CN108935470A - A kind of propanil aqueous suspension agent and preparation method thereof - Google Patents
A kind of propanil aqueous suspension agent and preparation method thereof Download PDFInfo
- Publication number
- CN108935470A CN108935470A CN201810748068.6A CN201810748068A CN108935470A CN 108935470 A CN108935470 A CN 108935470A CN 201810748068 A CN201810748068 A CN 201810748068A CN 108935470 A CN108935470 A CN 108935470A
- Authority
- CN
- China
- Prior art keywords
- propanil
- preparation
- aqueous suspension
- suspension agent
- agent composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof
- A01N37/22—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof the nitrogen atom being directly attached to an aromatic ring system, e.g. anilides
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
- A01N25/04—Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/30—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests characterised by the surfactants
Landscapes
- Life Sciences & Earth Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- Agronomy & Crop Science (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Toxicology (AREA)
- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention provides a kind of propanil aqueous suspension agent compositions and preparation method thereof comprising the following component of percentage: surfactant 3.25~12.75%；First thickener: 0.125~0.25%；Second thickener 0.625~2.5%；Antifreeze: 3.75~6.25%；Surplus is water.Compared with prior art, the present invention is with following the utility model has the advantages that in the case where applying identical medicine content, and drug effect is more preferable, to more environment-friendly.
Description
Technical field
The present invention relates to a kind of propanil aqueous suspension agent compositions and preparation method thereof, belong to chemical insecticide technical field.
Background technique
Aqueous suspension agent refers to the preparation being dispersed in solid pesticide raw medicine with 5 μm of particles below in water, has grain
Diameter is small, active surface area is big, preparation penetration is strong, at low cost, drug effect is high and because of raw medicine sustained release, is not easy to send out
It is raw due to active compound content is excessively high in unit area and the phytotoxicity that generates.And due to there is no organic solvent in preparation, it is not easy to produce
The advantages that raw is inflammable, environmentally friendly.So aqueous suspension agent is for the modern higher and higher for environmental requirement
The product of trend of the times.
Propanil is the highly selective contact killing type herbicide of amides, is mainly used for rice seedling bed or live streaming field, prevents and kill off barnyard grass
Specific drug, it can also be used to prevent and kill off other a variety of grass family and broadleaf weed, such as Monochoria vaginalis, Chinese celery, herba digitariae, herba setariae viridis.Enemy
Barnyard grass hardly transporting in plant is only worked in medicament contact site.Its mechanism of action be it is various, not only break
The photosynthesis of bad plant, but also inhibit respiration and the phosphorylation of oxygen public affairs, interfering nucleic acid is synthesized with protein.From
And the physiological function of sensitive plant is made to be affected, and accelerate dehydration, blade gradually dried-up, it is last dead.Since propanil is in rice
Hydrolyzed enzyme resolves into rapidly innocuous substance in vivo, since degradation capability of the rice to propanil is 20 times bigger than barnyard grass, so to water
Rice safety.For propanil when illumination is strong, drug effect is obvious, but due to being all using propanil missible oil currently on the market, temperature is higher than 30
DEG C, when being also easy to produce phytotoxicity, but using propanil aqueous suspension agent, slowly due to the release of aqueous suspension agent raw medicine, so medicine will not be generated
Evil.
From the point of view of environmental protection, it is optimal mode that propanil, which is made into aqueous suspension agent,.The enemy of high-content is made simultaneously
Barnyard grass aqueous suspension agent can effectively save the costs such as packaging, transportation cost, and a kind of protection to environment.
Propanil aqueous suspension agent is easy to precipitate crystal during storage, so in the market without the commodity of propanil aqueous suspension agent.
Summary of the invention
For the defects in the prior art, the object of the present invention is to provide a kind of propanil aqueous suspension agent composition and its preparations
Method.
The present invention is achieved by the following technical solutions:
A kind of propanil aqueous suspension agent composition and preparation method thereof comprising the following component of percentage:
Preferably, first thickener is xanthan gum.
Preferably, second thickener is aluminium-magnesium silicate.
Preferably, the antifreeze is propylene glycol.
Preferably, the surfactant is that cyclohexanone and sulphite are copolymerized the high-molecular compound to be formed.
Preferably, the surfactant the preparation method comprises the following steps:
By cyclohexanone and sulphite according to 1:(0.5~2) molar ratio after mixing, in the pressure of 0.7~1.35MPa
Continuous polymerization reaction is carried out under conditions of power, 80~100 DEG C of temperature, until average molecular weight is 1000~2500, is obtained thick
Product；
By the crude product after being evaporated under conditions of the pressure of 0.07~0.35MPa, 100~110 DEG C of temperature
To the copolymer of cyclohexanone and sulphite.
Preferably, the cyclohexanone and sulphite mix by the following method before carrying out polymerization reaction:
Cyclohexanone is heated to 70~80 DEG C under the pressure of 0.7~1.35MPa, the aqueous solution for containing 20~40% sulphite is added dropwise, is protected
Two hours of reaction temperature are held, after being added dropwise, temperature are kept to heat two hours.
A kind of propanil aqueous suspension agent composition as the aforementioned and preparation method thereof comprising following steps:
After mixing by propanil, surfactant, xanthan gum, aluminium-magnesium silicate, propylene glycol and water, being ground to partial size is 1
Discharge packaging after~5 μm；
It is mixed with propanil, surfactant, aluminium-magnesium silicate, propylene glycol and water or after the xanthan gum is configured to aqueous solution
After closing uniformly, discharge packaging after being ground to 1~5 μm.
Compared with prior art, the present invention have it is following the utility model has the advantages that
Qualified 40% propanil aqueous suspension agent can be produced using surfactant provided by the invention, with following spy
Property:
With ideal wetting and dispersing effect and its possess special space steric effect, can effectively inhibit crystallization
Increase.
Specific embodiment
The present invention is described in detail combined with specific embodiments below.Following embodiment will be helpful to the technology of this field
Personnel further understand the present invention, but the invention is not limited in any way.It should be pointed out that the ordinary skill of this field
For personnel, without departing from the inventive concept of the premise, various modifications and improvements can be made.These belong to the present invention
Protection scope.
The surfactant selected in the present invention is that cyclohexanone and sulphite are copolymerized the high-molecular compound to be formed, and is made
Preparation Method are as follows:
Cyclohexanone is heated to 70~80 DEG C under the pressure of 0.7~1.35MPa, the aqueous solution containing sulphite is added dropwise,
It is kept for two hours of reaction temperature, after being added dropwise, temperature is kept to heat two hours；
It is anti-that mixture is carried out to continuous polymerization under conditions of pressure, 80~100 DEG C of the temperature in 0.7~1.35MPa
It answers, until molecular weight is 1000~2500, obtains crude product；
By the crude product after being evaporated under conditions of the pressure of 0.07~0.35MPa, 100~110 DEG C of temperature
To the copolymer of cyclohexanone and sulphite.
Embodiment 1
The present embodiment is related to a kind of propanil aqueous suspension agent composition and preparation method thereof comprising following steps:
By propanil, surfactant, xanthan gum, aluminium-magnesium silicate, propylene glycol and water respectively according to 40wt%, 5wt%,
The weight percent of 0.2wt%, 1wt%, 5wt% and 48.8wt% are matched, and are direct plungeed into reaction kettle and are stirred, and are stirred
After mixing uniformly, the packaging that discharges after being ground to qualified partial size is put into sand mill.
Embodiment 2
The present embodiment is related to a kind of propanil aqueous suspension agent composition and preparation method thereof comprising following steps:
1, the aqueous solution for xanthan gum being configured to 2% is spare.
2, by propanil, SCMSFC 2200, aluminium-magnesium silicate, propylene glycol and water respectively according to 44.444wt%, 5.555wt%,
The weight percent of 1.111wt%, 5.555wt%, 43.335wt% are matched, and are put into reaction kettle and are stirred, and are stirred
After uniformly, puts into sand mill and be ground to qualified partial size
3, slurry in aqueous solution in step 1 and step 2 is discharged packaging after mixing according to the ratio of 1:9.
Embodiment 3
The present embodiment is related to a kind of preparation method of propanil aqueous suspension agent comprising following steps:
1, the aqueous solution for xanthan gum being configured to 2% is spare.
2, by propanil, SCMSFC 2200, aluminium-magnesium silicate, propylene glycol and water respectively according to 44.444wt%, 5.555wt%,
The weight percent of 1.111wt%, 5.555wt%, 43.335wt% are matched, and are put into reaction kettle and are stirred, and are stirred
After uniformly, puts into sand mill and be ground to qualified partial size.
3, slurry in aqueous solution in step 1 and step 2 is put into cutter after mixing according to the ratio of 1:9 and is cut
It cuts.
The material sheared is put into sand mill to the packaging that discharges after being ground to qualified partial size again.
When prepared by the method surface activator composition prepares 40wt% propanil aqueous suspension agent, obtained propanil water
The performance detection structure of suspending agent is as shown in table 1.
Table 1
Table 1
Specific embodiments of the present invention are described above.It is to be appreciated that the invention is not limited to above-mentioned
Particular implementation, those skilled in the art can make various deformations or amendments within the scope of the claims, this not shadow
Ring substantive content of the invention.
Claims (8)
1. a kind of propanil aqueous suspension agent composition and preparation method thereof, which is characterized in that including the as follows of percentage
Component:
2. a kind of propanil aqueous suspension agent composition as described in claim 1 and preparation method thereof, which is characterized in that described first
Thickener is xanthan gum.
3. a kind of propanil aqueous suspension agent composition as described in claim 1 and preparation method thereof, which is characterized in that described second
Thickener is aluminium-magnesium silicate.
4. a kind of propanil aqueous suspension agent composition as described in claim 1 and preparation method thereof, which is characterized in that described freeze proof
Agent is propylene glycol.
5. a kind of propanil aqueous suspension agent composition as described in claim 1 and preparation method thereof, which is characterized in that the surface
Activating agent is that cyclohexanone and sulphite are copolymerized the high-molecular compound to be formed.
6. a kind of propanil aqueous suspension agent composition as claimed in claim 5 and preparation method thereof, which is characterized in that the surface
Activating agent the preparation method comprises the following steps:
By cyclohexanone and sulphite according to 1:(0.5~2) molar ratio after mixing, 0.7~1.35MPa pressure, 80
Continuous polymerization reaction is carried out under conditions of~100 DEG C of temperature, until average molecular weight is 1000~2500, obtains crude product；
The crude product is obtained into ring after evaporating under conditions of the pressure of 0.07~0.35MPa, 100~110 DEG C of temperature
The copolymer of hexanone and sulphite.
7. a kind of propanil aqueous suspension agent composition as claimed in claim 6 and preparation method thereof, which is characterized in that the hexamethylene
Ketone and sulphite mix: before carrying out polymerization reaction by cyclohexanone under the pressure of 0.7~1.35MPa by the following method
70~80 DEG C are heated to, the aqueous solution for containing 20~40% sulphite is added dropwise, is kept for two hours of reaction temperature, is added dropwise
Afterwards, temperature is kept to heat two hours.
8. a kind of propanil aqueous suspension agent composition a kind of as described in claim 1 and preparation method thereof, which is characterized in that including
Following steps:
After mixing by propanil, surfactant, xanthan gum, aluminium-magnesium silicate, propylene glycol and water, being ground to partial size is 1~5 μm
Discharging packaging afterwards；
Or it after the xanthan gum is configured to aqueous solution, is mixed with propanil, surfactant, aluminium-magnesium silicate, propylene glycol and water
After even, discharge packaging after being ground to 1~5 μm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810748068.6A CN108935470A (en) | 2018-07-10 | 2018-07-10 | A kind of propanil aqueous suspension agent and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810748068.6A CN108935470A (en) | 2018-07-10 | 2018-07-10 | A kind of propanil aqueous suspension agent and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108935470A true CN108935470A (en) | 2018-12-07 |
Family
ID=64483525
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810748068.6A Pending CN108935470A (en) | 2018-07-10 | 2018-07-10 | A kind of propanil aqueous suspension agent and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108935470A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112753704A (en) * | 2020-12-31 | 2021-05-07 | 河北威远生物化工有限公司 | Novel suspending agent containing benthia grass and propanil |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1277801A (en) * | 1999-06-18 | 2000-12-27 | 罗姆和哈斯公司 | Method for preparing suspended pesticides concentrates |
| US20150099637A1 (en) * | 2013-10-06 | 2015-04-09 | Bomi Framroze | New method to improve the performance of herbicide formulations |
| CN106719621A (en) * | 2017-03-15 | 2017-05-31 | 上海汇平化工有限公司 | Surface activator composition for Acetamiprid aqueous suspension agent and preparation method thereof |
| CN107207415A (en) * | 2015-01-19 | 2017-09-26 | Upl 有限公司 | The crystalline modification of propanil |
-
2018
- 2018-07-10 CN CN201810748068.6A patent/CN108935470A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1277801A (en) * | 1999-06-18 | 2000-12-27 | 罗姆和哈斯公司 | Method for preparing suspended pesticides concentrates |
| US20150099637A1 (en) * | 2013-10-06 | 2015-04-09 | Bomi Framroze | New method to improve the performance of herbicide formulations |
| CN107207415A (en) * | 2015-01-19 | 2017-09-26 | Upl 有限公司 | The crystalline modification of propanil |
| CN106719621A (en) * | 2017-03-15 | 2017-05-31 | 上海汇平化工有限公司 | Surface activator composition for Acetamiprid aqueous suspension agent and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112753704A (en) * | 2020-12-31 | 2021-05-07 | 河北威远生物化工有限公司 | Novel suspending agent containing benthia grass and propanil |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102283196B (en) | Controlled release preparation for removing mikania micrantha and preparation method thereof | |
| CN103598192B (en) | A kind of bactericidal composition containing tetramycin and Zhongshengmycin | |
| CN106719621A (en) | Surface activator composition for Acetamiprid aqueous suspension agent and preparation method thereof | |
| CN101642124A (en) | Tribenuron-methyl oil flowable concentrale and preparation method thereof | |
| CN101112195A (en) | Avermectin micro-emulsion and method for preparing the same | |
| CN105230640A (en) | Bactericidal composition containing tetramycin and benziothiazolinone | |
| CN108935470A (en) | A kind of propanil aqueous suspension agent and preparation method thereof | |
| CN101647458A (en) | Acaricidal composition containing spirodiclofen | |
| CN105340913A (en) | Sterilization composition containing benziothiazolinone and kasugamycin | |
| CN109221140A (en) | A kind of Pesticidal combination containing (R)-4-isopropenyl-1-methyl-1-cyclohexene and pyridine quinazoline | |
| CN101715765A (en) | Fomesafen soluble solid medicament form | |
| CN111436450A (en) | Compound preparation of post-emergence herbicide for corn field and preparation method | |
| CN101595867A (en) | A kind of first dimension salt indoxacarb suspending agent and preparation method thereof | |
| CN103636624A (en) | Sterilizing composition containing tetramycin and symplectic bacteria amine acetate | |
| CN101659576A (en) | Medicinal synergist for flower plants | |
| CN101554158B (en) | Emamectin-benzoate and methomyl microemulsion and preparation method thereof | |
| CN105494407A (en) | Herbicide composition containing metamifop and cafenstrole | |
| CN105340927A (en) | Sterilization composition containing benziothiazolinone and Zhongshengmycin | |
| CN103518755B (en) | Herbicide for paddy field isoproturon and manufacture method | |
| CN102187868B (en) | Flubendiamide and emamectin benzoate blended emulsion and preparation method thereof | |
| CN101595869B (en) | Abamectin indoxacarb suspending agent and preparation method thereof | |
| CN103651363A (en) | Pesticidal composition containing spiromesifen and nereistoxin | |
| CN105394039A (en) | Bactericidal composition containing oxine-copper and ethylicin | |
| CN102550588A (en) | Method for preparing acetamiprid-containing water-soluble granules | |
| CN103300011B (en) | A kind of Pesticidal combination containing fluorine mite piperazine |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20181207 |