CN108946914A - A kind of coal chemical industrial waste water advanced treating CoSD reaction tower - Google Patents

A kind of coal chemical industrial waste water advanced treating CoSD reaction tower Download PDF

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Publication number
CN108946914A
CN108946914A CN201810820383.5A CN201810820383A CN108946914A CN 108946914 A CN108946914 A CN 108946914A CN 201810820383 A CN201810820383 A CN 201810820383A CN 108946914 A CN108946914 A CN 108946914A
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China
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reaction tower
waste water
helix tube
industrial waste
coal chemical
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CN201810820383.5A
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Chinese (zh)
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CN108946914B (en
Inventor
石宏扬
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Liaoning Donghao Chemical Co ltd
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/72Treatment of water, waste water, or sewage by oxidation
    • C02F1/78Treatment of water, waste water, or sewage by oxidation with ozone
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/72Treatment of water, waste water, or sewage by oxidation
    • C02F1/725Treatment of water, waste water, or sewage by oxidation by catalytic oxidation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2201/00Apparatus for treatment of water, waste water or sewage
    • C02F2201/002Construction details of the apparatus
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2201/00Apparatus for treatment of water, waste water or sewage
    • C02F2201/002Construction details of the apparatus
    • C02F2201/007Modular design

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Treatment Of Water By Oxidation Or Reduction (AREA)

Abstract

The invention belongs to coal chemical industrial waste water processing technology field, specifically a kind of coal chemical industrial waste water advanced treating CoSD reaction tower, including reaction tower ontology and knockout tower, the intrinsic bottom surface of reaction tower are equipped with vertical ozonizer;The upper end of knockout tower is connect by aqueduct with the side of reaction tower ontology;Further include helix tube and swing module, flexible helix tube, connection inside helix tube both ends and ozonizer are set on the ozonizer;The swing module includes sliding block, gear, oscillating rod and support ring, and two sides are equipped with straight-tooth on the sliding block, and sliding block is used for band moving gear and rotates;The gear is mounted on ozone inside pipe wall, and gear side and oscillating rod one end are affixed;The oscillating rod other end is equipped with support ring;The support ring socket is on the coil.The present invention is by helix tube and swings module, so that ozone fast reaction in reaction tower, to realize the efficient advanced treating of coal chemical industrial waste water.

Description

A kind of coal chemical industrial waste water advanced treating CoSD reaction tower
Technical field
The invention belongs to coal chemical industrial waste water processing technology field, specifically a kind of coal chemical industrial waste water advanced treating CoSD Reaction tower.
Background technique
Coal chemical industrial waste water is a kind of complicated component and difficult for biological degradation organic wastewater, and main organic principle is phenols chemical combination Object, polycyclic aromatic hydrocarbon (PAH) and heterocyclic compound containing S, N, O etc., toxic, harmful difficult for biological degradation pollutant, although by Pretreatment, multi-stage biological processing, even materialization advanced treating, the still difficult discharge standard for reaching national requirements of water outlet.Therefore, coalification The qualified discharge of work waste water has become the bottleneck for restricting Developing Coal Chemical Industry, carries out further depth to coal chemical industrial waste water Processing has become the urgent need of coal chemical industry development.
Ozone oxidation is the currently used further treatment technique of coal chemical industrial waste water, its advantage is that the strong oxidizing property of ozone and go out The decoloring ability of color;The disadvantage is that ozone utilization rate is low, there are the secondary pollution of ozone tail gas, water purification are at high cost, to organic matter Degradation has selectivity, affects its further commercial introduction application.Ozone catalytic is generated using catalyst ozone Hydroxyl radical free radical more stronger than ozone oxidation ability, and hydroxyl radical free radical, without selectivity, the cost of ozone catalytic only has smelly The 40% of oxygen oxidation, pollutants removal rate is far longer than ozone oxidation, what the ozone that can degrade at normal temperatures and pressures was difficult to aoxidize Organic matter is the optimization technique of coal chemical industrial waste water advanced treating.
Also occur some further treatment technique schemes using ozone in the prior art, such as application No. is 2017107699716 Chinese patent discloses a kind of inexpensive coal chemical industrial waste water advanced treating CoSD reaction tower, including Reaction tower ontology, reaction tower ontology upper end is equipped with wastewater inlet, and the intrinsic bottom surface of reaction tower is equipped with vertical ozone The lower surface of pipe, the reaction tower ontology is equipped with ozone booster pump, can be launched and be urged to reaction tower ontology by the first feeding port Agent can pass through ozonizer and aeration to reaction tower ontology extraction ozone by ozone booster pump so that reaction is more thorough Pipe discharges gas into reaction tower ontology, so that reaction is more abundant, it can be by unreacted in reaction tower ontology by aspiration pump Ozone be drawn into knockout tower, waste residue in sewage can be separated by knockout tower, further by Water warfare, the low cost coal Wastewater from chemical industry advanced treating CoSD react tower structure it is simple, it is easy to operate, be not only able to ozone adequately using, avoid generating Secondary pollution, and save water purification cost.
The technical solution can be realized the advanced treating of coal chemical industrial waste water, but ozone and waste water reacts not in the program Enough abundant, efficiency has much room for improvement;In view of the foregoing drawbacks, the invention proposes a kind of coal chemical industrial waste water advanced treating CoSD reactions Tower can be realized efficient Sewage advanced treatment.
Summary of the invention
In order to make up for the deficiencies of the prior art, a kind of coal chemical industrial waste water advanced treating CoSD reaction tower proposed by the present invention, By the way that sewage to be pumped into reaction tower ontology by wastewater inlet, while ozone catalyst being put into reaction tower ontology, then is led to It crosses and ozone is extracted into ozone booster pump in ozonizer to, ozone is then discharged into reaction tower sheet with the helix tube of ozonizer connection In vivo;When being filled with ozone in ozonizer, the sliding block in ozonizer is to top slide, to drive the tooth on ozone inside pipe wall Wheel, so drive oscillating rod, oscillating rod drives again support ring swing, further such that helix tube swing so that ozone and Waste water comes into full contact with, and improves reaction efficiency.
The technical solution adopted by the present invention to solve the technical problems is: a kind of coal chemical industrial waste water depth of the present invention CoSD reaction tower, including reaction tower ontology and knockout tower are handled, reaction tower ontology upper end is equipped with wastewater inlet, reaction tower sheet Intracorporal bottom surface is equipped with vertical ozonizer;The lower surface of the reaction tower ontology is equipped with ozone booster pump;The reaction tower sheet The upper end of body side is equipped with the first feeding port;The upper end of knockout tower is connect by aqueduct with the side of reaction tower ontology;Also wrap It includes helix tube and swings module, flexible helix tube, connection inside helix tube both ends and ozonizer, institute are set on the ozonizer Helix tube is stated equipped with equally distributed venthole;The swing module includes sliding block, gear, oscillating rod and support ring, described Sliding block be arranged inside ozonizer;Two sides are equipped with straight-tooth on the sliding block, and sliding block is used for band moving gear and rotates;The gear peace On ozone inside pipe wall, gear side and oscillating rod one end are affixed;The oscillating rod other end is equipped with support ring;The support Ring set connects on the coil.When work, sewage is pumped into reaction tower ontology by wastewater inlet, ozone catalyst is put into instead In Ying Taben body, by the way that ozone to be extracted into ozonizer by ozone booster pump, then with the helix tube of ozonizer connection by ozone It is discharged into reaction tower ontology;When being filled with ozone in ozonizer, the sliding block in ozonizer is to top slide, thus with ozone is driven Gear on inside pipe wall, to drive oscillating rod, oscillating rod drives support ring to swing again, so that helix tube is swung, thus So that ozone comes into full contact with waste water, reaction efficiency is improved.
Preferably, the oscillating rod is connected with support ring by connecting rod;Described connecting rod one end is hinged on oscillating rod, connecting rod The other end is fixed in support ring.When work, the connecting rod connected on oscillating rod and support ring, when oscillating rod stress is swung, band Dynamic connecting rod swing improves reaction efficiency so as to achieve the effect that stir waste water.
Preferably, the support ring is made of an intermediate ring and two side rings, and side ring is located at intermediate ring two sides, institute It states side ring and is connect with intermediate ring by elastic element.When work, when connecting rod swing, it will drive support ring and push out spiral Pipe, so that the support ring connected by elastic element reduces helix tube local pressure, to improve helix tube to contract Service life.
Preferably, the elastic element is spring or arc elastic plate;Arc elastic plate is to helix tube inner bulge.Work When, when connecting rod swing, drive support ring to contract, the waste water in arc elastic plate is extruded, to improve waste water Flowing, and then can be improved reaction efficiency.
Preferably, fillet is arranged in the side ring and helix tube contact side.When work, when connecting rod swing, set on the inside of side ring It sets fillet and reduces helix tube local pressure, so as to improve the service life of helix tube.
Preferably, horn-like through-hole is set in the support ring.Horn-like through-hole is set when work, in support ring, So that the mobility of waste water is improved by pinching when waste water passes through, so that ozone is sufficiently mixed with waste water, so as to improve reaction Efficiency.
Preferably, the through-bore axis is vertical with connecting rod.When work, when link rotatable, resistance when waste water passes through through-hole Reduce so as to preferably be passed through from through-hole, so that reaction efficiency improves.
Beneficial effects of the present invention are as follows:
1. ozone catalyst is put into instead by the present invention by the way that sewage to be pumped into reaction tower ontology by wastewater inlet It, then will be smelly with the helix tube of ozonizer connection in Ying Taben body, then by the way that ozone to be extracted into ozonizer by ozone booster pump In oxygen evolution to reaction tower ontology;When being filled with ozone in ozonizer, the sliding block in ozonizer is to top slide, to drive smelly Gear on oxygen inside pipe wall;And then drive and swing, oscillating rod drives support ring to swing again, further such that helix tube is swung;And And connecting rod is set between oscillating rod and support ring, when oscillating rod stress is swung, connecting rod swing is driven to stir waste water;So as to Enough so that ozone comes into full contact with waste water, reaction efficiency is improved.
2. the present invention is by the way that support ring to be arranged to be made of three rings, and when connecting rod swing, connecting rod drives support Ring pushes out helix tube, so that the support ring connected by elastic element reduces helix tube local pressure to contract; And fillet is set on the inside of side ring, is further reduced helix tube stress;So as to improve the service life of helix tube.
3. the present invention is by being specifically configured to spring or arc elastic plate for elastic element, to the arc of helix tube side protrusion The waste water that elastic plate can be squeezed when support ring is swung in arc elastic plate improves so as to improve the mobility of waste water Reaction efficiency;And horn-like through-hole is set in support ring, and through-bore axis is vertical with connecting rod, so that being received when waste water passes through It is poly-, the resistance of waste water process is reduced so as to preferably pass through from through-hole, the mobility of waste water is improved, so that ozone and waste water It is sufficiently mixed, so as to further increase reaction efficiency.
Detailed description of the invention
The present invention will be further explained below with reference to the attached drawings.
Fig. 1 is overall structure diagram of the invention;
Fig. 2 is the partial enlarged view in Fig. 1 at A;
Fig. 3 is the cross-sectional view of B-B in Fig. 2;
Fig. 4 is the structural schematic diagram of support ring of the invention;
In figure: reaction tower ontology 1, the first feeding port 12, knockout tower 2, ozonizer 3, helix tube 4, is swung wastewater inlet 11 Module 5, sliding block 51, gear 51, oscillating rod 53, support ring 54, connecting rod 55, intermediate ring 6, side ring 7, arc elastic plate 8, fillet 9, Through-hole 10.
Specific embodiment
In order to be easy to understand the technical means, the creative features, the aims and the efficiencies achieved by the present invention, tie below Specific embodiment is closed, the present invention is further explained.
As shown in Figures 1 to 4, a kind of coal chemical industrial waste water advanced treating CoSD reaction tower of the present invention, including reaction Tower ontology 1 and knockout tower 2,1 upper end of reaction tower ontology are equipped with wastewater inlet 11, and the bottom surface in reaction tower ontology 1 is equipped with perpendicular Straight ozonizer 3;The lower surface of the reaction tower ontology 1 is equipped with ozone booster pump;The upper end of 1 side of reaction tower ontology is set There is the first feeding port 12;The upper end of knockout tower 2 is connect by aqueduct with the side of reaction tower ontology 1;It further include 4 He of helix tube Module 5 is swung, flexible helix tube 4,4 both ends of helix tube and 3 inside connection of ozonizer, the spiral shell are set on the ozonizer 3 Coil 4 is equipped with equally distributed venthole;The swing module 5 includes sliding block 51, gear 52, oscillating rod 53 and support ring 54, the sliding block 51 is arranged inside ozonizer 3;Two sides are equipped with straight-tooth on the sliding block 51, and sliding block 51 is used for band moving gear 52 rotations;The gear 52 is mounted on 3 inner wall of ozonizer, and 52 side of gear and 53 one end of oscillating rod are affixed;The oscillating rod 53 other ends are equipped with support ring 54;The support ring 54 is socketed on helix tube 4.When work, sewage is passed through into wastewater inlet 11 It is pumped into reaction tower ontology 1, ozone catalyst is put into reaction tower ontology 1, it is smelly by the way that ozone to be extracted by ozone booster pump In oxygen pipe 3, then ozone is discharged into reaction tower ontology 1 by the helix tube 4 with 3 connection of ozonizer;Ozone is filled in ozonizer 3 When, the sliding block 51 in ozonizer 3 is to top slide, thus with the gear 52 on 3 inner wall of ozonizer is driven, to drive oscillating rod 53, oscillating rod 53 drives support ring 54 to swing again, so that helix tube 4 is swung, so that ozone comes into full contact with waste water, Improve reaction efficiency.
As a kind of embodiment of the invention, the oscillating rod 53 and support ring 54 are connected by connecting rod 55;The company 55 one end of bar is hinged on oscillating rod 53, and 55 other end of connecting rod is fixed in support ring 54.When work, oscillating rod 53 and support ring The connecting rod 55 connected on 54 drives connecting rod 55 to swing when 53 stress of oscillating rod is swung so as to reach the effect of stirring waste water Fruit, and then improve reaction efficiency.
As a kind of embodiment of the invention, the support ring 54 is made of an intermediate ring 6 and two side rings 7, side Ring 7 is located at intermediate 6 two sides of ring, and the side ring 7 is connect with intermediate ring 6 by elastic element.When work, when connecting rod 55 is swung When, it will drive support ring 54 and push out helix tube 4, so that the support ring 54 connected by elastic element is to contract, 4 local pressure of helix tube is reduced, to improve the service life of helix tube 4.
As a kind of embodiment of the invention, a kind of coal chemical industrial waste water advanced treating according to claim 3 CoSD reaction tower, the elastic element are spring or arc elastic plate 8;Arc elastic plate 8 is to 4 inner bulge of helix tube.Work When, when connecting rod 55 is swung, drive support ring 54 to contract, the waste water in arc elastic plate 8 is extruded, to improve useless The flowing of water, and then can be improved reaction efficiency.
As a kind of embodiment of the invention, the side ring 7 contacts side with helix tube 4 and fillet 9 is arranged.When work, when When connecting rod 55 is swung, setting fillet 9 reduces 4 local pressure of helix tube on the inside of side ring 7, so as to improve the use of helix tube 4 Service life.
As a kind of embodiment of the invention, horn-like through-hole 10 is set in the support ring 54.When work, support Horn-like through-hole 10 is set on ring 54, so that the mobility of waste water is improved by pinching when waste water passes through, so that ozone and waste water It is sufficiently mixed, so as to improve reaction efficiency.
As a kind of embodiment of the invention, 10 axis of through-hole is vertical with connecting rod 55.When work, when 55 turns of connecting rod When dynamic, resistance reduces so as to preferably pass through from through-hole 10 when waste water passes through through-hole 10, so that reaction efficiency improves.
When work, sewage is pumped into reaction tower ontology 1 by wastewater inlet 11, and ozone catalyst is put into reaction tower ontology In 1, by the way that ozone to be extracted into ozonizer 3 by ozone booster pump, then the helix tube 4 with 3 connection of ozonizer discharges foul smell Into reaction tower ontology 1;When being filled with ozone in ozonizer 3, the sliding block 51 in ozonizer 3 is to top slide, to drive ozone Gear 52 on 3 inner wall of pipe, to drive oscillating rod 53, oscillating rod 53 drives support ring 54 to swing again, so that helix tube 4 It swings, so that ozone comes into full contact with waste water, improves reaction efficiency;And it is arranged between oscillating rod 53 and support ring 54 Connecting rod 55 drives connecting rod 55 to swing to stir waste water when 53 stress of oscillating rod is swung;And when connecting rod 55 is swung, even Bar 55 drives support ring 54 to push out helix tube 4, so that the support connected by elastic element being made of three rings Ring 54 reduces 4 local pressure of helix tube, to improve the service life of helix tube 4 to contract;It is set on the inside of side ring 7 simultaneously Fillet 9 is set, 4 stress of helix tube is further reduced;Its elastic element is specially spring or arc elastic plate 8, to 4 side of helix tube The arc elastic plate 8 of protrusion can squeeze the waste water in arc elastic plate 8 when support ring 54 is swung, to improve the stream of waste water Dynamic property, can be improved reaction efficiency;And horn-like through-hole 10 is set in support ring 54, and 10 axis of through-hole and connecting rod 55 hang down Directly, so that reducing the resistance that waste water passes through by pinching when waste water passes through so as to preferably pass through from through-hole 10, improving waste water Mobility so that ozone is sufficiently mixed with waste water, so as to improve reaction efficiency.
The basic principles, main features and advantages of the invention have been shown and described above.The technical staff of the industry should Understand, the present invention is not limited to the above embodiments, and the above embodiments and description only describe originals of the invention Reason, without departing from the spirit and scope of the present invention, various changes and improvements may be made to the invention, these changes and improvements It all fall within the protetion scope of the claimed invention.The claimed scope of the invention is by appended claims and its equivalent circle It is fixed.

Claims (7)

1. a kind of coal chemical industrial waste water advanced treating CoSD reaction tower, including reaction tower ontology (1) and knockout tower (2), the reaction Tower ontology (1) upper end is equipped with wastewater inlet (11), and the bottom surface in reaction tower ontology (1) is equipped with vertical ozonizer (3);It is described anti- The lower surface of tower ontology (1) is answered to be equipped with ozone booster pump;The upper end of reaction tower ontology (1) side is equipped with the first feeding port (12);The upper end of knockout tower (2) is connect by aqueduct with the side of reaction tower ontology (1);It is characterized by also including spirals It manages (4) and swings module (5), set flexible helix tube (4) on the ozonizer (3), helix tube (4) both ends and ozonizer (3) internal connection, the helix tube (4) are equipped with equally distributed venthole;The swing module (5) include sliding block (51), Gear (52), oscillating rod (53) and support ring (54), the sliding block (51) setting are internal in ozonizer (3);The sliding block (51) two sides are equipped with straight-tooth, and sliding block (51) is used for band moving gear (52) and rotates;The gear (52) is mounted on ozonizer (3) inner wall On, gear (52) side and oscillating rod (53) one end are affixed;Oscillating rod (53) other end is equipped with support ring (54);The branch Pushing out ring (54) is socketed on helix tube (4).
2. a kind of coal chemical industrial waste water advanced treating CoSD reaction tower according to claim 1, it is characterised in that: the swing Bar (53) and support ring (54) are connected by connecting rod (55);Described connecting rod (55) one end is hinged on oscillating rod (53), connecting rod (55) other end is fixed on support ring (54).
3. a kind of coal chemical industrial waste water advanced treating CoSD reaction tower according to claim 2, it is characterised in that: the support Ring (54) is made of an intermediate ring (6) and two side rings (7), and side ring (7) is located at intermediate ring (6) two sides, the side ring (7) it is connect with intermediate ring (6) by elastic element.
4. a kind of coal chemical industrial waste water advanced treating CoSD reaction tower according to claim 3, it is characterised in that: the elasticity Element is spring or arc elastic plate (8);Arc elastic plate (8) is to helix tube (4) inner bulge.
5. a kind of coal chemical industrial waste water advanced treating CoSD reaction tower according to claim 4, it is characterised in that: the side ring (7) fillet (9) are set with helix tube (4) contact side.
6. a kind of coal chemical industrial waste water advanced treating CoSD reaction tower according to claim 1, it is characterised in that: the support Horn-like through-hole (10) are set on ring (54).
7. a kind of coal chemical industrial waste water advanced treating CoSD reaction tower according to claim 6, it is characterised in that: the through-hole (10) axis is vertical with connecting rod (55).
CN201810820383.5A 2018-07-24 2018-07-24 Coal chemical industry advanced wastewater treatment CoSD reaction tower Active CN108946914B (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112827759A (en) * 2020-12-30 2021-05-25 广东新纪源复合材料股份有限公司 Composite optical pre-coating film and preparation method thereof
CN115520953A (en) * 2022-06-28 2022-12-27 胡长龙 Coal chemical industry advanced wastewater treatment CoSD reaction tower

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20130073075A (en) * 2011-12-23 2013-07-03 주식회사 포스코아이씨티 Apparatus and method for treating waste water of food
CN206014451U (en) * 2016-08-15 2017-03-15 李恩屹 A kind of high efficiency air float machine of quick process
CN107364960A (en) * 2017-08-29 2017-11-21 湖南中本智能科技发展有限公司 A kind of rotary sanitary sewage aeration mechanism
CN107364947A (en) * 2017-08-31 2017-11-21 中山市程博工业产品设计有限公司 A kind of inexpensive coal chemical industrial waste water advanced treating CoSD reaction towers
CN107746106A (en) * 2017-11-25 2018-03-02 深圳市娅安科技有限公司 A kind of high efficient aeration pond for being used to handle sanitary sewage

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20130073075A (en) * 2011-12-23 2013-07-03 주식회사 포스코아이씨티 Apparatus and method for treating waste water of food
CN206014451U (en) * 2016-08-15 2017-03-15 李恩屹 A kind of high efficiency air float machine of quick process
CN107364960A (en) * 2017-08-29 2017-11-21 湖南中本智能科技发展有限公司 A kind of rotary sanitary sewage aeration mechanism
CN107364947A (en) * 2017-08-31 2017-11-21 中山市程博工业产品设计有限公司 A kind of inexpensive coal chemical industrial waste water advanced treating CoSD reaction towers
CN107746106A (en) * 2017-11-25 2018-03-02 深圳市娅安科技有限公司 A kind of high efficient aeration pond for being used to handle sanitary sewage

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112827759A (en) * 2020-12-30 2021-05-25 广东新纪源复合材料股份有限公司 Composite optical pre-coating film and preparation method thereof
CN115520953A (en) * 2022-06-28 2022-12-27 胡长龙 Coal chemical industry advanced wastewater treatment CoSD reaction tower

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