CN108948448A - A kind of sole material and dermatoglyph sole production method - Google Patents
A kind of sole material and dermatoglyph sole production method Download PDFInfo
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- CN108948448A CN108948448A CN201810500195.4A CN201810500195A CN108948448A CN 108948448 A CN108948448 A CN 108948448A CN 201810500195 A CN201810500195 A CN 201810500195A CN 108948448 A CN108948448 A CN 108948448A
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- parts
- sole
- rubber
- dermatoglyph
- production method
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B13/00—Soles; Sole-and-heel integral units
- A43B13/02—Soles; Sole-and-heel integral units characterised by the material
- A43B13/04—Plastics, rubber or vulcanised fibre
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)
Abstract
The present invention relates to shoes manufacturing technology fields, specifically a kind of sole material and dermatoglyph sole production method, the sole material is grouped as by the group of following mass parts: 10-15 parts of high styrene rubber, 22-27 parts of solution polymerized butadiene styrene rubber, 35-40 parts of butadiene rubber, 18-23 parts of natural rubber, 45-50 parts of nano silica, 20-25 parts of nanometer calcium carbonate, 4.0-4.5 parts of PEG4000, 1.8-2.2 parts of rubber white smoke active agent, 1.4-1.6 parts of stearic acid, 3.5-4.5 parts of ZnCO3, 0.8-1.2 parts of antioxidant, 1.8-2.2 parts of coupling agent, 0.5 part of microwax, 1.5-2.0 parts of sulphur, 2.0-2.5 parts of vulcanization accelerator.It using dermatoglyph sole made of sole material and production method of the invention, has the advantages that with excellent leather pattern effect and rubber property, ensure that the good non-skid property of sole, wear-resisting property, tortuous performance.
Description
Technical field
The present invention relates to shoes manufacturing technology field, specifically a kind of sole material and dermatoglyph sole production method.
Background technique
The leather pattern effect of sole directly affects the aesthetics of sole, fashion and safety；Many countries and regions are
Using the beautiful and stylish as the direction of research and development of products of sole, using safety as a technical indicator of sole；Sole leather pattern effect
Improvement can be further improved the aesthetics of shoes, while guarantee consumer dress safety, be conducive to China and break through footwear
The trade barrier of importer continue to keep the status of footwear big export country, winning the reputation of high quality footwear exported country.
China is that the world's largest footwear manufacture and big export country, footwear yield account for the 53% of world's total output product, out
Mouth accounts for 60% or more of world export problem, and the shoe industry in Guangdong ranks first in the country, and the exploitation and industrialization of dermatoglyph material are answered
With, technological gap of the China on the series of products has not only been filled up, the footwear material manufacturing in China is made to closely follow the paces in the world,
Reach international similar product advanced level, and the manufacturing quality level of China's footwear material will be promoted, makes the footwear material in China more
With international competitiveness.In the prior art, the outsole of leather pattern effect leans on import entirely, and technology is blocked；Import dermatoglyph is big simultaneously
Bottom complex manufacturing technology, cost of manufacture is high, and life cycle of the product is long；The big bottom material non-skid property of import dermatoglyph is poor simultaneously, no
Conducive to safe walking, wear-resisting resistance to tortuous performance is general；Part dermatoglyph sole serves as leather pattern effect bottom, leather pattern effect by mold pattern
Difference, no stereovision are short of beautiful and stylish property without true leather pattern effect.
Summary of the invention
In order to overcome the above the deficiencies in the prior art, the task of the present invention is provide a kind of sole material and a kind of using should
The dermatoglyph sole production method of sole material.
A kind of sole material is grouped as by the group of following mass parts: 10-15 parts of high styrene rubber, solution polymerized butadiene styrene rubber
22-27 parts, 35-40 parts of butadiene rubber, 18-23 parts of natural rubber, 45-50 parts of nano silica, nanometer calcium carbonate 20-25
Part, 4.0-4.5 parts of PEG4000,1.8-2.2 parts of rubber white smoke active agent, 1.4-1.6 parts of stearic acid, 3.5-4.5 parts of ZnCO3,
0.8-1.2 parts of antioxidant, 1.8-2.2 parts of coupling agent, 0.5 part of microwax, 1.5-2.0 parts of sulphur, vulcanization accelerator 2.0-2.5
Part.
Preferably, the high styrene rubber is high styrene rubber HS60.
Preferably, the nanometer calcium carbonate is nanometer calcium carbonate CC-R.
Preferably, the vulcanization accelerator is vulcanization accelerator TBBS.
Preferably, the natural rubber is Vietnam SVR-3L.
A kind of dermatoglyph sole production method using above-mentioned sole material, comprising the following steps:
A, above-mentioned various components are prepared by above-mentioned proportion by weight, the component of preparation is kneaded in mixer, mixed
The refining time 8 minutes, 130 DEG C of melting temperature；
B, according to the thickness requirements of sole, tabletting is carried out by open mill, sizing material is then punched by cutting machine；
C, the sizing material of punching is vulcanized in mold, temperature is controlled at 160-170 DEG C, molding time 300-400 seconds；
D, the roller compression process of decorative pattern is carried out.
It preferably, further include step E after the step C: after being carried out to the sole that vulcanization is completed at process deburring
Reason.
Preferably, further include step F after the step E: surface spray is carried out to rear process deburring treated sole
Paint processing after surface lacquer processing, then carries out the roller compression process in the step D.
Preferably, the surface treatment mode of the mold in the step C is to be electroplated after spraying ash or polishing after polishing.
Using dermatoglyph sole made of sole material and production method of the invention, compared with prior art, have as follows
Advantage:
By rubber as basis material, using polar rubber and its modified rubber as composite, with inorganic nano material
Material is used as enhancement nanofiller, while being set by mold effect process and mould process, by lacquer spraying technique, embosses work
Skill makes prepared sole have excellent leather pattern effect, beautiful and stylish appearance, while having excellent rubber property, protects
The good non-skid property of sole, wear-resisting property, tortuous performance are demonstrate,proved；The high styrene rubber and natural rubber of addition have good
Outsole dimensional stability；The nanometer calcium carbonate of addition has low bounce, ensure that excellent leather pattern effect；Addition contains intermingle with
Butadiene-styrene rubber has good attachment attraction, gripping power, improves on-slip agent；The processing of mold effect and lacquer spraying technique guarantee
The gloss light of dermatoglyph sole；The shortening of mold ensure that the stability of sole final size；The pressure of special figure roller
System has determined the leather pattern effect of product.
Specific embodiment
In order to make the objectives, technical solutions, and advantages of the present invention clearer, with reference to embodiments, to the present invention
It is further elaborated.It should be appreciated that saying that the specific embodiment of description is used only for explaining the present invention herein, it is not used to
Limit the present invention.
Embodiment 1:
A kind of sole material of the invention is grouped as by the group of following mass parts: 10 parts of high styrene rubber, containing intermingle with fourth
22 parts of benzene rubber, 35 parts of butadiene rubber, 18 parts of natural rubber, 45 parts of nano silica, 20 parts of nanometer calcium carbonate, PEG4000
4.0 parts, 1.8 parts of rubber white smoke active agent, 1.4 parts of stearic acid, 3.5 parts of ZnCO3,0.8 part of antioxidant, 1.8 parts of coupling agent,
0.5 part of microwax, 1.5 parts of sulphur, 2.0 parts of vulcanization accelerator.
Embodiment 2:
Another sole material of the invention is grouped as by the group of following mass parts: 10 parts of high styrene rubber, being contained intermingle with
27 parts of butadiene-styrene rubber, 40 parts of butadiene rubber, 23 parts of natural rubber, 50 parts of nano silica, 25 parts of nanometer calcium carbonate,
4.5 parts of PEG4000,2.2 parts of rubber white smoke active agent, 1.6 parts of stearic acid, 4.5 parts of ZnCO3,1.2 parts of antioxidant, coupling
2.2 parts of agent, 0.5 part of microwax, 2.0 parts of sulphur, 2.5 parts of vulcanization accelerator.
Embodiment 3:
Of the invention there are also a kind of sole material is grouped as by the group of following mass parts: 15 parts of high styrene rubber, molten
22 parts of poly- butadiene-styrene rubber, 35 parts of butadiene rubber, 18 parts of natural rubber, 45 parts of nano silica, 20 parts of nanometer calcium carbonate,
4.0 parts of PEG4000,1.8 parts of rubber white smoke active agent, 1.4 parts of stearic acid, 3.5 parts of ZnCO3,0.8 part of antioxidant, coupling
1.8 parts of agent, 0.5 part of microwax, 1.5 parts of sulphur, vulcanization promotes 2.0 parts.
Embodiment 4:
Of the invention there are also a kind of sole material is grouped as by the group of following mass parts: 15 parts of high styrene rubber, molten
27 parts of poly- butadiene-styrene rubber, 40 parts of butadiene rubber, 23 parts of natural rubber, 50 parts of nano silica, 25 parts of nanometer calcium carbonate,
4.5 parts of PEG4000,2.2 parts of rubber white smoke active agent, 1.6 parts of stearic acid, 4.5 parts of ZnCO3,1.2 parts of antioxidant, coupling
2.2 parts of agent, 0.5 part of microwax, 2.0 parts of sulphur, 2.5 parts of vulcanization accelerator.
A kind of production method of dermatoglyph sole, using the sole material of any one above-mentioned specific embodiment, including it is following
Step:
Above-mentioned various components are prepared by above-mentioned proportion by weight, the component of preparation is kneaded in mixer, are kneaded
Time 8 minutes, 130 DEG C of melting temperature；According to the thickness requirements of sole, tabletting is carried out by open mill, then passes through cutting machine
It is punched sizing material；The sizing material of punching is vulcanized in mold, temperature is controlled at 160-170 DEG C, molding time 300-400 seconds,
The surface treatment mode of the mold is to be electroplated after spraying ash or polishing after polishing, and the ratio processed of opening of mold shortens 1.0-1.5mm；It is right
Process deburring is handled after the sole that vulcanization is completed carries out；Surface lacquer processing is carried out to rear process deburring treated sole；It is right
The roller compression process of surface lacquer treated sole carries out special decorative pattern, process terminate.
Using dermatoglyph sole made of sole material and production method of the invention, compared with prior art, have as follows
Advantage:
By rubber as basis material, using polar rubber and its modified rubber as composite, with inorganic nano material
Material is used as enhancement nanofiller, while being set by mold effect process and mould process, by lacquer spraying technique, embosses work
Skill makes prepared sole have excellent leather pattern effect, beautiful and stylish appearance, while having excellent rubber property, protects
The good non-skid property of sole, wear-resisting property, tortuous performance are demonstrate,proved；The high styrene rubber and natural rubber of addition have good
Outsole dimensional stability；The nanometer calcium carbonate of addition has low bounce, ensure that excellent leather pattern effect；Addition contains intermingle with
Butadiene-styrene rubber has good attachment attraction, gripping power, improves on-slip agent；The processing of mold effect and lacquer spraying technique guarantee
The gloss light of dermatoglyph sole；The shortening of mold ensure that the stability of sole final size；The pressure of special figure roller
System has determined the leather pattern effect of product.
Confirming performance experiment:
To using dermatoglyph sole made of sole material and production method of the invention, following confirming performance experiment is carried out:
Test condition: 23 DEG C of environment of test, 65 ° of ± 5 ° of % of relative humidity.
Test method: (1) ASTM-F609 is tested in on-slip；(2) wear-resisting test ISO4649；(3) tortuous test QB/T1002-
2005；(4) leather pattern effect determines.
1 test result of embodiment:
(1) on-slip test (ASTM-F609): dry type anti-skid factor 1.22；Wet type anti-skid factor 0.85；
(2) wear-resisting test (ISO4649): DIN 155MM3；
(3) tortuous test (QB/T1002-2005): -10 DEG C of 40000 breaches are without growth；
(4) leather pattern effect determines: matte surface brightness effects；Leather pattern effect is obvious, and dermatoglyph is naturally, without rebound.
2 test result of embodiment:
(1) on-slip test (ASTM-F609): dry type anti-skid factor 1.15；Wet type anti-skid factor 0.75；
(2) wear-resisting test (ISO4649): DIN 165MM3；
(3) tortuous test (QB/T1002-2005): -10 DEG C of 40000 breaches are without growth；
(4) leather pattern effect determines: matte surface brightness effects；Leather pattern effect is obvious, and dermatoglyph is naturally, without rebound.
3 test result of embodiment:
(1) on-slip test (ASTM-F609): dry type anti-skid factor 1.25；Wet type anti-skid factor 0.88；
(2) wear-resisting test (ISO4649): DIN 145MM3；
(3) tortuous test (QB/T1002-2005): -10 DEG C of 40000 breaches are without growth；
(4) leather pattern effect determines: matte surface brightness effects；Leather pattern effect is obvious, and dermatoglyph is naturally, without rebound；
4 test result of embodiment:
(1) on-slip test (ASTM-F609): dry type anti-skid factor 1.30；Wet type anti-skid factor 0.90；
(2) wear-resisting test (ISO4649): DIN 150MM3；
(3) tortuous test (QB/T1002-2005): -10 DEG C of 40000 breaches are without growth；
(4) leather pattern effect determines: matte surface brightness effects；Leather pattern effect is obvious, and dermatoglyph is naturally, without rebound.
Test result shows dermatoglyph sole of the invention, and every test data is substantially better than international physical property measurement mark
It is quasi-.Leather pattern effect is obvious, and dermatoglyph is naturally, matte surface brightness effects are good.
Following attachment is international physical property measurement standard:
(1) ASTM-F609 testing standard: dry type ﹥ 0.8；Wet type ﹥ 0.4；
(2) ISO4649 testing standard: DIN≤250mm3；
(3) ISO4649 testing standard: QB/T1002-2005 testing standard: -10 DEG C of 40000 breaches increase length≤10MM.
Above description is only the preferred embodiment of the application and the explanation to institute's application technology principle.Those skilled in the art
Member is it should be appreciated that invention scope involved in the application, however it is not limited to technology made of the specific combination of above-mentioned technical characteristic
Scheme, while should also cover in the case where not departing from the inventive concept, it is carried out by above-mentioned technical characteristic or its equivalent feature
Any combination and the other technical solutions formed.Such as features described above has similar function with (but being not limited to) disclosed herein
Can technical characteristic replaced mutually and the technical solution that is formed.
Claims (9)
1. a kind of sole material, which is characterized in that be grouped as by the group of following mass parts: 10-15 parts of high styrene rubber, containing intermingle with
22-27 parts of butadiene-styrene rubber, 35-40 parts of butadiene rubber, 18-23 parts of natural rubber, 45-50 parts of nano silica, nano-calcium carbonate
20-25 parts of calcium, 4.0-4.5 parts of PEG4000,1.8-2.2 parts of rubber white smoke active agent, 1.4-1.6 parts of stearic acid, ZnCO3
3.5-4.5 parts, 0.8-1.2 parts of antioxidant, 1.8-2.2 parts of coupling agent, 0.5 part of microwax, 1.5-2.0 parts of sulphur, vulcanization promotees
Into 2.0-2.5 parts of agent.
2. sole material according to claim 1, which is characterized in that the high styrene rubber is high styrene rubber
HS60。
3. sole material according to claim 1, which is characterized in that the nanometer calcium carbonate is nanometer calcium carbonate CC-R.
4. sole material according to claim 1, which is characterized in that the vulcanization accelerator is vulcanization accelerator TBBS.
5. sole material according to claim 1, which is characterized in that the natural rubber is Vietnam SVR-3L.
6. a kind of dermatoglyph sole production method using any sole material of claim 1-5, which is characterized in that including with
Lower step:
A, above-mentioned various components are prepared by above-mentioned proportion by weight, the component of preparation is kneaded in mixer, when mixing
Between 8 minutes, 130 DEG C of melting temperature；
B, according to the thickness requirements of sole, tabletting is carried out by open mill, sizing material is then punched by cutting machine；
C, the sizing material of punching is vulcanized in mold, temperature is controlled at 160-170 DEG C, molding time 300-400 seconds；
D, the roller compression process of decorative pattern is carried out.
7. dermatoglyph sole production method according to claim 6, which is characterized in that further include step after the step C
Rapid E: process deburring is handled after carrying out to the sole that vulcanization is completed.
8. dermatoglyph sole production method according to claim 7, which is characterized in that further include step after the step E
Rapid F: surface lacquer processing is carried out to rear process deburring treated sole, after surface lacquer processing, then is carried out in the step D
Roller compression process.
9. dermatoglyph sole production method according to claim 6, which is characterized in that the mold in the step C
Surface treatment mode is to be electroplated after spraying ash or polishing after polishing.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810500195.4A CN108948448A (en) | 2018-05-23 | 2018-05-23 | A kind of sole material and dermatoglyph sole production method |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810500195.4A CN108948448A (en) | 2018-05-23 | 2018-05-23 | A kind of sole material and dermatoglyph sole production method |
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| Publication Number | Publication Date |
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| CN108948448A true CN108948448A (en) | 2018-12-07 |
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| CN201810500195.4A Pending CN108948448A (en) | 2018-05-23 | 2018-05-23 | A kind of sole material and dermatoglyph sole production method |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109776896A (en) * | 2018-12-28 | 2019-05-21 | 浙江中远鞋业有限公司 | The sole of rubber overshoes prepares material |
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| CN102796288A (en) * | 2012-08-09 | 2012-11-28 | 际华三五三七制鞋有限责任公司 | Novel antiskid antistatic rubber sole and preparation method thereof |
| CN102964645A (en) * | 2012-11-29 | 2013-03-13 | 泰亚鞋业股份有限公司 | Ice surface anti-slip rubber sports shoe soles and manufacturing method thereof |
| CN104804228A (en) * | 2015-02-28 | 2015-07-29 | 广东志达行新材料有限公司 | Synthesized light rubber material for sole and preparation method of synthesized light rubber material |
| CN106432831A (en) * | 2016-08-31 | 2017-02-22 | 广州市邦尔福鞋材有限公司 | Rubber for shoe sole and method for preparing shoe sole |
| CN107964141A (en) * | 2017-12-12 | 2018-04-27 | 温州市小林鞋材有限公司 | A kind of tear-proof sole and preparation method thereof |
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2018
- 2018-05-23 CN CN201810500195.4A patent/CN108948448A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102212216A (en) * | 2010-04-09 | 2011-10-12 | 中国皮革和制鞋工业研究院 | Sneaker sole material with high wear resistance and low hardness and preparation method thereof |
| CN102796288A (en) * | 2012-08-09 | 2012-11-28 | 际华三五三七制鞋有限责任公司 | Novel antiskid antistatic rubber sole and preparation method thereof |
| CN102964645A (en) * | 2012-11-29 | 2013-03-13 | 泰亚鞋业股份有限公司 | Ice surface anti-slip rubber sports shoe soles and manufacturing method thereof |
| CN104804228A (en) * | 2015-02-28 | 2015-07-29 | 广东志达行新材料有限公司 | Synthesized light rubber material for sole and preparation method of synthesized light rubber material |
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| CN109776896A (en) * | 2018-12-28 | 2019-05-21 | 浙江中远鞋业有限公司 | The sole of rubber overshoes prepares material |
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