CN108975800A - A kind of premixing mortar and preparation method thereof blending domestic garbage burning electricity generation bottom ash - Google Patents

A kind of premixing mortar and preparation method thereof blending domestic garbage burning electricity generation bottom ash Download PDF

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Publication number
CN108975800A
CN108975800A CN201811162515.6A CN201811162515A CN108975800A CN 108975800 A CN108975800 A CN 108975800A CN 201811162515 A CN201811162515 A CN 201811162515A CN 108975800 A CN108975800 A CN 108975800A
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CN
China
Prior art keywords
waste residue
water
electricity generation
blending
domestic garbage
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201811162515.6A
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Chinese (zh)
Inventor
董云
刘畅
邹易君
王敏
彭宁波
张国瀛
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Nanjing Tech University
Huaiyin Institute of Technology
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Nanjing Tech University
Huaiyin Institute of Technology
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Application filed by Nanjing Tech University, Huaiyin Institute of Technology filed Critical Nanjing Tech University
Priority to CN201811162515.6A priority Critical patent/CN108975800A/en
Publication of CN108975800A publication Critical patent/CN108975800A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B20/00Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups C04B14/00 - C04B18/00 and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups C04B14/00 - C04B18/00 specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials
    • C04B20/02Treatment
    • C04B20/023Chemical treatment
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/50Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Processing Of Solid Wastes (AREA)

Abstract

The invention discloses a kind of premixing mortars and preparation method for blending domestic garbage burning electricity generation waste residue, domestic garbage burning electricity generation waste residue is carried out the processing such as to smash and grind, classification obtains the recycled aggregate sand of substitution yellow sand and replaces the regenerative micro powder of flyash, part of cement, the premixing mortar requisite quality of production.Thoroughly solve house refuse power generation waste residue all of, fully achieve " zero " discharge target, develop high added value tailings product;The production cost of Concrete Enterprises premixing mortar is also reduced simultaneously.

Description

A kind of premixing mortar and preparation method thereof blending domestic garbage burning electricity generation bottom ash
Technical field
The present invention relates to solid waste recycling and reusing fields, and in particular to utilizes domestic garbage burning electricity generation waste residue system The method and product of standby premixing mortar.
Background technique
With the fast development of China's Development of China's Urbanization, the yield of domestic waste is constantly promoted.By 2017 Bottom, the storage of China's domestic waste are still increased every year with 5%~8% speed more than 8,000,000,000 tons, how innoxious place House refuse is managed, solves the problems, such as that rubbish surrounds city, garbage environment pollution has become current urgent problem to be solved.
The common method of China's processing domestic waste has sanitary landfills, burning disposal, compost, anaerobic digestion etc., The processing of middle consumer waste incineration has minimizing, innoxious, recycling compared to other processing modes, without long-term responsibility and just The prompt advantage for efficiently waiting five aspects.The especially emergence of mechanical kiln grate furnace and fluidization in recent years is waste incineration skill The development of art creates advantage, promotes the development of incineration treatment of garbage technology.The product generated after waste incineration is called Lime-ash.Lime-ash collects source by it, is generally divided into 3 classes: bottom ash, cigarette ash purification system flying dust and mixing bottom ash.Bottom ash, which refers to, burns The residue being discharged after burning from siege tail end, quality accounts for about 80% or so of lime-ash gross weight, therefore it is the main component of lime-ash, So lime-ash is generally defaulted as bottom ash.The bottom ash quality that domestic garbage burning electricity generation generates only has the 20% of original rubbish quality ~30%, volume only accounts for 10% or so of original volumes, tentatively realizes the purpose of minimizing.But how house refuse to be burnt Burning bottom ash (hereinafter referred to as " bottom ash ") further resource utilization is the topic that people widely pay close attention to.
We need to take scientific and reasonable measure to be allowed to turn waste into wealth to handle and utilize these rubbish, for our institutes It utilizes.The waste residue that the power generation of digestion process house refuse generates how is carried out, the efficient utilization of this part waste residue is realized, researchs and develops High added value tailings product fully achieves the target of waste-to-energy plant waste residue " zero " discharge, it has also become house refuse power generation The necessity that enterprise improves benefit with social harmonious development.
Summary of the invention
The technical problem to be solved in the present invention is to provide a kind of premixing mortar systems for blending domestic garbage burning electricity generation waste residue Preparation Method, crushing grinding house refuse power generation bottom ash are allocated as replacing the recycled aggregate sand of yellow ground and replace flyash, part of cement Regenerative micro powder, premixing mortar is made, resistance to compression, flexural strength can be guaranteed, and it is useless to not only solve house refuse power generation The processing problem of slag, while also saving the production cost of premixing mortar.
The invention is realized by the following technical scheme:
A kind of premixing mortar preparation method blending domestic garbage burning electricity generation waste residue, comprising the following steps:
1) by house refuse power generation waste residue drying 12h to constant weight, it is crushed waste residue partial size≤5mm, 1~5mm's of separation screening partial size Waste residue is that recycled aggregate is husky, and the polymerization of the activity excitant of its quality 2~3 ‰, 0.5~1 ‰ is added in the waste residue of partial size < 1mm Polyol grinding aids are ground, and obtain fineness up to the regenerative micro powder of 6000~7000 mesh, exciting agent includes mass ratio 1:2~3 Triacetic acid ammonium and sodium chloride mix;
2) regenerative micro powder, cement, recycled aggregate sand, water-reducing agent and tackifier are weighed by following mass ratio:
0.15~0.25 part of regenerative micro powder
0.75~0.85 part of cement
2~3 parts of recycled aggregate sand
1~2 part of water-reducing agent
0.5~1 part of tackifier
Excess water;
3) regenerative micro powder of above-mentioned weighing, cement, recycled aggregate sand are poured into blender, is stirred evenly, then pour into weighing Water-reducing agent, regulator and the common mix of water are uniform, obtain premixing mortar.
House refuse power generation waste residue crushing grinding, a part are allocated as recycled aggregate sand and replace yellow ground, and another part is added special The activity excitant and grinding aid of system, which are further ground, is made regenerative micro powder, replaces flyash and part of cement, is applied to premixing Mortar, thus realize house refuse power generation waste residue all of.
Can exploitation house refuse power generation waste residue be applied in premixing mortar, realize sufficiently grinding for house refuse power generation waste residue Mill, reaches the activity of corresponding fine grinding degree and admixture product, this answers the later period of house refuse power generation waste residue admixture With conclusive influence will be generated, develops specific grinding aid and activity excitant is critical problem.If not adding this grinding aid Agent need to extend milling time 40% and just reach required fineness, and not add the waste residue gelation activity only up to 50% or so of activity excitant, Be added this activity excitant activity can >=70%.
The present invention is further improved scheme, the water-reducing agent be lignin sulfonate or Ppolynuclear aromatic salt or Water-soluble resin Sulfonates.
The further improvement project of the present invention is that the drying of step (1) house refuse power generation waste residue removes iron power removing after being crushed.
The present invention also provides prepare resulting blending house refuse power generation according to method either described in claims 1 to 3 The premixing mortar of waste residue.
Compared with prior art, the present invention having following obvious advantage:
The present invention smash and grind etc. processing to house refuse power generation waste residue, classification obtain the recycled aggregate sand of substitution yellow ground with Replace the regenerative micro powder of flyash, part of cement, the premixing mortar requisite quality of production.It is useless thoroughly to solve house refuse power generation Slag all of, fully achieve " zero " discharge target, develop high added value tailings product;Concrete is also reduced simultaneously The production cost of enterprise's premixing mortar.
Specific embodiment
The present invention is further elaborated with below by embodiment.
Embodiment 1
The premixing mortar preparation method of blending domestic garbage burning electricity generation waste residue of the invention, comprising the following steps:
1) by house refuse power generation waste residue, drying to constant weight, is crushed waste residue partial size≤5mm, the waste residue of 1~5mm of separation screening partial size For recycled aggregate sand, the polymerized polyalcohol grinding aid of the activity excitant of its quality 2 ‰, 1 ‰ is added in the waste residue of partial size < 1mm It is ground, obtains fineness up to the regenerative micro powder of 6000~7000 mesh, exciting agent includes the triacetic acid ammonium and chlorine of mass ratio 1:2 Change sodium to mix;
2) regenerative micro powder, cement, recycled aggregate sand, water-reducing agent and tackifier are weighed by following mass ratio:
0.2 part of regenerative micro powder
0.8 part of cement
Recycled aggregate is 3 parts husky
1 part of water-reducing agent
1 part of tackifier
Water surplus;
3) regenerative micro powder of above-mentioned weighing, cement, recycled aggregate sand are poured into blender, is stirred evenly, then pour into weighing Water-reducing agent, regulator and the common mix of water are uniform, obtain premixing mortar.
Embodiment 2
1) house refuse power generation waste residue drying is made into its moisture content≤0.5%, is crushed waste residue partial size≤5mm, separation screening partial size 1 The waste residue of~5mm be recycled aggregate sand, the waste residue of partial size < 1mm be added the activity excitant of its quality 3 ‰, 1 ‰ polymerization it is more First alcohol grinding aid is ground, and obtains fineness up to the regenerative micro powder of 6000~7000 mesh, exciting agent includes the three of mass ratio 1:3 Ammonium acetate and sodium chloride mix;
2) regenerative micro powder, cement, recycled aggregate sand, water-reducing agent and tackifier are weighed by following mass ratio:
0.15 part of regenerative micro powder
0.85 part of cement
Recycled aggregate is 3 parts husky
1.5 parts of water-reducing agent
0.5 part of tackifier
Water surplus;
3) regenerative micro powder of above-mentioned weighing, cement, recycled aggregate sand are poured into blender, is stirred evenly, then pour into weighing Water-reducing agent, regulator and the common mix of water are uniform, obtain premixing mortar.
Embodiment 3
1) house refuse power generation waste residue drying is made into its moisture content≤0.5%, is crushed waste residue partial size≤5mm, separation screening partial size 1 The waste residue of~5mm is that recycled aggregate is husky, the waste residue of partial size < 1mm be added the activity excitant of its quality 3 ‰, 1 ‰ polymerization it is more First alcohol grinding aid is ground, and obtains fineness up to the regenerative micro powder of 6000~7000 mesh, exciting agent includes the three of mass ratio 1:1.5 Ammonium acetate and sodium chloride mix;
2) regenerative micro powder, cement, recycled aggregate sand, water-reducing agent and tackifier are weighed by following mass ratio:
0.25 part of regenerative micro powder
0.75 part of cement
Recycled aggregate is 2 parts husky
2 parts of water-reducing agent
0.5 part of tackifier
Water surplus;
3) regenerative micro powder of above-mentioned weighing, cement, recycled aggregate sand are poured into blender, is stirred evenly, then pour into weighing Water-reducing agent, regulator and the common mix of water are uniform, obtain premixing mortar.
Comparative example 1
Grinding aid is not added in embodiment 1, remaining implementation is identical.
Comparative example 2
Activity excitant is not added in embodiment 1, remaining implementation is identical.
Comparative example 3
The preparation of conventional premixing mortar, slurry take 0.2 part of flyash, 1 part of cement, 3 parts of yellow ground pour into blender and stir evenly, then fall Enter water-reducing agent, tackifier and water stir evenly it is obtained.
Example 1-3 and comparative example 1-3 is made 40mm × 40mm × 160mm test block and resists after standard curing 28 days Pressure, flexural strength detection, performance such as table 1:
Compared with comparative example 3, product resistance to compression, flexural strength performance are not much different embodiment 1, but because house refuse power generation waste residue without Cost of material, cost mainly handle transportation cost, it is per ton it is minimum can produce 15 yuan of economy cost or more, key is reality The high-efficiency resource recycling for having showed house refuse power generation waste residue avoids environmental pollution caused by simple utilize, reduces nature bone The natural resources and energy consumption of material exploitation and manufacture of cement.
Example 1 is compared with comparative example 1, and because of the addition of no grinding aid, milling time, which adds to be twice, is also difficult to reach required thin Degree, not only wastes electric power resource, and this resistance to compression, flexural strength are significantly poor.
Embodiment 1 is compared with comparative example 2, and because not adding the waste residue activity only up to 50% or so of activity excitant, resistance to compression resists Roll over intensity it is poor, and embodiment 1 be added this activity excitant activity can >=70%.

Claims (4)

1. a kind of premixing mortar preparation method for blending domestic garbage burning electricity generation bottom ash, which comprises the following steps:
1) house refuse power generation bottom ash is dried into 12h to constant weight, is crushed waste residue partial size≤5mm, separation screens out 1~5mm of partial size Waste residue be recycled aggregate sand, the bottom ash of partial size < 1mm be added the activity excitant of its quality 2~3 ‰, 0.5~1 ‰ it is poly- It closes polyol grinding aids to be ground, obtains fineness up to the bottom ash regenerative micro powder of 6000~7000 mesh, exciting agent includes mass ratio The triacetic acid ammonium and sodium chloride of 1:2~3 mix;
2) regenerative micro powder, cement, recycled aggregate sand, water-reducing agent and tackifier are weighed by following mass ratio:
0.15~0.25 part of regenerative micro powder
0.75~0.85 part of cement
2~3 parts of recycled aggregate sand
1~2 part of water-reducing agent
0.5~1 part of tackifier
Excess water;
3) regenerative micro powder of above-mentioned weighing, cement, recycled aggregate sand are poured into blender, is stirred evenly, then pour into weighing Water-reducing agent, regulator and the common mix of water are uniform, obtain premixing mortar.
2. a kind of premixing mortar preparation method for blending domestic garbage burning electricity generation waste residue according to claim 1, special Sign is: the water-reducing agent is lignin sulfonate or Ppolynuclear aromatic salt or water-soluble resin Sulfonates.
3. a kind of premixing mortar preparation method for blending domestic garbage burning electricity generation waste residue according to claim 1, special Sign is: the drying of step (1) house refuse power generation waste residue removes iron power removing after being crushed.
4. preparing the resulting premixing for blending domestic garbage burning electricity generation waste residue according to method either described in claims 1 to 3 Mortar.
CN201811162515.6A 2018-09-30 2018-09-30 A kind of premixing mortar and preparation method thereof blending domestic garbage burning electricity generation bottom ash Pending CN108975800A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110228973A (en) * 2019-06-13 2019-09-13 淮阴工学院 A kind of burning city domestic garbage bottom ash regeneration method for preparing mortar
CN110981323A (en) * 2019-11-21 2020-04-10 淮阴工学院 High-ductility cement-based material regenerated from waste incineration bottom slag and preparation method thereof
CN111348880A (en) * 2020-03-27 2020-06-30 福州大学 Domestic garbage incinerator slag alkali slag aerated concrete building block and preparation method thereof
CN111499310A (en) * 2020-05-15 2020-08-07 南宁市吉发环保科技有限公司 Method for producing dry powder mortar by recycling waste incineration slag

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20070066129A (en) * 2005-12-21 2007-06-27 박의신 Insulation, soundproof and quake proof self leveling mortar
CN103496895A (en) * 2013-09-18 2014-01-08 桑德环境资源股份有限公司 Method for producing baking-free bricks by utilizing solid waste
CN103864363A (en) * 2014-02-10 2014-06-18 安徽众凯架业有限责任公司 Corrosion-resistant thermal insulation mortar and manufacturing method thereof
CN104529273A (en) * 2014-12-09 2015-04-22 李松涛 Novel waterproof thermal-insulation mortar containing household garbage burning ash
CN106830777A (en) * 2016-12-19 2017-06-13 深圳广田集团股份有限公司 Regeneration fill concrete and its application prepared by consumer waste incineration residue

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20070066129A (en) * 2005-12-21 2007-06-27 박의신 Insulation, soundproof and quake proof self leveling mortar
CN103496895A (en) * 2013-09-18 2014-01-08 桑德环境资源股份有限公司 Method for producing baking-free bricks by utilizing solid waste
CN103864363A (en) * 2014-02-10 2014-06-18 安徽众凯架业有限责任公司 Corrosion-resistant thermal insulation mortar and manufacturing method thereof
CN104529273A (en) * 2014-12-09 2015-04-22 李松涛 Novel waterproof thermal-insulation mortar containing household garbage burning ash
CN106830777A (en) * 2016-12-19 2017-06-13 深圳广田集团股份有限公司 Regeneration fill concrete and its application prepared by consumer waste incineration residue

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110228973A (en) * 2019-06-13 2019-09-13 淮阴工学院 A kind of burning city domestic garbage bottom ash regeneration method for preparing mortar
CN110981323A (en) * 2019-11-21 2020-04-10 淮阴工学院 High-ductility cement-based material regenerated from waste incineration bottom slag and preparation method thereof
CN111348880A (en) * 2020-03-27 2020-06-30 福州大学 Domestic garbage incinerator slag alkali slag aerated concrete building block and preparation method thereof
CN111499310A (en) * 2020-05-15 2020-08-07 南宁市吉发环保科技有限公司 Method for producing dry powder mortar by recycling waste incineration slag

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Application publication date: 20181211