CN108970606A - A kind of dynamic interception stainless steel wire Bi2WO6The preparation method of devitrified glass modification - Google Patents

A kind of dynamic interception stainless steel wire Bi2WO6The preparation method of devitrified glass modification Download PDF

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Publication number
CN108970606A
CN108970606A CN201810827233.7A CN201810827233A CN108970606A CN 108970606 A CN108970606 A CN 108970606A CN 201810827233 A CN201810827233 A CN 201810827233A CN 108970606 A CN108970606 A CN 108970606A
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CN
China
Prior art keywords
steel wire
stainless steel
devitrified glass
dynamic interception
preparation
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Pending
Application number
CN201810827233.7A
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Chinese (zh)
Inventor
张迎晨
吴红艳
王保生
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Nanjing West Europe Environmental Technology Co Ltd
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Nanjing West Europe Environmental Technology Co Ltd
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Priority to CN201810827233.7A priority Critical patent/CN108970606A/en
Publication of CN108970606A publication Critical patent/CN108970606A/en
Pending legal-status Critical Current

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24Chromium, molybdenum or tungsten
    • B01J23/31Chromium, molybdenum or tungsten combined with bismuth
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/007Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by irradiation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86Catalytic processes
    • B01D53/8678Removing components of undefined structure
    • B01D53/8687Organic components
    • B01J35/39
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C10/00Devitrified glass ceramics, i.e. glass ceramics having a crystalline phase dispersed in a glassy phase and constituting at least 50% by weight of the total composition
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24HEATING; RANGES; VENTILATING
    • F24CDOMESTIC STOVES OR RANGES ; DETAILS OF DOMESTIC STOVES OR RANGES, OF GENERAL APPLICATION
    • F24C15/00Details
    • F24C15/20Removing cooking fumes
    • F24C15/2035Arrangement or mounting of filters
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/70Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
    • B01D2257/708Volatile organic compounds V.O.C.'s
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2259/00Type of treatment
    • B01D2259/80Employing electric, magnetic, electromagnetic or wave energy, or particle radiation
    • B01D2259/802Visible light
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2207/00Compositions specially applicable for the manufacture of vitreous enamels
    • C03C2207/04Compositions specially applicable for the manufacture of vitreous enamels for steel
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/20Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters

Abstract

The invention discloses an a kind of dynamic interception stainless steel wire Bi2WO6The preparation method of devitrified glass modification, belongs to cooking fume purification handling technical field, includes the following steps: to prepare Bi2WO6Devitrified glass micro mist;Using the surface of thermal spraying treatment dynamic interception stainless steel wire, Bi is made2WO6Devitrified glass glaze paint dynamic interception stainless steel wire;By Bi2WO6Devitrified glass glaze paint dynamic interception is placed on dynamic interception device with stainless steel wire, realizes Bi2WO6The automatically cleaning of devitrified glass glaze paint dynamic interception stainless steel wire and the function of degradation VOC.The present invention takes full advantage of the thermal energy and luminous energy of fume purifying hearth itself, energy conservation and environmental protection, multi-purpose content, simple process.

Description

A kind of dynamic interception stainless steel wire Bi2WO6The preparation method of devitrified glass modification
Technical field
The present invention relates to a kind of Bi2WO6The preparation method of devitrified glass modification, more particularly to a kind of dynamic interception with not Become rusty steel wire Bi2WO6The preparation method of devitrified glass modification, belongs to cooking fume purification handling technical field.
Background technique
Contain a large amount of pollutant in oil flue waste gas caused by the occasions such as food and drink culinary art, industrial treatment, for protection ring Border resource, these oil flue waste gas can be just discharged into air after having to pass through purified treatment, traditional oil smoke air cleaning facility Purifying rate it is often lower, the air being discharged after purified treatment still contains a large amount of oil smoke and other pollutant components, leads The PM2.5 index in air is caused to increase.
It has been proved by practice that dynamic interception fume purifier of fume is arranged at the air intake of oil smoke air cleaning facility front end It is a kind of effective means for improving interception rate, the oil smoke air cleaning unit of the prior art is mainly by a spider and from this Several spokes that cartridge radially outward radiates are constituted, and when work, the power drive unit of oil smoke air cleaning facility passes through center The rotation of spoke described in dish driving so that into the solid particle impingements such as oil smoke in oil smoke air cleaning facility on spoke after by It is thrown away outward in centrifugal action, a large amount of oil smoke and pollutant can be intercepted, effectively improve fume purifying rate, however, inventor exists Implement to find during the application, the dynamic interception fume purifier of fume of the prior art, oil smoke interception rate is still not up to ideal Effect.
Bi2WO6It is a kind of typical n-type semiconductor, forbidden bandwidth 2.75eV, it is by Bi2O22+ layers and WO42- The perovskite lamellar structure that layer is alternately formed along c-axis, has in electrode material, solar energy conversion, catalyst etc. and widely answers With having there is document report: Kudo and Hiji discovery Bi2WO6Photochemical catalyst has photocatalysis and Zou etc. to the development of O2 It was found that the organic compound that can degrade under visible light, as a kind of novel semiconductor material, Bi2WO6Catalysis material is ground A new approach will be opened up for photocatalysis removal and degradable organic pollutant by studying carefully, and be had in terms of the depollution of environment and new energy development There is very important practical value, due to Bi2WO6Itself there is special layer structure, narrow forbidden bandwidth can be adequately sharp With sunlight, so research Bi2WO6Catalysis material improves its utilization to sunlight, new to curbing environmental pollution and developing Have great importance in terms of the energy.
It is well known that effective photocatalytic process needs to have following condition: the high migration of light induced electron and hole Rate;Direct visible light catalytic effect;Suitable bandwidth;To the high absorption capacity of organic pollutant, it is considered that, light is urged Changing the precondition that reaction occurs is that receptor potential is lower than semiconductor conduction band potential, higher than semiconductor valence band potential for bulk potential, The migration of effective photo-generated charge carriers could be obtained in this way.
Dynamic interception spoke surfaces finish is huge on intercepting efficiency influence, and accordingly, inventor proposes: dynamic interception is not with Become rusty steel wire Bi2WO6The preparation method method of devitrified glass modification, by Bi2WO6Devitrified glass glaze paint dynamic interception stainless steel wire It is placed in dynamic interception device, realizes Bi2WO6The automatically cleaning of devitrified glass glaze paint dynamic interception stainless steel wire and the function of degradation VOC Can, Bi2WO6Devitrified glass glaze paint is bright and clean, is conducive to the centrifugal clarification of greasy dirt.The present invention makes full use of fume purifying hearth itself Thermal energy, luminous energy, energy conservation and environmental protection, multi-purpose content, simple process.
Summary of the invention
The main object of the present invention is to provide for a kind of thermal energy using fume purifying hearth itself and luminous energy preparation is dynamic State, which intercepts, uses stainless steel wire Bi2WO6The method of devitrified glass modification, not only energy conservation and environmental protection, but also simple process.
The purpose of the present invention can reach by using following technical solution:
A kind of dynamic interception stainless steel wire Bi2WO6The preparation method of devitrified glass modification, includes the following steps:
Step 1: preparation Bi2WO6Devitrified glass micro mist;
Step 2: using the surface of thermal spraying treatment dynamic interception stainless steel wire, Bi is made2WO6Devitrified glass glaze paint is dynamic Stainless steel wire is used in state interception;
Step 3: by Bi2WO6Devitrified glass glaze paint dynamic interception is placed on dynamic interception device with stainless steel wire, is realized Bi2WO6The automatically cleaning of devitrified glass glaze paint dynamic interception stainless steel wire and the function of degradation VOC.
Further, in the step 1, Bi is prepared2WO6The granularity of devitrified glass micro mist is in 0.1-10um.
Further, in the step 1, Bi is prepared2WO6The granularity of devitrified glass micro mist is in 1.0um.
Further, in the step 1, Bi is prepared2WO6The granularity of devitrified glass micro mist is in 0.5um.
Further, in the step 1, Bi2WO6The specific component of devitrified glass micro mist can be Bi2WO6Devitrified glass, It is also possible to B2O3Bi2O3WO3Or graphene mixes Li2B4O7Bi2WO6One of and their modification component.
Further, in the step 1, modified component can be Bi2WO6/BiVO4/ carbon nanotube or Bi2WO6/BiVO4/ Coconut carbon.
Further, in the step 2, using the surface of thermal spraying treatment dynamic interception stainless steel wire, by Bi2WO6It is micro- Crystal glass powder thermal jet is coated onto the surface of dynamic interception stainless steel wire, and Bi is made2WO6Devitrified glass glaze paint dynamic interception is with stainless Steel wire.
Further, in the step 2, using the surface of thermal spraying treatment dynamic interception stainless steel wire, at thermal spraying Reason method can be plasma spray coating supersonic spray coating living.
Further, in the step 3, Bi2WO6Devitrified glass glaze paint is bright and clean, is conducive to the centrifugal clarification of greasy dirt.
Advantageous effects of the invention: dynamic interception provided by the invention stainless steel wire Bi2WO6Devitrified glass modification Preparation method, by Bi2WO6Microcrystalline glass powder thermal jet is coated onto dynamic interception and Bi is made with stainless steel wire surface2WO6Devitrified glass Glaze paint dynamic interception stainless steel wire, by Bi2WO6Devitrified glass glaze paint dynamic interception is placed in dynamic interception device with stainless steel wire, Realize Bi2WO6The automatically cleaning of devitrified glass glaze paint dynamic interception stainless steel wire and the function of explanation VOC, take full advantage of oil smoke The thermal energy and luminous energy of purifying hearth itself, energy conservation and environmental protection, multi-purpose content, simple process.
Specific embodiment
To make the more clear and clear technical solution of the present invention of those skilled in the art, below with reference to embodiment to this hair Bright to be described in further detail, embodiments of the present invention are not limited thereto.
Dynamic interception provided in this embodiment stainless steel wire Bi2WO6The preparation method of devitrified glass modification, including it is as follows Step:
Step 1: preparation Bi2WO6Devitrified glass micro mist prepares Bi2WO6The granularity of devitrified glass micro mist in 0.1-10um, Bi2WO6The specific component of devitrified glass micro mist can be Bi2WO6Devitrified glass is also possible to B2O3Bi2O3WO3Or graphene is mixed Miscellaneous Li2B4O7Bi2WO6One of and their modification component, modified component can be Bi2WO6/BiVO4/ carbon nanotube or Bi2WO6/BiVO4/ coconut carbon;
Step 2: using the surface of thermal spraying treatment dynamic interception stainless steel wire, by Bi2WO6Microcrystalline glass powder thermal spraying To the surface of dynamic interception stainless steel wire, Bi is made2WO6Devitrified glass glaze paint dynamic interception stainless steel wire, thermal spraying treatment Method can be plasma spray coating supersonic spray coating living;
Step 3: by Bi2WO6Devitrified glass glaze paint dynamic interception is placed on dynamic interception device with stainless steel wire, is realized Bi2WO6The automatically cleaning of devitrified glass glaze paint dynamic interception stainless steel wire and the function of degradation VOC, Bi2WO6Devitrified glass glaze paint It is bright and clean, be conducive to the centrifugal clarification of greasy dirt.
Further, detailed such as the following example 1 and embodiment 2:
Embodiment 1:
The dynamic interception stainless steel wire Bi that the present embodiment 1 provides2WO6The preparation method of devitrified glass modification, including it is as follows Step: it prepares graphene and mixes Bi2WO6Microcrystalline glass powder prepares containing graphene to 1um size, using plasma spraying device Mix Bi2WO6Microcrystalline glass powder coats dynamic interception stainless steel wire surface, and graphene is mixed Bi2WO6Devitrified glass glaze paint Dynamic interception is placed in dynamic interception device with stainless steel wire, realizes Bi2WO6Devitrified glass glaze paint dynamic interception stainless steel wire The function of automatically cleaning and degradation VOC, the present embodiment 1 make full use of thermal energy, the luminous energy of fume purifying hearth itself, energy conservation and environmental protection, Multi-purpose content, simple process.
Embodiment 2:
The dynamic interception stainless steel wire Bi that the present embodiment 2 provides2WO6The preparation method of devitrified glass modification, including it is as follows Step: it prepares graphene and mixes Bi2WO6Microcrystalline glass powder prepares containing graphene to 0.5um size, using ultrasonic hot spray apparatus Mix Bi2WO6Microcrystalline glass powder coats dynamic interception stainless steel wire surface, and graphene is mixed Bi2WO6Devitrified glass glaze paint Dynamic interception is placed in dynamic interception device with stainless steel wire, realizes Bi2WO6Devitrified glass glaze paint dynamic interception stainless steel wire The function of automatically cleaning and degradation VOC, the present embodiment 2 make full use of thermal energy, the luminous energy of fume purifying hearth itself, energy conservation and environmental protection, Multi-purpose content, simple process.
In conclusion in the present embodiment, dynamic interception provided in this embodiment stainless steel wire Bi2WO6Devitrified glass is repaired The preparation method of decorations, by Bi2WO6Microcrystalline glass powder thermal jet is coated onto dynamic interception and Bi is made with stainless steel wire surface2WO6Crystallite glass Glass glaze paint dynamic interception stainless steel wire, by Bi2WO6Devitrified glass glaze paint dynamic interception is placed in dynamic interception dress with stainless steel wire It sets, realizes Bi2WO6The automatically cleaning of devitrified glass glaze paint dynamic interception stainless steel wire and the function of explanation VOC, take full advantage of The thermal energy and luminous energy of fume purifying hearth itself, energy conservation and environmental protection, multi-purpose content, simple process.
The above, further embodiment only of the present invention, but scope of protection of the present invention is not limited thereto, and it is any Within the scope of the present disclosure, according to the technique and scheme of the present invention and its design adds those familiar with the art With equivalent substitution or change, protection scope of the present invention is belonged to.

Claims (9)

1. a kind of dynamic interception stainless steel wire Bi2WO6The preparation method of devitrified glass modification, which is characterized in that including walking as follows It is rapid:
Step 1: preparation Bi2WO6Devitrified glass micro mist;
Step 2: using the surface of thermal spraying treatment dynamic interception stainless steel wire, Bi is made2WO6Devitrified glass glaze paint dynamic is blocked It cuts and uses stainless steel wire;
Step 3: by Bi2WO6Devitrified glass glaze paint dynamic interception is placed on dynamic interception device with stainless steel wire, realizes Bi2WO6It is micro- The automatically cleaning of crystal glass glaze paint dynamic interception stainless steel wire and the function of degradation VOC.
2. a kind of dynamic interception stainless steel wire Bi according to claim 12WO6The preparation method of devitrified glass modification, It is characterized in that, in the step 1, prepares Bi2WO6The granularity of devitrified glass micro mist is in 0.1-10um.
3. a kind of dynamic interception stainless steel wire Bi according to claim 22WO6The preparation method of devitrified glass modification, It is characterized in that, in the step 1, prepares Bi2WO6The granularity of devitrified glass micro mist is in 1.0um.
4. a kind of dynamic interception stainless steel wire Bi according to claim 22WO6The preparation method of devitrified glass modification, It is characterized in that, in the step 1, prepares Bi2WO6The granularity of devitrified glass micro mist is in 0.5um.
5. a kind of dynamic interception stainless steel wire Bi according to claim 22WO6The preparation method of devitrified glass modification, It is characterized in that, in the step 1, Bi2WO6The specific component of devitrified glass micro mist can be Bi2WO6Devitrified glass is also possible to B2O3Bi2O3WO3Or graphene mixes Li2B4O7Bi2WO6One of and their modification component.
6. a kind of dynamic interception stainless steel wire Bi according to claim 52WO6The preparation method of devitrified glass modification, It is characterized in that, in the step 1, modified component can be Bi2WO6/BiVO4/ carbon nanotube or Bi2WO6/BiVO4/ coconut carbon.
7. a kind of dynamic interception stainless steel wire Bi according to claim 12WO6The preparation method of devitrified glass modification, It is characterized in that, in the step 2, using the surface of thermal spraying treatment dynamic interception stainless steel wire, by Bi2WO6Microcrystalline glass powder Thermal jet is coated onto the surface of dynamic interception stainless steel wire, and Bi is made2WO6Devitrified glass glaze paint dynamic interception stainless steel wire.
8. a kind of dynamic interception stainless steel wire Bi according to claim 12WO6The preparation method of devitrified glass modification, It is characterized in that, in the step 2, using the surface of thermal spraying treatment dynamic interception stainless steel wire, hot spraying method for treatment can To be plasma spray coating supersonic spray coating living.
9. a kind of dynamic interception stainless steel wire Bi according to claim 12WO6The preparation method of devitrified glass modification, It is characterized in that, in the step 3, Bi2WO6Devitrified glass glaze paint is bright and clean, is conducive to the centrifugal clarification of greasy dirt.
CN201810827233.7A 2018-07-25 2018-07-25 A kind of dynamic interception stainless steel wire Bi2WO6The preparation method of devitrified glass modification Pending CN108970606A (en)

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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101716536A (en) * 2009-12-22 2010-06-02 上海大学 Manufacture method of self-cleaning smoke exhaust ventilator guard based on photocatalysis technology
CN102121720A (en) * 2011-03-31 2011-07-13 芦建锋 Light quantum oily fume purifier
CN102963934A (en) * 2012-12-12 2013-03-13 中国科学院上海硅酸盐研究所 Preparation method of bismuth tungstate quantum dot and preparation method of bismuth tungstate quantum dot-graphene composite material
CN104174288A (en) * 2014-08-21 2014-12-03 上海玖富环保科技有限公司 Water curtain and photocatalysis combined oil fume treating equipment
JP2017124393A (en) * 2015-07-31 2017-07-20 Toto株式会社 Photocatalytic material and manufacturing method therefor
CN106999847A (en) * 2014-09-10 2017-08-01 日东电工株式会社 Improved air cleaning system and the method for removing formaldehyde

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101716536A (en) * 2009-12-22 2010-06-02 上海大学 Manufacture method of self-cleaning smoke exhaust ventilator guard based on photocatalysis technology
CN102121720A (en) * 2011-03-31 2011-07-13 芦建锋 Light quantum oily fume purifier
CN102963934A (en) * 2012-12-12 2013-03-13 中国科学院上海硅酸盐研究所 Preparation method of bismuth tungstate quantum dot and preparation method of bismuth tungstate quantum dot-graphene composite material
CN104174288A (en) * 2014-08-21 2014-12-03 上海玖富环保科技有限公司 Water curtain and photocatalysis combined oil fume treating equipment
CN106999847A (en) * 2014-09-10 2017-08-01 日东电工株式会社 Improved air cleaning system and the method for removing formaldehyde
JP2017124393A (en) * 2015-07-31 2017-07-20 Toto株式会社 Photocatalytic material and manufacturing method therefor

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Application publication date: 20181211