CN108976927A - A kind of gulgul suitable for wood artwork - Google Patents
A kind of gulgul suitable for wood artwork Download PDFInfo
- Publication number
- CN108976927A CN108976927A CN201810882171.XA CN201810882171A CN108976927A CN 108976927 A CN108976927 A CN 108976927A CN 201810882171 A CN201810882171 A CN 201810882171A CN 108976927 A CN108976927 A CN 108976927A
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- China
- Prior art keywords
- parts
- gulgul
- wood
- solution
- mothproof
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
- C09D125/02—Homopolymers or copolymers of hydrocarbons
- C09D125/04—Homopolymers or copolymers of styrene
- C09D125/08—Copolymers of styrene
- C09D125/14—Copolymers of styrene with unsaturated esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Chemical And Physical Treatments For Wood And The Like (AREA)
Abstract
The present invention relates to wood artwork processing technique fields, disclose a kind of gulgul suitable for wood artwork, metal-organic hybrid functional complexes are used to be added in coating as moth-proof material, eliminate the invasion problem of insect pest, and moisture is prevented to enter timber by lumen capillary well, to reach waterproof and corrosion-resistant effect, the gulgul being prepared plays fabulous shielding action, it can prevent insect pest intrusion wood surface and inside, it has both mothproof anti-corrosion and old effect is prevented in beautification, the present invention overcomes a series of problems that wood treated with maring bore preservative in the processing of existing Wood craft handles initiation not in place, assign that coating is good hydrophobic and mothproof performance, mothproof effect is good, working process is high-efficient, with easy to operate, securely and reliably, the advantages that maintaining the service life long, and solves existing mothproof inorganic agent It is difficult to the problem of degrading using rear waste liquid, is a kind of technical solution being extremely worth of widely use.
Description
Technical field
The invention belongs to wood artwork processing technique fields, and in particular to a kind of mothproof painting suitable for wood artwork
Material.
Background technique
The Wood craft of broad sense with various wood (including various bamboo classes) for primary raw material, and the Wood craft of narrow sense
It mainly uses various wood for raw material, has machine production, there is pure hand-made, there is half machine semi-hand production, it is exquisite in workmanship, if
Meter is simple, different style, and natural in color is new and original.Wood craft is different from general furniture, be suitable for it is dark and damp, avoid drying, therefore
Wood craft should not be especially exposed to the sun, and never air-conditioning is blown against furniture, and spring, autumn, three seasons of winter will keep room air
It does not dry, is preferably squirted with humidifier, aquaricullure, also adjustable indoor air humidity of raising flowers.
Damaging by worms for timber is the major reason for causing wooden structures to destroy, and the insect pest type for endangering timber structure at present is a lot of,
It is wherein endangered caused by all kinds of ants the most generally, and serious, and reduces the preservation of timber against decay performance.In wood artwork
It needs to carry out Anti-moth-eating processing to timber using necessary means in processing.Existing mothproof inorganic agent can not be long-acting lasting
It is mothproof, and do not have shielding action.
Summary of the invention
The purpose of the present invention is being directed to existing problem, a kind of gulgul suitable for wood artwork is provided, is made
Standby obtained gulgul plays fabulous shielding action, can prevent insect pest intrusion wood surface and inside, have both mothproof
Old effect is prevented in anti-corrosion and beautification.
The present invention is achieved by the following technical solutions:
A kind of gulgul suitable for wood artwork, is made of following component in parts by weight: styrene-acrylic emulsion 60-70
Part, 18-20 parts of melamine resin, 14-16 parts of anatase thpe white powder, metal -5.0-6.0 parts of organic hybrid functional complexes,
It is 2.0-2.5 parts of surfactant, 0.5-0.7 parts of thickener, 0.10-0.12 parts of wetting agent, 0.06-0.08 parts of defoaming agent, mould proof
0.03-0.05 parts of agent, 30-40 parts of water；The metal-organic hybrid functional complexes preparation method the following steps are included:
(1) 5.5-6.0 milliliters of butyl titanates are weighed to be added in 10-12 milliliters of dehydrated alcohols, is dispersed with stirring uniformly, it is molten to obtain A
Liquid weighs 1.5-1.8 grams and 2.5-2.6 grams of o-phenylenediamine of acetic acid and is dissolved in the hydrochloric acid solution that 8-10 milliliters prepare in advance, obtains B
Solution；
(2) B solution is slowly added dropwise in solution A, and be stirred continuously, 85-90 DEG C is heated under stirring, back flow reaction 5-
6 hours, it is cooled to 40-45 DEG C after reaction, reaction solution is poured into 50-60 milliliters of 0-2 DEG C of ice water, it is lasting to stir, then
It is neutralized with the unsaturated carbonate solution at 20 DEG C, adjusts pH value between 8.2-8.3, stood and solid is precipitated, filtering, at 50-55 DEG C
Lower baking 3-4 hours, pulverizes.
It is further described as to above scheme, the styrene-acrylic emulsion solid content is between 55-58%.
It is further described as to above scheme, the defoaming agent is dimethyl silicone polymer.
It is further described as to above scheme, the thickener is Sodium Polyacrylate, in sodium polymethacrylate
It is one or more of.
It is further described as to above scheme, step (1) the hydrochloric acid solution molar concentration prepared is 2.0-2.4
Mol/L.
The present invention has the advantage that solve in existing Wood craft processing at wood treated with maring bore preservative compared with prior art
The a series of problems for managing initiation not in place, the present invention provides a kind of gulguls suitable for wood artwork, use metal-
Organic hybrid functional complexes are added in coating as moth-proof material, eliminate the invasion problem of insect pest, and prevent well
Moisture enters timber by lumen capillary, to reach waterproof and corrosion-resistant effect, the gulgul that is prepared is risen
Fabulous shielding action has been arrived, insect pest intrusion wood surface and inside can be prevented, mothproof anti-corrosion is had both and old effect is prevented in beautification,
The present invention overcomes a series of problems that wood treated with maring bore preservative in the processing of existing Wood craft handles initiation not in place, and it is good to assign coating
Good hydrophobic and mothproof performance, mothproof effect is good, and working process is high-efficient, has easy to operate, securely and reliably, maintains the service life
The advantages that long, and solve the problems, such as that existing mothproof inorganic agent is difficult to degrade using rear waste liquid, it is that one kind is extremely worthy to be popularized
The technical solution used.
Specific embodiment
To make the purpose of the present invention, technical solution and effect clearer, clear and definite, combined with specific embodiments below to this hair
It is bright to be described further, it should be understood that the specific embodiments described herein are merely illustrative of the present invention, is not used to limit
Technical solution provided by the present invention.
Embodiment 1
A kind of gulgul suitable for wood artwork, is made of following component in parts by weight: 60 parts of styrene-acrylic emulsion, three
18 parts of cymel, 14 parts of anatase thpe white powder, metal -5.0 parts of organic hybrid functional complexes, 2.0 parts of surfactant,
0.5 part of thickener, 0.10 part of wetting agent, 0.06 part of defoaming agent, 0.03 part of mould inhibitor, 30 parts of water；The metal-organic hybrid function
Be able to cooperate object preparation method the following steps are included:
(1) 5.5 milliliters of butyl titanates are weighed to be added in 10 milliliters of dehydrated alcohols, is dispersed with stirring uniformly, is obtained solution A, weigh
1.5 grams and 2.5 grams of o-phenylenediamine of acetic acid are dissolved in the hydrochloric acid solution that 8 milliliters prepare in advance, obtain B solution；
(2) B solution is slowly added dropwise in solution A, and be stirred continuously, 85 DEG C are heated under stirring, back flow reaction 5 is small
When, it is cooled to 40 DEG C after reaction, reaction solution is poured into 50 milliliters of 0 DEG C of ice water, it is lasting to stir, then with full at 20 DEG C
It is neutralized with carbon acid solution, adjusts pH value between 8.2-8.3, stood and solid is precipitated, filtering is baked 3 hours at 50 DEG C, is ground
At powder.
It is further described as to above scheme, the styrene-acrylic emulsion solid content is between 55-58%.
It is further described as to above scheme, the defoaming agent is dimethyl silicone polymer.
It is further described as to above scheme, the thickener is Sodium Polyacrylate, in sodium polymethacrylate
It is one or more of.
It is further described as to above scheme, step (1) the hydrochloric acid solution molar concentration prepared is rubbed for 2.0
You/liter.
Embodiment 2
A kind of gulgul suitable for wood artwork, is made of following component in parts by weight: 65 parts of styrene-acrylic emulsion, three
19 parts of cymel, 15 parts of anatase thpe white powder, metal -5.5 parts of organic hybrid functional complexes, 2.2 parts of surfactant,
0.6 part of thickener, 0.11 part of wetting agent, 0.07 part of defoaming agent, 0.04 part of mould inhibitor, 35 parts of water；The metal-organic hybrid function
Be able to cooperate object preparation method the following steps are included:
(1) 5.8 milliliters of butyl titanates are weighed to be added in 11 milliliters of dehydrated alcohols, is dispersed with stirring uniformly, is obtained solution A, weigh
1.6 grams and 2.55 grams of o-phenylenediamine of acetic acid are dissolved in the hydrochloric acid solution that 9 milliliters prepare in advance, obtain B solution；
(2) B solution is slowly added dropwise in solution A, and be stirred continuously, 88 DEG C are heated under stirring, back flow reaction 5.5 is small
When, it is cooled to 42 DEG C after reaction, reaction solution is poured into 55 milliliters of 1 DEG C of ice water, it is lasting to stir, then with full at 20 DEG C
It is neutralized with carbon acid solution, adjusts pH value between 8.2-8.3, stood and solid is precipitated, filtering is baked 3.5 hours at 52 DEG C, ground
Grinds.
It is further described as to above scheme, the styrene-acrylic emulsion solid content is between 55-58%.
It is further described as to above scheme, the defoaming agent is dimethyl silicone polymer.
It is further described as to above scheme, the thickener is Sodium Polyacrylate, in sodium polymethacrylate
It is one or more of.
It is further described as to above scheme, step (1) the hydrochloric acid solution molar concentration prepared is rubbed for 2.2
You/liter.
Embodiment 3
A kind of gulgul suitable for wood artwork, is made of following component in parts by weight: 70 parts of styrene-acrylic emulsion, three
20 parts of cymel, 16 parts of anatase thpe white powder, metal -6.0 parts of organic hybrid functional complexes, 2.5 parts of surfactant,
0.7 part of thickener, 0.12 part of wetting agent, 0.08 part of defoaming agent, 0.05 part of mould inhibitor, 40 parts of water；The metal-organic hybrid function
Be able to cooperate object preparation method the following steps are included:
(1) 6.0 milliliters of butyl titanates are weighed to be added in 12 milliliters of dehydrated alcohols, is dispersed with stirring uniformly, is obtained solution A, weigh
1.8 grams and 2.6 grams of o-phenylenediamine of acetic acid are dissolved in the hydrochloric acid solution that 10 milliliters prepare in advance, obtain B solution；
(2) B solution is slowly added dropwise in solution A, and be stirred continuously, 90 DEG C are heated under stirring, back flow reaction 6 is small
When, it is cooled to 45 DEG C after reaction, reaction solution is poured into 60 milliliters of 2 DEG C of ice water, it is lasting to stir, then with full at 20 DEG C
It is neutralized with carbon acid solution, adjusts pH value between 8.2-8.3, stood and solid is precipitated, filtering is baked 4 hours at 55 DEG C, is ground
At powder.
It is further described as to above scheme, the styrene-acrylic emulsion solid content is between 55-58%.
It is further described as to above scheme, the defoaming agent is dimethyl silicone polymer.
It is further described as to above scheme, the thickener is Sodium Polyacrylate, in sodium polymethacrylate
It is one or more of.
It is further described as to above scheme, step (1) the hydrochloric acid solution molar concentration prepared is rubbed for 2.4
You/liter.
Comparative example 1
Difference with embodiment 1 is only that, replaces the styrene-acrylic emulsion using polyacrylate emulsion, remaining is consistent.
Comparative example 2
Difference with embodiment 2 is only that, is omitted the preparation of the metal-organic hybrid functional complexes, is used aqueous poly- ammonia
Ester resin replaces, remaining is consistent.
Comparative example 3
Difference with embodiment 3 is only that, in the preparation of metal-organic hybrid functional complexes, omits solution A in step (1)
Preparation, remaining is consistent.
Comparative example 4
Difference with embodiment 3 is only that, in the preparation of metal-organic hybrid functional complexes, omits B solution in step (1)
Preparation, remaining is consistent.
Comparative experiments
It is suitable for the gulgul of wood artwork, using the method processing preparation of embodiment 1-3 and comparative example 1-4 respectively with special
Benefit number is a kind of for involved in the fire prevention of wood-structure old building reparation, anti-corrosion, gulgul disclosed in CN107236441A
As a control group, the blank control group of any mothproof processing is not done in setting to coating, uses cottonwood plank stuff as subjects, setting
Using each 10 pieces of repeat samples of each group mothproof treatment method (including blank control), unrelated change in the preparation of each group test specimen is kept
Amount is consistent, using Workers of Coptotermes formosanus Shiraki as test test worm, measures mothproof anti-corrosion effect, insect resistance test: refers to GB/T 12860-
2000 " timber preservative is to termite toxic effect laboratory test methods " are tested；Preservation test: GB/T 1394.1- is referred to
2009 " the timber natural Durability Test methods/natural corrosion resistance laboratory test methods of timber " are tested；It calculates effective
Average value records mothproof process performance result as shown in the table:
(mothproof classification standard are as follows: 0 grade: free from insect pests, sample weight loss late is less than 0.5%；1 grade: slightly damage by worms, sample weight damage
Mistake rate is between 0.5-1.0%；2 grades: medium to damage by worms, sample weight loss late is between 1.0-3.0%；3 grades: it is more serious to damage by worms,
Sample weight loss late is between 3.0-8.0%；4 grades: seriously damaging by worms, sample weight loss late is greater than 8.0%.)
The present invention overcomes a series of problems that wood treated with maring bore preservative in the processing of existing Wood craft handles initiation not in place, assign and applying
Expect good hydrophobic and mothproof performance, mothproof effect is good, and working process is high-efficient, have it is easy to operate, securely and reliably, maintain
The advantages that service life is long, and solve the problems, such as that existing mothproof inorganic agent is difficult to degrade using rear waste liquid, it is a kind of extremely worth
The technical solution of popularization and use.
Claims (5)
1. a kind of gulgul suitable for wood artwork, which is characterized in that be made in parts by weight of following component: benzene
60-70 parts of acrylic emulsion, 18-20 parts of melamine resin, 14-16 parts of anatase thpe white powder, metal-organic hybrid functional complexes
5.0-6.0 parts, 2.0-2.5 parts of surfactant, 0.5-0.7 parts of thickener, 0.10-0.12 parts of wetting agent, defoaming agent 0.06-
0.08 part, 0.03-0.05 parts of mould inhibitor, 30-40 parts of water；The metal-organic hybrid functional complexes preparation method include with
Lower step:
(1) 5.5-6.0 milliliters of butyl titanates are weighed to be added in 10-12 milliliters of dehydrated alcohols, is dispersed with stirring uniformly, it is molten to obtain A
Liquid weighs 1.5-1.8 grams and 2.5-2.6 grams of o-phenylenediamine of acetic acid and is dissolved in the hydrochloric acid solution that 8-10 milliliters prepare in advance, obtains B
Solution；
(2) B solution is slowly added dropwise in solution A, and be stirred continuously, 85-90 DEG C is heated under stirring, back flow reaction 5-
6 hours, it is cooled to 40-45 DEG C after reaction, reaction solution is poured into 50-60 milliliters of 0-2 DEG C of ice water, it is lasting to stir, then
It is neutralized with the unsaturated carbonate solution at 20 DEG C, adjusts pH value between 8.2-8.3, stood and solid is precipitated, filtering, at 50-55 DEG C
Lower baking 3-4 hours, pulverizes.
2. a kind of gulgul suitable for wood artwork as described in claim 1, which is characterized in that the styrene-acrylic emulsion is solid
Content is between 55-58%.
3. a kind of gulgul suitable for wood artwork as described in claim 1, which is characterized in that the defoaming agent is poly-
Dimethyl siloxane.
4. a kind of gulgul suitable for wood artwork as described in claim 1, which is characterized in that the thickener is poly-
One or more of sodium acrylate, sodium polymethacrylate.
5. a kind of gulgul suitable for wood artwork as described in claim 1, which is characterized in that step (1) is described to match
Good hydrochloric acid solution molar concentration is 2.0-2.4 mol/L.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810882171.XA CN108976927A (en) | 2018-08-06 | 2018-08-06 | A kind of gulgul suitable for wood artwork |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810882171.XA CN108976927A (en) | 2018-08-06 | 2018-08-06 | A kind of gulgul suitable for wood artwork |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108976927A true CN108976927A (en) | 2018-12-11 |
Family
ID=64555403
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810882171.XA Pending CN108976927A (en) | 2018-08-06 | 2018-08-06 | A kind of gulgul suitable for wood artwork |
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Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1962459A (en) * | 2006-12-01 | 2007-05-16 | 浙江大学 | Method for preparing modified titanium oxide sol, powder and film |
| CN101444724A (en) * | 2008-12-24 | 2009-06-03 | 南开大学 | Method for preparing high activity non-metallic ion co-doped titanium dioxide photochemical catalyst |
| CN102181215A (en) * | 2011-05-23 | 2011-09-14 | 中山市丽莎涂料有限公司 | Waterborne wood lacquer |
| CN105368172A (en) * | 2015-11-18 | 2016-03-02 | 广德县常丰竹木业制品有限公司 | Faint scent bamboo wood processing latex paint and preparation method thereof |
| CN105802416A (en) * | 2016-04-11 | 2016-07-27 | 董早霞 | Waterborne antibacterial coating and preparation method thereof |
| CN107189599A (en) * | 2017-06-30 | 2017-09-22 | 郝茂佳 | A kind of timber termite-proof coating and preparation method thereof |
-
2018
- 2018-08-06 CN CN201810882171.XA patent/CN108976927A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1962459A (en) * | 2006-12-01 | 2007-05-16 | 浙江大学 | Method for preparing modified titanium oxide sol, powder and film |
| CN101444724A (en) * | 2008-12-24 | 2009-06-03 | 南开大学 | Method for preparing high activity non-metallic ion co-doped titanium dioxide photochemical catalyst |
| CN102181215A (en) * | 2011-05-23 | 2011-09-14 | 中山市丽莎涂料有限公司 | Waterborne wood lacquer |
| CN105368172A (en) * | 2015-11-18 | 2016-03-02 | 广德县常丰竹木业制品有限公司 | Faint scent bamboo wood processing latex paint and preparation method thereof |
| CN105802416A (en) * | 2016-04-11 | 2016-07-27 | 董早霞 | Waterborne antibacterial coating and preparation method thereof |
| CN107189599A (en) * | 2017-06-30 | 2017-09-22 | 郝茂佳 | A kind of timber termite-proof coating and preparation method thereof |
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Application publication date: 20181211 |