CN108948915A - A kind of low reflecting rate color steel plate surface coating material - Google Patents
A kind of low reflecting rate color steel plate surface coating material Download PDFInfo
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/32—Radiation-absorbing paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
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- C08K2003/382—Boron-containing compounds and nitrogen
- C08K2003/385—Binary compounds of nitrogen with boron
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
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- C—CHEMISTRY; METALLURGY
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
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Abstract
The invention discloses a kind of low reflecting rate color steel plate surface coating materials, it is related to colorful steel plate paint technical field, including following raw material: acrylic resin, furane resins, red halloysite, periclase powder, isopropanol, snail mucus, acetylbutyrylcellulose, ultra-fine hexagonal nanometer boron nitride particle, promotor, crosslinking agent, coupling agent.Color steel plate of the invention coating functional, application performance is good, and suitable application area is extensive, and the service life is longer.
Description
Technical field
The present invention relates to colorful steel plate paint technical fields, and in particular to a kind of low reflecting rate color steel plate surface coating material.
Background technique
Color painted steel strip abbreviation Coil Coating Products, color steel plate are by high-quality cold-rolled steel sheet, hot-dip galvanizing sheet steel or Al-Zn coated steel
(roller coating) or the toasted solidification of laminating organic coating are applied after surface degreasing, phosphatization, the conversion of chromic acid salt treatment for substrate
And manufactured product.With social development, the progress of science and technology, market is to the dicoration of coating, weatherability, durability, function
Energy property etc. claims higher and higher.Color steel plate in the prior art is mostly used with organic coating with composite high-molecular organic principle
It is blended, the scope of application and functionality are narrow, poor durability, and especially existing colorful steel plate paint is for a long time on the market
It can fall off, be cracked and fade using rear dope layer, higher requirement is also unable to satisfy in terms of endurance quality, thus largely
By expensive import coating, the cost of color steel plate is improved, the market competitiveness is reduced, hinders color steel plate at home
Development.It can be seen that develop a kind of color steel plate of high comprehensive performance is highly desirable with organic coating.
The patent application of Publication No. CN105670464A discloses a kind of colorful steel plate paint and its manufacturing method, be with
Made of lower weight configuration, including 15-20kg of polyester resin, 10-15kg of silicate fiber cotton, 5-10kg of mica powder, desulfurization stone
10-15kg of cream, 5-10kg of fire retardant, 5-10kg of fiber, 5-10kg of waterglass, 5-10kg of aluminium oxide, brightener 15-
20kg；Preparation method of the present invention is specific as follows: raw material weighed first, in accordance with each component raw material, then pours into water in reaction kettle,
When being heated to 30-40 DEG C, be added polyester resin, silicate fiber cotton, mica powder, desulfurized gypsum, fire retardant, fiber, waterglass,
Aluminium oxide, brightener stirring, then are warming up to 90 DEG C, after 30 points of heat preservation to get.This kind of colorful steel plate paint is non-toxic and tasteless corrosion-free
Property, preparation is simple, and it is low in cost, but adhesive force is poor.
The patent application for authorizing Publication No. CN103073990B, discloses a kind of UV light for tectorial color steel plate
Change coating composition, each component including following weight percent content: the polyester acrylate 5~20% of high functional group gathers
Urethane acrylate 15~32%, epoxy acrylate 5~16%, monofunctional acrylates' ester monomer 1~5%, high functional group
Acrylate monomer 10~25%, the acrylate 2~5% of acroleic acid esterification, photoinitiator 2~6%, levelling agent 0.1~
1.5%, polymerization inhibitor 0.01~0.05%, solvent 40~58%.This kind of paint solidification speed is fast, and filming performance is good, but its table
Face performance is poor, and salt tolerance is not corroded.
Summary of the invention
The purpose of the present invention is to provide a kind of low reflecting rate color steel plate surface coating material, this kind of coating functional is answered
Good with performance, suitable application area is extensive, and the service life is longer.
In order to achieve the above object, the present invention is achieved through the following technical solutions:
A kind of low reflecting rate color steel plate surface coating material, including following raw material by weight:
49-53 parts of acrylic resin；
24-26 parts of furane resins；
4.5-5.5 parts of red halloysite；
6.5-7.5 parts of periclase powder；
9-11 parts of isopropanol；
4-5 parts of snail mucus；
1.2-1.6 parts of acetylbutyrylcellulose；
2.8-3.5 parts of ultra-fine hexagonal nanometer boron nitride particle；
0.65-0.75 parts of promotor；
0.95-1.05 parts of crosslinking agent；
0.55-0.65 parts of coupling agent.
Further, above-mentioned coating includes following raw material by weight:
53 parts of acrylic resin；
26 parts of furane resins；
5.5 parts of red halloysite；
7.5 parts of periclase powder；
11 parts of isopropanol；
5 parts of snail mucus；
1.6 parts of acetylbutyrylcellulose；
3.5 parts of ultra-fine hexagonal nanometer boron nitride particle；
0.75 part of promotor；
1.05 parts of crosslinking agent；
0.65 part of coupling agent.
Preferably, above-mentioned promotor is using tetramethyl thiourea, promotor 962, promotor LTH according to weight ratio 1.6:2.5:
2.8 are sufficiently blended to obtain.
Preferably, above-mentioned crosslinking agent is using Diacetone Acrylamide, amino resins according to weight ratio (2-3): (3-5) is abundant
It is blended to obtain.
Further, above-mentioned crosslinking agent is sufficiently mixed according to weight ratio 2.8:4.5 using Diacetone Acrylamide, amino resins
It is made.
Preferably, above-mentioned coupling agent is even using anti-settling Aluminate ASA, epoxy silane coupling KH-560, rare earth
Join agent according to weight ratio (2.3-2.7): (4.5-5.5): (1.2-1.6) is sufficiently blended to obtain.
Further, above-mentioned coupling agent uses anti-settling Aluminate ASA, epoxy silane coupling KH-560, rare earth
Coupling agent is sufficiently blended to obtain according to weight ratio 2.7:5.5:1.6.
Further, above-mentioned coating further includes the anti-cracking agent that parts by weight are 1.2.
Preferably, above-mentioned anti-cracking agent is using polyacrylonitrile chopped strand, shepardite chopped strand according to weight ratio 3.5:1.5
It is sufficiently blended to obtain.
Further, above-mentioned coating the preparation method is as follows:
I: red halloysite and periclase powder are taken, the RO water of weight percent 116% is added, grinding stirring makes it completely dissolved,
85 DEG C are heated to, acrylic resin is added and mixes, and insulated and stirred 7.5min at a temperature of 85 DEG C, obtains mixing A；
II: under stirring condition, the coupling agent of promotor and parts by weight 76% that parts by weight 65% are added is sufficiently mixed
It closes, adds furane resins mixing, and be heated to 88 DEG C, insulated and stirred 11.5min is added after it is cooled to 54 DEG C
Snail mucus is sufficiently mixed, and obtains mixed material B；
III: isopropanol is added into mixed material B and mixes, then under agitation, be added remaining weight number promotor and
Coupling agent is sufficiently mixed, and is heated to 85 DEG C, and acetylbutyrylcellulose is added and ultra-fine hexagonal nanometer boron nitride particle fills
Divide mixing, and insulated and stirred 6.5min, obtains mixing C；
IV: mixing C being poured into agitator tank, is mixed under the conditions of vacuum degree is 0.110MPa, temperature is 76 DEG C anti-
Remaining other raw materials are added before answering 165min, stirring to terminate when 42s, during which agitator tank speed of agitator is 750r/min.
The present invention has following the utility model has the advantages that coating preparation of the invention is simple and convenient, compatibility between each material component
Can be good, properties of product are stablized, and it is not volatile, easily store；By to the ingenious selection of raw materials for production and its creation of preparation process
Property improve, the cooperative interaction of the compositions such as acrylic resin, furane resins, red halloysite, periclase powder in raw material, reached with
Lower effect:
(1) application property: dry solidification speed is fast, is adaptable to shape in any shape complicated interface with object, after brushing not
The problems such as will appear sagging, out-of-flatness, Wu Erdao is accessible, easy for construction；
(2) feature of environmental protection: the pernicious gases such as no radon, formaldehyde, benzene and irritation peculiar smell generate, and contamination hazard is small, environmentally protective,
It is healthy and safe；
(3) decorative: the crosslinking of paint film structure sheaf is firm, and wear-resisting, scratch-resistant, stain resistant is strong, fade-proof, good decorative property；
(4) durability: long service life has excellent weatherability and corrosion resistance, and adhesive force is strong, water-and fire-proof, table
Face performance is good, is not in that surface layer falls off, cracks and other issues after shock resistance, and paint film complete and smooth is loosened without bulge, flexible
Property is good, counter-bending；
(5) be electromagnetically shielded absorbability: electromagnetic shielding performance is good, and efficiency is high, reduces electromagnetic radiation transmitting and lives to people
The interference damage of work；
(6) reflective: illumination reflectivity is low, and light pollution harm is small.
Specific embodiment
Below with reference to embodiment, further description of the specific embodiments of the present invention, and following embodiment is only used for more
Technical solution of the present invention is clearly demonstrated, and not intended to limit the protection scope of the present invention.
It all raw materials in embodiment and its produces composition and can be obtained by disclosed commercially available channel；
Embodiment 1
The present embodiment is related to a kind of low reflecting rate color steel plate surface coating material and preparation method thereof, and the coating is by below by weight
Measure the raw material composition of part meter:
47 parts of acrylic resin；
22 parts of furane resins；
4 parts of red halloysite；
6 parts of periclase powder；
8 parts of isopropanol；
3.5 parts of snail mucus；
1 part of acetylbutyrylcellulose；
2.5 parts of ultra-fine hexagonal nanometer boron nitride particle；
0.6 part of promotor；
0.9 part of crosslinking agent；
0.5 part of coupling agent；
Promotor in the present embodiment, crosslinking agent and coupling agent selection and produce as shown in table 1 below:
Table 1
The preparation method of the present embodiment coating follows the steps below:
I: red halloysite and periclase powder are taken, the RO water of weight percent 112% is added, grinding stirring makes it completely dissolved,
82 DEG C are heated to, acrylic resin is added and mixes, and insulated and stirred 9min at a temperature of 82 DEG C, obtains mixing A；
II: under stirring condition, the coupling agent of promotor and parts by weight 73% that parts by weight 62% are added is sufficiently mixed
It closes, adds furane resins mixing, and be heated to 85 DEG C, snail is added after it is cooled to 50 DEG C in insulated and stirred 13min
Ox mucus is sufficiently mixed, and obtains mixed material B；
III: isopropanol is added into mixed material B and mixes, then under agitation, be added remaining weight number promotor and
Coupling agent is sufficiently mixed, and is heated to 82 DEG C, and acetylbutyrylcellulose is added and ultra-fine hexagonal nanometer boron nitride particle fills
Divide mixing, and insulated and stirred 8min, obtains mixing C；
IV: mixing C being poured into agitator tank, is mixed under the conditions of vacuum degree is 0.095MPa, temperature is 72 DEG C anti-
Crosslinking agent is added when 36s before answering 180min, stirring to terminate, during which agitator tank speed of agitator is 600r/min.
Embodiment 2
The present embodiment is related to a kind of low reflecting rate color steel plate surface coating material and preparation method thereof, and the coating is by below by weight
Measure the raw material composition of part meter:
49 parts of acrylic resin；
24 parts of furane resins；
4.5 parts of red halloysite；
6.5 parts of periclase powder；
9 parts of isopropanol；
4 parts of snail mucus；
1.2 parts of acetylbutyrylcellulose；
2.8 parts of ultra-fine hexagonal nanometer boron nitride particle；
0.65 part of promotor；
0.95 part of crosslinking agent；
0.55 part of coupling agent；
Promotor in the present embodiment, crosslinking agent and coupling agent selection and produce as shown in table 2 below:
Table 2
The preparation method of the present embodiment coating follows the steps below:
I: red halloysite and periclase powder are taken, the RO water of weight percent 114% is added, grinding stirring makes it completely dissolved,
83 DEG C are heated to, acrylic resin is added and mixes, and insulated and stirred 8.5min at a temperature of 83 DEG C, obtains mixing A；
II: under stirring condition, the coupling agent of promotor and parts by weight 74% that parts by weight 63% are added is sufficiently mixed
It closes, adds furane resins mixing, and be heated to 86 DEG C, insulated and stirred 12.5min is added after it is cooled to 52 DEG C
Snail mucus is sufficiently mixed, and obtains mixed material B；
III: isopropanol is added into mixed material B and mixes, then under agitation, be added remaining weight number promotor and
Coupling agent is sufficiently mixed, and is heated to 83 DEG C, and acetylbutyrylcellulose is added and ultra-fine hexagonal nanometer boron nitride particle fills
Divide mixing, and insulated and stirred 7.5min, obtains mixing C；
IV: mixing C being poured into agitator tank, reaction is mixed under the conditions of vacuum degree is 0.1MPa, temperature is 74 DEG C
Crosslinking agent is added when 38s before stirring terminates in 175min, and during which agitator tank speed of agitator is 650r/min.
Embodiment 3
The present embodiment is related to a kind of low reflecting rate color steel plate surface coating material and preparation method thereof, and the coating is by below by weight
Measure the raw material composition of part meter:
51 parts of acrylic resin；
25 parts of furane resins；
5 parts of red halloysite；
7 parts of periclase powder；
10 parts of isopropanol；
4.5 parts of snail mucus；
1.4 parts of acetylbutyrylcellulose；
3.2 parts of ultra-fine hexagonal nanometer boron nitride particle；
0.7 part of promotor；
1.0 parts of crosslinking agent；
0.6 part of coupling agent；
1 part of anti-cracking agent；
Promotor in the present embodiment, crosslinking agent, coupling agent and anti-cracking agent selection and produce as shown in table 3 below:
Table 3
The preparation method of the present embodiment coating follows the steps below:
I: red halloysite and periclase powder are taken, the RO water of weight percent 115% is added, grinding stirring makes it completely dissolved,
84 DEG C are heated to, acrylic resin is added and mixes, and insulated and stirred 8min at a temperature of 84 DEG C, obtains mixing A；
II: under stirring condition, the coupling agent of promotor and parts by weight 75% that parts by weight 64% are added is sufficiently mixed
It closes, adds furane resins mixing, and be heated to 87 DEG C, snail is added after it is cooled to 53 DEG C in insulated and stirred 12min
Ox mucus is sufficiently mixed, and obtains mixed material B；
III: isopropanol is added into mixed material B and mixes, then under agitation, be added remaining weight number promotor and
Coupling agent is sufficiently mixed, and is heated to 84 DEG C, and acetylbutyrylcellulose is added and ultra-fine hexagonal nanometer boron nitride particle fills
Divide mixing, and insulated and stirred 7min, obtains mixing C；
IV: mixing C being poured into agitator tank, is mixed under the conditions of vacuum degree is 0.105MPa, temperature is 75 DEG C anti-
Remaining other raw materials are added before answering 170min, stirring to terminate when 40s, during which agitator tank speed of agitator is 700r/min.
Embodiment 4
The present embodiment is related to a kind of low reflecting rate color steel plate surface coating material and preparation method thereof, and the coating is by below by weight
Measure the raw material composition of part meter:
53 parts of acrylic resin；
26 parts of furane resins；
5.5 parts of red halloysite；
7.5 parts of periclase powder；
11 parts of isopropanol；
5 parts of snail mucus；
1.6 parts of acetylbutyrylcellulose；
3.5 parts of ultra-fine hexagonal nanometer boron nitride particle；
0.75 part of promotor；
1.05 parts of crosslinking agent；
0.65 part of coupling agent；
1.2 parts of anti-cracking agent；
Promotor in the present embodiment, crosslinking agent, coupling agent and anti-cracking agent selection and produce as shown in table 4 below:
Table 4
The preparation method of the present embodiment coating follows the steps below:
I: red halloysite and periclase powder are taken, the RO water of weight percent 116% is added, grinding stirring makes it completely dissolved,
85 DEG C are heated to, acrylic resin is added and mixes, and insulated and stirred 7.5min at a temperature of 85 DEG C, obtains mixing A；
II: under stirring condition, the coupling agent of promotor and parts by weight 76% that parts by weight 65% are added is sufficiently mixed
It closes, adds furane resins mixing, and be heated to 88 DEG C, insulated and stirred 11.5min is added after it is cooled to 54 DEG C
Snail mucus is sufficiently mixed, and obtains mixed material B；
III: isopropanol is added into mixed material B and mixes, then under agitation, be added remaining weight number promotor and
Coupling agent is sufficiently mixed, and is heated to 85 DEG C, and acetylbutyrylcellulose is added and ultra-fine hexagonal nanometer boron nitride particle fills
Divide mixing, and insulated and stirred 6.5min, obtains mixing C；
IV: mixing C being poured into agitator tank, is mixed under the conditions of vacuum degree is 0.110MPa, temperature is 76 DEG C anti-
Remaining other raw materials are added before answering 165min, stirring to terminate when 42s, during which agitator tank speed of agitator is 750r/min.
Embodiment 5
The present embodiment is related to a kind of low reflecting rate color steel plate surface coating material and preparation method thereof, and the coating is by below by weight
Measure the raw material composition of part meter:
55 parts of acrylic resin；
28 parts of furane resins；
6 parts of red halloysite；
8.5 parts of periclase powder；
12 parts of isopropanol；
5.5 parts of snail mucus；
2 parts of acetylbutyrylcellulose；
4 parts of ultra-fine hexagonal nanometer boron nitride particle；
0.8 part of promotor；
1.1 parts of crosslinking agent；
0.7 part of coupling agent；
1.4 parts of anti-cracking agent；
Promotor in the present embodiment, crosslinking agent, coupling agent and anti-cracking agent selection and produce as shown in table 5 below:
Table 5
The preparation method of the present embodiment coating follows the steps below:
I: red halloysite and periclase powder are taken, the RO water of weight percent 118% is added, grinding stirring makes it completely dissolved,
86 DEG C are heated to, acrylic resin is added and mixes, and insulated and stirred 7min at a temperature of 86 DEG C, obtains mixing A；
II: under stirring condition, the coupling agent of promotor and parts by weight 77% that parts by weight 66% are added is sufficiently mixed
It closes, adds furane resins mixing, and be heated to 89 DEG C, snail is added after it is cooled to 55 DEG C in insulated and stirred 11min
Ox mucus is sufficiently mixed, and obtains mixed material B；
III: isopropanol is added into mixed material B and mixes, then under agitation, be added remaining weight number promotor and
Coupling agent is sufficiently mixed, and is heated to 86 DEG C, and acetylbutyrylcellulose is added and ultra-fine hexagonal nanometer boron nitride particle fills
Divide mixing, and insulated and stirred 6min, obtains mixing C；
IV: mixing C being poured into agitator tank, is mixed under the conditions of vacuum degree is 0.115MPa, temperature is 78 DEG C anti-
Remaining other raw materials are added before answering 160min, stirring to terminate when 44s, during which agitator tank speed of agitator is 800r/min.
Comparative example 1
This comparative example is related to a kind of colorful steel plate paint, and compared to embodiment 1, promotor is answered in comparative example removing composition
With other compositions, content and preparation method thereof are same as Example 1.
Comparative example 2
This comparative example is related to a kind of colorful steel plate paint, and compared to embodiment 2, crosslinking agent is answered in comparative example removing composition
With other compositions, content and preparation method thereof are same as Example 2.
Comparative example 3
This comparative example is related to a kind of colorful steel plate paint, and compared to embodiment 3, coupling agent is answered in comparative example removing composition
With other compositions, content and preparation method thereof are same as Example 3.
Comparative example 4
This comparative example is related to a kind of colorful steel plate paint, and compared to embodiment 4, anti-cracking agent is answered in comparative example removing composition
With other compositions, content and preparation method thereof are same as Example 4.
Comparative example 5
This comparative example is related to a kind of colorful steel plate paint, and compared to embodiment 5, which removes promotor in composition, hands over
Join agent, the application of coupling agent, anti-cracking agent, other compositions, content and preparation method thereof are same as Example 5.
Comparative example 6
This comparative example is related to a kind of preparation method of colorful steel plate paint, and compared to embodiment 5, there is only preparation methods not
Together, other compositions and its content are same as Example 5 in coating, the colorful steel plate paint of this comparative example the preparation method is as follows:
By raw material propylene acid resin, furane resins, red halloysite, periclase powder, isopropanol, snail mucus, acetylbutyrylcellulose, ultra-fine
Hexagonal nanometer boron nitride particle, promotor, coupling agent are delivered in agitator tank jointly, vacuum degree is 0.115MPa, temperature is
Reaction 160min is mixed under the conditions of 78 DEG C, remaining other raw materials are added before stirring terminates when 44s, during which agitator tank stirring turns
Speed is 800r/min.
Comparative example 7
This comparative example is related to a kind of colorful steel plate paint, the raw material including following kg by weight meter: 15-20kg of polyester resin,
10-15kg of silicate fiber cotton, 5-10kg of mica powder, 10-15kg of desulfurized gypsum, 5-10kg of fire retardant, 5-10kg of fiber,
5-10kg of waterglass, 5-10kg of aluminium oxide, 15-20kg of brightener.
Implementation result
For the beneficial effect for verifying the present invention, following property is carried out to coating made from above-described embodiment 1-5 and comparative example 1-7
The detection of energy index:
One: referring to JG-T224-2007 construction steel structure anticorrosive paint examination criteria and method, correlation performance parameters are such as
Shown in the following table 6 and table 7:
Table 6:
Table 7: comparative example (comparative example 1-7 respectively corresponds 1#-7#)
As shown in upper table 6 and table 7, colorful steel plate paint of the invention is significantly better than that comparative example in performance in all respects, has
There is progress significantly and promoted, application performance is more preferable, and the service life is longer.
Two: the detection of electromagnetic wave shielding and reflective
Electromagnetic shielding detection: according to GB/T30142-2013 plane electromagnetic shielding material shield effectiveness measurement method, electricity
Magnet rate is set as 3GHz, measures electromagnet shield effect in the following table 8；
Reflective detection (tone is blue): intensity of illumination is set as 80000lx, measures illumination reflectivity (%) in the following table 8；
Table 8
Illustrate: in above-mentioned table, electromagnet shield effect is higher, and shield effectiveness is better；Illumination reflectivity is smaller, and intensity of light reflection is got over
It is weak.
As shown in upper table 8, colorful steel plate paint of the invention improves 3- compared to comparative example on electromagnet shield effect
28dB reduces 0-20 percentage points in illumination reflectivity performance applications, and therefore, colorful steel plate paint of the invention has significant
Ground progress and promotion, functional stronger, application field is more extensive.
In conjunction with the excellent effect of the present invention, applicant is illustrated constituent part and preparation method of the invention:
(1) snail mucus: the mucus that snail mucus is secreted out of as animal body, application field is relatively narrow at present, mostly makes up
Product field, still, applicant has been surprisingly found that in development process, cooperates with interaction with base-materials, fillers such as acrylic resins,
The adhesive force and film forming of finished product coating can be significantly improved, while also improving the corrosion-resistant equal physics and chemistry of film surface
Energy；
(2) promotor: tetramethyl thiourea, promotor 962, promotor LTH are provided with certain reaction promotion functions, but
In order to adapt to the formation of coating system of the invention, found through many experiments, using above-mentioned composition according to weight ratio (1-2): (1-
3): the compound accelerant that (2-3) is blended, the quick and stable of reaction system when can not only realize coating preparation, moreover it is possible to have
Effect promotes the adhesive force and physicochemical property of finished product coating system；
(3) crosslinking agent: Diacetone Acrylamide, amino resins are common crosslinking agent, and applicant is in development process
It was found that the addition of Diacetone Acrylamide or amino resins list composition is difficult to reach the beneficial effect of this coating system, by skilful
Wonderfully by above two composition according to weight ratio (2-3): the product that (3-5) is sufficiently blended can admirably achieve this hair
Bright technical effect and purpose obtains the more excellent performances such as water-fast, corrosion-resistant.
(4) coupling agent: epoxy silane coupling KH-560 is most common coupling agent in coating system, is most being started
Test in, the compatibility and interface characteristics, the finished product prepared that are difficult to improve separately as coupling agent of the invention between raw material
Coating property is bad, and then, application people have been surprisingly found that is contained in anti-settling Aluminate ASA can be with active hydrogen reaction
Group can occur bonding action with the inorganic filler in this coating system, can substantially improve red halloysite, periclase powder, ultra-fine six
The compatibility and binding force of square boron nitride nanometer granular filler and acrylic resin and furane resins, coordinated rare-earth coupling agent
According to weight ratio (2-3): (4-6): (1-2) is blended, and is not only stablized coating system of the invention, is reached result of prevention, may be used also
Improve the adhesive strength of coating system.
(5) agitator tank revolving speed: the final speed of agitator of coating system of the present invention is worthy of careful study, optimum interval 600-
800r/min is lower than the revolving speed section, reacts insufficient, it is difficult to embody the beneficial effect of finished product coating；Higher than the revolving speed section,
Production cost will be will increase, or even cause the reduction or missing of comprehensive performance.
Certainly, because of the requirement of the mentality of designing and goal of the invention of coating of the present invention, remaining of the invention component selection and contain
Amount selection is obviously also non-obvious, and those skilled in the art combine the prior art that can readily occur in absolutely not.This is at this
Have further embodiment in terms of the preparation method of invention coating, in conjunction with the embodiment of the present invention it can be seen that, preparation of the invention
Method uses four steps designs, and raw material is added by several times in batches, and step is simple and orderly, rather than uses the one of prior art routine
(such as comparative example 6) is added in secondary property, and this preparation process is adapted with the special proportion of coating components of the present invention, only with adopting
With this technique, it just can guarantee that the smooth sequential of reaction system carries out, ensure the superiority for the coating property finally prepared.
The foregoing is only a preferred embodiment of the present invention, is not intended to restrict the invention, although referring to aforementioned reality
Applying example, invention is explained in detail, for those skilled in the art, still can be to aforementioned each implementation
Technical solution documented by example is modified or equivalent replacement of some of the technical features.It is all in essence of the invention
Within mind and principle, any modification, equivalent replacement, improvement and so on be should all be included in the protection scope of the present invention.
Claims (10)
1. a kind of low reflecting rate color steel plate surface coating material, which is characterized in that including following raw material by weight:
49-53 parts of acrylic resin；
24-26 parts of furane resins；
4.5-5.5 parts of red halloysite；
6.5-7.5 parts of periclase powder；
9-11 parts of isopropanol；
4-5 parts of snail mucus；
1.2-1.6 parts of acetylbutyrylcellulose；
2.8-3.5 parts of ultra-fine hexagonal nanometer boron nitride particle；
0.65-0.75 parts of promotor；
0.95-1.05 parts of crosslinking agent；
0.55-0.65 parts of coupling agent.
2. a kind of low reflecting rate color steel plate surface coating material according to claim 1, which is characterized in that including below by weight
Measure the raw material of part meter:
53 parts of acrylic resin；
26 parts of furane resins；
5.5 parts of red halloysite；
7.5 parts of periclase powder；
11 parts of isopropanol；
5 parts of snail mucus；
1.6 parts of acetylbutyrylcellulose；
3.5 parts of ultra-fine hexagonal nanometer boron nitride particle；
0.75 part of promotor；
1.05 parts of crosslinking agent；
0.65 part of coupling agent.
3. a kind of low reflecting rate color steel plate surface coating material according to claim 1, which is characterized in that the promotor is
Tetramethyl thiourea, promotor 962, promotor LTH are sufficiently blended to obtain according to weight ratio 1.6:2.5:2.8.
4. a kind of low reflecting rate color steel plate surface coating material according to claim 1, which is characterized in that the crosslinking agent is
Diacetone Acrylamide, amino resins are according to weight ratio (2-3): (3-5) is sufficiently blended to obtain.
5. a kind of low reflecting rate color steel plate surface coating material according to claim 4, which is characterized in that the crosslinking agent is
Diacetone Acrylamide, amino resins are sufficiently blended to obtain according to weight ratio 2.8:4.5.
6. a kind of low reflecting rate color steel plate surface coating material according to claim 1, which is characterized in that the coupling agent is
Anti-settling Aluminate ASA, epoxy silane coupling KH-560, rare-earth coupling agent are according to weight ratio (2.3-2.7): (4.5-
5.5): (1.2-1.6) is sufficiently blended to obtain.
7. a kind of low reflecting rate color steel plate surface coating material according to claim 6, which is characterized in that the coupling agent is
Anti-settling Aluminate ASA, epoxy silane coupling KH-560, rare-earth coupling agent are abundant according to weight ratio 2.7:5.5:1.6
It is blended to obtain.
8. a kind of low reflecting rate color steel plate surface coating material according to claim 1, which is characterized in that the coating also wraps
Include the anti-cracking agent that parts by weight are 1.2.
9. a kind of low reflecting rate color steel plate surface coating material according to claim 8, which is characterized in that the anti-cracking agent is
Polyacrylonitrile chopped strand, shepardite chopped strand are sufficiently blended to obtain according to weight ratio 3.5:1.5.
10. a kind of low reflecting rate color steel plate surface coating material according to claim 1, which is characterized in that the coating
The preparation method is as follows:
I: taking red halloysite and periclase powder, the RO water of weight percent 116% is added, grinding stirring makes it completely dissolved, heats
85 DEG C are warming up to, acrylic resin is added and mixes, and insulated and stirred 7.5min at a temperature of 85 DEG C, obtains mixing A；
II: under stirring condition, the coupling agent of promotor and parts by weight 76% that parts by weight 65% are added is sufficiently mixed, then
Furane resins are added to mix, and are heated to 88 DEG C, it is viscous that snail is added after it is cooled to 54 DEG C in insulated and stirred 11.5min
Liquid is sufficiently mixed, and obtains mixed material B；
III: isopropanol is added into mixed material B and mixes, then under agitation, promotor and the coupling of remaining weight number is added
Agent is sufficiently mixed, and is heated to 85 DEG C, and it is sufficiently mixed that acetylbutyrylcellulose and ultra-fine hexagonal nanometer boron nitride particle is added
It closes, and insulated and stirred 6.5min, obtains mixing C；
IV: mixing C being poured into agitator tank, reaction is mixed under the conditions of vacuum degree is 0.110MPa, temperature is 76 DEG C
Remaining other raw materials are added in 165min when 42s before stirring terminates, during which agitator tank speed of agitator is 750r/min.
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| CN201810658317.2A CN108948915A (en) | 2018-06-25 | 2018-06-25 | A kind of low reflecting rate color steel plate surface coating material |
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| CN201810658317.2A CN108948915A (en) | 2018-06-25 | 2018-06-25 | A kind of low reflecting rate color steel plate surface coating material |
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| CN103289552A (en) * | 2013-05-22 | 2013-09-11 | 无锡市华明化工有限公司 | Coating |
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| CN105440877A (en) * | 2015-12-09 | 2016-03-30 | 青岛唐鹏钢结构工程有限公司 | Weather-resistant composite paint for color steel plates |
| CN105647300A (en) * | 2016-02-19 | 2016-06-08 | 徐冉 | Expandable fireproof paint and preparation method thereof |
| CN106947337A (en) * | 2017-03-07 | 2017-07-14 | 沈阳宣伯新材料科技有限公司 | A kind of color steel heat reflection waterborne metallic paint |
| CN107987783A (en) * | 2017-12-01 | 2018-05-04 | 高产明 | A kind of preparation method of the heat-resisting ultraviolet cured adhesive of high-adhesive-strength |
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2018
- 2018-06-25 CN CN201810658317.2A patent/CN108948915A/en not_active Withdrawn
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103289552A (en) * | 2013-05-22 | 2013-09-11 | 无锡市华明化工有限公司 | Coating |
| CN104927444A (en) * | 2015-06-24 | 2015-09-23 | 青岛麦科三维高新技术有限公司 | Oil paint resistant to weather |
| CN105440877A (en) * | 2015-12-09 | 2016-03-30 | 青岛唐鹏钢结构工程有限公司 | Weather-resistant composite paint for color steel plates |
| CN105647300A (en) * | 2016-02-19 | 2016-06-08 | 徐冉 | Expandable fireproof paint and preparation method thereof |
| CN106947337A (en) * | 2017-03-07 | 2017-07-14 | 沈阳宣伯新材料科技有限公司 | A kind of color steel heat reflection waterborne metallic paint |
| CN107987783A (en) * | 2017-12-01 | 2018-05-04 | 高产明 | A kind of preparation method of the heat-resisting ultraviolet cured adhesive of high-adhesive-strength |
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