CN108912914A - Coating for waterproof color steel plate - Google Patents
Coating for waterproof color steel plate Download PDFInfo
- Publication number
- CN108912914A CN108912914A CN201810658305.XA CN201810658305A CN108912914A CN 108912914 A CN108912914 A CN 108912914A CN 201810658305 A CN201810658305 A CN 201810658305A CN 108912914 A CN108912914 A CN 108912914A
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- steel plate
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- color steel
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- 239000011248 coating agent Substances 0.000 title claims abstract description 61
- 238000000576 coating method Methods 0.000 title claims abstract description 61
- 229910000831 Steel Inorganic materials 0.000 title claims abstract description 48
- 239000010959 steel Substances 0.000 title claims abstract description 48
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims abstract description 36
- 239000007822 coupling agent Substances 0.000 claims abstract description 36
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims abstract description 32
- 239000003431 cross linking reagent Substances 0.000 claims abstract description 24
- 239000000843 powder Substances 0.000 claims abstract description 21
- 239000002994 raw material Substances 0.000 claims abstract description 21
- 239000004925 Acrylic resin Substances 0.000 claims abstract description 18
- 229920000178 Acrylic resin Polymers 0.000 claims abstract description 18
- 235000012245 magnesium oxide Nutrition 0.000 claims abstract description 18
- 239000000395 magnesium oxide Substances 0.000 claims abstract description 18
- 210000003097 mucus Anatomy 0.000 claims abstract description 18
- 229910052582 BN Inorganic materials 0.000 claims abstract description 17
- PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 claims abstract description 17
- 241000237858 Gastropoda Species 0.000 claims abstract description 15
- 238000002156 mixing Methods 0.000 claims description 33
- 238000002360 preparation method Methods 0.000 claims description 29
- 239000000203 mixture Substances 0.000 claims description 25
- 238000003756 stirring Methods 0.000 claims description 25
- 239000011347 resin Substances 0.000 claims description 18
- 229920005989 resin Polymers 0.000 claims description 18
- YLQBMQCUIZJEEH-UHFFFAOYSA-N Furan Chemical compound C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 claims description 17
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 17
- 239000000463 material Substances 0.000 claims description 17
- 239000002245 particle Substances 0.000 claims description 15
- 239000003795 chemical substances by application Substances 0.000 claims description 13
- 238000006243 chemical reaction Methods 0.000 claims description 10
- 238000005336 cracking Methods 0.000 claims description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 8
- 238000013019 agitation Methods 0.000 claims description 7
- 238000000227 grinding Methods 0.000 claims description 7
- 229920003180 amino resin Polymers 0.000 claims description 6
- 239000003080 antimitotic agent Substances 0.000 claims description 4
- 230000008878 coupling Effects 0.000 claims description 4
- 238000010168 coupling process Methods 0.000 claims description 4
- 238000005859 coupling reaction Methods 0.000 claims description 4
- 239000004593 Epoxy Substances 0.000 claims description 3
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 3
- 150000004645 aluminates Chemical class 0.000 claims description 3
- 229920002239 polyacrylonitrile Polymers 0.000 claims description 3
- 229910052761 rare earth metal Inorganic materials 0.000 claims description 3
- 150000002910 rare earth metals Chemical class 0.000 claims description 3
- 229910000077 silane Inorganic materials 0.000 claims description 3
- -1 polypropylene Polymers 0.000 claims description 2
- 238000010792 warming Methods 0.000 claims description 2
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims 2
- RXLHQYBVVJDNNI-UHFFFAOYSA-N NC(=O)N.CS(C)(C)C Chemical group NC(=O)N.CS(C)(C)C RXLHQYBVVJDNNI-UHFFFAOYSA-N 0.000 claims 2
- SWXVUIWOUIDPGS-UHFFFAOYSA-N diacetone alcohol Chemical group CC(=O)CC(C)(C)O SWXVUIWOUIDPGS-UHFFFAOYSA-N 0.000 claims 2
- 239000004743 Polypropylene Substances 0.000 claims 1
- 239000007788 liquid Substances 0.000 claims 1
- 150000002825 nitriles Chemical class 0.000 claims 1
- 229920001155 polypropylene Polymers 0.000 claims 1
- 239000003973 paint Substances 0.000 abstract description 21
- HPTYUNKZVDYXLP-UHFFFAOYSA-N aluminum;trihydroxy(trihydroxysilyloxy)silane;hydrate Chemical compound O.[Al].[Al].O[Si](O)(O)O[Si](O)(O)O HPTYUNKZVDYXLP-UHFFFAOYSA-N 0.000 abstract 1
- 229920006217 cellulose acetate butyrate Polymers 0.000 abstract 1
- 239000007849 furan resin Substances 0.000 abstract 1
- 229910052621 halloysite Inorganic materials 0.000 abstract 1
- 239000002105 nanoparticle Substances 0.000 abstract 1
- 230000000052 comparative effect Effects 0.000 description 32
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 9
- 230000000694 effects Effects 0.000 description 8
- 239000000835 fiber Substances 0.000 description 7
- 238000005286 illumination Methods 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 239000000853 adhesive Substances 0.000 description 5
- 230000001070 adhesive effect Effects 0.000 description 5
- 238000002310 reflectometry Methods 0.000 description 5
- 230000009286 beneficial effect Effects 0.000 description 4
- 238000001514 detection method Methods 0.000 description 4
- 238000011161 development Methods 0.000 description 4
- OMNKZBIFPJNNIO-UHFFFAOYSA-N n-(2-methyl-4-oxopentan-2-yl)prop-2-enamide Chemical compound CC(=O)CC(C)(C)NC(=O)C=C OMNKZBIFPJNNIO-UHFFFAOYSA-N 0.000 description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 229920000742 Cotton Polymers 0.000 description 3
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 3
- MNOILHPDHOHILI-UHFFFAOYSA-N Tetramethylthiourea Chemical compound CN(C)C(=S)N(C)C MNOILHPDHOHILI-UHFFFAOYSA-N 0.000 description 3
- 230000007797 corrosion Effects 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 3
- 239000003063 flame retardant Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000010445 mica Substances 0.000 description 3
- 229910052618 mica group Inorganic materials 0.000 description 3
- 229920001225 polyester resin Polymers 0.000 description 3
- 239000004645 polyester resin Substances 0.000 description 3
- 235000019353 potassium silicate Nutrition 0.000 description 3
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 3
- 238000007711 solidification Methods 0.000 description 3
- 230000008023 solidification Effects 0.000 description 3
- 238000010276 construction Methods 0.000 description 2
- 230000006378 damage Effects 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 230000006870 function Effects 0.000 description 2
- 125000000524 functional group Chemical group 0.000 description 2
- 239000010440 gypsum Substances 0.000 description 2
- 229910052602 gypsum Inorganic materials 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 229910018137 Al-Zn Inorganic materials 0.000 description 1
- 229910018573 Al—Zn Inorganic materials 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- KRVSOGSZCMJSLX-UHFFFAOYSA-L chromic acid Chemical class O[Cr](O)(=O)=O KRVSOGSZCMJSLX-UHFFFAOYSA-L 0.000 description 1
- 239000008199 coating composition Substances 0.000 description 1
- 239000010960 cold rolled steel Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 230000009133 cooperative interaction Effects 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 238000005238 degreasing Methods 0.000 description 1
- 238000006477 desulfuration reaction Methods 0.000 description 1
- 230000023556 desulfurization Effects 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 230000005670 electromagnetic radiation Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000032050 esterification Effects 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- UHESRSKEBRADOO-UHFFFAOYSA-N ethyl carbamate;prop-2-enoic acid Chemical compound OC(=O)C=C.CCOC(N)=O UHESRSKEBRADOO-UHFFFAOYSA-N 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 230000009975 flexible effect Effects 0.000 description 1
- 238000005246 galvanizing Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 230000015784 hyperosmotic salinity response Effects 0.000 description 1
- 230000008676 import Effects 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 239000011256 inorganic filler Substances 0.000 description 1
- 229910003475 inorganic filler Inorganic materials 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 230000007794 irritation Effects 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- 238000000691 measurement method Methods 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 230000000505 pernicious effect Effects 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- KCTAWXVAICEBSD-UHFFFAOYSA-N prop-2-enoyloxy prop-2-eneperoxoate Chemical compound C=CC(=O)OOOC(=O)C=C KCTAWXVAICEBSD-UHFFFAOYSA-N 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 229910052704 radon Inorganic materials 0.000 description 1
- SYUHGPGVQRZVTB-UHFFFAOYSA-N radon atom Chemical compound [Rn] SYUHGPGVQRZVTB-UHFFFAOYSA-N 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000007761 roller coating Methods 0.000 description 1
- 238000007665 sagging Methods 0.000 description 1
- 230000003678 scratch resistant effect Effects 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 230000009967 tasteless effect Effects 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/004—Reflecting paints; Signal paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/32—Radiation-absorbing paints
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/38—Boron-containing compounds
- C08K2003/382—Boron-containing compounds and nitrogen
- C08K2003/385—Binary compounds of nitrogen with boron
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a waterproof paint for a color steel plate, which relates to the technical field of paint for color steel plates and comprises the following raw materials: acrylic resin, furan resin, halloysite, periclase powder, isopropanol, snail mucus, cellulose acetate butyrate, superfine hexagonal boron nitride nanoparticles, an accelerant, a cross-linking agent and a coupling agent. The coating for the color steel plate has the advantages of strong functionality, good application performance, wide application field and longer service life.
Description
Technical field
The present invention relates to colorful steel plate paint technical fields, and in particular to a kind of waterproof color steel plate coating.
Background technique
Color painted steel strip abbreviation Coil Coating Products, color steel plate are by high-quality cold-rolled steel sheet, hot-dip galvanizing sheet steel or Al-Zn coated steel
(roller coating) or the toasted solidification of laminating organic coating are applied after surface degreasing, phosphatization, the conversion of chromic acid salt treatment for substrate
And manufactured product.With social development, the progress of science and technology, market is to the dicoration of coating, weatherability, durability, function
Energy property etc. claims higher and higher.Color steel plate in the prior art is mostly used with organic coating with composite high-molecular organic principle
It is blended, the scope of application and functionality are narrow, poor durability, and especially existing colorful steel plate paint is for a long time on the market
It can fall off, be cracked and fade using rear dope layer, higher requirement is also unable to satisfy in terms of endurance quality, thus largely
By expensive import coating, the cost of color steel plate is improved, the market competitiveness is reduced, hinders color steel plate at home
Development.It can be seen that develop a kind of color steel plate of high comprehensive performance is highly desirable with organic coating.
The patent application of Publication No. CN 105670464A discloses a kind of colorful steel plate paint and its manufacturing method, be with
Made of lower weight configuration, including 15-20kg of polyester resin, 10-15kg of silicate fiber cotton, 5-10kg of mica powder, desulfurization stone
10-15kg of cream, 5-10kg of fire retardant, 5-10kg of fiber, 5-10kg of waterglass, 5-10kg of aluminium oxide, brightener 15-
20kg；Preparation method of the present invention is specific as follows：Raw material is weighed first, in accordance with each component raw material, then pours into water in reaction kettle,
When being heated to 30-40 DEG C, be added polyester resin, silicate fiber cotton, mica powder, desulfurized gypsum, fire retardant, fiber, waterglass,
Aluminium oxide, brightener stirring, then are warming up to 90 DEG C, after 30 points of heat preservation to get.This kind of colorful steel plate paint is non-toxic and tasteless corrosion-free
Property, preparation is simple, and it is low in cost, but adhesive force is poor.
The patent application for authorizing Publication No. CN103073990B, discloses a kind of UV light for tectorial color steel plate
Change coating composition, each component including following weight percent content：The polyester acrylate 5~20% of high functional group gathers
Urethane acrylate 15~32%, epoxy acrylate 5~16%, monofunctional acrylates' ester monomer 1~5%, high functional group
Acrylate monomer 10~25%, the acrylate 2~5% of acroleic acid esterification, photoinitiator 2~6%, levelling agent 0.1~
1.5%, polymerization inhibitor 0.01~0.05%, solvent 40~58%.This kind of paint solidification speed is fast, and filming performance is good, but its table
Face performance is poor, and salt tolerance is not corroded.
Summary of the invention
The purpose of the present invention is to provide a kind of waterproof color steel plate coating, this kind of coating functional, and application performance is good,
Suitable application area is extensive, and the service life is longer.
In order to achieve the above object, the present invention is achieved through the following technical solutions：
A kind of waterproof color steel plate coating is made of following raw material by weight：
49 parts of acrylic resin；
24 parts of furane resins；
4.5 parts of red halloysite；
6.5 parts of periclase powder；
9 parts of isopropanol；
4 parts of snail mucus；
1.2 parts of acetylbutyrylcellulose；
2.8 parts of ultra-fine hexagonal nanometer boron nitride particle；
0.65 part of promotor；
0.95 part of crosslinking agent；
0.55 part of coupling agent.
Preferably, above-mentioned promotor is using tetramethyl thiourea, promotor 962, promotor LTH according to weight ratio (1.2-
1.6):(1.5-2.5):(2.3-2.8) is sufficiently blended to obtain.
Further, above-mentioned promotor is using tetramethyl thiourea, promotor 962, promotor LTH according to weight ratio 1.2:
1.5:2.3 are sufficiently blended to obtain.
Preferably, above-mentioned crosslinking agent is using Diacetone Acrylamide, amino resins according to weight ratio (2.1-2.8):(3.4-
4.5) it is sufficiently blended to obtain.
Further, above-mentioned crosslinking agent is using Diacetone Acrylamide, amino resins according to weight ratio 2.1:3.4 is sufficiently mixed
It is made.
Preferably, above-mentioned coupling agent is even using anti-settling Aluminate ASA, epoxy silane coupling KH-560, rare earth
Join agent according to weight ratio 2.3:4.5:1.2 are sufficiently blended to obtain.
Further, the preparation method of above-mentioned coating is as follows：
Ⅰ：Red halloysite and periclase powder are taken, the RO water of weight percent 114% is added, grinding stirring makes it completely dissolved,
83 DEG C are heated to, acrylic resin is added and mixes, and insulated and stirred 8.5min at a temperature of 83 DEG C, obtains mixing A；
Ⅱ：Under stirring condition, the coupling agent of promotor and parts by weight 74% that parts by weight 63% are added is sufficiently mixed
It closes, adds furane resins mixing, and be heated to 86 DEG C, insulated and stirred 12.5min is added after it is cooled to 52 DEG C
Snail mucus is sufficiently mixed, and obtains mixed material B；
Ⅲ：Isopropanol is added into mixed material B to mix, then under agitation, be added remaining weight number promotor and
Coupling agent is sufficiently mixed, and is heated to 83 DEG C, and acetylbutyrylcellulose is added and ultra-fine hexagonal nanometer boron nitride particle fills
Divide mixing, and insulated and stirred 7.5min, obtains mixing C；
Ⅳ：Mixing C is poured into agitator tank, reaction is mixed under the conditions of vacuum degree is 0.1MPa, temperature is 74 DEG C
Crosslinking agent is added when 38s before stirring terminates in 175min.
Further, in above-mentioned steps IV, the speed of agitator of agitator tank is set as 650r/min.
Further, above-mentioned coating further includes antimitotic agent, which is polyacrylonitrile chopped strand, the chopped fibre of shepardite
Tie up the mixture of two kinds of compositions.
Preferably, above-mentioned antimitotic agent is using polyacrylonitrile chopped strand, shepardite chopped strand according to weight ratio (3-4):
(1-2) is sufficiently blended.
The present invention has following beneficial effect：Coating preparation of the invention is simple and convenient, compatibility between each material component
Can be good, properties of product are stablized, and it is not volatile, easily store；By to the ingenious selection of raw materials for production and its creation of preparation process
Property improve, the cooperative interaction of the compositions such as acrylic resin, furane resins, red halloysite, periclase powder in raw material, reached with
Lower effect：
(1) application property：Dry solidification speed is fast, is adaptable to shape in any shape complicated interface with object, after brushing not
The problems such as will appear sagging, out-of-flatness, Wu Erdao is accessible, easy for construction；
(2) feature of environmental protection：The pernicious gases such as no radon, formaldehyde, benzene and irritation peculiar smell generate, and contamination hazard is small, environmentally protective,
It is healthy and safe；
(3) decorative：The crosslinking of paint film structure sheaf is firm, and wear-resisting, scratch-resistant, stain resistant is strong, fade-proof, good decorative property；
(4) durability：Long service life has excellent weatherability and corrosion resistance, and adhesive force is strong, water-and fire-proof, table
Face performance is good, is not in that surface layer falls off, cracks and other issues after shock resistance, and paint film complete and smooth is loosened without bulge, flexible
Property is good, counter-bending；
(5) it is electromagnetically shielded absorbability：Electromagnetic shielding performance is good, and efficiency is high, reduces electromagnetic radiation transmitting and lives to people
The interference damage of work；
(6) reflective：Illumination reflectivity is low, and light pollution harm is small.
Specific embodiment
Below with reference to embodiment, further description of the specific embodiments of the present invention, and following embodiment is only used for more
Technical solution of the present invention is clearly demonstrated, and not intended to limit the protection scope of the present invention.
It all raw materials in embodiment and its produces composition and can be obtained by disclosed commercially available channel；
Embodiment 1
The present embodiment is related to a kind of waterproof color steel plate coating and preparation method thereof, the coating by it is following by weight
Raw material composition：
47 parts of acrylic resin；
22 parts of furane resins；
4 parts of red halloysite；
6 parts of periclase powder；
8 parts of isopropanol；
3.5 parts of snail mucus；
1 part of acetylbutyrylcellulose；
2.5 parts of ultra-fine hexagonal nanometer boron nitride particle；
0.6 part of promotor；
0.9 part of crosslinking agent；
0.5 part of coupling agent；
Promotor in the present embodiment, crosslinking agent and coupling agent selection and produce as shown in table 1 below：
Table 1
The preparation method of the present embodiment coating follows the steps below：
Ⅰ：Red halloysite and periclase powder are taken, the RO water of weight percent 112% is added, grinding stirring makes it completely dissolved,
82 DEG C are heated to, acrylic resin is added and mixes, and insulated and stirred 9min at a temperature of 82 DEG C, obtains mixing A；
Ⅱ：Under stirring condition, the coupling agent of promotor and parts by weight 73% that parts by weight 62% are added is sufficiently mixed
It closes, adds furane resins mixing, and be heated to 85 DEG C, snail is added after it is cooled to 50 DEG C in insulated and stirred 13min
Ox mucus is sufficiently mixed, and obtains mixed material B；
Ⅲ：Isopropanol is added into mixed material B to mix, then under agitation, be added remaining weight number promotor and
Coupling agent is sufficiently mixed, and is heated to 82 DEG C, and acetylbutyrylcellulose is added and ultra-fine hexagonal nanometer boron nitride particle fills
Divide mixing, and insulated and stirred 8min, obtains mixing C；
Ⅳ：Mixing C is poured into agitator tank, is mixed under the conditions of vacuum degree is 0.095MPa, temperature is 72 DEG C anti-
Crosslinking agent is added when 36s before answering 180min, stirring to terminate, during which agitator tank speed of agitator is 600r/min.
Embodiment 2
The present embodiment is related to a kind of waterproof color steel plate coating and preparation method thereof, the coating by it is following by weight
Raw material composition：
49 parts of acrylic resin；
24 parts of furane resins；
4.5 parts of red halloysite；
6.5 parts of periclase powder；
9 parts of isopropanol；
4 parts of snail mucus；
1.2 parts of acetylbutyrylcellulose；
2.8 parts of ultra-fine hexagonal nanometer boron nitride particle；
0.65 part of promotor；
0.95 part of crosslinking agent；
0.55 part of coupling agent；
Promotor in the present embodiment, crosslinking agent and coupling agent selection and produce as shown in table 2 below：
Table 2
The preparation method of the present embodiment coating follows the steps below：
Ⅰ：Red halloysite and periclase powder are taken, the RO water of weight percent 114% is added, grinding stirring makes it completely dissolved,
83 DEG C are heated to, acrylic resin is added and mixes, and insulated and stirred 8.5min at a temperature of 83 DEG C, obtains mixing A；
Ⅱ：Under stirring condition, the coupling agent of promotor and parts by weight 74% that parts by weight 63% are added is sufficiently mixed
It closes, adds furane resins mixing, and be heated to 86 DEG C, insulated and stirred 12.5min is added after it is cooled to 52 DEG C
Snail mucus is sufficiently mixed, and obtains mixed material B；
Ⅲ：Isopropanol is added into mixed material B to mix, then under agitation, be added remaining weight number promotor and
Coupling agent is sufficiently mixed, and is heated to 83 DEG C, and acetylbutyrylcellulose is added and ultra-fine hexagonal nanometer boron nitride particle fills
Divide mixing, and insulated and stirred 7.5min, obtains mixing C；
Ⅳ：Mixing C is poured into agitator tank, reaction is mixed under the conditions of vacuum degree is 0.1MPa, temperature is 74 DEG C
Crosslinking agent is added when 38s before stirring terminates in 175min, and during which agitator tank speed of agitator is 650r/min.
Embodiment 3
The present embodiment is related to a kind of waterproof color steel plate coating and preparation method thereof, the coating by it is following by weight
Raw material composition：
51 parts of acrylic resin；
25 parts of furane resins；
5 parts of red halloysite；
7 parts of periclase powder；
10 parts of isopropanol；
4.5 parts of snail mucus；
1.4 parts of acetylbutyrylcellulose；
3.2 parts of ultra-fine hexagonal nanometer boron nitride particle；
0.7 part of promotor；
1.0 parts of crosslinking agent；
0.6 part of coupling agent；
1 part of anti-cracking agent；
Promotor in the present embodiment, crosslinking agent, coupling agent and anti-cracking agent selection and produce as shown in table 3 below：
Table 3
The preparation method of the present embodiment coating follows the steps below：
Ⅰ：Red halloysite and periclase powder are taken, the RO water of weight percent 115% is added, grinding stirring makes it completely dissolved,
84 DEG C are heated to, acrylic resin is added and mixes, and insulated and stirred 8min at a temperature of 84 DEG C, obtains mixing A；
Ⅱ：Under stirring condition, the coupling agent of promotor and parts by weight 75% that parts by weight 64% are added is sufficiently mixed
It closes, adds furane resins mixing, and be heated to 87 DEG C, snail is added after it is cooled to 53 DEG C in insulated and stirred 12min
Ox mucus is sufficiently mixed, and obtains mixed material B；
Ⅲ：Isopropanol is added into mixed material B to mix, then under agitation, be added remaining weight number promotor and
Coupling agent is sufficiently mixed, and is heated to 84 DEG C, and acetylbutyrylcellulose is added and ultra-fine hexagonal nanometer boron nitride particle fills
Divide mixing, and insulated and stirred 7min, obtains mixing C；
Ⅳ：Mixing C is poured into agitator tank, is mixed under the conditions of vacuum degree is 0.105MPa, temperature is 75 DEG C anti-
Remaining other raw materials are added before answering 170min, stirring to terminate when 40s, during which agitator tank speed of agitator is 700r/min.
Embodiment 4
The present embodiment is related to a kind of waterproof color steel plate coating and preparation method thereof, the coating by it is following by weight
Raw material composition：
53 parts of acrylic resin；
26 parts of furane resins；
5.5 parts of red halloysite；
7.5 parts of periclase powder；
11 parts of isopropanol；
5 parts of snail mucus；
1.6 parts of acetylbutyrylcellulose；
3.5 parts of ultra-fine hexagonal nanometer boron nitride particle；
0.75 part of promotor；
1.05 parts of crosslinking agent；
0.65 part of coupling agent；
1.2 parts of anti-cracking agent；
Promotor in the present embodiment, crosslinking agent, coupling agent and anti-cracking agent selection and produce as shown in table 4 below：
Table 4
The preparation method of the present embodiment coating follows the steps below：
Ⅰ：Red halloysite and periclase powder are taken, the RO water of weight percent 116% is added, grinding stirring makes it completely dissolved,
85 DEG C are heated to, acrylic resin is added and mixes, and insulated and stirred 7.5min at a temperature of 85 DEG C, obtains mixing A；
Ⅱ：Under stirring condition, the coupling agent of promotor and parts by weight 76% that parts by weight 65% are added is sufficiently mixed
It closes, adds furane resins mixing, and be heated to 88 DEG C, insulated and stirred 11.5min is added after it is cooled to 54 DEG C
Snail mucus is sufficiently mixed, and obtains mixed material B；
Ⅲ：Isopropanol is added into mixed material B to mix, then under agitation, be added remaining weight number promotor and
Coupling agent is sufficiently mixed, and is heated to 85 DEG C, and acetylbutyrylcellulose is added and ultra-fine hexagonal nanometer boron nitride particle fills
Divide mixing, and insulated and stirred 6.5min, obtains mixing C；
Ⅳ：Mixing C is poured into agitator tank, is mixed under the conditions of vacuum degree is 0.110MPa, temperature is 76 DEG C anti-
Remaining other raw materials are added before answering 165min, stirring to terminate when 42s, during which agitator tank speed of agitator is 750r/min.
Embodiment 5
The present embodiment is related to a kind of waterproof color steel plate coating and preparation method thereof, the coating by it is following by weight
Raw material composition：
55 parts of acrylic resin；
28 parts of furane resins；
6 parts of red halloysite；
8.5 parts of periclase powder；
12 parts of isopropanol；
5.5 parts of snail mucus；
2 parts of acetylbutyrylcellulose；
4 parts of ultra-fine hexagonal nanometer boron nitride particle；
0.8 part of promotor；
1.1 parts of crosslinking agent；
0.7 part of coupling agent；
1.4 parts of anti-cracking agent；
Promotor in the present embodiment, crosslinking agent, coupling agent and anti-cracking agent selection and produce as shown in table 5 below：
Table 5
The preparation method of the present embodiment coating follows the steps below：
Ⅰ：Red halloysite and periclase powder are taken, the RO water of weight percent 118% is added, grinding stirring makes it completely dissolved,
86 DEG C are heated to, acrylic resin is added and mixes, and insulated and stirred 7min at a temperature of 86 DEG C, obtains mixing A；
Ⅱ：Under stirring condition, the coupling agent of promotor and parts by weight 77% that parts by weight 66% are added is sufficiently mixed
It closes, adds furane resins mixing, and be heated to 89 DEG C, snail is added after it is cooled to 55 DEG C in insulated and stirred 11min
Ox mucus is sufficiently mixed, and obtains mixed material B；
Ⅲ：Isopropanol is added into mixed material B to mix, then under agitation, be added remaining weight number promotor and
Coupling agent is sufficiently mixed, and is heated to 86 DEG C, and acetylbutyrylcellulose is added and ultra-fine hexagonal nanometer boron nitride particle fills
Divide mixing, and insulated and stirred 6min, obtains mixing C；
Ⅳ：Mixing C is poured into agitator tank, is mixed under the conditions of vacuum degree is 0.115MPa, temperature is 78 DEG C anti-
Remaining other raw materials are added before answering 160min, stirring to terminate when 44s, during which agitator tank speed of agitator is 800r/min.
Comparative example 1
This comparative example is related to a kind of colorful steel plate paint, and compared to embodiment 1, promotor is answered in comparative example removing composition
With other compositions, content and preparation method thereof are same as Example 1.
Comparative example 2
This comparative example is related to a kind of colorful steel plate paint, and compared to embodiment 2, crosslinking agent is answered in comparative example removing composition
With other compositions, content and preparation method thereof are same as Example 2.
Comparative example 3
This comparative example is related to a kind of colorful steel plate paint, and compared to embodiment 3, coupling agent is answered in comparative example removing composition
With other compositions, content and preparation method thereof are same as Example 3.
Comparative example 4
This comparative example is related to a kind of colorful steel plate paint, and compared to embodiment 4, anti-cracking agent is answered in comparative example removing composition
With other compositions, content and preparation method thereof are same as Example 4.
Comparative example 5
This comparative example is related to a kind of colorful steel plate paint, and compared to embodiment 5, which removes promotor in composition, hands over
Join agent, the application of coupling agent, anti-cracking agent, other compositions, content and preparation method thereof are same as Example 5.
Comparative example 6
This comparative example is related to a kind of preparation method of colorful steel plate paint, and compared to embodiment 5, there is only preparation methods not
Together, other compositions and its content are same as Example 5 in coating, and the preparation method of the colorful steel plate paint of this comparative example is as follows：
By raw material propylene acid resin, furane resins, red halloysite, periclase powder, isopropanol, snail mucus, acetylbutyrylcellulose, ultra-fine
Hexagonal nanometer boron nitride particle, promotor, coupling agent are delivered in agitator tank jointly, vacuum degree is 0.115MPa, temperature is
Reaction 160min is mixed under the conditions of 78 DEG C, remaining other raw materials are added before stirring terminates when 44s, during which agitator tank stirring turns
Speed is 800r/min.
Comparative example 7
This comparative example is related to a kind of colorful steel plate paint, the raw material including following kg by weight meter：15-20kg of polyester resin,
10-15kg of silicate fiber cotton, 5-10kg of mica powder, 10-15kg of desulfurized gypsum, 5-10kg of fire retardant, 5-10kg of fiber,
5-10kg of waterglass, 5-10kg of aluminium oxide, 15-20kg of brightener.
Implementation result
For the beneficial effect for verifying the present invention, following property is carried out to coating made from above-described embodiment 1-5 and comparative example 1-7
The detection of energy index：
One：Referring to JG-T 224-2007 construction steel structure anticorrosive paint examination criteria and method, correlation performance parameters are such as
Shown in the following table 6 and table 7：
Table 6：
Table 7：Comparative example (comparative example 1-7 respectively corresponds 1#-7#)
As shown in upper table 6 and table 7, colorful steel plate paint of the invention is significantly better than that comparative example in performance in all respects, has
There is significantly progress and promoted, application performance is more preferable, and the service life is longer.
Two：The detection of electromagnetic wave shielding and reflective
Electromagnetic shielding detection：According to GB/T 30142-2013 plane electromagnetic shielding material shield effectiveness measurement method, electricity
Magnet rate is set as 3GHz, measures electromagnet shield effect in the following table 8；
Reflective detection (tone is blue)：Intensity of illumination is set as 80000lx, measures illumination reflectivity (%) in the following table 8；
Table 8
| Object | Electromagnet shield effect dB | Illumination reflectivity (%) |
| Embodiment 1 | ≥62 | 8 |
| Embodiment 2 | ≥66 | 10 |
| Embodiment 3 | ≥65 | 7 |
| Embodiment 4 | ≥60 | 8 |
| Embodiment 5 | ≥56 | 9 |
| Comparative example 1 | ≥47 | 12 |
| Comparative example 2 | ≥45 | 9 |
| Comparative example 3 | ≥53 | 8 |
| Comparative example 4 | ≥52 | 8 |
| Comparative example 5 | ≥42 | 13 |
| Comparative example 6 | ≥38 | 15 |
| Comparative example 7 | ≥46 | 27 |
Explanation：In above-mentioned table, electromagnet shield effect is higher, and shield effectiveness is better；Illumination reflectivity is smaller, and intensity of light reflection is got over
It is weak.
As shown in upper table 8, colorful steel plate paint of the invention is above improved compared to comparative example in electromagnet shield effect application
3-28dB reduces 0-20 percentage points in illumination reflectivity performance applications, and therefore, colorful steel plate paint of the invention has aobvious
It writes ground progress and is promoted, functional stronger, application field is more extensive.
In conjunction with the excellent effect of the present invention, applicant is illustrated constituent part and preparation method of the invention：
(1) snail mucus：The mucus that snail mucus is secreted out of as animal body, application field is relatively narrow at present, mostly makes up
Product field, still, applicant has been surprisingly found that in development process, cooperates with interaction with base-materials, fillers such as acrylic resins,
The adhesive force and film forming of finished product coating can be significantly improved, while also improving the corrosion-resistant equal physics and chemistry of film surface
Energy；
(2) promotor：Tetramethyl thiourea, promotor 962, promotor LTH are provided with certain reaction promotion functions, but
In order to adapt to the formation of coating system of the invention, found through many experiments, using above-mentioned composition according to weight ratio (1-2):(1-
3):The compound accelerant that (2-3) is blended, the quick and stable of reaction system when can not only realize coating preparation, moreover it is possible to have
Effect promotes the adhesive force and physicochemical property of finished product coating system；
(3) crosslinking agent：Diacetone Acrylamide, amino resins are common crosslinking agent, and applicant is in development process
It was found that the addition of Diacetone Acrylamide or amino resins list composition is difficult to reach the beneficial effect of this coating system, by skilful
Wonderfully by above two composition according to weight ratio (2-3):The product that (3-5) is sufficiently blended can admirably achieve this hair
Bright technical effect and purpose obtains the more excellent performances such as water-fast, corrosion-resistant.
(4) coupling agent：Epoxy silane coupling KH-560 is most common coupling agent in coating system, is most being started
Test in, the compatibility and interface characteristics, the finished product prepared that are difficult to improve separately as coupling agent of the invention between raw material
Coating property is bad, and then, application people have been surprisingly found that is contained in anti-settling Aluminate ASA can be with active hydrogen reaction
Group can occur bonding action with the inorganic filler in this coating system, can substantially improve red halloysite, periclase powder, ultra-fine six
The compatibility and binding force of square boron nitride nanometer granular filler and acrylic resin and furane resins, coordinated rare-earth coupling agent
According to weight ratio (2-3):(4-6):(1-2) is blended, and is not only stablized coating system of the invention, is reached result of prevention, may be used also
Improve the adhesive strength of coating system.
(5) agitator tank revolving speed：The final speed of agitator of coating system of the present invention is worthy of careful study, optimum interval 600-
800r/min is lower than the revolving speed section, reacts insufficient, it is difficult to embody the beneficial effect of finished product coating；Higher than the revolving speed section,
Production cost will be will increase, or even cause the reduction or missing of comprehensive performance.
Certainly, because of the requirement of the mentality of designing and goal of the invention of coating of the present invention, remaining of the invention component selection and contain
Amount selection is obviously also non-obvious, and those skilled in the art combine the prior art that can readily occur in absolutely not.This is at this
Have further embodiment in terms of the preparation method of invention coating, in conjunction with the embodiment of the present invention it can be seen that, preparation of the invention
Method uses four steps designs, and raw material is added by several times in batches, and step is simple and orderly, rather than uses the one of prior art routine
(such as comparative example 6) is added in secondary property, and this preparation process is adapted with the special proportion of coating components of the present invention, only with adopting
With this technique, it just can guarantee that the smooth sequential of reaction system carries out, ensure the superiority for the coating property finally prepared.
The foregoing is only a preferred embodiment of the present invention, is not intended to restrict the invention, although referring to aforementioned reality
Applying example, invention is explained in detail, for those skilled in the art, still can be to aforementioned each implementation
Technical solution documented by example is modified or equivalent replacement of some of the technical features.It is all in essence of the invention
Within mind and principle, any modification, equivalent replacement, improvement and so on be should all be included in the protection scope of the present invention.
Claims (10)
1. a kind of waterproof color steel plate coating, which is characterized in that be made of following raw material by weight：
49 parts of acrylic resin；
24 parts of furane resins；
4.5 parts of red halloysite；
6.5 parts of periclase powder；
9 parts of isopropanol；
4 parts of snail mucus；
1.2 parts of acetylbutyrylcellulose；
2.8 parts of ultra-fine hexagonal nanometer boron nitride particle；
0.65 part of promotor；
0.95 part of crosslinking agent；
0.55 part of coupling agent.
2. a kind of waterproof color steel plate coating according to claim 1, which is characterized in that the promotor is tetramethyl sulphur
Urea, promotor 962, promotor LTH are according to weight ratio (1.2-1.6):(1.5-2.5):(2.3-2.8) is sufficiently blended to obtain.
3. a kind of waterproof color steel plate coating according to claim 2, which is characterized in that the promotor is tetramethyl sulphur
Urea, promotor 962, promotor LTH are according to weight ratio 1.2:1.5:2.3 are sufficiently blended to obtain.
4. a kind of waterproof color steel plate coating according to claim 1, which is characterized in that the crosslinking agent is diacetone third
Acrylamide, amino resins are according to weight ratio (2.1-2.8):(3.4-4.5) is sufficiently blended to obtain.
5. a kind of waterproof color steel plate coating according to claim 4, which is characterized in that the crosslinking agent is diacetone third
Acrylamide, amino resins are according to weight ratio 2.1:3.4 are sufficiently blended to obtain.
6. a kind of waterproof color steel plate coating according to claim 1, which is characterized in that the coupling agent is anti-settling
Aluminate ASA, epoxy silane coupling KH-560, rare-earth coupling agent are according to weight ratio 2.3:4.5:1.2 are sufficiently blended to obtain.
7. a kind of waterproof color steel plate coating according to claim 1, which is characterized in that the preparation method of the coating is such as
Under：
Ⅰ：Red halloysite and periclase powder are taken, the RO water of weight percent 114% is added, grinding stirring makes it completely dissolved, heats
83 DEG C are warming up to, acrylic resin is added and mixes, and insulated and stirred 8.5min at a temperature of 83 DEG C, obtains mixing A；
Ⅱ：Under stirring condition, the coupling agent of promotor and parts by weight 74% that parts by weight 63% are added is sufficiently mixed, then
Furane resins are added to mix, and are heated to 86 DEG C, it is viscous that snail is added after it is cooled to 52 DEG C in insulated and stirred 12.5min
Liquid is sufficiently mixed, and obtains mixed material B；
Ⅲ：Isopropanol is added into mixed material B to mix, then under agitation, promotor and the coupling of remaining weight number is added
Agent is sufficiently mixed, and is heated to 83 DEG C, and it is sufficiently mixed that acetylbutyrylcellulose and ultra-fine hexagonal nanometer boron nitride particle is added
It closes, and insulated and stirred 7.5min, obtains mixing C；
Ⅳ：Mixing C is poured into agitator tank, reaction is mixed under the conditions of vacuum degree is 0.1MPa, temperature is 74 DEG C
Crosslinking agent is added when 38s before stirring terminates in 175min.
8. a kind of waterproof color steel plate coating according to claim 7, which is characterized in that in step IV, the stirring
The speed of agitator of tank is 650r/min.
9. a kind of waterproof color steel plate coating according to claim 1, which is characterized in that the coating further includes cracking resistance
Agent, the antimitotic agent are the mixture of two kinds of polyacrylonitrile chopped strand, shepardite chopped strand compositions.
10. a kind of waterproof color steel plate coating according to claim 9, which is characterized in that the antimitotic agent is polypropylene
Nitrile chopped strand, shepardite chopped strand are according to weight ratio (3-4):(1-2) is sufficiently blended.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810658305.XA CN108912914A (en) | 2018-06-25 | 2018-06-25 | Coating for waterproof color steel plate |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810658305.XA CN108912914A (en) | 2018-06-25 | 2018-06-25 | Coating for waterproof color steel plate |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108912914A true CN108912914A (en) | 2018-11-30 |
Family
ID=64420642
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810658305.XA Withdrawn CN108912914A (en) | 2018-06-25 | 2018-06-25 | Coating for waterproof color steel plate |
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| Country | Link |
|---|---|
| CN (1) | CN108912914A (en) |
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2018
- 2018-06-25 CN CN201810658305.XA patent/CN108912914A/en not_active Withdrawn
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