CN108948699A - A kind of injection colored ribbon tank and preparation method thereof - Google Patents
A kind of injection colored ribbon tank and preparation method thereof Download PDFInfo
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- CN108948699A CN108948699A CN201810849474.1A CN201810849474A CN108948699A CN 108948699 A CN108948699 A CN 108948699A CN 201810849474 A CN201810849474 A CN 201810849474A CN 108948699 A CN108948699 A CN 108948699A
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- Prior art keywords
- tank
- colored ribbon
- injection
- bamboo charcoal
- parts
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/04—Polyesters derived from hydroxycarboxylic acids, e.g. lactones
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/04—Homopolymers or copolymers of styrene
- C08L25/06—Polystyrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/06—Biodegradable
Abstract
The present invention relates to a kind of injection colored ribbon tank and preparation method thereof, belongs to and celebrate stage property technical field.The present invention selects degradation material as substrate, and utilize the organic acid being rich in bamboo vinegar, with sterilization, antibacterial, insect prevention effect, and to sulfur-bearing, the stink of the foul gas such as nitrogen, which is removed, has universal, it is effectively adsorbed using the conjugate double bond system electronics synergistic activity bamboo charcoal of bamboo vinegar itself, the odor molecules such as the ammonia in air and hydrogen sulfide are complexed, also the spatial configuration for the odor molecules being adsorbed can be made to change simultaneously, weaken the chemical combination key in odor molecules, so that the unstability of odor molecules increases, it is easy to be chemically reacted with other molecules, it ultimately produces tasteless, nontoxic organic salt, eliminate gas with foreign flavor, cooperate with the nitrogen in the zinc atom and stink of activation, sulphur atom forms very strong chemical combination key to thoroughly eliminate stink, and it is nontoxic, residue is harmless, easily biological-degradable, and eliminate peculiar smell, it is right No skin irritation.
Description
Technical field
The present invention relates to a kind of injection colored ribbon tank and preparation method thereof, belongs to and celebrate stage property technical field.
Background technique
It is at present the festive air such as the wedding of a surname's dye, dancing party, dinner party, birthday birthday and opening ceremony, mostly uses and use paper
The various colored ribbons manufactured with plastic film by dip dyeing or spraying, as interior decoration or are shed on human body, above-mentioned coloured silk
The disadvantages of that there are toughness is low for band, sheds difficulty.
Present color ribbon aerosol, there is serious defects in production, big to environmental disruption, difficult to degrade, are unsatisfactory for
Ecological requirements, such as existing colored ribbon manufacturer mostly use greatly nonylphenol polyoxyethylene ether, and biological degradability is poor, to environmental disruption
Greatly, and aerosol colored ribbon is big to the corrosivity of inhalator jar, and the strong influence effective life of aerosol colored ribbon, cost input are big.
In addition, uniformity is poor when existing aerosol colored ribbon sprays, material fluidity is weak in tank, it is difficult to injection molding, easily appearance fracture,
The phenomenon that blocking, the smell is awful, of poor quality to skin irritation great synthesis, is unfavorable for marketing.Therefore, to urgent need in work
Improvement is further improved in skill, formula to break through.
Summary of the invention
The technical problems to be solved by the invention: it for present color ribbon aerosol, is lacked in production there is serious
It falls into, it is big to environmental disruption, it is difficult to degrade, ecological requirements are unsatisfactory for, and the smell is awful for aerosol colored ribbon, big to skin irritation asks
Topic provides a kind of injection colored ribbon tank and preparation method thereof.
In order to solve the above technical problems, the technical solution adopted by the present invention is that:
A kind of injection colored ribbon tank, the injection colored ribbon tank are made of following weight parts raw material:
100~120 parts of compound macromolecular polymers, 30~50 parts of oxidants, 20~40 parts of lubricants, 3~10 parts of natural pigments,
3~10 parts of carbon tetrachloride, 1~3 part of bamboo vinegar, 1~2 part of essence, 100~180g Freon 12.
The compound macromolecular polymer be after high molecular polymer is dry with modification bamboo charcoal 20:1~40:1 in mass ratio
Mixing is made.
The high molecular polymer be polylactic acid, polyacrylate, polymethacrylates, polyethylene, polystyrene and
One of polyvinyl chloride is a variety of.
The drying process is dry 4~5h at 110~120 DEG C, be warming up to and 140~150 DEG C and be evacuated to 10~
1000Pa dries 15~18h.
It is 5% zinc acetate solution after 1:100~1:200 is mixed in mass ratio that the modification bamboo charcoal, which is bamboo charcoal with mass fraction,
Hydro-thermal reaction is made.
The hydrothermal reaction process is to be warming up to 200~240 DEG C with 10~20 DEG C/min heating rate, insulation reaction 20~
30h。
The oxidant is dicumyl peroxide, and the lubricant is in white oil, silicone oil, chlorinated paraffin and butyl stearate
It is one or more.
A kind of preparation method of injection colored ribbon tank, specific steps are as follows:
(1) taking bamboo charcoal to be immersed in mass fraction is to stir evenly in 5% zinc acetate solution, is reloaded into ptfe autoclave
20~30h of insulation reaction, obtains modification bamboo charcoal；
(2) take high molecular polymer to be placed in rotary drum dryer dry, then be fitted into batch mixer under nitrogen atmosphere, with 10 DEG C/
Modification bamboo charcoal is added in min rate program after being warming up to 180~200 DEG C, heat preservation is kneaded 20~30min, must answer after being cooled to room temperature
Close high molecular polymer；
(3) compound macromolecular polymer, oxidant, mix lubricant is taken uniformly to be packed into the sealing pressure resistance for being equipped with injection apparatus afterwards
In container, natural pigment, carbon tetrachloride, bamboo vinegar, essence are added, and sealed pressure vessel addition mouth is closed, most
Freon 12 is injected in backward sealed pressure vessel, colored ribbon tank must be sprayed.
The present invention is compared with other methods, and advantageous effects are:
The present invention selects degradation material as substrate, and using the organic acid being rich in bamboo vinegar, has sterilization, antibacterial, prevents
Worm effect, and the stink of the foul gas such as sulfur-bearing, nitrogen is removed with universal, utilize the conjugate double bond system of bamboo vinegar itself
The odor molecules such as electronics synergistic activity bamboo charcoal effectively adsorbs, is complexed in air ammonia and hydrogen sulfide, while can also make to be inhaled
The spatial configuration of attached odor molecules changes, and weakens the chemical combination key in odor molecules, so that odor molecules is unstable
Property increase, be easy chemically reacted with other molecules (such as acid-base reaction, be catalyzed react, redox reaction), finally give birth to
At tasteless, nontoxic organic salt, gas with foreign flavor is eliminated, cooperates with the nitrogen in the zinc atom and stink of activation, sulphur atom to be formed very strong
Chemical combination key to thoroughly eliminating stink, and nontoxic, residue is harmless, easily biological-degradable, solves existing injection colored ribbon
It is big to environmental disruption, difficult to degrade, the problem of being unsatisfactory for ecological requirements, and peculiar smell is eliminated, to no skin irritation.
Specific embodiment
3~5g bamboo charcoal is taken, being immersed in 500~600g mass fraction is to stir in 5% zinc acetate solution with 300~400r/min
It is fitted into ptfe autoclave after mixing 20~30min, is warming up to 200~240 DEG C with 10~20 DEG C/min heating rate, protects
Temperature 20~30h of reaction, obtains modification bamboo charcoal, 100~120g high molecular polymer is taken to be placed in rotary drum dryer, at 110~120 DEG C
4~5h of lower drying is warming up to 140~150 DEG C and is evacuated to the dry 15~18h of 10~1000Pa, then fills under nitrogen atmosphere
Enter in batch mixer, 3~5g modification bamboo charcoal is added after being warming up to 180~200 DEG C with 10 DEG C/min rate program, temperature is kept to be kneaded
20~30min obtains compound macromolecular polymer, takes 100~120g compound macromolecular polymer, 30~50g after being cooled to room temperature
Oxidant, 20~40g lubricant are packed into are equipped in the sealed pressure vessel of injection apparatus after mixing, add 3~
10g natural pigment, 3~10g carbon tetrachloride, 1~3g bamboo vinegar, 1~2g essence, and sealed pressure vessel addition mouth is sealed
It closes, 100~180g Freon 12 is finally injected into sealed pressure vessel, colored ribbon tank must be sprayed.
Example 1
3g bamboo charcoal is taken, being immersed in 500g mass fraction is to be packed into poly- four after stirring 20min with 300r/min in 5% zinc acetate solution
In vinyl fluoride reaction kettle, 200 DEG C are warming up to 10 DEG C/min heating rate, insulation reaction 20h obtains modification bamboo charcoal, takes 100g high
Molecularly Imprinted Polymer is placed in rotary drum dryer, the dry 4h at 110 DEG C, is warming up to 140 DEG C and is evacuated to the dry 15h of 10Pa,
It is fitted into batch mixer under nitrogen atmosphere again, 3g modification bamboo charcoal is added after being warming up to 180 DEG C with 10 DEG C/min rate program, keep
Temperature is kneaded 20min, and compound macromolecular polymer is obtained after being cooled to room temperature, and takes 100g compound macromolecular polymer, 30g oxidation
Agent, 20g lubricant are packed into are equipped in the sealed pressure vessel of injection apparatus after mixing, add 3g natural pigment, 3g
Carbon tetrachloride, 1g bamboo vinegar, 1g essence, and sealed pressure vessel addition mouth is closed, finally into sealed pressure vessel
100g Freon 12 is injected, colored ribbon tank must be sprayed.
Example 2
5g bamboo charcoal is taken, being immersed in 500g mass fraction is to be packed into poly- four after stirring 20min with 300r/min in 5% zinc acetate solution
In vinyl fluoride reaction kettle, 240 DEG C are warming up to 20 DEG C/min heating rate, insulation reaction 30h obtains modification bamboo charcoal, takes 100g high
Molecularly Imprinted Polymer is placed in rotary drum dryer, and the dry 4h at 110 DEG C is warming up to 150 DEG C and is evacuated to 1000Pa drying
18h, then be fitted into batch mixer under nitrogen atmosphere, 3g modification bamboo charcoal is added after being warming up to 180 DEG C with 10 DEG C/min rate program,
It keeps temperature to be kneaded 20min, compound macromolecular polymer is obtained after being cooled to room temperature, takes 120g compound macromolecular polymer, 50g oxygen
Agent, 20g lubricant are packed into are equipped in the sealed pressure vessel of injection apparatus after mixing, add 3g natural pigment,
10g carbon tetrachloride, 3g bamboo vinegar, 2g essence, and sealed pressure vessel addition mouth is closed, finally to sealed pressure vessel
Interior injection 100g Freon 12, must spray colored ribbon tank.
Example 3
5g bamboo charcoal is taken, being immersed in 600g mass fraction is to be packed into poly- four after stirring 30min with 400r/min in 5% zinc acetate solution
In vinyl fluoride reaction kettle, 240 DEG C are warming up to 20 DEG C/min heating rate, insulation reaction 30h obtains modification bamboo charcoal, takes 120g high
Molecularly Imprinted Polymer is placed in rotary drum dryer, and the dry 5h at 120 DEG C is warming up to 150 DEG C and is evacuated to 1000Pa drying
18h, then be fitted into batch mixer under nitrogen atmosphere, 5g modification bamboo charcoal is added after being warming up to 200 DEG C with 10 DEG C/min rate program,
It keeps temperature to be kneaded 30min, compound macromolecular polymer is obtained after being cooled to room temperature, takes 120g compound macromolecular polymer, 50g oxygen
Agent, 40g lubricant are packed into are equipped in the sealed pressure vessel of injection apparatus after mixing, add 10g natural colour
Element, 10g carbon tetrachloride, 3g bamboo vinegar, 2g essence, and sealed pressure vessel addition mouth is closed, finally to sealing pressure resistance
180g Freon 12 is injected in container, must spray colored ribbon tank.
Injection colored ribbon tank prepared by the present invention and commercially available injection colored ribbon tank are detected, specific testing result such as following table
Table 1:
Table 1 sprays colored ribbon tank performance characterization
Injection colored ribbon tank prepared by the present invention as shown in Table 1, residue is harmless, easily biological-degradable, solves existing injection
The problem of colored ribbon is big to environmental disruption, difficult to degrade, is unsatisfactory for ecological requirements, and peculiar smell is eliminated, to no skin irritation, there is pole
Its vast market prospect and application value.
Claims (8)
1. a kind of injection colored ribbon tank, which is characterized in that the injection colored ribbon tank is made of following weight parts raw material:
100~120 parts of compound macromolecular polymers, 30~50 parts of oxidants, 20~40 parts of lubricants, 3~10 parts of natural pigments,
3~10 parts of carbon tetrachloride, 1~3 part of bamboo vinegar, 1~2 part of essence, 100~180g Freon 12.
2. a kind of injection colored ribbon tank as described in claim 1, which is characterized in that the compound macromolecular polymer is macromolecule
It is made after polymer is dry with modification bamboo charcoal 20:1~40:1 in mass ratio mixing.
3. a kind of injection colored ribbon tank as claimed in claim 2, which is characterized in that the high molecular polymer is polylactic acid, gathers
One of acrylate, polymethacrylates, polyethylene, polystyrene and polyvinyl chloride are a variety of.
4. a kind of injection colored ribbon tank as claimed in claim 2, which is characterized in that the drying process is at 110~120 DEG C
Dry 4~5h is warming up to 140~150 DEG C and is evacuated to the dry 15~18h of 10~1000Pa.
5. a kind of injection colored ribbon tank as claimed in claim 2, which is characterized in that the modification bamboo charcoal is bamboo charcoal and mass fraction
It is made for hydro-thermal reaction after 5% zinc acetate solution 1:100~1:200 in mass ratio mixing.
6. a kind of injection colored ribbon tank as claimed in claim 5, which is characterized in that the hydrothermal reaction process is with 10~20
DEG C/min heating rate is warming up to 200~240 DEG C, 20~30h of insulation reaction.
7. a kind of injection colored ribbon tank as described in claim 1, which is characterized in that the oxidant is dicumyl peroxide, institute
Stating lubricant is one of white oil, silicone oil, chlorinated paraffin and butyl stearate or a variety of.
8. a kind of preparation method of injection colored ribbon tank as described in claim 1~7 any one, which is characterized in that specific step
Suddenly are as follows:
(1) taking bamboo charcoal to be immersed in mass fraction is to stir evenly in 5% zinc acetate solution, is reloaded into ptfe autoclave
20~30h of insulation reaction, obtains modification bamboo charcoal；
(2) take high molecular polymer to be placed in rotary drum dryer dry, then be fitted into batch mixer under nitrogen atmosphere, with 10 DEG C/
Modification bamboo charcoal is added in min rate program after being warming up to 180~200 DEG C, heat preservation is kneaded 20~30min, must answer after being cooled to room temperature
Close high molecular polymer；
(3) compound macromolecular polymer, oxidant, mix lubricant is taken uniformly to be packed into the sealing pressure resistance for being equipped with injection apparatus afterwards
In container, natural pigment, carbon tetrachloride, bamboo vinegar, essence are added, and sealed pressure vessel addition mouth is closed, most
Freon 12 is injected in backward sealed pressure vessel, colored ribbon tank must be sprayed.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810849474.1A CN108948699A (en) | 2018-07-28 | 2018-07-28 | A kind of injection colored ribbon tank and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810849474.1A CN108948699A (en) | 2018-07-28 | 2018-07-28 | A kind of injection colored ribbon tank and preparation method thereof |
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| Publication Number | Publication Date |
|---|---|
| CN108948699A true CN108948699A (en) | 2018-12-07 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810849474.1A Pending CN108948699A (en) | 2018-07-28 | 2018-07-28 | A kind of injection colored ribbon tank and preparation method thereof |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1052682A (en) * | 1990-07-28 | 1991-07-03 | 延吉市海星化学制品厂 | Utilize high molecular polymer to prepare the method for colored ribbon |
| CN1094064A (en) * | 1994-03-29 | 1994-10-26 | 朴京淑 | Spraying colour strips and preparation method thereof |
| CN103535376A (en) * | 2013-09-15 | 2014-01-29 | 浙江理工大学 | Preparation method of nanometer zinc oxide-bamboo charcoal composite particle with antibacterial and adsorption functions |
| CN106925229A (en) * | 2017-04-12 | 2017-07-07 | 福州大学 | A kind of iron zinc-base wood composite quality activated carbon desulphurization agent and preparation method thereof |
-
2018
- 2018-07-28 CN CN201810849474.1A patent/CN108948699A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1052682A (en) * | 1990-07-28 | 1991-07-03 | 延吉市海星化学制品厂 | Utilize high molecular polymer to prepare the method for colored ribbon |
| CN1094064A (en) * | 1994-03-29 | 1994-10-26 | 朴京淑 | Spraying colour strips and preparation method thereof |
| CN103535376A (en) * | 2013-09-15 | 2014-01-29 | 浙江理工大学 | Preparation method of nanometer zinc oxide-bamboo charcoal composite particle with antibacterial and adsorption functions |
| CN106925229A (en) * | 2017-04-12 | 2017-07-07 | 福州大学 | A kind of iron zinc-base wood composite quality activated carbon desulphurization agent and preparation method thereof |
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Application publication date: 20181207 |
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