetate 30%；
Dimethylbenzene 6%.
5. a kind of carpet lawn as described in claim 1 glue, which is characterized in that be made of the raw material for including following parts by weight:
6. a kind of carpet lawn as described in claim 1 glue, it is characterised in that: further include antioxygen glue.
7. a kind of method for preparing carpet lawn as described in claim 1 glue, characterized in that it comprises the following steps:
1) refining glue；The natural rubber of 4-12% parts by weight is first cut into fritter, then refines eight times, cuts into pieces on rubber mixing machine
For use；
2) it mixes；The solvent of 50-60% parts by weight is taken to pour into reaction kettle, the natural rubber investment for then taking step 1) to refine is anti-
Answer in kettle, then into reaction kettle put into 4-5% parts by weight high styrene rubber, stirring and dissolving 18-24 hours, reaction kettle
It is warmed to 64-107 DEG C, after waiting the rubber in reaction kettles to be completely dissolved, then puts into the poly- a methyl styrene tree of 6-10% parts by weight
The terpene resin of rouge, the aldehyde ketone resin of 3-6% parts by weight and 10-15% parts by weight；Stirring 4-6 hours, after waiting its complete miscibility,
In the antioxidant for the white carbon black and 0.15-0.3% parts by weight for putting into 1-2% parts by weight into reaction kettle, it is small to continue stirring one
When；
3) it filters, solution made of step 2) is filtered, finished product is obtained.
8. the method for preparing carpet lawn glue as claimed in claim 7, it is characterised in that: put into 6-10% in the step 2)
After the poly- a methylstyrene resins of parts by weight, the aldehyde ketone resin of 3-6% parts by weight and the terpene resin of 10-15% parts by weight, then
Put into the antioxygen glue of 2-3% parts by weight.
9. the method for preparing carpet lawn glue as claimed in claim 7, which is characterized in that the preparation method of the solvent: will
No. 120 solvent naphthas, the ethyl acetate of 28-46% parts by weight and the dimethylbenzene of 4-10% parts by weight of 25-35% parts by weight enter mixed
It is mixed in clutch ware, obtains solvent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810859413.3A CN108977136A (en) | 2018-08-01 | 2018-08-01 | A kind of carpet lawn glue and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810859413.3A CN108977136A (en) | 2018-08-01 | 2018-08-01 | A kind of carpet lawn glue and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108977136A true CN108977136A (en) | 2018-12-11 |
Family
ID=64552170
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810859413.3A Pending CN108977136A (en) | 2018-08-01 | 2018-08-01 | A kind of carpet lawn glue and preparation method thereof |
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| Country | Link |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20020066529A1 (en) * | 2000-10-17 | 2002-06-06 | Teturo Tanno | Aqueous emulsion composition, method of backing carpet, and carpet |
| CN102115646A (en) * | 2010-08-18 | 2011-07-06 | 常熟市长江胶带有限公司 | Processing technology of viscous glue used on adhesive tape |
| CN105542675A (en) * | 2016-01-29 | 2016-05-04 | 宁波吉象塑胶制品有限公司 | Preparation method of wear-resistant adhesive tape |
| CN107778546A (en) * | 2016-08-29 | 2018-03-09 | 泰州市丰力工业皮带有限公司 | A kind of environment-friendly rubber and preparation method thereof |
-
2018
- 2018-08-01 CN CN201810859413.3A patent/CN108977136A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20020066529A1 (en) * | 2000-10-17 | 2002-06-06 | Teturo Tanno | Aqueous emulsion composition, method of backing carpet, and carpet |
| CN102115646A (en) * | 2010-08-18 | 2011-07-06 | 常熟市长江胶带有限公司 | Processing technology of viscous glue used on adhesive tape |
| CN105542675A (en) * | 2016-01-29 | 2016-05-04 | 宁波吉象塑胶制品有限公司 | Preparation method of wear-resistant adhesive tape |
| CN107778546A (en) * | 2016-08-29 | 2018-03-09 | 泰州市丰力工业皮带有限公司 | A kind of environment-friendly rubber and preparation method thereof |
Non-Patent Citations (2)
| Title |
|---|
| 丁绍兰主编: "《革制品材料学》", 31 July 2017, 中国轻工业出版社 * |
| 李广宇主编: "《胶黏剂原材料手册》", 31 August 2004, 国防工业出版社 * |
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| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
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Application publication date: 20181211 |