CN108950138A - A kind of high efficiency preparation method of alfer and ferro-aluminum base series alloy - Google Patents
A kind of high efficiency preparation method of alfer and ferro-aluminum base series alloy Download PDFInfo
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- CN108950138A CN108950138A CN201810951880.9A CN201810951880A CN108950138A CN 108950138 A CN108950138 A CN 108950138A CN 201810951880 A CN201810951880 A CN 201810951880A CN 108950138 A CN108950138 A CN 108950138A
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
- C21C7/00—Treating molten ferrous alloys, e.g. steel, not covered by groups C21C1/00 - C21C5/00
- C21C7/04—Removing impurities by adding a treating agent
- C21C7/06—Deoxidising, e.g. killing
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
- C21C7/00—Treating molten ferrous alloys, e.g. steel, not covered by groups C21C1/00 - C21C5/00
- C21C7/0006—Adding metallic additives
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C1/00—Making non-ferrous alloys
- C22C1/02—Making non-ferrous alloys by melting
- C22C1/026—Alloys based on aluminium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C21/00—Alloys based on aluminium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C33/00—Making ferrous alloys
- C22C33/04—Making ferrous alloys by melting
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C35/00—Master alloys for iron or steel
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/06—Ferrous alloys, e.g. steel alloys containing aluminium
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Mechanical Engineering (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Refinement Of Pig-Iron, Manufacture Of Cast Iron, And Steel Manufacture Other Than In Revolving Furnaces (AREA)
- Vertical, Hearth, Or Arc Furnaces (AREA)
Abstract
The present invention is a kind of high efficiency preparation method of alfer, comprising the following steps: (i) uses intermediate frequency furnace or electric furnace by scrap melting at molten steel, removes slag stand-by;(ii) aluminium ingot is put into alloy packet, and toasts and is melted into molten aluminum;(iii) the alloy packet equipped with molten aluminum is transported under intermediate frequency furnace or electric furnace fire door, directly being rushed to be blended into alloy packet with the molten steel in intermediate frequency furnace or electric furnace becomes aluminium alloy, and poly- slag and slagging-off;(iv) alloy packet handling to casting machine is poured, completes the preparation of alfer.The preparation method of alfer and ferro-aluminum base series alloy provided by the invention, simple for process, high production efficiency, the more other methods of production efficiency improve 50-100%;In addition, the yield of alloy such as metallic aluminium, magnesium, calcium are high, low energy consumption, and production cost is low and solves the problems, such as ferro-aluminum dusting during natural storage in air.
Description
Technical field
The present invention relates to a kind of preparation method of steel-smelting alloy, specifically a kind of alfer and ferro-aluminum base system column are closed
The high efficiency preparation method of gold.
Background technique
It is big except being taken on process for making for the yield for improving the active metals such as deoxidation in steel making and alloy element aluminium, magnesium, calcium
Measure outside technical measures, in recent years will above-mentioned active element and iron form alloy after use, be that raising its recovery rate is most effective
One of method.
There are mainly two types of the current techniques of the preparation method of ferro-aluminum base series alloy, the first is directly to be put into aluminium and iron
It smelts, is poured after qualified, such as number of patent application 201610198922.7, publication number CN105671412A, the applying date in intermediate frequency furnace
2016-04-01, the patent of invention of entitled " production technology of deoxidation in steel making alfer " disclose a kind of alfer
Production technology first has to smelt, and then Argon in ferro-aluminum liquid, last ferro-aluminum casting, each step of these three steps are very multiple again
It is miscellaneous, especially smelting process;Second is to use intermediate frequency furnace smelting molten steel, while toasting aluminium ingot with iron packet, will using high temperature iron liquid
Aluminium ingot punching fusing, by it is ladle-to-ladle uniformly after casting, such as number of patent application 201710361454.5, publication number CN107267813A,
Applying date 2017-05-22, patent name are that the patent of invention of " molten steel punching converts aluminium ingot and produces alfer preparation method " discloses
Aluminium ingot production alfer preparation method is converted in a kind of punching of molten steel, and the aluminium ingot after baking is converted in the punching of this method molten steel, due to aluminium ingot elder generation
600 DEG C are baked in ladle, aluminium ingot does not melt at this time, and converting by molten steel punching is completely melt aluminium ingot, due to being using steel
Aluminium ingot is converted in water punching, and molten steel unevenly causes alloy to be unevenly distributed in conjunction with aluminium ingot, needs to carry out subsequent ladle-to-ladle twice, technique
Complexity, low efficiency;In addition, this method temperature is nervous, sticked in containment wall after aluminium alloy temperature decline in ladle-to-ladle and casting process,
Reduce alloy yield and alloy packet service life;Moreover institute's aluminium metallurgy iron is deposited in and is easy to dusting in atmosphere, cannot fully meet makes
With requiring.
Summary of the invention
The technical problems to be solved by the present invention are: how to overcome in the prior art ferro-aluminum base system column alloy preparation technology it is multiple
Miscellaneous, the shortcomings that recovery rate is low, at high cost and ferro-aluminum natural storage is easy to dusting.
In order to solve the above technical problems, the present invention proposes the high efficiency system of a kind of alfer and ferro-aluminum base series alloy
Preparation Method, technical solution are as follows:
A kind of high efficiency preparation method of alfer, comprising the following steps: (i) use intermediate frequency furnace or electric furnace by scrap melting
At molten steel, remove slag stand-by;(ii) aluminium ingot is put into alloy packet, and toasts and is melted into molten aluminum;(iii) the conjunction of molten aluminum will be housed
Jin Bao is transported under intermediate frequency furnace or electric furnace fire door, and directly being rushed to be blended into alloy packet with the molten steel in intermediate frequency furnace or electric furnace becomes alloy
Liquid, and poly- slag and slagging-off;(iv) alloy packet handling to casting machine is poured, completes the preparation of alfer.
A kind of high efficiency preparation method of ferro-aluminum base series alloy, comprising the following steps: (i) use intermediate frequency furnace or electric furnace
By scrap melting at molten steel, remove slag stand-by;(ii) aluminium ingot is put into alloy packet, and toasts and is melted into molten aluminum;(iii) need to
The corresponding metal of other conjunction elements for being added into ferro-aluminum is added in molten aluminum or molten steel, makes its fusing;Other conjunction elements are corresponding
The rule that metal is added are as follows: if the melting point metal is more than or equal to 1000 DEG C, which is added in molten steel;If the metal
Then the metal is added in molten aluminum less than 1000 DEG C for fusing point;(iv) the alloy packet equipped with molten aluminum is transported to intermediate frequency furnace or electric furnace fire door
Under, directly being rushed to be blended into alloy packet with the molten steel in intermediate frequency furnace or electric furnace becomes aluminium alloy, and poly- slag and slagging-off;(v) by alloy
Packet handling is poured to casting machine, completes the preparation of ferro-aluminum base series alloy.
In this way, aluminium ingot is first melted into molten aluminum by the present invention in alloy packet, is then directly rushed with molten steel and convert molten aluminum, aluminium can
Be distributed in steel very uniformly, without repeatedly ladle-to-ladle, if desired add other conjunction elements, then the property of can choose by fusing point height
Addition molten steel in (such as manganese) make its fusing, (such as magnesium, calcium) in lower melting-point addition molten aluminum is made into its fusing, simple science;
It can be seen that present invention science is converted by " liquid " with rushing for " liquid ", process step design is ingenious, and simple science is easy, especially
It is that when needing to add other conjunction elements, ingenious can more select, one side process is reduced, and low energy consumption, and it is at low cost, on the other hand produce
High-efficient, the more other methods of production efficiency improve 50-100%, finally also solve ferro-aluminum powder during natural storage in air
The problem of change.
The technical solution that the present invention further limits is:
The high efficiency preparation method of alfer or ferro-aluminum base series alloy above-mentioned, step (i) in, the weight of steel scrap is to need
The 20-80% of the alfer weight of preparation, step (ii) in, the weight of aluminium ingot is the 20- for needing alfer weight to be prepared
80%, the sum of steel scrap and the weight of aluminium ingot are the alfer weight of preparation.
The high efficiency preparation method of alfer or ferro-aluminum base series alloy above-mentioned, by scrap melting at molten steel, control
Liquid steel temperature is 1580-1700 DEG C;Aluminium ingot is melted into molten aluminum, control temperature of aluminum liquid is 670-1100 DEG C;Molten steel directly rushes
Being blended into alloy packet becomes aluminium alloy, and control aluminium alloy temperature is 1150-1550 DEG C.Liquid steel temperature is set as 1580-1700
DEG C, temperature of aluminum liquid is set as 670-1100 DEG C, such molten steel punching can make aluminium alloy temperature control be 1150- after converting molten aluminum
1550 DEG C, 1150-1550 DEG C of temperature is more advantageous to the fusion of alloy, more uniformly spreads alloy in molten steel;In addition, aluminium
Liquid temperature is 670-1100 DEG C,, can if the corresponding metal of the element is added in molten aluminum when needing to add other conjunction elements
To be adjusted according to its fusing point at 670-1100 DEG C, allow to melt in molten aluminum.
The high efficiency preparation method of alfer or ferro-aluminum base series alloy above-mentioned, carries out poly- slag using Slag conglomeration agent, gathers
Slag agent is mixed by sodium chloride, Fluorspar Powder, pulverized limestone, Cab-O-sil, calcined bauxite in powder by weight 5:5:35:20:35.This ingredient
Slag conglomeration agent has the advantages that poly- slag is fast, at low cost, production is simple.
The invention has the advantages that the preparation method of alfer provided by the invention and ferro-aluminum base series alloy, technique letter
Single easy, high production efficiency, the more other methods of production efficiency improve 50-100%;In addition, the yield of alloy such as metallic aluminium, magnesium, calcium
Height, low energy consumption, and production cost is low and solves the problems, such as ferro-aluminum dusting during natural storage in air.
Specific embodiment
Embodiment 1
The present embodiment is a kind of high efficiency preparation method of alfer, comprising the following steps:
(i) it uses intermediate frequency furnace or electric furnace by scrap melting at molten steel, removes slag stand-by;Controlling liquid steel temperature is 1580-1600 DEG C;
(ii) aluminium ingot is put into alloy packet, and toasts and is melted into molten aluminum;Controlling temperature of aluminum liquid is 670-750 DEG C;Step
(i) in, the weight of steel scrap is need alfer weight to be prepared 80%, step (ii) in, the weight of aluminium ingot be need it is to be prepared
The 20% of alfer weight;
(iii) the alloy packet equipped with molten aluminum is transported under intermediate frequency furnace or electric furnace fire door, is directly rushed with the molten steel in intermediate frequency furnace or electric furnace
Being blended into alloy packet becomes aluminium alloy, and control aluminium alloy temperature is 1150-1250 DEG C, and poly- slag and slagging-off;Using Slag conglomeration agent into
The poly- slag of row, Slag conglomeration agent are mixed by sodium chloride, Fluorspar Powder, pulverized limestone, Cab-O-sil, calcined bauxite in powder by weight 5:5:35:20:35
It closes;
(iv) alloy packet handling to casting machine is poured, completes the preparation of alfer.
The preparation method of the alfer of the embodiment of the present invention, simple for process, high production efficiency, production efficiency is compared with it
Its method improves 50-70%;In addition, the yield of alloy such as metallic aluminium, magnesium, calcium are high, low energy consumption, and production cost is low and solves ferro-aluminum
In air during natural storage the problem of dusting.
Embodiment 2
The present embodiment is a kind of high efficiency preparation method of ferro-aluminum base series alloy, comprising the following steps:
(i) it uses intermediate frequency furnace or electric furnace by scrap melting at molten steel, removes slag stand-by;Controlling liquid steel temperature is 1600-1650 DEG C;
(ii) aluminium ingot is put into alloy packet, and toasts and is melted into molten aluminum;Controlling temperature of aluminum liquid is 850-900 DEG C;Step
(i) in, the weight of steel scrap is need ferro-aluminum base system column weight alloy to be prepared 70%, step (ii) in, the weight of aluminium ingot is to need
The 30% of the ferro-aluminum base system column weight alloy of preparation;
(iii) the corresponding magnesium metal of other conjunction elements for needing to be added into ferro-aluminum and calcium are added in molten aluminum, make its fusing;
(iv) the alloy packet equipped with molten aluminum is transported under intermediate frequency furnace or electric furnace fire door, is directly rushed with the molten steel in intermediate frequency furnace or electric furnace
Being blended into alloy packet becomes aluminium alloy, and control aluminium alloy temperature is 1250-1300 DEG C, and poly- slag and slagging-off;Using Slag conglomeration agent into
The poly- slag of row, Slag conglomeration agent are mixed by sodium chloride, Fluorspar Powder, pulverized limestone, Cab-O-sil, calcined bauxite in powder by weight 5:5:35:20:35
It closes;
(v) alloy packet handling to casting machine is poured, completes the preparation of ferro-aluminum base series alloy.
The preparation method of the ferro-aluminum base series alloy of the embodiment of the present invention, simple for process, high production efficiency, production effect
The more other methods of rate improve 70-80%;In addition, the yield of alloy such as metallic aluminium, magnesium, calcium are high, low energy consumption, and production cost is low and solves
Ferro-aluminum is in air during natural storage the problem of dusting.
Embodiment 3
The present embodiment is a kind of high efficiency preparation method of ferro-aluminum base series alloy, comprising the following steps:
(i) it uses intermediate frequency furnace or electric furnace by scrap melting at molten steel, removes slag stand-by;Controlling liquid steel temperature is 1650-1700 DEG C;
(ii) aluminium ingot is put into alloy packet, and toasts and is melted into molten aluminum;Controlling temperature of aluminum liquid is 670-800 DEG C;Step
(i) in, the weight of steel scrap is need ferro-aluminum base system column weight alloy to be prepared 50%, step (ii) in, the weight of aluminium ingot is to need
The 50% of the ferro-aluminum base system column weight alloy of preparation;
(iii) the corresponding manganese metal of other conjunction elements and copper that need to be added into ferro-aluminum are added in molten steel, makes its fusing;
(iv) the alloy packet equipped with molten aluminum is transported under intermediate frequency furnace or electric furnace fire door, is directly rushed with the molten steel in intermediate frequency furnace or electric furnace
Being blended into alloy packet becomes aluminium alloy, and control aluminium alloy temperature is 1450-1550 DEG C, and poly- slag and slagging-off;
(v) alloy packet handling to casting machine is poured, completes the preparation of ferro-aluminum base series alloy.
The preparation method of the ferro-aluminum base series alloy of the embodiment of the present invention, simple for process, high production efficiency, production effect
The more other methods of rate improve 80-90%;In addition, the yield of alloy such as metallic aluminium, magnesium, calcium are high, low energy consumption, and production cost is low and solves
Ferro-aluminum is in air during natural storage the problem of dusting.
Embodiment 4
The present embodiment is a kind of high efficiency preparation method of ferro-aluminum base series alloy, comprising the following steps:
(i) it uses intermediate frequency furnace or electric furnace by scrap melting at molten steel, removes slag stand-by;Controlling liquid steel temperature is 1600-1700 DEG C;
(ii) aluminium ingot is put into alloy packet, and toasts and is melted into molten aluminum;Controlling temperature of aluminum liquid is 1000-1100 DEG C;Step
Suddenly (i) in, the weight of steel scrap be need ferro-aluminum base system column weight alloy to be prepared 40%, step (ii) in, the weight of aluminium ingot is need
The 60% of ferro-aluminum base system column weight alloy to be prepared;
(iii) the corresponding magnesium metal of other conjunction elements that will need to be added into ferro-aluminum and calcium are added in molten aluminum, make its fusing;It need to
The corresponding manganese metal of other conjunction elements for being added into ferro-aluminum adds in molten steel, makes its fusing;
(iv) the alloy packet equipped with molten aluminum is transported under intermediate frequency furnace or electric furnace fire door, is directly rushed with the molten steel in intermediate frequency furnace or electric furnace
Being blended into alloy packet becomes aluminium alloy, and control aluminium alloy temperature is 1350-1550 DEG C, and poly- slag and slagging-off;
(v) alloy packet handling to casting machine is poured, completes the preparation of ferro-aluminum base series alloy.
The preparation method of the ferro-aluminum base series alloy of the embodiment of the present invention, simple for process, high production efficiency, production effect
The more other methods of rate improve 80-100%;In addition, the yield of alloy such as metallic aluminium, magnesium, calcium are high, low energy consumption, and production cost is low and solves
Ferro-aluminum is in air during natural storage the problem of dusting.
The above examples only illustrate the technical idea of the present invention, and this does not limit the scope of protection of the present invention, all
According to the technical idea provided by the invention, any changes made on the basis of the technical scheme each falls within the scope of the present invention
Within.
Claims (8)
1. a kind of high efficiency preparation method of alfer, it is characterised in that: the following steps are included:
(i) use intermediate frequency furnace or electric furnace by scrap melting at molten steel, it is stand-by after removing slag;
(ii) aluminium ingot is put into alloy packet, and toasts and is melted into molten aluminum;
(iii) the alloy packet equipped with molten aluminum is transported under intermediate frequency furnace or electric furnace fire door, is directly rushed with the molten steel in intermediate frequency furnace or electric furnace
Being blended into alloy packet becomes aluminium alloy, and poly- slag and slagging-off;
(iv) alloy packet handling to casting machine is poured, completes the preparation of alfer.
2. the high efficiency preparation method of alfer as described in claim 1, it is characterised in that: the step (i) in, it is described
The weight of steel scrap is the 20-80% for needing alfer weight to be prepared, the step (ii) in, the weight of aluminium ingot is to need to prepare
Alfer weight 20-80%, the sum of weight of the steel scrap and aluminium ingot for preparation alfer weight.
3. the high efficiency preparation method of alfer as described in claim 1, it is characterised in that: the step (i) in, will give up
Steel is fused into molten steel, and control liquid steel temperature is 1580-1700 DEG C;The step (ii) in, aluminium ingot is melted into molten aluminum, controls aluminium
Liquid temperature is 670-1100 DEG C;The step (iii) in, molten steel, which directly rushes to be blended into alloy packet, becomes aluminium alloy, controls aluminium alloy temperature
Degree is 1150-1550 DEG C.
4. the high efficiency preparation method of alfer as described in claim 1, it is characterised in that: the step (iii) in, use
Slag conglomeration agent carries out poly- slag, and the Slag conglomeration agent is by sodium chloride, Fluorspar Powder, pulverized limestone, Cab-O-sil, calcined bauxite in powder by weight 5:5:35:
20:35 is mixed.
5. a kind of high efficiency preparation method of ferro-aluminum base series alloy, it is characterised in that: the following steps are included:
(i) use intermediate frequency furnace or electric furnace by scrap melting at molten steel, it is stand-by after removing slag;
(ii) aluminium ingot is put into alloy packet, and toasts and is melted into molten aluminum;
(iii) the corresponding metal of the other conjunction elements for needing to be added into ferro-aluminum is added in molten aluminum or molten steel, makes its fusing;Other conjunctions
The rule that the corresponding metal of gold element is added are as follows: if the melting point metal is more than or equal to 1000 DEG C, which is added molten steel
In;If less than 1000 DEG C, which is added in molten aluminum for the melting point metal;
(iv) the alloy packet equipped with molten aluminum is transported under intermediate frequency furnace or electric furnace fire door, is directly rushed and is converted with molten steel in intermediate frequency furnace or electric furnace
Entering becomes aluminium alloy in alloy packet, and poly- slag and slagging-off;
(v) alloy packet handling to casting machine is poured, completes the preparation of ferro-aluminum base series alloy.
6. the high efficiency preparation method of ferro-aluminum base series alloy as claimed in claim 5, it is characterised in that: the step is (i)
In, the weight of the steel scrap is the 20-80% for needing alfer weight to be prepared, the step (ii) in, the weight of aluminium ingot is to need
The sum of weight and addition alloying element weight of the 20-80% of alfer weight to be prepared, the steel scrap and aluminium ingot are system
Standby ferro-aluminum base system column weight alloy.
7. the high efficiency preparation method of ferro-aluminum base series alloy as claimed in claim 5, it is characterised in that: the step is (i)
In, by scrap melting at molten steel, controlling liquid steel temperature is 1580-1700 DEG C;The step (ii) in, aluminium ingot is melted into aluminium
Liquid, control temperature of aluminum liquid are 670-1100 DEG C;The step (iv) in, molten steel, which directly rushes to be blended into alloy packet, becomes aluminium alloy, control
Alloyage liquid temperature is 1150-1550 DEG C.
8. the high efficiency preparation method of ferro-aluminum base series alloy as claimed in claim 5, it is characterised in that: the step is (iv)
In, poly- slag is carried out using Slag conglomeration agent, Slag conglomeration agent is by sodium chloride, Fluorspar Powder, pulverized limestone, Cab-O-sil, calcined bauxite in powder by weight 5:5:
35:20:35 is mixed.
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Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5956542A (en) * | 1982-09-24 | 1984-04-02 | Ibiden Co Ltd | Production of calcium alloy |
CN101591720A (en) * | 2009-04-16 | 2009-12-02 | 莱芜市泰钢新材料有限责任公司 | A kind of production method of aluminum-manganese-iron alloy |
CN104789775A (en) * | 2015-04-10 | 2015-07-22 | 东北大学 | Preparation method and use method of aluminum-containing magnesium-smelting reducing agent |
CN107267813A (en) * | 2017-05-22 | 2017-10-20 | 江苏江南铁合金有限公司 | Aluminium ingot production alfer preparation method is converted in molten steel punching |
-
2018
- 2018-08-21 CN CN201810951880.9A patent/CN108950138A/en active Pending
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5956542A (en) * | 1982-09-24 | 1984-04-02 | Ibiden Co Ltd | Production of calcium alloy |
CN101591720A (en) * | 2009-04-16 | 2009-12-02 | 莱芜市泰钢新材料有限责任公司 | A kind of production method of aluminum-manganese-iron alloy |
CN104789775A (en) * | 2015-04-10 | 2015-07-22 | 东北大学 | Preparation method and use method of aluminum-containing magnesium-smelting reducing agent |
CN107267813A (en) * | 2017-05-22 | 2017-10-20 | 江苏江南铁合金有限公司 | Aluminium ingot production alfer preparation method is converted in molten steel punching |
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