CN108951266A - A kind of environmental protective composite paper plate of antimildew and antibacterial and preparation method thereof - Google Patents
A kind of environmental protective composite paper plate of antimildew and antibacterial and preparation method thereof Download PDFInfo
- Publication number
- CN108951266A CN108951266A CN201810922637.4A CN201810922637A CN108951266A CN 108951266 A CN108951266 A CN 108951266A CN 201810922637 A CN201810922637 A CN 201810922637A CN 108951266 A CN108951266 A CN 108951266A
- Authority
- CN
- China
- Prior art keywords
- antimildew
- parts
- antibacterial
- environmental protective
- compound adhesive
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H11/00—Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only
- D21H11/02—Chemical or chemomechanical or chemothermomechanical pulp
- D21H11/04—Kraft or sulfate pulp
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C5/00—Other processes for obtaining cellulose, e.g. cooking cotton linters ; Processes characterised by the choice of cellulose-containing starting materials
- D21C5/005—Treatment of cellulose-containing material with microorganisms or enzymes
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21D—TREATMENT OF THE MATERIALS BEFORE PASSING TO THE PAPER-MAKING MACHINE
- D21D1/00—Methods of beating or refining; Beaters of the Hollander type
- D21D1/20—Methods of refining
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H13/00—Pulp or paper, comprising synthetic cellulose or non-cellulose fibres or web-forming material
- D21H13/36—Inorganic fibres or flakes
- D21H13/46—Non-siliceous fibres, e.g. from metal oxides
- D21H13/50—Carbon fibres
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/63—Inorganic compounds
- D21H17/67—Water-insoluble compounds, e.g. fillers, pigments
- D21H17/675—Oxides, hydroxides or carbonates
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/06—Paper forming aids
Landscapes
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- Microbiology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Dry Formation Of Fiberboard And The Like (AREA)
- Paper (AREA)
Abstract
The invention discloses a kind of environmental protective composite paper plates of antimildew and antibacterial, including raw material below: bleached sulphate softwood pulp, bamboo pulp, carbon fiber slurry, afforestation waste fibre stuff and suitable antimildew and antibacterial compound adhesive；Wherein, the raw material of the antimildew and antibacterial compound adhesive includes sepiolite powder, tea polyphenols and glutinous rice glue.The invention also discloses the preparation methods of the environmental protective composite paper plate of the antimildew and antibacterial.The environmental protective composite paper plate of antimildew and antibacterial prepared by the present invention has good antimildew and antibacterial performance, pass through being used cooperatively for a variety of slurries and antimildew and antibacterial compound adhesive, so that cardboard itself has antimildew and antibacterial performance, without additionally using antisepsis antistaling agent, safe ready, simultaneously as carrying out preparing antimildew and antibacterial compound adhesive using the environment amenable material such as sepiolite powder, tea polyphenols and glutinous rice glue, reduce the pollution caused by article and environment, has a vast market foreground.
Description
Technical field
The present invention relates to pulp technology for making paper, environmental protective composite paper plate of specifically a kind of antimildew and antibacterial and preparation method thereof.
Background technique
Cardboard is also known as paperboard, and be processed by various paper pulp, fiber is interweaved the ground paper page formed, cardboard and paper
Difference is usually distinguished with quantitative and thickness.During cardboard is commonly used in packing article, as boxboard, kraft liner board,
Manila board, white board, dipping unimpregnated liner board etc..
But traditional cardboard is when packing article, usually can due to environmental factor mould growth, in order to reduce
The harm of mould, preservative, the antistaling agent etc. for generalling use chemical reagent preparation carry out antimildew and antibacterial, not only increase people's
Labor intensity is also easy to pollute article and environment.Therefore, it is necessary to design a kind of environmental protective composite paper plate of antimildew and antibacterial.
Summary of the invention
It is above-mentioned to solve the purpose of the present invention is to provide environmental protective composite paper plate of a kind of antimildew and antibacterial and preparation method thereof
The problem of being proposed in background technique.
To achieve the above object, the invention provides the following technical scheme:
A kind of environmental protective composite paper plate of antimildew and antibacterial, including below according to the raw material of parts by weight: bleached sulphate softwood pulp 30-
60 parts, 45-80 parts of bamboo pulp, 1-6 parts of carbon fiber slurry, 3-8 parts of afforestation waste fibre stuff and suitable mould proof anti-
Bacterium compound adhesive；Wherein, the raw material of the antimildew and antibacterial compound adhesive includes sepiolite powder, tea polyphenols and glutinous rice glue.
As a further solution of the present invention: including below according to the raw material of parts by weight: bleached sulphate softwood pulp 36-
45 parts, 52-65 parts of bamboo pulp, 3-5 parts of carbon fiber slurry, 5-7 parts of afforestation waste fibre stuff and suitable mould proof anti-
Bacterium compound adhesive.
As further scheme of the invention: including below according to the raw material of parts by weight: bleached sulphate softwood pulp
40 parts, 60 parts of bamboo pulp, 4 parts of carbon fiber slurry, 6 parts of afforestation waste fibre stuff and suitable antimildew and antibacterial are compound
Glue.
As further scheme of the invention: the preparation method of the carbon fiber slurry is to weigh 170 according to parts by weight
Part water, is added carbon fiber 2-4 parts, is stirred dispersion 6-14 minutes with the mixing speed of 200-600r/min, 80- is then added
800 parts of water is uniformly mixed, then carries out ultrasonic disperse 8-18 minutes with ultrasonic cell disruptor, makes every liter of mixed liquor in illumination
Under floccule less than 18 to get the carbon fiber slurry.
As further scheme of the invention: the preparation method of the afforestation waste fibre stuff is suitable to weigh
The afforestation waste of amount is dried, and mould is added after crushing and carries out spontaneous fermentation processing 20 days, hair at 28 DEG C
Negative pressure filtration is carried out after the completion of ferment, being then fed into disc mill and carrying out defibrination to refining concentration is 3-6%, and cellulose is added in when defibrination
Biological enzyme discongests fiber to soften, up to afforestation waste fibre stuff after the completion of defibrination.
As further scheme of the invention: the preparation method of the antimildew and antibacterial compound adhesive is to weigh according to parts by weight
6 parts of sepiolite powder, 4 parts of tea polyphenols and 4 parts of glutinous rice glue are uniformly mixed, and suitable quantity of water is added and carries out ultraviolet irradiation processing to get described
Antimildew and antibacterial compound adhesive；Wherein, the solid content of the antimildew and antibacterial compound adhesive is 7%-11%；The time of the ultraviolet irradiation processing
For 5-15min, irradiation wavelengths 260-270nm, irradiation distance 120-140mm.
The preparation method of the environmental protective composite paper plate of the antimildew and antibacterial, steps are as follows:
1) bleached sulphate softwood pulp and bamboo pulp are weighed according to parts by weight and carries out pulping in pulper respectively and defibrination extremely mill
Slurry concentration is 3-6%, is then sent into mud pit jointly, sequentially adds carbon fiber slurry and afforestation waste fibre stuff, stir
It mixes uniformly mixed, obtains mixture A；
2) the PPE wet strength agent of 3-5% weight will be added in mixture A obtained in step 1), after mixing according to common process
It manufactured paper with pulp, be dehydrated, squeezed and dried, body paper B must be not coated with；
3) it will be not coated with body paper B obtained in step 2 to be glued on application roll, makes to apply at least one face for being not coated with body paper B
Then the multi-layer coated paper for having antimildew and antibacterial compound adhesive is bonded together by cloth antimildew and antibacterial compound adhesive, it is dry to get.
As further scheme of the invention: in step 3), the resin added of the sizing is 2-5gsm.
The environmental protective composite paper plate of the antimildew and antibacterial is preparing the purposes in cardboard.
Compared with prior art, the beneficial effects of the present invention are:
The environmental protective composite paper plate of antimildew and antibacterial prepared by the present invention has good antimildew and antibacterial performance, by a variety of slurries and prevents
Mould antibacterial compound adhesive is used cooperatively, so that cardboard itself has antimildew and antibacterial performance, without additionally using antisepsis antistaling agent, peace
It is complete convenient；Simultaneously as carrying out preparing antimildew and antibacterial using the environment amenable material such as sepiolite powder, tea polyphenols and glutinous rice glue
Compound adhesive reduces the pollution caused by article and environment, has a vast market foreground.
Specific embodiment
Technical solution of the present invention is described in more detail With reference to embodiment.
Embodiment 1
A kind of environmental protective composite paper plate of antimildew and antibacterial, including below according to the raw material of parts by weight: bleached sulphate softwood pulp 30
Part, 45 parts of bamboo pulp, 1 part of carbon fiber slurry, 3 parts of afforestation waste fibre stuff and suitable antimildew and antibacterial compound adhesive.
Wherein, the preparation method of the carbon fiber slurry is that 170 parts of water are weighed according to parts by weight, 3 parts of carbon fiber is added, with 400r/min
Mixing speed be stirred dispersion 8 minutes, then be added 400 parts water be uniformly mixed, then with ultrasonic cell disruptor into
Row ultrasonic disperse 12 minutes, make the floccule of every liter of mixed liquor under light illumination less than 18 to get the carbon fiber slurry；It is described
The preparation method of afforestation waste fibre stuff is to weigh suitable afforestation waste to be dried, after crushing
Be added mould is carried out at 28 DEG C spontaneous fermentation processing 20 days, carry out negative pressure filtration after fermentation, be then fed into disc mill into
Row defibrination to refining concentration is 4.2%, and cellulose biological enzyme is added when defibrination to soften and discongests fiber, up to garden after the completion of defibrination
Woods afforests waste fibre stuff；The preparation method of the antimildew and antibacterial compound adhesive be according to parts by weight weigh 6 parts of sepiolite powder,
4 parts and 4 parts of glutinous rice glue of tea polyphenols are uniformly mixed, and it is compound to get the antimildew and antibacterial that suitable quantity of water progress ultraviolet irradiation processing is added
Glue；The solid content of the antimildew and antibacterial compound adhesive is 9%；The time of the ultraviolet irradiation processing is 10min, and irradiation wavelengths are
265nm, irradiation distance 130mm.
In the present embodiment, the preparation method of the environmental protective composite paper plate of the antimildew and antibacterial, steps are as follows:
1) bleached sulphate softwood pulp and bamboo pulp are weighed according to parts by weight and carries out pulping in pulper respectively and defibrination extremely mill
Starching concentration is 4.5%, is then sent into mud pit jointly, sequentially adds carbon fiber slurry and afforestation waste fibre stuff, stir
It mixes uniformly mixed, obtains mixture A；
2) the PPE wet strength agent of 4% weight will be added in mixture A obtained in step 1), after mixing according to common process into
Row is manufactured paper with pulp, is dehydrated, squeezes and is dried, and body paper B must be not coated with；
3) body paper B will be not coated with obtained in step 2 to be glued on application roll, the resin added of the sizing is 4gsm, is made not
It applies and is coated with antimildew and antibacterial compound adhesive at least one face of body paper B, then glue the multi-layer coated paper for having antimildew and antibacterial compound adhesive
Be combined, it is dry to get.
Embodiment 2
A kind of environmental protective composite paper plate of antimildew and antibacterial, including below according to the raw material of parts by weight: bleached sulphate softwood pulp 60
Part, 80 parts of bamboo pulp, 6 parts of carbon fiber slurry, 8 parts of afforestation waste fibre stuff and suitable antimildew and antibacterial compound adhesive.
Wherein, the preparation method of the carbon fiber slurry is that 170 parts of water are weighed according to parts by weight, 3 parts of carbon fiber is added, with 400r/min
Mixing speed be stirred dispersion 8 minutes, then be added 400 parts water be uniformly mixed, then with ultrasonic cell disruptor into
Row ultrasonic disperse 12 minutes, make the floccule of every liter of mixed liquor under light illumination less than 18 to get the carbon fiber slurry；It is described
The preparation method of afforestation waste fibre stuff is to weigh suitable afforestation waste to be dried, after crushing
Be added mould is carried out at 28 DEG C spontaneous fermentation processing 20 days, carry out negative pressure filtration after fermentation, be then fed into disc mill into
Row defibrination to refining concentration is 4.2%, and cellulose biological enzyme is added when defibrination to soften and discongests fiber, up to garden after the completion of defibrination
Woods afforests waste fibre stuff；The preparation method of the antimildew and antibacterial compound adhesive be according to parts by weight weigh 6 parts of sepiolite powder,
4 parts and 4 parts of glutinous rice glue of tea polyphenols are uniformly mixed, and it is compound to get the antimildew and antibacterial that suitable quantity of water progress ultraviolet irradiation processing is added
Glue；The solid content of the antimildew and antibacterial compound adhesive is 9%；The time of the ultraviolet irradiation processing is 10min, and irradiation wavelengths are
265nm, irradiation distance 130mm.
In the present embodiment, the preparation method of the environmental protective composite paper plate of the antimildew and antibacterial, steps are as follows:
1) bleached sulphate softwood pulp and bamboo pulp are weighed according to parts by weight and carries out pulping in pulper respectively and defibrination extremely mill
Starching concentration is 4.5%, is then sent into mud pit jointly, sequentially adds carbon fiber slurry and afforestation waste fibre stuff, stir
It mixes uniformly mixed, obtains mixture A；
2) the PPE wet strength agent of 4% weight will be added in mixture A obtained in step 1), after mixing according to common process into
Row is manufactured paper with pulp, is dehydrated, squeezes and is dried, and body paper B must be not coated with；
3) body paper B will be not coated with obtained in step 2 to be glued on application roll, the resin added of the sizing is 4gsm, is made not
It applies and is coated with antimildew and antibacterial compound adhesive at least one face of body paper B, then glue the multi-layer coated paper for having antimildew and antibacterial compound adhesive
Be combined, it is dry to get.
Embodiment 3
A kind of environmental protective composite paper plate of antimildew and antibacterial, including below according to the raw material of parts by weight: bleached sulphate softwood pulp 45
Part, 62.5 parts of bamboo pulp, 3.5 parts of carbon fiber slurry, 5.5 parts of afforestation waste fibre stuff and suitable antimildew and antibacterial
Compound adhesive.Wherein, the preparation method of the carbon fiber slurry is that 170 parts of water are weighed according to parts by weight, is added 3 parts of carbon fiber, with
The mixing speed of 400r/min is stirred dispersion 8 minutes, and 400 parts of water is then added and is uniformly mixed, then uses supersonic cell
Pulverizer carries out ultrasonic disperse 12 minutes, makes the floccule of every liter of mixed liquor under light illumination less than 18 to get the carbon fiber
Slurry；The preparation method of the afforestation waste fibre stuff is to weigh suitable afforestation waste place is dried
Reason is added mould and carries out spontaneous fermentation processing 20 days at 28 DEG C, carries out negative pressure filtration after fermentation, be then fed into after crushing
It is 4.2% that disc mill, which carries out defibrination to refining concentration, and cellulose biological enzyme is added when defibrination to soften and discongests fiber, defibrination is completed
Afterwards up to afforestation waste fibre stuff；The preparation method of the antimildew and antibacterial compound adhesive is to weigh Hai Pao according to parts by weight
6 parts of mountain flour, 4 parts of tea polyphenols and 4 parts of glutinous rice glue are uniformly mixed, and suitable quantity of water is added and carries out ultraviolet irradiation processing to get described mould proof
Antibacterial compound adhesive；The solid content of the antimildew and antibacterial compound adhesive is 9%；The time of the ultraviolet irradiation processing is 10min, irradiation
Wavelength is 265nm, irradiation distance 130mm.
In the present embodiment, the preparation method of the environmental protective composite paper plate of the antimildew and antibacterial, steps are as follows:
1) bleached sulphate softwood pulp and bamboo pulp are weighed according to parts by weight and carries out pulping in pulper respectively and defibrination extremely mill
Starching concentration is 4.5%, is then sent into mud pit jointly, sequentially adds carbon fiber slurry and afforestation waste fibre stuff, stir
It mixes uniformly mixed, obtains mixture A；
2) the PPE wet strength agent of 4% weight will be added in mixture A obtained in step 1), after mixing according to common process into
Row is manufactured paper with pulp, is dehydrated, squeezes and is dried, and body paper B must be not coated with；
3) body paper B will be not coated with obtained in step 2 to be glued on application roll, the resin added of the sizing is 4gsm, is made not
It applies and is coated with antimildew and antibacterial compound adhesive at least one face of body paper B, then glue the multi-layer coated paper for having antimildew and antibacterial compound adhesive
Be combined, it is dry to get.
Embodiment 4
A kind of environmental protective composite paper plate of antimildew and antibacterial, including below according to the raw material of parts by weight: bleached sulphate softwood pulp 36
Part, 52 parts of bamboo pulp, 3 parts of carbon fiber slurry, 5 parts of afforestation waste fibre stuff and suitable antimildew and antibacterial compound adhesive.
Wherein, the preparation method of the carbon fiber slurry is that 170 parts of water are weighed according to parts by weight, 3 parts of carbon fiber is added, with 400r/min
Mixing speed be stirred dispersion 8 minutes, then be added 400 parts water be uniformly mixed, then with ultrasonic cell disruptor into
Row ultrasonic disperse 12 minutes, make the floccule of every liter of mixed liquor under light illumination less than 18 to get the carbon fiber slurry；It is described
The preparation method of afforestation waste fibre stuff is to weigh suitable afforestation waste to be dried, after crushing
Be added mould is carried out at 28 DEG C spontaneous fermentation processing 20 days, carry out negative pressure filtration after fermentation, be then fed into disc mill into
Row defibrination to refining concentration is 4.2%, and cellulose biological enzyme is added when defibrination to soften and discongests fiber, up to garden after the completion of defibrination
Woods afforests waste fibre stuff；The preparation method of the antimildew and antibacterial compound adhesive be according to parts by weight weigh 6 parts of sepiolite powder,
4 parts and 4 parts of glutinous rice glue of tea polyphenols are uniformly mixed, and it is compound to get the antimildew and antibacterial that suitable quantity of water progress ultraviolet irradiation processing is added
Glue；The solid content of the antimildew and antibacterial compound adhesive is 9%；The time of the ultraviolet irradiation processing is 10min, and irradiation wavelengths are
265nm, irradiation distance 130mm.
In the present embodiment, the preparation method of the environmental protective composite paper plate of the antimildew and antibacterial, steps are as follows:
1) bleached sulphate softwood pulp and bamboo pulp are weighed according to parts by weight and carries out pulping in pulper respectively and defibrination extremely mill
Starching concentration is 4.5%, is then sent into mud pit jointly, sequentially adds carbon fiber slurry and afforestation waste fibre stuff, stir
It mixes uniformly mixed, obtains mixture A；
2) the PPE wet strength agent of 4% weight will be added in mixture A obtained in step 1), after mixing according to common process into
Row is manufactured paper with pulp, is dehydrated, squeezes and is dried, and body paper B must be not coated with；
3) body paper B will be not coated with obtained in step 2 to be glued on application roll, the resin added of the sizing is 4gsm, is made not
It applies and is coated with antimildew and antibacterial compound adhesive at least one face of body paper B, then glue the multi-layer coated paper for having antimildew and antibacterial compound adhesive
Be combined, it is dry to get.
Embodiment 5
A kind of environmental protective composite paper plate of antimildew and antibacterial, including below according to the raw material of parts by weight: bleached sulphate softwood pulp 45
Part, 65 parts of bamboo pulp, 5 parts of carbon fiber slurry, 7 parts of afforestation waste fibre stuff and suitable antimildew and antibacterial compound adhesive.
Wherein, the preparation method of the carbon fiber slurry is that 170 parts of water are weighed according to parts by weight, 3 parts of carbon fiber is added, with 400r/min
Mixing speed be stirred dispersion 8 minutes, then be added 400 parts water be uniformly mixed, then with ultrasonic cell disruptor into
Row ultrasonic disperse 12 minutes, make the floccule of every liter of mixed liquor under light illumination less than 18 to get the carbon fiber slurry；It is described
The preparation method of afforestation waste fibre stuff is to weigh suitable afforestation waste to be dried, after crushing
Be added mould is carried out at 28 DEG C spontaneous fermentation processing 20 days, carry out negative pressure filtration after fermentation, be then fed into disc mill into
Row defibrination to refining concentration is 4.2%, and cellulose biological enzyme is added when defibrination to soften and discongests fiber, up to garden after the completion of defibrination
Woods afforests waste fibre stuff；The preparation method of the antimildew and antibacterial compound adhesive be according to parts by weight weigh 6 parts of sepiolite powder,
4 parts and 4 parts of glutinous rice glue of tea polyphenols are uniformly mixed, and it is compound to get the antimildew and antibacterial that suitable quantity of water progress ultraviolet irradiation processing is added
Glue；The solid content of the antimildew and antibacterial compound adhesive is 9%；The time of the ultraviolet irradiation processing is 10min, and irradiation wavelengths are
265nm, irradiation distance 130mm.
In the present embodiment, the preparation method of the environmental protective composite paper plate of the antimildew and antibacterial, steps are as follows:
1) bleached sulphate softwood pulp and bamboo pulp are weighed according to parts by weight and carries out pulping in pulper respectively and defibrination extremely mill
Starching concentration is 4.5%, is then sent into mud pit jointly, sequentially adds carbon fiber slurry and afforestation waste fibre stuff, stir
It mixes uniformly mixed, obtains mixture A；
2) the PPE wet strength agent of 4% weight will be added in mixture A obtained in step 1), after mixing according to common process into
Row is manufactured paper with pulp, is dehydrated, squeezes and is dried, and body paper B must be not coated with；
3) body paper B will be not coated with obtained in step 2 to be glued on application roll, the resin added of the sizing is 4gsm, is made not
It applies and is coated with antimildew and antibacterial compound adhesive at least one face of body paper B, then glue the multi-layer coated paper for having antimildew and antibacterial compound adhesive
Be combined, it is dry to get.
Embodiment 6
A kind of environmental protective composite paper plate of antimildew and antibacterial, including below according to the raw material of parts by weight: bleached sulphate softwood pulp
40.5 parts, 58.5 parts of bamboo pulp, 4 parts of carbon fiber slurry, 6 parts of afforestation waste fibre stuff and suitable antimildew and antibacterial
Compound adhesive.Wherein, the preparation method of the carbon fiber slurry is that 170 parts of water are weighed according to parts by weight, is added 3 parts of carbon fiber, with
The mixing speed of 400r/min is stirred dispersion 8 minutes, and 400 parts of water is then added and is uniformly mixed, then uses supersonic cell
Pulverizer carries out ultrasonic disperse 12 minutes, makes the floccule of every liter of mixed liquor under light illumination less than 18 to get the carbon fiber
Slurry；The preparation method of the afforestation waste fibre stuff is to weigh suitable afforestation waste place is dried
Reason is added mould and carries out spontaneous fermentation processing 20 days at 28 DEG C, carries out negative pressure filtration after fermentation, be then fed into after crushing
It is 4.2% that disc mill, which carries out defibrination to refining concentration, and cellulose biological enzyme is added when defibrination to soften and discongests fiber, defibrination is completed
Afterwards up to afforestation waste fibre stuff；The preparation method of the antimildew and antibacterial compound adhesive is to weigh Hai Pao according to parts by weight
6 parts of mountain flour, 4 parts of tea polyphenols and 4 parts of glutinous rice glue are uniformly mixed, and suitable quantity of water is added and carries out ultraviolet irradiation processing to get described mould proof
Antibacterial compound adhesive；The solid content of the antimildew and antibacterial compound adhesive is 9%；The time of the ultraviolet irradiation processing is 10min, irradiation
Wavelength is 265nm, irradiation distance 130mm.
In the present embodiment, the preparation method of the environmental protective composite paper plate of the antimildew and antibacterial, steps are as follows:
1) bleached sulphate softwood pulp and bamboo pulp are weighed according to parts by weight and carries out pulping in pulper respectively and defibrination extremely mill
Starching concentration is 4.5%, is then sent into mud pit jointly, sequentially adds carbon fiber slurry and afforestation waste fibre stuff, stir
It mixes uniformly mixed, obtains mixture A；
2) the PPE wet strength agent of 4% weight will be added in mixture A obtained in step 1), after mixing according to common process into
Row is manufactured paper with pulp, is dehydrated, squeezes and is dried, and body paper B must be not coated with；
3) body paper B will be not coated with obtained in step 2 to be glued on application roll, the resin added of the sizing is 4gsm, is made not
It applies and is coated with antimildew and antibacterial compound adhesive at least one face of body paper B, then glue the multi-layer coated paper for having antimildew and antibacterial compound adhesive
Be combined, it is dry to get.
Embodiment 7
A kind of environmental protective composite paper plate of antimildew and antibacterial, including below according to the raw material of parts by weight: bleached sulphate softwood pulp 40
Part, 60 parts of bamboo pulp, 4 parts of carbon fiber slurry, 6 parts of afforestation waste fibre stuff and suitable antimildew and antibacterial compound adhesive.
Wherein, the preparation method of the carbon fiber slurry is that 170 parts of water are weighed according to parts by weight, 3 parts of carbon fiber is added, with 400r/min
Mixing speed be stirred dispersion 8 minutes, then be added 400 parts water be uniformly mixed, then with ultrasonic cell disruptor into
Row ultrasonic disperse 12 minutes, make the floccule of every liter of mixed liquor under light illumination less than 18 to get the carbon fiber slurry；It is described
The preparation method of afforestation waste fibre stuff is to weigh suitable afforestation waste to be dried, after crushing
Be added mould is carried out at 28 DEG C spontaneous fermentation processing 20 days, carry out negative pressure filtration after fermentation, be then fed into disc mill into
Row defibrination to refining concentration is 4.2%, and cellulose biological enzyme is added when defibrination to soften and discongests fiber, up to garden after the completion of defibrination
Woods afforests waste fibre stuff；The preparation method of the antimildew and antibacterial compound adhesive be according to parts by weight weigh 6 parts of sepiolite powder,
4 parts and 4 parts of glutinous rice glue of tea polyphenols are uniformly mixed, and it is compound to get the antimildew and antibacterial that suitable quantity of water progress ultraviolet irradiation processing is added
Glue；The solid content of the antimildew and antibacterial compound adhesive is 9%；The time of the ultraviolet irradiation processing is 10min, and irradiation wavelengths are
265nm, irradiation distance 130mm.
In the present embodiment, the preparation method of the environmental protective composite paper plate of the antimildew and antibacterial, steps are as follows:
1) bleached sulphate softwood pulp and bamboo pulp are weighed according to parts by weight and carries out pulping in pulper respectively and defibrination extremely mill
Starching concentration is 4.5%, is then sent into mud pit jointly, sequentially adds carbon fiber slurry and afforestation waste fibre stuff, stir
It mixes uniformly mixed, obtains mixture A；
2) the PPE wet strength agent of 4% weight will be added in mixture A obtained in step 1), after mixing according to common process into
Row is manufactured paper with pulp, is dehydrated, squeezes and is dried, and body paper B must be not coated with；
3) body paper B will be not coated with obtained in step 2 to be glued on application roll, the resin added of the sizing is 4gsm, is made not
It applies and is coated with antimildew and antibacterial compound adhesive at least one face of body paper B, then glue the multi-layer coated paper for having antimildew and antibacterial compound adhesive
Be combined, it is dry to get.
The environmental protective composite paper plate of antimildew and antibacterial prepared by the present invention has good antimildew and antibacterial performance, passes through a variety of slurries
Anti-corrosive fresh-keeping is used without additional so that cardboard itself has antimildew and antibacterial performance with being used cooperatively for antimildew and antibacterial compound adhesive
Agent, safe ready, simultaneously as it is anti-to carry out preparation using the environment amenable material such as sepiolite powder, tea polyphenols and glutinous rice glue
Mould antibacterial compound adhesive, reduces the pollution caused by article and environment, has a vast market foreground.
Better embodiment of the invention is explained in detail above, but the present invention is not limited to above-mentioned embodiment party
Formula within the knowledge of one of ordinary skill in the art can also be without departing from the purpose of the present invention
Various changes can be made.There is no necessity and possibility to exhaust all the enbodiments.And it thus amplifies out apparent
Variation or variation be still in the protection scope of this invention.
Claims (10)
1. a kind of environmental protective composite paper plate of antimildew and antibacterial, which is characterized in that including below according to the raw material of parts by weight: bleaching sulfuric acid
30-60 parts of salt softwood pulp, 45-80 parts of bamboo pulp, 1-6 parts of carbon fiber slurry, 3-8 parts of afforestation waste fibre stuff, with
And suitable antimildew and antibacterial compound adhesive；Wherein, the raw material of the antimildew and antibacterial compound adhesive includes sepiolite powder, tea polyphenols and glutinous rice
Glue.
2. the environmental protective composite paper plate of antimildew and antibacterial according to claim 1, which is characterized in that including below according to parts by weight
Raw material: 36-45 parts of bleached sulphate softwood pulp, 52-65 parts of bamboo pulp, 3-5 parts of carbon fiber slurry, afforestation waste are fine
Tie up slurry 5-7 parts and suitable antimildew and antibacterial compound adhesive.
3. the environmental protective composite paper plate of antimildew and antibacterial according to claim 2, which is characterized in that including below according to parts by weight
Raw material: 40 parts of bleached sulphate softwood pulp, 60 parts of bamboo pulp, 4 parts of carbon fiber slurry, afforestation waste fibre stuff 6
Part and suitable antimildew and antibacterial compound adhesive.
4. the environmental protective composite paper plate of antimildew and antibacterial according to claim 1 or 2 or 3, which is characterized in that the carbon fiber slurry
The preparation method of material is that 170 parts of water are weighed according to parts by weight, is added carbon fiber 2-4 parts, is stirred dispersion 6-14 minutes, then
80-800 parts of water is added to be uniformly mixed, then carries out ultrasonic disperse 8-18 minutes with ultrasonic cell disruptor to get the carbon
Fibre stuff.
5. the environmental protective composite paper plate of antimildew and antibacterial according to claim 4, which is characterized in that the afforestation waste
The preparation method of fibre stuff is to weigh suitable afforestation waste to be dried, and mould is added after crushing and carries out certainly
Right fermentation process carries out negative pressure filtration after fermentation, is then fed into disc mill and carries out defibrination, defibrination is green up to gardens after the completion
Change waste fibre stuff.
6. the environmental protective composite paper plate of antimildew and antibacterial according to claim 4, which is characterized in that the antimildew and antibacterial compound adhesive
Preparation method be 6 parts of sepiolite powder is weighed according to parts by weight, 4 parts of tea polyphenols and 4 parts of glutinous rice glue are uniformly mixed, suitable quantity of water is added
Ultraviolet irradiation processing is carried out to get the antimildew and antibacterial compound adhesive；Wherein, the solid content of the antimildew and antibacterial compound adhesive is 7%-
11%。
7. the environmental protective composite paper plate of antimildew and antibacterial according to claim 6, which is characterized in that the ultraviolet irradiation processing
Time is 5-15min, irradiation wavelengths 260-270nm, irradiation distance 120-140mm.
8. a kind of preparation method of the environmental protective composite paper plate of antimildew and antibacterial as claimed in claim 1, which is characterized in that
Steps are as follows:
1) bleached sulphate softwood pulp and bamboo pulp are weighed according to parts by weight and carries out pulping in pulper respectively and defibrination extremely mill
Slurry concentration is 3-6%, is then sent into mud pit jointly, sequentially adds carbon fiber slurry and afforestation waste fibre stuff, stir
It mixes uniformly mixed, obtains mixture A；
2) the PPE wet strength agent of 3-5% weight will be added in mixture A obtained in step 1), after mixing according to common process
It manufactured paper with pulp, be dehydrated, squeezed and dried, body paper B must be not coated with；
3) it will be not coated with body paper B obtained in step 2 to be glued on application roll, then there is antimildew and antibacterial to answer for multi-layer coated
The paper for closing glue is bonded together, it is dry to get.
9. the preparation method of the environmental protective composite paper plate of antimildew and antibacterial according to claim 8, which is characterized in that step 3)
In, the resin added of the sizing is 2-5gsm.
10. a kind of environmental protective composite paper plate of antimildew and antibacterial as claimed in claim 1 is preparing the purposes in cardboard.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810922637.4A CN108951266A (en) | 2018-08-14 | 2018-08-14 | A kind of environmental protective composite paper plate of antimildew and antibacterial and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810922637.4A CN108951266A (en) | 2018-08-14 | 2018-08-14 | A kind of environmental protective composite paper plate of antimildew and antibacterial and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108951266A true CN108951266A (en) | 2018-12-07 |
Family
ID=64469758
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810922637.4A Pending CN108951266A (en) | 2018-08-14 | 2018-08-14 | A kind of environmental protective composite paper plate of antimildew and antibacterial and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108951266A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114717880A (en) * | 2022-04-02 | 2022-07-08 | 重庆翅之展环保科技有限公司 | Mould-proof antibacterial environment-friendly composite paperboard and preparation method and device thereof |
| CN116411486A (en) * | 2023-04-13 | 2023-07-11 | 正业包装（中山）有限公司 | Mildew-proof antibacterial degradable environment-friendly composite paperboard material and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN2399428Y (en) * | 1999-12-22 | 2000-10-04 | 张俊玲 | Special heating electric pressure board for textile dyeing |
| CN101619553A (en) * | 2008-11-28 | 2010-01-06 | 富阳市钱旺纸业有限公司 | A kind of production process of composite functional paper |
| CN104130034A (en) * | 2014-06-19 | 2014-11-05 | 临沂市清宇环境资源综合利用研究院 | Method for producing fiber board and organic fertilizer by utilizing garden waste |
| CN106087523A (en) * | 2016-08-03 | 2016-11-09 | 海南金海浆纸业有限公司 | A kind of papermaking process of on-line coater water-transfer printing paper base stock body paper |
| CN107877980A (en) * | 2017-12-18 | 2018-04-06 | 上海海洋大学 | Environmental protective composite paper plate of antimildew and antibacterial and preparation method thereof |
-
2018
- 2018-08-14 CN CN201810922637.4A patent/CN108951266A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN2399428Y (en) * | 1999-12-22 | 2000-10-04 | 张俊玲 | Special heating electric pressure board for textile dyeing |
| CN101619553A (en) * | 2008-11-28 | 2010-01-06 | 富阳市钱旺纸业有限公司 | A kind of production process of composite functional paper |
| CN104130034A (en) * | 2014-06-19 | 2014-11-05 | 临沂市清宇环境资源综合利用研究院 | Method for producing fiber board and organic fertilizer by utilizing garden waste |
| CN106087523A (en) * | 2016-08-03 | 2016-11-09 | 海南金海浆纸业有限公司 | A kind of papermaking process of on-line coater water-transfer printing paper base stock body paper |
| CN107877980A (en) * | 2017-12-18 | 2018-04-06 | 上海海洋大学 | Environmental protective composite paper plate of antimildew and antibacterial and preparation method thereof |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114717880A (en) * | 2022-04-02 | 2022-07-08 | 重庆翅之展环保科技有限公司 | Mould-proof antibacterial environment-friendly composite paperboard and preparation method and device thereof |
| CN116411486A (en) * | 2023-04-13 | 2023-07-11 | 正业包装（中山）有限公司 | Mildew-proof antibacterial degradable environment-friendly composite paperboard material and preparation method thereof |
| CN116411486B (en) * | 2023-04-13 | 2024-05-14 | 正业包装（中山）有限公司 | Mildew-proof antibacterial degradable environment-friendly composite paperboard material and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102212983B (en) | High-intensity environment-friendly craft paper and manufacturing method thereof | |
| CN110284368A (en) | It is a kind of without moulding biomass-based grease proofing antibacterial food wrapping paper preparation method | |
| CN106351056A (en) | High-strength corrugated-paper production process | |
| CN105369669A (en) | Method for preparing high-strength corrugated paper | |
| CN102561091B (en) | High strength linerboard making technology with low wood pulp dosage | |
| CN106283929A (en) | A kind of containing cabo and/or the coated white cardboard of Nicotiana tabacum L. and production technology | |
| CN109082928B (en) | Tobacco stem coated white cardboard and preparation method and application thereof | |
| CN109183487B (en) | Method for making salt packaging paper | |
| CN110512457B (en) | Method for manufacturing oil-proof laminating base paper | |
| CN107268327A (en) | A kind of natural color pulp and its preparation technology, using and preparation facilities | |
| CN102733252A (en) | Method for producing outer bag paper of fruit cultivating bag by using waste linerboards | |
| CN108951266A (en) | A kind of environmental protective composite paper plate of antimildew and antibacterial and preparation method thereof | |
| CN110653981B (en) | Production process of environment-friendly packaging box | |
| CN102605671A (en) | Production method of art paper containing crude fibers | |
| CN105672053B (en) | A kind of spool fiber board | |
| CN111979815A (en) | Preparation method of moisture regain-resistant, delamination-resistant and high-strength environment-friendly kraft liner cardboard paper | |
| CN104911937B (en) | A kind of paper and preparation method thereof | |
| CN106827150A (en) | Building template manufacture craft | |
| CN108035192A (en) | A kind of 14g/m2The production method of ultra-thin high grade of transparency copy paper | |
| CN104452467B (en) | A kind of slim natural color food wrapper and preparation method thereof | |
| CN109423909A (en) | It is a kind of using grass class plant as the process integration of raw material | |
| CN101591870A (en) | A kind of manufacture craft of high-strength pulp plate | |
| CN101985819B (en) | Process for producing low-basis-weight waxed base paper | |
| CN104711903B (en) | A kind of fruit inspecting of multi-layer compound structure and preparation method thereof | |
| CN109487609B (en) | Production method of low-basis-weight kraft liner cardboard paper |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20181207 |