CN108976688A - A kind of high-stability nano metallic pigments master batch - Google Patents
A kind of high-stability nano metallic pigments master batch Download PDFInfo
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- CN108976688A CN108976688A CN201810592579.3A CN201810592579A CN108976688A CN 108976688 A CN108976688 A CN 108976688A CN 201810592579 A CN201810592579 A CN 201810592579A CN 108976688 A CN108976688 A CN 108976688A
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- pigment
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- 239000000049 pigment Substances 0.000 title claims abstract description 54
- 239000004594 Masterbatch (MB) Substances 0.000 title claims abstract description 41
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 claims abstract description 34
- 239000000654 additive Substances 0.000 claims abstract description 26
- 150000002736 metal compounds Chemical class 0.000 claims abstract description 25
- 230000000996 additive effect Effects 0.000 claims abstract description 19
- 239000000945 filler Substances 0.000 claims abstract description 16
- 239000000126 substance Substances 0.000 claims abstract description 16
- 239000000314 lubricant Substances 0.000 claims abstract description 13
- 239000006096 absorbing agent Substances 0.000 claims abstract description 12
- 239000002270 dispersing agent Substances 0.000 claims abstract description 12
- 239000012760 heat stabilizer Substances 0.000 claims abstract description 11
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical class [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 43
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 24
- 238000000034 method Methods 0.000 claims description 24
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 16
- 230000008569 process Effects 0.000 claims description 16
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 15
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 15
- 239000002245 particle Substances 0.000 claims description 14
- 239000011812 mixed powder Substances 0.000 claims description 13
- 238000001035 drying Methods 0.000 claims description 12
- 239000007788 liquid Substances 0.000 claims description 12
- 239000007864 aqueous solution Substances 0.000 claims description 11
- 239000000463 material Substances 0.000 claims description 11
- 239000000843 powder Substances 0.000 claims description 11
- 238000010298 pulverizing process Methods 0.000 claims description 11
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 10
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 10
- 238000002360 preparation method Methods 0.000 claims description 10
- 229910000077 silane Inorganic materials 0.000 claims description 10
- 239000004411 aluminium Substances 0.000 claims description 9
- 229910052782 aluminium Inorganic materials 0.000 claims description 9
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 9
- 238000007738 vacuum evaporation Methods 0.000 claims description 9
- 239000000969 carrier Substances 0.000 claims description 7
- 229910003437 indium oxide Inorganic materials 0.000 claims description 7
- PJXISJQVUVHSOJ-UHFFFAOYSA-N indium(iii) oxide Chemical compound [O-2].[O-2].[O-2].[In+3].[In+3] PJXISJQVUVHSOJ-UHFFFAOYSA-N 0.000 claims description 7
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 claims description 6
- 239000003963 antioxidant agent Substances 0.000 claims description 6
- 230000003078 antioxidant effect Effects 0.000 claims description 6
- 238000001704 evaporation Methods 0.000 claims description 6
- 230000008020 evaporation Effects 0.000 claims description 6
- 229920001912 maleic anhydride grafted polyethylene Polymers 0.000 claims description 6
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical group COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 5
- 238000006243 chemical reaction Methods 0.000 claims description 5
- 238000001914 filtration Methods 0.000 claims description 5
- 238000007654 immersion Methods 0.000 claims description 5
- 229910052757 nitrogen Inorganic materials 0.000 claims description 5
- 238000003756 stirring Methods 0.000 claims description 5
- 238000010792 warming Methods 0.000 claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- 239000003643 water by type Substances 0.000 claims description 5
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 4
- 229920001577 copolymer Polymers 0.000 claims description 4
- 239000001023 inorganic pigment Substances 0.000 claims description 4
- 239000004209 oxidized polyethylene wax Substances 0.000 claims description 4
- 235000013873 oxidized polyethylene wax Nutrition 0.000 claims description 4
- 239000011347 resin Substances 0.000 claims description 4
- 229920005989 resin Polymers 0.000 claims description 4
- 229910052717 sulfur Inorganic materials 0.000 claims description 4
- 239000011593 sulfur Substances 0.000 claims description 4
- 229940124543 ultraviolet light absorber Drugs 0.000 claims description 4
- 239000006087 Silane Coupling Agent Substances 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- MCPKSFINULVDNX-UHFFFAOYSA-N drometrizole Chemical compound CC1=CC=C(O)C(N2N=C3C=CC=CC3=N2)=C1 MCPKSFINULVDNX-UHFFFAOYSA-N 0.000 claims description 3
- 239000012860 organic pigment Substances 0.000 claims description 3
- 229920002545 silicone oil Polymers 0.000 claims description 3
- 239000000243 solution Substances 0.000 claims description 3
- 239000006097 ultraviolet radiation absorber Substances 0.000 claims description 3
- 102000008186 Collagen Human genes 0.000 claims description 2
- 108010035532 Collagen Proteins 0.000 claims description 2
- 240000007594 Oryza sativa Species 0.000 claims description 2
- 235000007164 Oryza sativa Nutrition 0.000 claims description 2
- 229920001436 collagen Polymers 0.000 claims description 2
- 229910052746 lanthanum Inorganic materials 0.000 claims description 2
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 claims description 2
- GBMDVOWEEQVZKZ-UHFFFAOYSA-N methanol;hydrate Chemical compound O.OC GBMDVOWEEQVZKZ-UHFFFAOYSA-N 0.000 claims description 2
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 claims description 2
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 claims description 2
- 235000009566 rice Nutrition 0.000 claims description 2
- 238000010025 steaming Methods 0.000 claims description 2
- 239000002905 metal composite material Substances 0.000 claims 1
- 238000004040 coloring Methods 0.000 abstract description 16
- 230000000694 effects Effects 0.000 abstract description 11
- 230000008901 benefit Effects 0.000 abstract description 4
- 239000003086 colorant Substances 0.000 abstract description 4
- 239000004595 color masterbatch Substances 0.000 abstract 1
- 239000010408 film Substances 0.000 description 22
- 230000000052 comparative effect Effects 0.000 description 12
- 239000004615 ingredient Substances 0.000 description 5
- 239000002923 metal particle Substances 0.000 description 5
- 229920003023 plastic Polymers 0.000 description 5
- 239000004033 plastic Substances 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 4
- 238000005406 washing Methods 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 3
- 239000008367 deionised water Substances 0.000 description 3
- 229910021641 deionized water Inorganic materials 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- FYDKNKUEBJQCCN-UHFFFAOYSA-N lanthanum(3+);trinitrate Chemical compound [La+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O FYDKNKUEBJQCCN-UHFFFAOYSA-N 0.000 description 3
- 229940099259 vaseline Drugs 0.000 description 3
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 239000007822 coupling agent Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- -1 silicon Alkane Chemical class 0.000 description 2
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 238000004378 air conditioning Methods 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 238000003486 chemical etching Methods 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 238000012505 colouration Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 description 1
- LRDFRRGEGBBSRN-UHFFFAOYSA-N isobutyronitrile Chemical compound CC(C)C#N LRDFRRGEGBBSRN-UHFFFAOYSA-N 0.000 description 1
- 239000006210 lotion Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 150000008301 phosphite esters Chemical group 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 239000001054 red pigment Substances 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 230000009967 tasteless effect Effects 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/20—Compounding polymers with additives, e.g. colouring
- C08J3/22—Compounding polymers with additives, e.g. colouring using masterbatch techniques
- C08J3/226—Compounding polymers with additives, e.g. colouring using masterbatch techniques using a polymer as a carrier
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2355/00—Characterised by the use of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08J2323/00 - C08J2353/00
- C08J2355/02—Acrylonitrile-Butadiene-Styrene [ABS] polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2423/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2423/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2423/04—Homopolymers or copolymers of ethene
- C08J2423/08—Copolymers of ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2433/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
- C08J2433/18—Homopolymers or copolymers of nitriles
- C08J2433/20—Homopolymers or copolymers of acrylonitrile
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2451/00—Characterised by the use of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers
- C08J2451/06—Characterised by the use of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/06—Pretreated ingredients and ingredients covered by the main groups C08K3/00 - C08K7/00
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
- C08K2003/0812—Aluminium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
- C08K2003/0843—Cobalt
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/04—Ingredients treated with organic substances
- C08K9/06—Ingredients treated with organic substances with silicon-containing compounds
Abstract
The invention discloses a kind of high-stability nano metallic pigments master batches, are made of following substance: carrier, pigment, nano metal compound additive, dispersing agent, heat stabilizer, ultraviolet absorbing agent, lubricant, filler.When a kind of pigment master batch produced by the present invention is applied to the coloring of ABS product, it does not need that ABS resin is dried in advance, and this pigment master batch has many advantages, such as that stability is high, coloring color difference is small, coloring effect is good, overcome the problems such as existing color is unstable, color difference is big, effect is bad when existing ABS color master-batch colours, moreover it is possible to promote the mechanical strength characteristics of ABS product well.
Description
Technical field
The invention belongs to plastic processing processing technology fields, and in particular to a kind of high-stability nano metallic pigments master batch.
Background technique
ABS resin is the terpolymer of acrylonitrile, butadiene and styrene, and blending method, copolymerization method and lotion can be used
Graft Method production.By adjusting the composition of three kinds of monomers in ABS, can prepare with ultrahigh impact type, universal and special type
The material of (such as plating grade) various trades mark.The plastic products prepared using ABS material are nontoxic, tasteless, and rigidity and tough performance are full
The requirement in the fields such as sufficient household electrical appliance, light industry stationery sports goods, auto industry and chemical industry, using very extensive.
Currently, the household electrical appliance plastic fittings of many higher gears mainly uses ABS plastic.With family's electrical article personalization and
The direction of differential development trend, color towards diversification and bright-colouredization of household electrical appliance is developed, and the requirement to coloring is also in day
Benefit improves.The molecular structure and composition of ABS ternary polymerization lead to the ABS colors of the various trades mark, and there is some difference, this is for system
The coloring of product is totally unfavorable.ABS resin is easy to absorb moisture, before processing it is generally necessary to which drying, drying process are easy to cause
ABS discoloration, generates colour fluctuation.
When the white domestic appliances such as components such as air-conditioning, refrigerator and washing machine are coloured using Masterbatch, due to common Masterbatch
Generally use ABS for carrier, adding proportion is smaller, and there are the mobile performance of Masterbatch is poor, Masterbatch holds in processing and forming
It easily sinks to the bottom and causes Masterbatch macroscopic view is unevenly distributed in the plastic, be easy to appear the problems such as color is unstable, color difference is not easy to control.
With the continuous improvement that client requires product appearance, ABS plastic processing enterprise proposes higher want to the stability of color
It asks.
Masterbatch addition manufacture is mostly used for the coloring treatment of plastic product at present, using pigment as colorant
Referred to as pigment master batch.Due to ABS resin self-characteristic, common pigment master batch colours using effect for it on the market
It is bad.
Summary of the invention
The purpose of the present invention is being directed to existing problem, a kind of high-stability nano metallic pigments master batch is provided.
The present invention is achieved by the following technical solutions:
A kind of high-stability nano metallic pigments master batch, is made of the substance of following parts by weight:
30 ~ 50 parts of carriers, 60 ~ 70 parts of pigment, 5 ~ 8 parts of nano metal compound additives, 4 ~ 9 parts of dispersing agents, 0.1 ~ 1 part of thermostabilization
Agent, 0.1 ~ 0.5 part of ultraviolet absorbing agent, 1 ~ 3 part of lubricant, 20 ~ 25 parts of fillers.
Preferably, it is made of the substance of following parts by weight:
40 parts of carriers, 65 parts of pigment, 7 parts of nano metal compound additives, 8 parts of dispersing agents, 0.5 part of heat stabilizer, 0.3 part it is ultraviolet
Light absorbers, 2 parts of lubricants, 23 parts of fillers.
Further, the carrier is maleic anhydride grafted polyethylene, acrylonitritrile-styrene resin, ethylene-octene
Any one in copolymer.
Further, the pigment is the mixture of inorganic pigment, organic pigment or both.
Further, the preparation method of the nano metal compound additive includes the following steps:
(1) nanometer aluminium powder, nano indium oxide particle and nano-cobalt powder are mixed according to 7 ~ 9:1 of weight ratio ~ 2:3 ~ 5, is obtained mixed
It is spare to close powder；
(2) it is water-soluble for 0.2 ~ 0.4% collagen that step (1) resulting mixed powder is put into the mass fraction of 2 ~ 4 times of its gross mass
In liquid, adjusting whole pH value is 5.0 ~ 5.5, with centrifugal filtration after 2000 ~ 2400 revs/min of 8 ~ 10h of revolving speed stir process, then
It is spare after being dried under conditions of being put in 40 ~ 45 DEG C；
(3) methanol-water for being 40 ~ 50% by the volume fraction of step (2) treated mixed powder puts into 8 ~ 10 times of its gross mass
In solution, ultrasonic vibration handles 3 ~ 5min, is then warming up to 55 ~ 60 DEG C under nitrogen protection, is added such as into methanol aqueous solution
The substance of lower corresponding molal volume ratio: the nitre of the methyl methacrylate monomer of 0.3 ~ 0.4mol/L, 0.005 ~ 0.008mol/L
The azodiisobutyronitrile of sour lanthanum, 0.01 ~ 0.015mol/L, is then stirred continuously 7 ~ 9h of reaction, is finally put into vacuum steaming
It is successively evaporated in vacuo in hair equipment, film collection, pulverization process, takes out to obtain nano metal compound additive after the completion.
Further, described in step (3) be evaporated in vacuo processing when control vacuum evaporation apparatus in pressure be 1 ×
10-4 ~ 2×10-4 The temperature control of Pa, evaporation are 1300 ~ 1360 DEG C；Film film used when collecting is by ABS resin system
At collection processing is preceding to be first cooled to film -120 ~ -130 DEG C in advance；The particle of nano metal compound additive after pulverization process is straight
Diameter is not more than 6mm.It is first that nanometer aluminium powder, nano indium oxide particle and nano-cobalt powder is composite modified at compound nano metal particles
Son, then be collected with film, film is pre-chilled can reduce metal well by high temperature evaporation at metallic vapour particle
The high temperature surface-active of steam particle, is fixed conducive to Scatter Gather, and it is compound to obtain a kind of film-nano metal particles after the completion
Material finally carries out pulverization process, is convenient for the granulation processing of master batch.
Further, the dispersing agent is oxidized polyethylene wax, any one in maleic anhydride grafted polyethylene wax；
The heat stabilizer is sulfur-bearing antioxidant, any one in phosphite antioxidant.
Further, the ultraviolet absorbing agent is Ultraviolet Absorber UV-P, appointing in ultraviolet absorbing agent UV-O
It anticipates one kind；The lubricant is vaseline, any one in silicone oil.
Further, the filler is modified calcium carbonate, and the preparation method of the modified calcium carbonate includes the following steps:
(1) first by calcium carbonate be put into mass fraction be 5 ~ 8% citric acid in 10 ~ 15min of immersion treatment, spent after taking-up from
Sub- water is spare after rinsing one time；
(2) by step (1), treated that calcium carbonate is put into high temperature furnace heats, control the temperature in high temperature furnace be 320 ~
360 DEG C, heat 40 ~ 45min after take out it is spare；
(3) by step (2), treated that calcium carbonate is immersed in silane coupler modified liquid, takes out, places into after 1 ~ 1.5h
1 ~ 2h is dried in the drying box that temperature is 85 ~ 90 DEG C.
Further, silane coupler modified liquid described in step (3) by following parts by weight material composition: 15 ~ 20
Part silane coupling agent, 70 ~ 75 parts of ethylene glycol, 8 ~ 12 parts of deionized waters.
A kind of pigment master batch suitable for ABS coloring processing has been made in the present invention, mainly carries out to the constituent of master batch
Special selection collocation, wherein a kind of nano metal compound additive ingredient is added to, specifically based on nanometer aluminium powder
Substance, corresponding addition has compounded nano indium oxide particle and nano-cobalt powder ingredient, and is modified to the mixture that it is formed
It handles, the nanometer aluminium powder-nano indium oxide-for being finally made a kind of collagen-methylmethacrylate copolymer package is received
The surface active groups type of the compound nano metal particles of rice cobalt powder, this nano metal particles is abundant, and activity is good, with carrier at
Point and ABS resin matrix between compatibility it is good, can effectively adsorb grafting and be fixed on the surface of pigment, reduce the boundary of pigment
Face surface energy, improves the dispersed filler effect of pigment, generally existing in ABS processing coloring so as to improve common pigments
Coloring is uneven, coloring effect is bad, influences the problems such as mechanical quality of material, and furthermore nano metal particles can also promote pigment
Resistant to chemical etching, covering power and anti-grinded hardness index, the synthesis for improving pigment master batch use characteristic；Also added filler at
Point, specifically a kind of modified calcium carbonate has good resin compatible, and has biggish specific surface area and adsorption energy
Power improves the processing of pigment master batch using characteristic, also acts the effect of reinforcement, enable to be not required to when ABS color articles
ABS resin is dried, reduce the cost and difficulty of processing.
The present invention has the advantage that compared with prior art
When a kind of pigment master batch produced by the present invention is applied to the coloring of ABS product, do not need that ABS resin is dried in advance
Processing, and this pigment master batch has many advantages, such as that stability is high, coloring color difference is small, coloring effect is good, overcomes existing ABS coloring
The problems such as existing color is unstable when masterbatch colouration, color difference is big, effect is bad, moreover it is possible to promote the mechanics of ABS product well
Strength characteristics has good application value.
Specific embodiment
Embodiment 1
A kind of high-stability nano metallic pigments master batch, is made of the substance of following parts by weight:
30 parts of carriers, 60 parts of pigment, 5 parts of nano metal compound additives, 4 parts of dispersing agents, 0.1 part of heat stabilizer, 0.1 part it is ultraviolet
Light absorbers, 1 part of lubricant, 20 parts of fillers.
Further, the carrier is maleic anhydride grafted polyethylene.
Further, the pigment is inorganic pigment.
Further, the preparation method of the nano metal compound additive includes the following steps:
(1) nanometer aluminium powder, nano indium oxide particle and nano-cobalt powder are mixed according to weight ratio 7:1:3, it is standby obtains mixed powder
With；
(2) step (1) resulting mixed powder is put into the collagenic aqueous solution that the mass fraction of 2 times of its gross mass is 0.2%,
Adjusting whole pH value is 5.0, with centrifugal filtration after 2000 revs/min of revolving speed stir process 8h, then is put under conditions of 40 DEG C
It is spare after drying process；
(3) in the methanol aqueous solution for being 40% by the volume fraction of step (2) treated mixed powder puts into 8 times of its gross mass,
Ultrasonic vibration handles 3min, is then warming up to 55 DEG C under nitrogen protection, and following corresponding mole body is added into methanol aqueous solution
Product ratio substance: the methyl methacrylate monomer of 0.3mol/L, the lanthanum nitrate of 0.005mol/L, 0.01mol/L azo two
Isobutyronitrile, be then stirred continuously reaction 7h, finally put into vacuum evaporation apparatus be successively evaporated in vacuo, film receive
Collection, pulverization process, take out to obtain nano metal compound additive after the completion.
Further, described in step (3) be evaporated in vacuo processing when control vacuum evaporation apparatus in pressure be 1 ×
10-4 The temperature control of Pa, evaporation are 1300 DEG C；Film film used when collecting is made of ABS resin, and it is preceding first to collect processing
Film is cooled to -120 DEG C in advance；The particle diameter of nano metal compound additive after pulverization process is not more than 6mm.
Further, the dispersing agent is oxidized polyethylene wax；The heat stabilizer is sulfur-bearing antioxidant.
Further, the ultraviolet absorbing agent is Ultraviolet Absorber UV-P；The lubricant is vaseline.
Further, the filler is modified calcium carbonate, and the preparation method of the modified calcium carbonate includes the following steps:
(1) calcium carbonate is first put into immersion treatment 10min in the citric acid that mass fraction is 5%, is rushed after taking-up with deionized water
It is spare after washing one time；
(2) by step (1), treated that calcium carbonate is put into high temperature furnace heats, and controlling the temperature in high temperature furnace is 320
DEG C, it is taken out after heat treatment 40min spare；
(3) by step (2), treated that calcium carbonate is immersed in silane coupler modified liquid, takes out after 1h, places into temperature
To be dried 1h in 85 DEG C of drying boxes.
Further, silane coupler modified liquid described in step (3) by following parts by weight material composition: 15 parts of silicon
Alkane coupling agent, 70 parts of ethylene glycol, 8 parts of deionized waters.
Embodiment 2
A kind of high-stability nano metallic pigments master batch, is made of the substance of following parts by weight:
40 parts of carriers, 65 parts of pigment, 7 parts of nano metal compound additives, 8 parts of dispersing agents, 0.5 part of heat stabilizer, 0.3 part it is ultraviolet
Light absorbers, 2 parts of lubricants, 23 parts of fillers.
Further, the carrier is acrylonitritrile-styrene resin.
Further, the pigment is inorganic pigment.
Further, the preparation method of the nano metal compound additive includes the following steps:
(1) nanometer aluminium powder, nano indium oxide particle and nano-cobalt powder are mixed according to weight ratio 8:1.5:4, obtains mixed powder
It is spare；
(2) step (1) resulting mixed powder is put into the collagenic aqueous solution that the mass fraction of 3 times of its gross mass is 0.3%,
Adjusting whole pH value is 5.3, with centrifugal filtration after 2200 revs/min of revolving speed stir process 9h, then is put under conditions of 43 DEG C
It is spare after drying process；
(3) in the methanol aqueous solution for being 45% by the volume fraction of step (2) treated mixed powder puts into 9 times of its gross mass,
Ultrasonic vibration handles 4min, is then warming up to 58 DEG C under nitrogen protection, and following corresponding mole body is added into methanol aqueous solution
Product ratio substance: the methyl methacrylate monomer of 0.35mol/L, the lanthanum nitrate of 0.007mol/L, 0.013mol/L azo
Bis-isobutyronitrile, be then stirred continuously reaction 8h, finally put into vacuum evaporation apparatus be successively evaporated in vacuo, film
It collects, pulverization process, takes out to obtain nano metal compound additive after the completion.
Further, described in step (3) be evaporated in vacuo processing when control vacuum evaporation apparatus in pressure be 1.5 ×
10-4The temperature control of Pa, evaporation are 1330 DEG C；Film film used when collecting is made of ABS resin, first will before collecting processing
Film is cooled to -125 DEG C in advance；The particle diameter of nano metal compound additive after pulverization process is not more than 6mm.
Further, the dispersing agent is oxidized polyethylene wax；The heat stabilizer is sulfur-bearing antioxidant.
Further, the ultraviolet absorbing agent is ultraviolet absorbing agent UV-O；The lubricant is vaseline.
Further, the filler is modified calcium carbonate, and the preparation method of the modified calcium carbonate includes the following steps:
(1) calcium carbonate is first put into immersion treatment 13min in the citric acid that mass fraction is 7%, is rushed after taking-up with deionized water
It is spare after washing one time；
(2) by step (1), treated that calcium carbonate is put into high temperature furnace heats, and controlling the temperature in high temperature furnace is 340
DEG C, it is taken out after heat treatment 43min spare；
(3) by step (2), treated that calcium carbonate is immersed in silane coupler modified liquid, takes out after 1.2h, places into temperature
Degree is drying process 1.5h in 88 DEG C of drying box.
Further, silane coupler modified liquid described in step (3) by following parts by weight material composition: 18 parts of silicon
Alkane coupling agent, 73 parts of ethylene glycol, 10 parts of deionized waters.
Embodiment 3
A kind of high-stability nano metallic pigments master batch, is made of the substance of following parts by weight:
50 parts of carriers, 70 parts of pigment, 8 parts of nano metal compound additives, 9 parts of dispersing agents, 1 part of heat stabilizer, 0.5 part of ultraviolet light
Absorbent, 3 parts of lubricants, 25 parts of fillers.
Further, the carrier is ethylene-octene copolymer.
Further, the pigment is organic pigment.
Further, the preparation method of the nano metal compound additive includes the following steps:
(1) nanometer aluminium powder, nano indium oxide particle and nano-cobalt powder are mixed according to weight ratio 9:2:5, it is standby obtains mixed powder
With；
(2) step (1) resulting mixed powder is put into the collagenic aqueous solution that the mass fraction of 4 times of its gross mass is 0.4%,
Adjusting whole pH value is 5.5, with centrifugal filtration after 2400 revs/min of revolving speed stir process 10h, then is put under conditions of 45 DEG C
It is spare after drying process；
(3) methanol aqueous solution for being 50% by the volume fraction of step (2) treated mixed powder puts into 10 times of its gross mass
In, ultrasonic vibration handles 5min, is then warming up to 60 DEG C under nitrogen protection, and following corresponding mole is added into methanol aqueous solution
The substance of volume ratio: the methyl methacrylate monomer of 0.4mol/L, the lanthanum nitrate of 0.008mol/L, 0.015mol/L azo
Bis-isobutyronitrile, be then stirred continuously reaction 9h, finally put into vacuum evaporation apparatus be successively evaporated in vacuo, film
It collects, pulverization process, takes out to obtain nano metal compound additive after the completion.
Further, described in step (3) be evaporated in vacuo processing when control vacuum evaporation apparatus in pressure be 2 ×
10-4 The temperature control of Pa, evaporation are 1360 DEG C；Film film used when collecting is made of ABS resin, and it is preceding first to collect processing
Film is cooled to -130 DEG C in advance；The particle diameter of nano metal compound additive after pulverization process is not more than 6mm.
Further, the dispersing agent is maleic anhydride grafted polyethylene wax；The heat stabilizer is phosphite ester
Antioxidant.
Further, the ultraviolet absorbing agent is ultraviolet absorbing agent UV-O；The lubricant is silicone oil.
Further, the filler is modified calcium carbonate, and the preparation method of the modified calcium carbonate includes the following steps:
(1) calcium carbonate is first put into immersion treatment 15min in the citric acid that mass fraction is 8%, is rushed after taking-up with deionized water
It is spare after washing one time；
(2) by step (1), treated that calcium carbonate is put into high temperature furnace heats, and controlling the temperature in high temperature furnace is 360
DEG C, it is taken out after heat treatment 45min spare；
(3) by step (2), treated that calcium carbonate is immersed in silane coupler modified liquid, takes out after 1.5h, places into temperature
Degree is drying process 2h in 90 DEG C of drying box.
Further, silane coupler modified liquid described in step (3) by following parts by weight material composition: 20 parts
Silane coupling agent, 75 parts of ethylene glycol, 12 parts of deionized waters.
Comparative example 1
This comparative example 1 compared with Example 2, with etc. mass parts nanometer aluminium powder replace nano metal compound additive at
Point, method and step in addition to this is all the same.
Comparative example 2
This comparative example 2 compared with Example 2, eliminates nano metal compound additive ingredient, method and step in addition to this
It is all the same.
Comparative example 3
This comparative example 3 compared with Example 2, with etc. the commercially available calcium carbonate of mass parts replace filler ingredient, side in addition to this
Method step is all the same.
Comparative example 4
This comparative example 4 compared with Example 2, eliminates filler ingredient, and method and step in addition to this is all the same.
Control group
Existing commercially available ABS product coloring pigment master batch.
In order to compare effect of the present invention, by above-described embodiment 2, comparative example 1, comparative example 2, comparative example 3,
The corresponding pigment master batch of comparative example 4, control group in ABS resin processing and fabricating, do not do ABS resin by when production
Dry processing, the weight percent of pigment master batch addition are 3%, and wherein the pigment in pigment master batch selects Shanghai victory rainbow pigment chemical industry
The C.I.P.R.48:2 red pigment of industry and trade Development Co., Ltd of group production, after the completion to ABS film sample made of each group blown film
Product are tested for the property, and specific correlation data is as shown in table 1 below:
Table 1
Note: optical density described in upper table 1 is the characterization that pigment covers force characteristic, specifically first measures the transmission of sample thin film
Rate, and it is converted into the OD value of standard film thickness (0.02mm), the inverse of transmissivity represents the ability of film barrier light, claims
For light resistance rate O, O=I0 / I1, optical density D=lgO, wherein I0It is incident intensity, I1It is transmitted intensity；OD value is bigger
It is higher to represent covering power.
Nano metal pigment master batch produced by the present invention can be obviously improved to ABS resin product it can be seen from upper table 1
Coloring effect, have good value for applications.
Claims (10)
1. a kind of high-stability nano metallic pigments master batch, which is characterized in that be made of the substance of following parts by weight:
30 ~ 50 parts of carriers, 60 ~ 70 parts of pigment, 5 ~ 8 parts of nano metal compound additives, 4 ~ 9 parts of dispersing agents, 0.1 ~ 1 part of thermostabilization
Agent, 0.1 ~ 0.5 part of ultraviolet absorbing agent, 1 ~ 3 part of lubricant, 20 ~ 25 parts of fillers.
2. a kind of high-stability nano metallic pigments master batch according to claim 1, which is characterized in that by following parts by weight
Substance be made:
40 parts of carriers, 65 parts of pigment, 7 parts of nano metal compound additives, 8 parts of dispersing agents, 0.5 part of heat stabilizer, 0.3 part it is ultraviolet
Light absorbers, 2 parts of lubricants, 23 parts of fillers.
3. a kind of high-stability nano metallic pigments master batch according to claim 1 or 2, which is characterized in that the load
Body is maleic anhydride grafted polyethylene, acrylonitritrile-styrene resin, any one in ethylene-octene copolymer.
4. a kind of high-stability nano metallic pigments master batch according to claim 1 or 2, which is characterized in that the face
Material is the mixture of inorganic pigment, organic pigment or both.
5. a kind of high-stability nano metallic pigments master batch according to claim 1 or 2, which is characterized in that described receives
The preparation method of rice metal composite additive includes the following steps:
(1) nanometer aluminium powder, nano indium oxide particle and nano-cobalt powder are mixed according to 7 ~ 9:1 of weight ratio ~ 2:3 ~ 5, is obtained mixed
It is spare to close powder；
(2) it is water-soluble for 0.2 ~ 0.4% collagen that step (1) resulting mixed powder is put into the mass fraction of 2 ~ 4 times of its gross mass
In liquid, adjusting whole pH value is 5.0 ~ 5.5, with centrifugal filtration after 2000 ~ 2400 revs/min of 8 ~ 10h of revolving speed stir process, then
It is spare after being dried under conditions of being put in 40 ~ 45 DEG C；
(3) methanol-water for being 40 ~ 50% by the volume fraction of step (2) treated mixed powder puts into 8 ~ 10 times of its gross mass
In solution, ultrasonic vibration handles 3 ~ 5min, is then warming up to 55 ~ 60 DEG C under nitrogen protection, is added such as into methanol aqueous solution
The substance of lower corresponding molal volume ratio: the nitre of the methyl methacrylate monomer of 0.3 ~ 0.4mol/L, 0.005 ~ 0.008mol/L
The azodiisobutyronitrile of sour lanthanum, 0.01 ~ 0.015mol/L, is then stirred continuously 7 ~ 9h of reaction, is finally put into vacuum steaming
It is successively evaporated in vacuo in hair equipment, film collection, pulverization process, takes out to obtain nano metal compound additive after the completion.
6. a kind of high-stability nano metallic pigments master batch according to claim 5, which is characterized in that institute in step (3)
Pressure when the vacuum evaporation processing stated in control vacuum evaporation apparatus is 1 × 10-4 ~ 2×10-4 Pa, the temperature control of evaporation
It is 1300 ~ 1360 DEG C；Film film used when collecting is made of ABS resin, and film is first cooled to -120 in advance before collecting processing
~-130℃；The particle diameter of nano metal compound additive after pulverization process is not more than 6mm.
7. a kind of high-stability nano metallic pigments master batch according to claim 1 or 2, which is characterized in that point
Powder is oxidized polyethylene wax, any one in maleic anhydride grafted polyethylene wax；The heat stabilizer is sulfur-bearing antioxygen
Any one in agent, phosphite antioxidant.
8. a kind of high-stability nano metallic pigments master batch according to claim 1 or 2, which is characterized in that the purple
Ultraviolet absorbers are Ultraviolet Absorber UV-P, any one in ultraviolet absorbing agent UV-O；The lubricant is all scholars
Any one in woods, silicone oil.
9. a kind of high-stability nano metallic pigments master batch according to claim 1 or 2, which is characterized in that described fills out
Material is modified calcium carbonate, and the preparation method of the modified calcium carbonate includes the following steps:
(1) first by calcium carbonate be put into mass fraction be 5 ~ 8% citric acid in 10 ~ 15min of immersion treatment, spent after taking-up from
Sub- water is spare after rinsing one time；
(2) by step (1), treated that calcium carbonate is put into high temperature furnace heats, control the temperature in high temperature furnace be 320 ~
360 DEG C, heat 40 ~ 45min after take out it is spare；
(3) by step (2), treated that calcium carbonate is immersed in silane coupler modified liquid, takes out, places into after 1 ~ 1.5h
1 ~ 2h is dried in the drying box that temperature is 85 ~ 90 DEG C.
10. a kind of high-stability nano metallic pigments master batch according to claim 9, which is characterized in that institute in step (3)
The silane coupler modified liquid stated by following parts by weight material composition: 15 ~ 20 parts of silane coupling agents, 70 ~ 75 parts of ethylene glycol, 8 ~
12 parts of deionized waters.
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1554713A (en) * | 2003-12-24 | 2004-12-15 | 东南大学 | Collagen base nano infrared low emissivity colouring pigment and preparing method |
| JP2006022143A (en) * | 2004-07-06 | 2006-01-26 | Tokyo Printing Ink Mfg Co Ltd | Color master batch for thermoplastic resin and its manufacturing method |
| CN101121806A (en) * | 2006-08-11 | 2008-02-13 | 广州市波斯塑胶颜料有限公司 | ABS color master batch with increased color stability and preparation method thereof |
| CN101691438A (en) * | 2009-09-22 | 2010-04-07 | 广州市波斯塑胶颜料有限公司 | ABS color master batch |
| CN101967298A (en) * | 2010-07-14 | 2011-02-09 | 山东海泽纳米材料有限公司 | Novel nano calcium carbonate used for plastic film and preparation method thereof |
-
2018
- 2018-06-11 CN CN201810592579.3A patent/CN108976688A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1554713A (en) * | 2003-12-24 | 2004-12-15 | 东南大学 | Collagen base nano infrared low emissivity colouring pigment and preparing method |
| JP2006022143A (en) * | 2004-07-06 | 2006-01-26 | Tokyo Printing Ink Mfg Co Ltd | Color master batch for thermoplastic resin and its manufacturing method |
| CN101121806A (en) * | 2006-08-11 | 2008-02-13 | 广州市波斯塑胶颜料有限公司 | ABS color master batch with increased color stability and preparation method thereof |
| CN101691438A (en) * | 2009-09-22 | 2010-04-07 | 广州市波斯塑胶颜料有限公司 | ABS color master batch |
| CN101967298A (en) * | 2010-07-14 | 2011-02-09 | 山东海泽纳米材料有限公司 | Novel nano calcium carbonate used for plastic film and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 曹玉廷: "钙塑建筑材料中添加柠檬酸后的理化性能研究" * |
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