CN108943919A - 一种防弹玻璃及其制备方法 - Google Patents
一种防弹玻璃及其制备方法 Download PDFInfo
- Publication number
- CN108943919A CN108943919A CN201811117648.1A CN201811117648A CN108943919A CN 108943919 A CN108943919 A CN 108943919A CN 201811117648 A CN201811117648 A CN 201811117648A CN 108943919 A CN108943919 A CN 108943919A
- Authority
- CN
- China
- Prior art keywords
- layer
- glassy layer
- glassy
- glass
- heat
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000011521 glass Substances 0.000 title claims abstract description 70
- 238000002360 preparation method Methods 0.000 title claims abstract description 13
- 239000010410 layer Substances 0.000 claims abstract description 167
- 239000012790 adhesive layer Substances 0.000 claims abstract description 40
- 239000002131 composite material Substances 0.000 claims description 24
- 238000002834 transmittance Methods 0.000 claims description 18
- 239000004411 aluminium Substances 0.000 claims description 14
- 229910052782 aluminium Inorganic materials 0.000 claims description 14
- 150000001875 compounds Chemical class 0.000 claims description 12
- 239000011248 coating agent Substances 0.000 claims description 11
- 238000000576 coating method Methods 0.000 claims description 11
- 238000007789 sealing Methods 0.000 claims description 9
- 238000005516 engineering process Methods 0.000 claims description 7
- 239000004590 silicone sealant Substances 0.000 claims description 7
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 5
- 239000005329 float glass Substances 0.000 claims description 5
- 238000000151 deposition Methods 0.000 claims description 4
- 239000005357 flat glass Substances 0.000 claims description 2
- 239000005341 toughened glass Substances 0.000 claims description 2
- 239000011324 bead Substances 0.000 claims 2
- 238000004026 adhesive bonding Methods 0.000 claims 1
- 238000007711 solidification Methods 0.000 claims 1
- 230000008023 solidification Effects 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 9
- 230000009286 beneficial effect Effects 0.000 abstract description 2
- 239000004417 polycarbonate Substances 0.000 description 23
- 239000004814 polyurethane Substances 0.000 description 21
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 description 19
- 239000003292 glue Substances 0.000 description 14
- 238000009413 insulation Methods 0.000 description 14
- 230000005540 biological transmission Effects 0.000 description 8
- 229920003023 plastic Polymers 0.000 description 8
- 239000004033 plastic Substances 0.000 description 8
- 238000004382 potting Methods 0.000 description 8
- 238000000034 method Methods 0.000 description 7
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 6
- 238000001816 cooling Methods 0.000 description 6
- 239000000463 material Substances 0.000 description 5
- 239000002245 particle Substances 0.000 description 5
- 239000005340 laminated glass Substances 0.000 description 4
- 229920000642 polymer Polymers 0.000 description 4
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 3
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 3
- 229910052737 gold Inorganic materials 0.000 description 3
- 239000010931 gold Substances 0.000 description 3
- 229910052738 indium Inorganic materials 0.000 description 3
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- 238000002955 isolation Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 229910052759 nickel Inorganic materials 0.000 description 3
- 229910000510 noble metal Inorganic materials 0.000 description 3
- 230000003287 optical effect Effects 0.000 description 3
- 229920000515 polycarbonate Polymers 0.000 description 3
- 230000004224 protection Effects 0.000 description 3
- 229910052709 silver Inorganic materials 0.000 description 3
- 239000004332 silver Substances 0.000 description 3
- -1 that is Substances 0.000 description 3
- 229910052719 titanium Inorganic materials 0.000 description 3
- 239000010936 titanium Substances 0.000 description 3
- 230000005611 electricity Effects 0.000 description 2
- 229920006351 engineering plastic Polymers 0.000 description 2
- 239000012528 membrane Substances 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- 229920001296 polysiloxane Polymers 0.000 description 2
- 229920002635 polyurethane Polymers 0.000 description 2
- 239000005336 safety glass Substances 0.000 description 2
- 125000006850 spacer group Chemical group 0.000 description 2
- KXDHJXZQYSOELW-UHFFFAOYSA-M Carbamate Chemical compound NC([O-])=O KXDHJXZQYSOELW-UHFFFAOYSA-M 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 208000032170 Congenital Abnormalities Diseases 0.000 description 1
- 206010010356 Congenital anomaly Diseases 0.000 description 1
- 230000006750 UV protection Effects 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000007698 birth defect Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 125000005587 carbonate group Chemical group 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 125000004185 ester group Chemical group 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 229910003437 indium oxide Inorganic materials 0.000 description 1
- PJXISJQVUVHSOJ-UHFFFAOYSA-N indium(iii) oxide Chemical compound [O-2].[O-2].[O-2].[In+3].[In+3] PJXISJQVUVHSOJ-UHFFFAOYSA-N 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 238000001755 magnetron sputter deposition Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000012994 photoredox catalyst Substances 0.000 description 1
- 238000010248 power generation Methods 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 230000003595 spectral effect Effects 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 238000004544 sputter deposition Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 238000005496 tempering Methods 0.000 description 1
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 1
- 229910001887 tin oxide Inorganic materials 0.000 description 1
- 239000012780 transparent material Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
- B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
- B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
- B32B17/1055—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer
- B32B17/10779—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer containing polyester
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
- B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
- B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
- B32B17/10009—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets
- B32B17/10064—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets comprising at least two glass sheets, only one of which being an outer layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
- B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
- B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
- B32B17/10807—Making laminated safety glass or glazing; Apparatus therefor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
- B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
- B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
- B32B17/10807—Making laminated safety glass or glazing; Apparatus therefor
- B32B17/1088—Making laminated safety glass or glazing; Apparatus therefor by superposing a plurality of layered products
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
- B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
- B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
- B32B17/10807—Making laminated safety glass or glazing; Apparatus therefor
- B32B17/10899—Making laminated safety glass or glazing; Apparatus therefor by introducing interlayers of synthetic resin
- B32B17/10908—Making laminated safety glass or glazing; Apparatus therefor by introducing interlayers of synthetic resin in liquid form
- B32B17/10917—Making laminated safety glass or glazing; Apparatus therefor by introducing interlayers of synthetic resin in liquid form between two pre-positioned glass layers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
- B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
- B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
- B32B17/10807—Making laminated safety glass or glazing; Apparatus therefor
- B32B17/1099—After-treatment of the layered product, e.g. cooling
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B3/00—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form
- B32B3/02—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by features of form at particular places, e.g. in edge regions
- B32B3/08—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by features of form at particular places, e.g. in edge regions characterised by added members at particular parts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B33/00—Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/06—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the heating method
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/08—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the cooling method
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/10—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the pressing technique, e.g. using action of vacuum or fluid pressure
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/12—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/12—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
- B32B37/1284—Application of adhesive
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B38/00—Ancillary operations in connection with laminating processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
- B32B7/08—Interconnection of layers by mechanical means
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
- B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/001—General methods for coating; Devices therefor
- C03C17/002—General methods for coating; Devices therefor for flat glass, e.g. float glass
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/20—Properties of the layers or laminate having particular electrical or magnetic properties, e.g. piezoelectric
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/30—Properties of the layers or laminate having particular thermal properties
- B32B2307/304—Insulating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/30—Properties of the layers or laminate having particular thermal properties
- B32B2307/31—Heat sealable
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2218/00—Methods for coating glass
- C03C2218/10—Deposition methods
- C03C2218/15—Deposition methods from the vapour phase
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Mechanical Engineering (AREA)
- Physics & Mathematics (AREA)
- Fluid Mechanics (AREA)
- Joining Of Glass To Other Materials (AREA)
Abstract
本发明属于玻璃加工技术领域,提供了一种防弹玻璃及其制备方法。所述防弹玻璃包括依次设置的第一玻璃层、第二玻璃层和防弹层,所述第一玻璃层和第二玻璃层之间为第一粘接层,第二玻璃层和防弹层之间为第二粘接层,所述第一粘接层和第二粘接层为隔热粘接层,所述防弹层具有隔热空气层。本发明的有益效果在于:隔热粘接层可以将热量有效阻隔,隔热空气层可进一步提高保温隔热效果。
Description
技术领域
本发明属于玻璃加工技术领域,具体涉及一种防弹玻璃及其制备方法。
背景技术
防弹玻璃作为一种透明材料,具有极高的强度和韧性,可以承受强烈冲击和破坏,在满足透光观察要求的同时抵御枪弹射击而不被穿透,在安全防护方面有着广泛的用途,常用于银行、贵重物品陈列柜、监狱等地的门窗部位,以最大程度的保护人身安全,为了实现防弹功能,防弹玻璃常设计为多层的层状结构,但普通防弹玻璃较低的保温隔热性能。
公告号为CN 206968122 U的发明公开了一种防弹玻璃,包括多层玻璃与一层聚碳酸酯层,通过PVB胶片进行粘接。
传统防弹玻璃不可发电,不能调节室内光线,同时为了达到需要的防弹效果,必须采用多层玻璃和PVB胶片组成防弹玻璃,总体体积较重,对于承接框要求和安装动力要求较高;同时传统防弹玻璃具有较低的保温隔热性能。
发明内容
本发明的目的在于提供一种防弹玻璃及其制备方法,以解决现有技术中存在的技术问题。
本发明所采用的技术手段是:一种防弹玻璃,包括:依次设置的第一玻璃层、第二玻璃层和防弹层,所述第一玻璃层和第二玻璃层之间为第一粘接层,第二玻璃层和防弹层之间为第二粘接层,所述第一粘接层和第二粘接层为隔热粘接层,所述防弹层具有隔热空气层。所述隔热粘接层和隔热空气层使防弹玻璃具有良好的保温隔热效果,可以有效降低夏天室内温度,并可减少冬天室内热量流失。
可选的技术方案中,所述第一粘接层为PVB、SGP、PU高隔热胶片中的一种,厚度为0.38-2.28mm,透光率90%以上。优选地,所述第一粘接层为经隔热纳米掺锑氧化锡或隔热纳米掺锡氧化铟处理的PVB隔热胶片,具有更好的抗击外来撞击,提高防盗、隔音和防紫外线性能。
可选的技术方案中,所述第二粘接层为高隔热PU灌注胶粘接层,厚度为1-2mm。
可选的技术方案中,所述第二玻璃层为芯片镀膜玻璃层,所述芯片镀膜玻璃层厚度为3-6mm,透光率为20%-50%。优选地,所述芯片镀膜玻璃层为普通浮法玻璃,可实现防弹玻璃的发电。
可选的技术方案中,所述防弹层为PC防弹层,依次包括PC层、第三玻璃层和第四玻璃层;所述PC层和第三玻璃层之间为第一空气层,所述第三玻璃层和所述第四玻璃层之间为第二空气层。使用PC防弹层不仅防弹效果更好,产品质量更轻,有利于安装。
可选的技术方案中,所述PC层厚度为2-6mm,透光率90%以上。
可选的技术方案中,所述PC层与第三玻璃层之间通过铝间隔条和硅酮密封胶粘接密封形成第一空气层;所述第三玻璃层与第四玻璃层之间通过铝间隔条和硅酮密封胶粘接密封形成第二空气层。双层空气层结构进一步提高了防弹玻璃的保温隔热效果。
可选的技术方案中,所述第一玻璃层、第三玻璃层和第四玻璃层为浮法玻璃,钢化玻璃、平板玻璃、夹丝玻璃中的一种,厚度为3-6mm。
可选的技术方案中,所述第一玻璃层外侧设置有高反射隔热薄膜层。优选地,所述高反射隔热薄膜层为采用磁控溅射工艺将金、银、钛、镍、铟等贵金属均匀溅射到光学级PET基材上制成的多层至密的高隔热金属膜层,对太阳光谱中的红外热量起到持久反射隔热作用。所述高反射隔热膜为靠反射来达到隔热目的的智能光谱选择性隔热膜,解决了吸热型膜隔热膜的先天性缺陷二次辐射传热问题。
本发明还提供一种上述防弹玻璃的制备工艺,所述制备工艺包括以下步骤:
(1)采用共蒸发技术在玻璃层表面沉积光伏芯片镀层,采用激光刻划不同的芯片镀层间隔尺寸及排布密度,得到具有不同透光率的第二玻璃层;
(2)将第一玻璃层、第一粘接层、第二玻璃层从上到下依次叠加合片,预压得到复合样品;
(3)将步骤(2)中制备的复合样品放入高压釜中,高温压制得到高压复合样品;
(4)将步骤(3)中制备的高压复合样品在第二玻璃层与PC层之间进行PU灌封粘接,冷却固化后得到第二粘接层。
进一步地,步骤(2)在辊压机中预压,保持辊压后玻璃表面温度为70℃左右,冷却备用,得到预压复合样品。
进一步地,步骤(3)预压复合样品放入高压釜中,升温升压至120-140℃,1-1.5MPa,保持30-60min,后降温至40℃以下,后缓慢卸压,打开高压釜得到高压复合样品。
进一步地,步骤(4)将隔PU胶主料与固化剂2000转/min搅拌混合均匀,真空脱泡后,将步骤(3)中制备的复合样品在第二玻璃层一面与PC层之间进行PU灌封粘接,冷却固化后得到PU灌注胶粘接层。
进一步地,所述制备工艺还可以包含步骤(5)和步骤(6),具体包括:
(5)在PC层与第三玻璃层之间、第三玻璃层与第四玻璃层10之间分别通过铝间隔条和硅酮密封胶粘接密封形成第一空气层和第二空气层;
(6)在第一玻璃层表面粘接高反射隔热薄膜层。
进一步的,步骤(5)中的所述铝间隔条内填充有可吸收水汽的分子筛颗粒。
与现有技术相比,本发明产生的有益效果是:
(1)本发明的防弹玻璃通过设置高隔热PVB胶片、高隔热PU灌封胶及高反射薄膜及可以将热量有效阻隔,通过双层空气层结构进一步提高了保温隔热效果。
(2)本发明的防弹玻璃中具有PC防弹层,不仅产品防弹效果更好,产品质量更轻,有利于安装。
(3)本发明防弹玻璃中的芯片镀膜玻璃层不仅可以发电,而且通过激光刻划后可以调节室内光线。
附图说明
图1为本发明实施例1中防弹玻璃的材料组成结构示意图。
其中:1、高反射隔热薄膜层,2、第一玻璃层,3、隔热PVB胶膜粘接层,4、第二玻璃层,5、隔热PU灌注胶粘接层,6、高透光PC塑料层,7、第一空气层,8、第三玻璃层,9、第二空气层,10、第四玻璃层。
具体实施方式
下面结合附图对本发明的技术方案进行清楚、完整的描述,显然所描述的实施例是本发明一部分实施例,而不是全部的实施例。基于本发明中的实施例,本领域普通技术人员在没有做出创造性劳动的前提下所获的所有其他实施例,都属于本发明的保护范围。
术语PC即聚碳酸酯(英文:Polycarbonate,缩写为PC)是指分子链中含有碳酸酯基的高分子聚合物,根据酯基的结构可分为脂肪族、芳香族、脂肪族-芳香族等多种类型,由于聚碳酸酯结构上的特殊性,已成为五大工程塑料中增长速度最快的通用工程塑料。
聚合物是指通过将不论是相同或不同类的单体进行聚合而制备的聚合化合物。通用术语聚合物因而包含均聚物(通常用来指由唯一一种单体制备的聚合物)以及互聚物。
术语PVB即聚乙烯醇缩丁醛(英文:Polyvinyl Butyral,缩写为PVB)。PVB胶片为半透明膜片,对无机玻璃有很好粘结力,具有透明、耐热、耐寒、机械强度高等特性,是制造夹层玻璃用的最佳粘合材料。PVB胶片能吸收冲击能量,不产生破碎片,这种安全玻璃广泛应用于汽车、高层建筑、银行柜台,各种防弹玻璃等。在具有安全性能的同时,还有优异的隔音,光控,保温,隔热,防震等性能,是世界上最理想的安全玻璃加工材料。
术语SGP(Sentry Glas Plus)中间膜是由杜邦公司研发,具有重大革新技术的夹层玻璃中间膜。SGP超越了现有技术,大大拓展了夹层玻璃性能。SGP的撕裂强度是普通PVB的5倍度,硬度是普通PVB的100倍。SGP的高强度、高透明、耐久性、多种结构及灵活的安装,使其能轻易适应当今建筑市场的最新最严格的要求。相对普通夹层玻璃,SGP夹层玻璃可提高防弹玻璃的性能,可在一定程度上减小夹层玻璃的厚度。
术语PU即聚胺酯(英语:Polyurethane,缩写为PU)是指主链中含有氨基甲酸酯特征单元的一类高分子,这种高分子材料广泛用于黏合剂,涂层,低速轮胎,垫圈,车垫等工业领域。
实施例1
按照如下制备方法制备本实施例中防弹玻璃
(1)将厚度为3mm的玻璃层进行清洗干燥后,在上表面采用共蒸发技术沉积光伏芯片镀层,并采用激光法刻划不同的芯片镀层间隔尺寸及排布密度,从而得到透光率为50%的第二玻璃层4;
(2)将透光率为50%的第二玻璃层4的芯片镀层朝上,将第一玻璃层2清洗干燥后,将第一玻璃层2、隔热PVB胶膜粘接层3及第二玻璃层4从上到下依次叠加合片,放入预热后的辊压机中预压,保持辊压后玻璃表面温度为70℃左右,冷却备用,得到预压复合样品;
(3)将步骤(2)制备的预压复合样品放入高压釜中,升温升压至120℃,1MPa,保持30min,后降温至40℃以下,后缓慢卸压,打开高压釜得到高压复合样品;
(4)将隔热PU胶主料与固化剂2000转/min搅拌混合均匀,真空脱泡后,将步骤(3)中制备的复合样品在第二玻璃层4非镀膜一面与高透光PC塑料层6之间进行PU胶灌封粘接,冷却固化后得到隔热PU灌注胶粘接层5;
(5)将步骤(4)中制备的复合样品在高透光PC塑料层6一面与第三玻璃层8之间通过铝间隔条和硅酮密封胶进行粘接密封,形成第一空气层7,同时铝间隔条内填充有可吸收水汽的分子筛颗粒。
(6)将步骤(5)中制备的复合样品在第三玻璃层8一面与第四玻璃层10之间通过铝间隔条和硅酮密封胶进行粘接密封,形成第二空气层9,同时铝间隔条内填充有可吸收水汽的分子筛颗粒。
(7)将步骤(6)制备的复合样品,在第一玻璃层2上表面粘接高反射隔热薄膜层1。
如附图1所示,本实施例制备的具有防弹玻璃,自上而下依次为高反射隔热薄膜层1,第一玻璃层2,隔热PVB胶膜粘接层3,第二玻璃层4,隔热PU灌注胶粘接层5,高透光PC塑料层6,第一空气层7,第三玻璃层8,第二空气层9,第四玻璃层10。
其中,高反射隔热薄膜层1厚度为50μm,具体地,高反射隔热薄膜层1为采用磁控溅射工艺将金、银、钛、镍、铟等贵金属均匀溅射到光学级PET基材上制成的多层至密的高隔热金属膜层;隔热PVB胶膜粘接层3厚度为0.38mm,透光率大于90%;第二玻璃层4为基于普通浮法玻璃制作的芯片镀膜玻璃层,厚度为3mm,透光率50%;隔热PU灌注胶粘接层5的厚度为1mm;高透光PC塑料层6厚度为2mm,透光率大于90%;第一玻璃层、第三玻璃层8和第四玻璃层10为夹丝玻璃层,厚度均为3mm;第一空气层7和第二空气层9厚度相同,厚度均为2mm,可有效的提高保温隔热效果。
实施例2
按照如下制备方法制备本实施例中防弹玻璃
(1)将厚度为6mm的玻璃层进行清洗干燥后,在上表面采用共蒸发技术沉积光伏芯片镀层,并采用激光法刻划不同的芯片镀层间隔尺寸及排布密度,从而得到透光率为20%的第二玻璃层4;
(2)将透光率为20%的第二玻璃层4的芯片镀层朝上,将第一玻璃层2清洗干燥后,将第一玻璃层2、隔热PVB胶膜粘接层3及第二玻璃层4从上到下依次叠加合片,放入预热后的辊压机中预压,保持辊压后玻璃表面温度为70℃左右,冷却备用,得到预压复合样品;
(3)将步骤(2)制备的预压复合样品放入高压釜中,升温升压至140℃,1.5MPa,保持60min,后降温至40℃以下,后缓慢卸压,打开高压釜得到高压复合样品;
(4)将隔热PU胶主料与固化剂2000转/min搅拌混合均匀,真空脱泡后,将步骤(3)中制备的复合样品在第二玻璃层4非镀膜一面与高透光PC塑料层6之间进行PU胶灌封粘接,冷却固化后得到隔热PU灌注胶粘接层5;
(5)将步骤(4)中制备的复合样品在高透光PC塑料层6一面与第三玻璃层8之间通过铝间隔条和硅酮密封胶进行粘接密封,形成第一空气层7,同时铝间隔条内填充有可吸收水汽的分子筛颗粒。
(6)将步骤(5)中制备的复合样品在第三玻璃层8一面与第四玻璃层10之间通过铝间隔条和硅酮密封胶进行粘接密封,形成第二空气层9,同时铝间隔条内填充有可吸收水汽的分子筛颗粒。
(7)将步骤(6)制备的复合样品,在第一玻璃层2上表面粘接高反射隔热薄膜层1。
其中,高反射隔热薄膜层1厚度为500μm,具体地,高反射隔热薄膜层1为采用磁控溅射工艺将金、银、钛、镍、铟等贵金属均匀溅射到光学级PET基材上制成的多层至密的高隔热金属膜层;隔热PVB胶膜粘接层3厚度为2.28mm,透光率大于90%;第二玻璃层4为基于普通浮法玻璃制作的芯片镀膜玻璃层,厚度为6mm,透光率20%;隔热PU灌注胶粘接层5的厚度为2mm;高透光PC塑料层6厚度为6mm,透光率大于90%;第一玻璃层、第三玻璃层8和第四玻璃层10为钢化玻璃层,厚度均为6mm;第一空气层7和第二空气层9厚度相同,厚度均为4mm,可有效的提高保温隔热效果。
以上所述仅为本发明的优选实施例而已,并不用于限制本发明,对于本领域的技术人员来说,本发明可以有各种更改和变化。凡在本发明的精神和原则之内,所作的任何修改、等同替换、改进等,均应包含在本发明的保护范围之内。
Claims (10)
1.一种防弹玻璃,包括:依次设置的第一玻璃层、第二玻璃层和防弹层,所述第一玻璃层和第二玻璃层之间为第一粘接层,第二玻璃层和防弹层之间为第二粘接层,其特征在于,所述第一粘接层和第二粘接层为隔热粘接层,所述防弹层具有隔热空气层。
2.根据权利要求1所述的防弹玻璃,其特征在于,所述第一粘接层为PVB、SGP、PU高隔热胶片中的一种,厚度为0.38-2.28mm,透光率90%以上。
3.根据权利要求1所述的防弹玻璃,其特征在于,所述第二粘接层为高隔热PU灌注胶粘接层,厚度为1-2mm。
4.根据权利要求1所述的防弹玻璃,其特征在于,所述第二玻璃层为芯片镀膜玻璃层,所述芯片镀膜玻璃层厚度为3-6mm,透光率为20%-50%。
5.根据权利要求1所述的防弹玻璃,其特征在于,所述防弹层为PC防弹层,依次包括PC层、第三玻璃层和第四玻璃层;所述PC层和第三玻璃层之间为第一空气层,所述第三玻璃层和所述第四玻璃层之间为第二空气层。
6.根据权利要求5所述的防弹玻璃,其特征在于,所述PC层厚度为2-6mm,透光率90%以上。
7.根据权利要求5所述的防弹玻璃,其特征在于,所述PC层与第三玻璃层之间通过铝间隔条和硅酮密封胶粘接密封形成第一空气层;所述第三玻璃层与第四玻璃层之间通过铝间隔条和硅酮密封胶粘接密封形成第二空气层。
8.根据权利要求5所述的防弹玻璃,其特征在于,所述第一玻璃层、第三玻璃层和第四玻璃层为浮法玻璃,钢化玻璃、平板玻璃、夹丝玻璃中的一种,厚度为3-6mm。
9.根据权利要求1所述的防弹玻璃,其特征在于,所述第一玻璃层外侧设置有高反射隔热薄膜层。
10.根据权利要求1-9任一项所述的防弹玻璃的制备方法,所述制备方法包括以下步骤:
(1)采用共蒸发技术在玻璃层表面沉积光伏芯片镀层,采用激光刻划不同的芯片镀层间隔尺寸及排布密度,得到具有不同透光率的第二玻璃层;
(2)将第一玻璃层、第一粘接层、第二玻璃层从上到下依次叠加合片,预压得到复合样品;
(3)将步骤(2)中制备的复合样品高温压制得到高压复合样品;
(4)将步骤(3)中制备的高压复合样品在第二玻璃层与PC层之间进行PU灌封粘接,冷却固化后得到第二粘接层。
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201811117648.1A CN108943919B (zh) | 2018-09-21 | 2018-09-21 | 一种防弹玻璃及其制备方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201811117648.1A CN108943919B (zh) | 2018-09-21 | 2018-09-21 | 一种防弹玻璃及其制备方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN108943919A true CN108943919A (zh) | 2018-12-07 |
CN108943919B CN108943919B (zh) | 2023-10-10 |
Family
ID=64472306
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201811117648.1A Active CN108943919B (zh) | 2018-09-21 | 2018-09-21 | 一种防弹玻璃及其制备方法 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN108943919B (zh) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN112054079A (zh) * | 2020-09-03 | 2020-12-08 | 成都中建材光电材料有限公司 | 用于光伏建筑一体化的发电玻璃及其制备方法 |
CN112165286A (zh) * | 2020-09-03 | 2021-01-01 | 成都中建材光电材料有限公司 | 防弹防辐射屏蔽电磁信号的发电玻璃及其制备方法 |
CN114173510A (zh) * | 2021-12-08 | 2022-03-11 | 上海交通大学 | 一种具有空气隔热层的微型多层隔热结构及其制备和应用 |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CH646671A5 (en) * | 1979-01-19 | 1984-12-14 | Ver Glaswerke Gmbh | Twin-shell, bulletproof (armoured) insulating glass pane |
DE102006042538A1 (de) * | 2006-09-11 | 2008-03-27 | Futech Gmbh | Verbundglas, Verglasungselement und Verfahren zu deren Herstellung |
US20080210287A1 (en) * | 2006-12-29 | 2008-09-04 | Willi Volpp | Intrusion resistant safety glazings and solar cell modules |
EP2110238A1 (de) * | 2008-04-17 | 2009-10-21 | Sälzer Sicherheitstechnik GmbH | Sprengwirkungshemmender Scheibenaufbau |
CN203331502U (zh) * | 2013-07-01 | 2013-12-11 | 许昌学院 | 一种能抵御机械冲击的防辐射光伏玻璃 |
CN209037125U (zh) * | 2018-09-21 | 2019-06-28 | 汉能移动能源控股集团有限公司 | 一种防弹玻璃 |
-
2018
- 2018-09-21 CN CN201811117648.1A patent/CN108943919B/zh active Active
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CH646671A5 (en) * | 1979-01-19 | 1984-12-14 | Ver Glaswerke Gmbh | Twin-shell, bulletproof (armoured) insulating glass pane |
DE102006042538A1 (de) * | 2006-09-11 | 2008-03-27 | Futech Gmbh | Verbundglas, Verglasungselement und Verfahren zu deren Herstellung |
US20080210287A1 (en) * | 2006-12-29 | 2008-09-04 | Willi Volpp | Intrusion resistant safety glazings and solar cell modules |
EP2110238A1 (de) * | 2008-04-17 | 2009-10-21 | Sälzer Sicherheitstechnik GmbH | Sprengwirkungshemmender Scheibenaufbau |
CN203331502U (zh) * | 2013-07-01 | 2013-12-11 | 许昌学院 | 一种能抵御机械冲击的防辐射光伏玻璃 |
CN209037125U (zh) * | 2018-09-21 | 2019-06-28 | 汉能移动能源控股集团有限公司 | 一种防弹玻璃 |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN112054079A (zh) * | 2020-09-03 | 2020-12-08 | 成都中建材光电材料有限公司 | 用于光伏建筑一体化的发电玻璃及其制备方法 |
CN112165286A (zh) * | 2020-09-03 | 2021-01-01 | 成都中建材光电材料有限公司 | 防弹防辐射屏蔽电磁信号的发电玻璃及其制备方法 |
CN114173510A (zh) * | 2021-12-08 | 2022-03-11 | 上海交通大学 | 一种具有空气隔热层的微型多层隔热结构及其制备和应用 |
CN114173510B (zh) * | 2021-12-08 | 2022-12-13 | 上海交通大学 | 一种具有空气隔热层的微型多层隔热结构及其制备和应用 |
Also Published As
Publication number | Publication date |
---|---|
CN108943919B (zh) | 2023-10-10 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN108943919A (zh) | 一种防弹玻璃及其制备方法 | |
US20110048219A1 (en) | Blast-resistant barrier | |
CN108022989A (zh) | 一种晶硅太阳能电池柔性芯板、双面玻璃光伏建材构件及其制备方法 | |
US11268316B2 (en) | Asymmetrical safe vacuum-insulated glazing unit | |
CN209037125U (zh) | 一种防弹玻璃 | |
CN107473607A (zh) | 一种夹胶式电致变色玻璃、制备方法及其应用 | |
CN106143520A (zh) | 一种可用于高速列车侧窗的节能玻璃及其制备方法 | |
CN101798185A (zh) | 具有隔热、防辐射功能的防弹玻璃、防火玻璃及其复合玻璃 | |
CN109109408A (zh) | 特种玻璃及其制备工艺 | |
CN204687475U (zh) | 低辐射贴膜、低辐射镀膜玻璃及中空玻璃 | |
CN203499478U (zh) | 一种中空玻璃 | |
CN104890318A (zh) | 建筑用节能防爆贴膜 | |
CN103029379A (zh) | 双面镀膜低辐射玻璃及其制备方法 | |
CN110712406B (zh) | 一种可发电防弹防火玻璃及其制备工艺 | |
CN214821563U (zh) | 一种单向防弹玻璃 | |
CN110556441A (zh) | 一种光伏组件及其制备方法和应用 | |
Zang et al. | Laminated glass | |
CN110407486A (zh) | 夹层玻璃、夹层玻璃的生产设备及夹层玻璃的制备方法 | |
CN204923498U (zh) | 一种聚光集热镜 | |
CN216788180U (zh) | 一种具有隔热功能的夹胶玻璃 | |
CN210419768U (zh) | 夹层玻璃及夹层玻璃的生产设备 | |
CN220947030U (zh) | 一种智能调光防弹玻璃结构 | |
CN217415087U (zh) | 一种多层中空高强度阳光板 | |
CN102923972A (zh) | 一种防弹玻璃的制造方法 | |
CN213733851U (zh) | 一种轻量化多层复合超薄玻璃 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
TA01 | Transfer of patent application right |
Effective date of registration: 20210729 Address after: 518066 Room 201, building a, No. 1, Qianwan 1st Road, Qianhai Shenzhen Hong Kong cooperation zone, Shenzhen, Guangdong (check in with Shenzhen Qianhai business secretary Co., Ltd.) Applicant after: Hongyi Technology Co.,Ltd. Address before: Hanneng mobile Energy Holding Group Co., Ltd., room 107, building 2, Olympic Village street, Chaoyang District, Beijing Applicant before: HANERGY MOBILE ENERGY HOLDING GROUP Co.,Ltd. |
|
TA01 | Transfer of patent application right | ||
GR01 | Patent grant | ||
GR01 | Patent grant |